Effect of Fly Ash and Carbon Reinforcement on Dry Sliding Wear Behaviour of Red Mud

This paper explains the sliding wear performance of red mud, fly ash, and carbon composite coating on mild steel. The complex mixture of red mud, fly ash, and carbon is plasma sprayed at 9 kW operating power level. The coatings are examined to study the coating morphology, XRD phase transformation, wear rate, and wear morphology. Wear rate (in terms of cumulative mass loss) with sliding time has been demonstrated in the study. At first pure red mud is plasma coated to observe the coating characteristics and then compounded with 20% carbon, 30% carbon, and 20% carbon + 30% fly ash, separately by weight and sliding wear test conducted using pin on disc wear tester. The trial was performed at fixed track diameter of 100mm and at sliding speed of 100 rpm (0.523m/s) at a load of 30N. The results are compared. Declined cumulative mass loss by inclusion of fly ash and carbon is seen. This might be due to augmented interfacial tension and dense film build-up at boundary layer.


Introduction
In the present scenario coating technologies manifest a promising momentum for emerging materials. Wear resistive coatings are claimed to be better tribological applications. Surface modification by improving wear resistance is most widely adopted by plasma spraying technique, which could affirm a great versatility and its application to a wide spectrum of materials. Wear resistive coatings can protect against different wear mediums like abrasive, adhesive, and corrosive. Some common wear resistive coating materials are nickel, iron, cobalt and molybdenum based alloys, carbides of ceramic, and tungsten [1,2]. Friction and dry sliding wear behavior of red mud filled banana fibre reinforced unsaturated polyester composites using Taguchi approach reported in [3]. Evaluation and characterization of plasma sprayed Cu slag-Al composite coatings on metal substrates have been outlined [4]. In retrospection, literatures were made available regarding the wear behaviour of WC with 12% Co coatings produced by Air Plasma Spraying method at different standoff distances [5].
Examinations on the basis of the wear behaviour of Mo and Mo + NiCrBSi thermally sprayed coatings being performed for the application as next generation ring face coatings [6]. Plasma sprayed ceramic coatings portrayed favorable tribological performance at high temperatures [7], showed high wear resistance [8], and were easy to be lubricated owing to the oil storage in pores of coatings [9]. But it is needful to say that plasma sprayed ceramic coatings exhibit some failure mechanisms during sliding such as plastic deformation, brittle fracture, and polish effects [10], which in turn demands a few additives, which could reduce the friction and wear of plasma sprayed ceramic coatings [11]. Several factors may influence the tribological behaviour of a coated surface ramified such as the geometry of the contact including macrogeometry and macrotopography of the surfaces; the material characteristics; basic mechanical properties and the microstructure; and finally the operating parameters controlling the coating deposition [12].
Red mud as an industrial waste material is considered to be the material of choice for coating applications. It is necessary to mention here that red mud in present decade  should be considered as alternative wealth for replacing some conventional expensive coating materials. Utilization of red mud and its implications are made available in the literature [13] in great detail. Few results on the basis of wear behaviour of red mud were being reported by some researchers. In addition to the above, morphology and solid particle erosion wear behaviour of red mud and fly ash composite were being available in the literature [14]. Dry sliding wear behaviour of rice husk and red mud filled epoxy composites using ANN is described [15]. An outline for resources, utilization, and processes of red mud in India is reviewed [16]. Data pertaining to dry sliding wear behaviour of fly ash and carbon added red mud composite coatings are not available in the literature and need to be addressed. Tribological studies on red mud reinforced aluminium metal matrix composites are disclosed [17]. Friction and wear behaviour of plasma sprayed fly ash added red mud coatings have been analysed [18].

Raw Materials for
Coating. The coating powder was formulated considering the raw materials as red mud, fly ash, and carbon. At incipient pure red mud is plasma coated. Then a powder mixture made up of red mud and different percentage of fly ash and carbon was being prepared separately. Table 1 shows the detailed composition of the powder composite.
To perceive the significance of activated carbon SEM and EDS analysis images have been reported in Figure 1. To recognize the elements in the composite powder of RM + 20% C and RM + 20% C + 30% FA an EDS analysis report has been divulged in Figure 2. A SEM (JEOL; JSM 6480 LV) has been implemented to survey the report.
The primary raw material as red mud was collected in powder form from National Aluminium Company, located at Damanjodi in the state of Odisha, India. The as-received powder was sieved to obtain particles in the required size range of 80-100 m. Raw fly ash was collected from the captive power plant of Rourkela steel plant, India, and sieved to maintain the same size range as that of red mud powder. The charcoal is used for the source of carbon. The specific size ranges of powder are mixed in a V-shaped blender for uniformity of composite.

Build-up of Substrate.
The mild steel rod is chopped to = 42 mm and Ø = 15 mm each. Grit blasting of the specimens was conducted from one side cross section at a pressure of 4 kg/cm 2 using alumina grits of grit size 80. The dead lock distance in the shot blasting was in between 120-150 mm. The mean roughness of the cross sections was found to be 5.8 m.
Hereafter the sample pieces are scrubbed in an ultrasonic cleaning unit followed by immediate plasma spraying.

