Effect of MgFeSi Inoculant on Properties of Cast 6061 Al Alloy for Brake Master Piston Application

TheinfluenceofvaryingamountofMgFeSiinoculantonpropertiesofcast6061Alalloyforbrakemasterpistonapplicationhasbeenstudiedandreportedinthispaper.Castsampleswereproducedatthreepouringtemperatures(700,750,and800 ∘ C) with MgFeSi varied from 1 to 3%. Wear resistance tests were performed on cast alloy in brake oil. Wear resistance tests results were validated by nondestructive examinations using photomicroscopy, SEM, EDX, and XRD data. The addition of MgFeSi influenced both the mechanical (hardness, strength, and wear resistance) and metallurgical properties (microstructures) of the cast alloy. Al grains were more refined and yielded good strength properties. Inoculating the melt with MgFeSi forms insoluble compound particles and is responsible for grain refinement. The increased amount of MgFeSi from 1 to 3% improved the wear resistance of the cast piston under lubricating condition using brake oil.


Introduction
The application and acceptability of sand casting are an important aspect of foundry/casting practices ranging from the numerous cottage and large-scale manufacturing industries [1]. Small and large engineering components (machine parts) are made from different metals and alloys such as steel, cast iron, copper, bronze, brass, and many other known aluminium alloys. The right practice of casting starts with the understanding the control and chemistry of the melt. Casting aluminium alloy entails proper handling of materials: type of furnace, fuel, the melting pot, the selection of fluxing additives, alloying elements, and the moulding sand composition. Superior properties can be achieved in aluminium alloys through systematic control of casting processes.
Literature is scarcely available on the MgFeSi inoculation of Al alloys, but some latest progress on reports of inoculants in alloy and casting similar to MgFeSi in Al alloys. These include inoculation treatment of ductile iron [2], cast iron [3], oxide particles inoculant in Al alloys [4], and pure aluminium inoculation treatment with titanium and boron [5][6][7][8]. The current study reports the effect of MgFeSi inoculation as a means of grain refinement and enhancing the mechanical properties (strength, hardness, etc.) of Al alloys.
The mechanical strength, hardness, and the microstructure of the aluminium cast could be improved by controlled melting, pouring temperature, and the solidification processes and proper management of other different controlling factors [9][10][11][12]. The pouring temperature for aluminium alloys usually ranges from 720 to 790 ∘ C, even though thin-section cast products can be poured at temperatures as high as 845 ∘ C as found in the literature [8].
The moulding sand permeability influences the cast product quality. The pouring temperature, solidification, and cooling rate are tailored to control the microstructure of the cast aluminium alloy. This influences the piston making [13,14] and it also affects the hardness of the cast alloy. This is in agreement with other researchers [10,15]. The hypereutectic aluminium alloys (390, B390, and 393) are used primarily for wear applications (engine blocks, compressors, pistons, pumps, pulleys, brake systems, etc.). They are also used for thin parts since they have exceptional fluidity [9,16].

Indian Journal of Materials Science
In this work, the Al-Si alloys are produced by sand casting. This technique is identified as a relevant method for the production of many aluminium alloy parts with outstanding metallurgical properties suitable for the desired level of application. In designing a right alloy for the production of cast piston, each of the alloying elements plays a significant role. It has considerable influence on the properties of the cast piston. For purposes of understanding the effects and importance of alloying elements, the alloying elements contained in the as-received piston are classified into three as major, minor, microstructure modifiers or impurities. Conversely, the impurity elements in some alloys might be major elements in others. The major alloying elements typically identified in scrap aluminium alloys are silicon (Si), magnesium (Mg), and copper (Cu). In general, the microstructure modifying elements are titanium (Ti), manganese (Mn), and chromium (Cr). The impurity elements are iron (Fe), chromium (Cr), and zinc (Zn) [9]. The copper in alloy imparts good strength and hardness, making it heat treatable, and possesses enhanced machinability.
The only deliberate and guarded additions of zinc (Zn) to aluminium casting alloys are in the 7XXX series. It happened just as an acceptable impurity element in many secondary (scrap-based) casting alloys. It is quite neutral; it neither adds nor subtracts alloys properties. Zinc is a dense (heavy) element, and it increases the alloys mass density [9]. The behaviour of Al-Si alloy can be explained using Al-Si phase diagram. In the present study, the amount of Si ranged from 0.7 to 1.3 approximate values from the as-received scrap to the cast Al with inoculant as in Figure 1.