Substrate Coating.
Coating of the substrate was done using conventional atmospheric plasma spraying (APS) unit available at surface engineering department of IMMT, Bhubaneswar, Odisha, India. All the mild steel specimens were coated from one cross section at 9 kW operating power level by controlling the voltage and current input to the arc. The powder feed rate was maintained to be constant at 15 gm/min by using a turntable type volumetric powder feeder. Plasma generation implemented by purging argon as primary and nitrogen as secondary gas agent. Spraying was done at an angle of 90 ∘ by maintaining the powder feeding as external to the gun. A compact outline of APS is reflected in Figure 3.

Wear Test Setup.
The wear test was conducted using a pin on disc appliance allotted by MAGNUM Engineers, Bangalore, India. A comprehensive outline of the setup is materialized in Figure 4. The concerned machine was used to evaluate the wear behaviour of the coatings against hardened ground steel disc (En-32) having hardness of 65 HRC and surface roughness of 0.5 m. The machine is so fabricated that it can examine wear rate both at lubricated and unlubricated conditions. A DC motor is implicated for rotating the disc with range of speed from 0 to 250 rpm with wear track

Coating Morphology Survey.
Interparticle bonding of the sprayed powders and coating surface adherence plays an important role to characterize the coating morphology [19]. Even though all the coating is performed at 9 kW operating power level, it is noteworthy to analyse the coating morphology for all coating types used in the present study and reported in Figure 5. In case of pure red mud coating, the snapshot signifies ( Figure 5(a)) nonuniform distribution of bigger globular particles. Improper melting and cavitations are visible. For RM + 20% C the coating morphology reveals more spotted cavitations which may be originated at the time of solidification and nonuniformity of surface. As the carbon content increased (RM + 30% C) the uniformity of the surface has been improved but still large-size cavitations are spotted with few semimolten particles. It is compelling to discuss the results for RM + 20% C + 30% FA coating; which is contrary to the past. Figure 5(d) reveals the outcome. Very small scale cavitations are marked with most of the regions' uniform and splat. This might be resulting from additional amount of Si, Al, and Fe content coming from fly ash.

XRD Phase Analysis of Raw Material and Coatings.
To discover the different phases occurring in the precursor powder and its coating; a Philips X-Ray Diffractometer is incorporated. Figure 6 shows the XRD of activated carbon powder. The XRD result for red mud powder is shown in Figure 7. aluminium iron oxide (AlFeO 3 ). After plasma coating there is a major phase change to fayalite (Fe 2 SiO 4 ) and dolomite as visible in Figure 8. Figure 9 shows the XRD diffractogram of (a) RM + 20% C + 30% FA powder and (b) RM + 20% C + 30% FA coating. The chief XRD peaks for the powder are silicon dioxide (SiO 2 ), hematite (Fe 2 O 3 ), limestone (CaCO 3 ), and titanium dioxide (TiO 2 ). After successful plasma coating the major phases reconstructed to manganese aluminate (MnAl 2 O 4 ).

Design of Wear
RM + 20% C + 30% FA powder  Figure 9: XRD of (a) RM + 20% C + 30% FA powder and (b) RM + 20% C + 30% FA coating. into 18 intervals with 3-minute time gap each. Mass loss in each intervening time was added and expressed as cumulative mass loss. The behaviour of cumulative mass loss with sliding time is expressed in Figure 10 for all coating types. It is observed that the cumulative mass loss is always more for pure red mud coating for all time intervals. As the carbon content in the red mud increases (addition of carbon by 20% and 30% by weight), the cumulative mass loss declines. Figure 10 signifies a minimum value of cumulative mass loss for RM + 20% C + 30% FA coating. This might be due to addition of carbon and fly ash to red mud resulting in improved bond strength and interfacial tension of the coating layer to the substrate border line by forming a denser film. This reveals the potential reuse of fly ash as reinforcing agent for coating material. Wear morphology for all coatings are exposed in Figure 11 aided by SEM after 30-minute sliding. The wear mechanism changes with time due to continuous sliding and rubbing action in the interlayer, impacting the surface roughness of coatings. It is believed that wear takes place only by abrasion and adhesion mechanism due to existence of continuous shear stress in between hard particles of the two surfaces in contact.

Conclusion
The above work attempted to study the dry sliding wear behaviour of red mud compounded with a limited extent of reinforcement of carbon and fly ash. A further study can be conducted to expand the limitations. It is obvious from this research that carbon and fly ash enhances the coating property of red mud by amending the surface physical properties. The work strongly attracts tribologists to investigate the response towards corrosion wear of prevailing coatings.
An optimization technique may be implemented to find the optimum percentage of carbon and fly ash. High temperature application for thermal security may be evaluated at suitable operating conditions. Further heat treatment of the coatings may be employed to disclose the acceptable demands.