The equilibrium phases diagram for the binary Al-Si system is shown in Figure 1. Hypoeutectic alloys are alloys having silicon content less than the eutectic composition. Many common hypoeutectic alloys fall between 5% and 10% silicon. It is conventional that the eutectic reaction occurs with 12.6% silicon at 577 ∘ C temperature [17]. A substantial quantity of Si dissolves in solid Al at higher temperatures. The maximum solubility is seen to be 1.6% at the eutectic temperature whereas only an insignificant quantity of Al dissolves in Si. Considering different phase diagrams for the Al-Si system in various literature, there are discrepancies as to the exactness of the eutectic composition and, to a less significant extent, the eutectic temperature. This is because the Al-Si eutectic formation is very responsive to a small change in quantity of impurities, particularly P, Na and other alkaline earth elements.
Eutectic alloys are formed between 10 and 13% Si and consist principally of Al-Si eutectic in the cast structure characterized by the following: a narrow range of freezing points, exceptional fluidity, high castability, and good wear resistance [13]. It is moderately ductile when being not alloyed and heat treatable to high strength property. When containing Cu, Mg, and occasionally Ni, eutectic Al alloys are used extensively for pistons. Cast hypereutectic alloys are obtained between 15 and 20% Si. The cast structure is made of primary Si particles entrapped in Al-Si eutectic matrix. They have good high-temperature strength with remarkable wear resistance but low machinability. They are good for pistons, engine blocks, and compressor components [13,14]. FeSiMg is widely used in the steelmaking and cast iron production and casting but literature is scarcely available (if any) on the use of FeSiMg in Al alloy casting. Thus, this is newly and briefly examined in the study. The hardness values and the mechanical strength are the only properties that are quantified in the study. Focus is given to the effect of the inoculant variation on the microstructure. Nevertheless, brief explanations were mentioned within the text. The authors had reported the mechanical properties of cast Al alloy in the previous study [13,14].

Materials and Method
2.1. Production of Cast Aluminium Alloy Samples. Aluminium alloy scrap was obtained from the brake master piston. A branded FeSiMg7Re1 with code name 7-1 was obtained from the chemical store. About 2 kg of the scrap was charged into the melting pot, fired, and melted using Taifa model electric furnace. The molten alloy was held for 10 minutes at three pouring temperature ranges between 750 and 800 ∘ C under a controlled atmosphere before pouring. Various quantities (1-3%) of MgFeSi inoculant were used to treat molten Al metal. The procedure followed is similar to cast iron [3]. The moulding flasks were preheated before the casting process. The cast-aluminium-alloy samples were obtained at pouring temperatures of 750 ± 10 ∘ C. The molten metal was allowed to solidify and cool to obtain eutectic Al-Si structured phase. The cast samples were removed from the sand mould, fettled, brush cleaned, and lightly machined on the lathe to get a rod of 300 mm length and 25 mm diameter. The cast (rod) was later cut to 2 mm thickness by 25 mm diameter for further processing.

Experimental Details
The hardness tests of Al alloy samples were determined using Brinell Hardness Tester. The microstructures of samples were Indian Journal of Materials Science 3 examined by using a High-Resolution Metallurgical Microscope with the digital camera (Nikon-Eclipse M600 model). The sections were examined under different magnifications (×10, ×100, ×200, ×400, and ×800).
The chemical composition of the cast samples was characterized by Atomic Absorption Spectroscopy (AAS-Thermo series 2000 model). The X-ray diffraction XRD (Mini-Diffractometer MD-10 model with digital facilities) was used to determine grain sizes and possible phases. In addition, Scanning Electron Microscope with Energy Dispersive Xray facilities (Jeol JSM-7600F Field Emission SEM/EDX) was used to examine the microstructures at high magnifications.
The study evaluates the surface integrity of cast samples by wear tests with the view to assessing the performance of the cast piston specimens in brake fluid. The wear tests were performed on the as-received (AR) scrap pistons and cast piston samples (with and without varying amount of MgFeSi) using a Wear Jig [13,18,19]. The samples are inserted into the Wear Jig and run for wear cycles range of 1225 to 122500 cycles varied at 1225 interval. The wear resistance is determined from wear volume (loss). The maximum volume loss of wear that can occur is described by [20] in Archard's equation: where is the volume of substance removed, is the distance slid, and is the cross-sectional area of the groove. Wear resistance is defined as the reciprocal of wear volume (in cm −3 or mm −3 ) as in The results of wear tests were used to interpret microstructural details, XRD, SEM/EDX, and AAS data generated from the research.

Results and Discussion
The chemical compositions of the as-received scrap alloy and the cast aluminium alloy samples used in this experiment are presented in Table 1(a).
Meanwhile the chemical composition of the branded FeSiMg7Re1 powder used for the present work as given by the manufacturer is presented in  Figure 2. It is obvious that the addition of MgFeSi has a positive influence on all the alloys tested. Higher wear resistance performance was obtained from the present work using 3% MgFeSi as compared with the results reported previously by Ajibola et al. [13,14].
The wear resistance of all the Al alloy materials reduces with the increasing number of the wear cycles. The asreceived Al alloy wears at a very close trend of wear rate as the 1% MgFeSi inoculated Al alloy. It is evident from the result (Figure 2) that there is increased wear resistance that results from the increased content of MgFeSi from 1% to 3%.

Microstructural Examination Scrap Sample and Cast Samples
The surfaces and microstructures of scrap samples and cast samples studied using higher resolution metallurgical microscope with digital camera and SEM under different magnifications are shown in Figures 3-10(b). The EDX data are integrated into Table 2    found downstream in wrought and foundry alloy products. The reduction in grain size is obtained by the nucleation of the aluminium phase that was achieved through MgFeSi inoculants used to provide the necessary nuclei. In the present study, the addition of MgFeSi initiated nucleation in collaboration with other factors like alloy composition, cooling rate, and the temperature gradient in the melt. With the addition of MgFeSi powder, 97.432% Al, 1.293% Si, 0.598% Mg, 0.202% Cu, 0.001% Zn, 0.051% Ti, 0.051% Mn, 0.041% Cr, and 0.331% Fe were obtained in the cast piston. It is explained that there is increase in the % Fe composition in the cast piston. This may be from both MgFeSi inoculation and/or the Fe pickup from the steel container (melting pot) due to higher solubility of Fe in molten Al [21]. The formation of MgAl 2 O 4 and the MgAl 2 O 4 particles is got from the addition of 0.49∼0.70 wt% Mg to pure Al [4]. But with the addition of 1-3% MgFeSi to the melt, large amount of Mg is dissolved and forms compounds such as MgO⋅Al 2 O 3 and Al 2 CuMg ( Table 4). The MgFeSi supplies more Mg, Fe, and Si into the Al melt. Among all, silicon (Si) is the most noteworthy single alloying constituent in many of aluminium casting alloys. Silicon is primarily accountable for good castability, with no hot tearing or hot cracking defects as depicted in Figure 5(a).
Silicon plays a vital role as an alloying element manyfold. Figure 5 shows the influence of increasing MgFeSi content on the cast alloy property. In Figure 5 (Table 2). Silicon is a very hard phase that contributes significantly to aluminium alloy wear resistance [13,14,22]. It joins other elements to enhance the alloy mechanical strength (Table 3) and to make alloys heat treatable [23]. The presence of magnesium (Mg) as alloying element strengthens and hardens aluminium castings ( Table 3). The presence of Mg phase contained in the alloy was identified and diffracted as Al 2 CuMg and MgO⋅Al 2 O 3 in the XRD analysis of the cast sample ( Table 4). The combination of Tables 3 and 4 may explain why the cast piston has high wear resistance compared to the as-received scrap piston sample (Figure 2).
In Figure 8(g), for casting at 700 ∘ C with 3% MgFeSi, the microstructure revealed the presence of undissolved MgFeSi (black portions) locked up in the matrices of the cast Al alloy (white segments). That was not observed at 750 and 800 ∘ C in Figures 8(h) and 8(i). This structure looks similar to a "bull eye" structure obtained previously from the addition of MgFeSi to cast iron by Alasoluyi et al. [3]. examination of the EDX data (Table 2) revealed the effect of the MgFeSi on the microstructure (the grains).
By combining the EDX data (Table 2) and XRD results (Table 3), it can be inferred that copper (Cu) among the alloying elements singularly has the greatest impact on the strength and hardness of cast aluminium alloys. In the present work, Al 2 CuMg, AlCu, and CuAl 2 structures are identified and diffracted in the cast sample by XRD analysis. A substantial amount of Cu (1.21∼2.86% wt) was revealed in the EDX data for all samples (Table 2). It is known that copper improves the machinability of the alloys by increasing matrix hardness, making it easier to generate small chips of cuttings and smooth machine finishes on the lathe and mill.
Trace quantities of three major microstructure modifying alloying elements (Ti, Mn, and Cr) are detected as inherited from the as-received scrap sample in the AAS data (Table 1). With titanium (Ti) present in the alloy, it forms TiAl 3 and refines primary aluminium grains or nucleates primary aluminium dendrites [24]. Szajnar and Wróbel [8] had established that the rise in size decrease of Al after inoculation with (Ti+B) results from the Ti 3 Al and CuTi 2 to heterogeneous nucleation formation. This is because Ti 3 Al and CuTi 2 compounds are the foundation for heterogeneous nucleation and powerfully affect size reduction enhancement in aluminium structure. When nucleation is more frequent, a large number of smaller grains (refined grains) is often obtained as seen in Figures 8(a)-8(h).
At temperature as high as 750 ∘ C, there are subsequent structural changes occurring when aluminium alloy forms an amalgam with Mn and/or Cr (Table 1). Report shows that Al alloy combined with Mn and/or Cr. That changes the customary platelet structured morphology to the Al 15 (MnFe) 3 Si 2 cubic phase ( Figure 6(e)) from the iron-rich Al 5 FeSi phase (Figure 6(f)). The obtainable size and amount of the Al 15 (MnFe) 3 Si 2 cubic phase have been reported to be a function of the concentration levels and solidification rate [9,14].
Iron (Fe) is present in most traditional casting alloys as a very useful impurity. The supersaturated molten alloy can dissolve the relatively unprotected and exposed tool steel while the molten alloy is in close contact. MgFeSi inoculation supplies Fe and Si, which combines with aluminium and other elements to form a mixture of hard, insoluble complex phases and is shown in Figures 6(b)-6(f). The Al 5 FeSi phase forms very thin platelets in the form of broom-like structures (Figures 7-10(b)).
In the present study, some of the specimens are cast at varying temperature 750 ± 50 ∘ C using moderately high moulding sand permeability [25]. Pouring an aluminium alloy at a temperature above 700 ∘ C often gives improved metallurgical properties such as strength, hardness, porosity, and microstructure [9][10][11]13]. The option of a pouring temperature at 750 ± 10 ∘ C is to moderate the gas content in the molten aluminium alloy and to obtain eutectic structure of cast alloy [25]. If the temperature of molten metal (especially for molten aluminium) is higher, the gas content increases, thus increasing the cast porosity if not properly managed by degassing methods.
The micrographs of the scrap alloy and cast aluminium alloy poured at 750 ∘ C are presented in Figures 6(a)-6(f) and 7(a)-7(c). The images in Figures 7(a), 7(b), and 7(c) were observed at ×800, ×400, and ×200 magnifications. The microstructures of the cast Al alloy with 3% MgFeSi appear with nucleation of larger number of small grains. The differences and similarities between the structures and grain sizes of scrap alloy and cast samples are compared in the study. This is with respect to the pouring temperature and MgFeSi inoculation. The as-received scrap alloy has more coarse grains (Figure 6(a)) than the cast samples (Figure 7(c)). Microstructures of as-received scrap alloy and cast samples are examined under higher resolution metallurgical microscope with a digital camera. An optical micrograph of the binary Al-Si alloy is shown in Figures 6(b)-6(d). The dark areas of the Al-Si eutectic and brighter areas of Al are observed with the eutectic Si. This possesses very fine transitional Al-Si eutectic according to the American Foundry Society (AFS) modification rating system [11,26].
The microstructural details show different phases resulting from the increase in content of Si, Mg, and Cu. Aluminium is lost to dross at high temperatures above 670 ∘ C (being understood from the dross theory), with consequent Fe pickup from the melting pot and cleaning tools, thus adding more to Fe content already present in the commercial alloy sourced from the as-received piston.
In the present work, adding MgFeSi inoculant to the molten Al forms different phases with enhanced properties. The aluminium alloy consists of Al 2 Si 4 O 10 , Al 15 (MnFe) 3 Si 2 , Al 2 CuMg, and Al 5 FeSi phases in eutectic Al-Si structures. Si combines with Mg to form Mg 2 Si, which is soluble in the solid alloy. When combined with copper, it forms the precipitationhardening phase, Al 2 CuMg [21], and some other compounds like AlCu and CuAl 2 . Subsequently, giving the cast alloy higher hardness and strength, thus these influenced the higher wear resistance value than the as-received scrap alloy.
Furthermore, the removal of oxide inclusions is one of the main challenges of recycling aluminium alloy scrap. At high temperatures 750 and 920 ∘ C, -Al 2 O 3 platelets and -Al 2 O 3 particles are, respectively, formed in molten commercially pure Al [4]. In the present instance, the oxidation on the surface of Al alloy melts is inevitable at high temperature due to the high affinity between the oxygen and Al when exposed where is the intergranular spacing, is the wavelength, and is the order of reflection of the X-ray. Additionally, the estimated average grain sizes of the Al alloy are presented as the approximate values (Table 4), determined from Scherrer's equation in (4).
Whereas 0.9 is the constant shape factor, relates to line amplification at half of the maximum intensity (in radians), and is the Bragg's angle and is the mean (average) size of the ordered crystals.
The diffraction angle (2 ) is related to the grain size by = 0.9 Δ (2 ) cos .
The SEM electron and EDX of the Al grains and grain boundaries of the cast Al alloy with and without MgFeSi inoculant are illustrated in Figures 9-10(b) and Table 2. Figure 9 presents electron image of the cast Al alloy (without inoculant). The targeted area contains 1.65% Mg,   Figure 11: The XRD diffractograms of cast aluminium alloy sample with 3% MgFeSi. 1.43% Fe, 1.31% Si, 1.04% Zn, 1.21% Cu, and 78.27% Al as revealed in the EDX spectra data (Table 2). In Figure 10, the SEM image of the cast Al alloy (with inoculant) is illustrated. The 600 m size area contains by weight 2.36% Mg, 3.51% Fe, 2.25% Si, 78.11% Al, 1.85% Zn, 2.86% Cu, and 1.16% Mn as obtained in EDX characterization data (Table 2). Figure 10(b) shows the SEM image of grain boundaries of cast Al alloy (with inoculant). The 600 m size area contains 72.23% Al, 3.39% Si, 2.43% Mg, 1.34% Cu, 4.27% Fe, and 1.71% Zn as revealed in EDX studies ( Table 2). The results obviously show that the alloy is rich in Si and Mg. The amount of Si present in the molten metal falls within the standard acceptable limit and thus is suitable enough to enhance the flowability, castability, phase transformation, refined sizes (Table 4 and Figure 11), mechanical strength (Figure 12), and the microstructures.
The differences in the mechanical properties of asreceived scrap and cast samples (with and without inoculant) are reflected in the results tests obtained in combining Tables 1-4 and Figures 11-12. The present results give better insight to understanding the performance and the differences in the wear properties of the as-received scrap and cast test samples previously reported by Ajibola et al. [13,14,19,33]. At large, refined grains and higher values of BHN and strength were obtained as the % MgFeSi was increased from 1 to 3%.

Conclusions
Aluminium alloy specimen was produced by sand casting. The addition of MgFeSi produced enhanced properties in the aluminium alloy consisting of Al 2 Si 4 O 10 , Al 15 (MnFe) 3 Si 2 , Al 2 CuMg, Al 5 FeSi, and phases in eutectic Al-Si structures, thus giving the cast alloy higher hardness value than the asreceived scrap alloy.
Nevertheless, the addition of MgFeSi changes in the chemical composition and influenced both the mechanical (hardness, strength, and wear resistance) and metallurgical properties (microstructures) of the cast alloy. The increased amount of MgFeSi from 1 to 3% enhanced the wear resistance of the cast piston in the brake oil. The grains were more refined as better strength. Inoculating the melt with MgFeSi forms insoluble compound particles, thus helping to increase the rate of nucleation.