The Comprehensive Comparison of Thermal and Physical-Mechanical Properties of the Recycled Rubber and Plastic Roofing Tiles versus Roofing Tiles Made with Different Traditional Materials

(e objectives of this research were to estimate the thermal transmittance and some physical-mechanical properties of a housing cover built with roofing tiles made from recycled plastics and rubber and compare them with three other traditional solutions for housing cover: ceramic roofing tiles, concrete roofing tiles, and zinc sheets. (is roofing tile has technical advantages over the others, due to its higher thermal insulation, higher resistance to freezing, higher resistance to hail, higher flexural resistance, lower specific weight, and lower water absorption, with lower cost than the traditional glazed black ceramic roofing tile. And it is also friendlier to the environment.


Brief History of the Technological Development of Tiles.
e origins of the roofing tiles go back to Antiquity.Towards the year 2000 BC, the Mesopotamian civilizations around the Tigris and Euphrates Rivers began to make clay tiles (ceramic), which behaved much better against the rain than the roofs made of straw, branches, and leaves that were used before.Due to its technical qualities of good mechanical resistance, impermeability, and ease of placement, its use soon spread throughout the Mediterranean being widely used by Greeks and Romans.Almost at the same time, they began to be manufactured in China [1,2].
Over time, roofing tiles of different shapes and styles were made, and their manufacturing process ceased to be manual to be mechanical.
During the 19th century, the first concrete roofing tile appeared in Bavaria.At this time, the use of mixtures with pigments to manufacture tiles with different colors began [3]. is roofing tile had these advantages with respect to the ceramic tile: a higher durability and resistance, lower cost, ease of placement, and greater variety of colors.An inconvenience of the concrete roofing tile is that it is heavier than the ceramic one, so it needs a support structure of greater dimensions and cost.
e roofing tile always means good taste and distinction.Formerly the roofing tile was used exclusively to cover the houses of the high society people, but at present the roofing tiles are much more affordable and can be found of all prices and varieties.However, it still happens that a house covered with roofing tiles in addition to being highly valued from the aesthetic point of view is considered to be a more expensive housing, thus increasing its value in the market.
Since the last century, the zinc sheet has been used in cover of houses.Its advantages are low price, water tightness, and resistance to impact (e.g., the hail).Disadvantages are its lower thermal and acoustic insulation compared to other traditional components for house covers and the moisture condensation problem.For this reason, it is mainly used in constructions of economic type.In cases where it is applied in more expensive constructions, it is always with a thermal insulating ceiling.
Since the end of the 20th century, the plastic roofing tile has been used as a high-tech building material.Its technical advantages are its better thermal insulation, variety of colors, ease of installation, and resistance to corrosion.It has not had the same success as the ceramic or the concrete roofing tile because its duration is limited, and it has less resistance to ultraviolet radiation and to hail [4].
In the history of the technological development of roofing tiles and sheets, until the end of the second millennium, the objectives were technical and economic (rainresistant, hail-resistant, flexural-resistant, and low-cost).

Changes in the Technological Development of the
Roofing Tiles with the New Paradigm of Sustainable Construction.Only from the penultimate decade of the twentieth century were taken into account ecological objectives to produce constructive components for house cover, including reducing the consumption of natural resources and the impact on the environment.e change was introduced by the new concept of sustainable construction.
e sustainable construction seeks to enable future generations not to be harmed by the construction human activity (until the present destruction of the environment).According to Kibert [5], we ought to build some premises that we could consider ecological and are listed below: (i) Conservation of resources (ii) Reuse of resources (iii) Use of recyclable and renewable resources in construction (iv) Considerations regarding the life cycle of the raw materials used, with the corresponding prevention of residues and emissions (v) Reduction in energy use (vi) Increased quality in materials, buildings, and urbanized environment (vii) Environmental protection (viii) Creating a healthy and nontoxic environment in buildings e traditional technologies used to manufacture constructive components cause environmental impact, to a greater or lesser extent.ey all involve the extraction of raw materials, in some cases nonrenewable resources.
In the last two decades, different countries have begun to manufacture constructive elements that have a minor impact on the environment, replacing natural raw materials by waste from the industry.
Research on roofing tiles with recycled materials hardly takes a few years: for example, the slate made with a plastic mixture of PVC, CPVC, PVDC, ABS, ASA, and EVA patented in Europe [6], the nylon sheets that simulate roofing tiles in the United States [7] and in Europe [8]; the roofing tiles developed in Brazil with long-life packages [9] and the thermomechanical properties determinations in recycled materials [10].
Adhering to the premise of protecting the environment, the Economical Experimental Housing Center in Córdoba, Argentina, has developed different constructive elements that are more ecological than the traditional ones, made from waste.A research project started in 2010 has developed the different components of a house cover (roofing tile, valance, and ridge) using entirely recycled materials such as plastics from the industry and rubber from end of life tires (ELTs).
In previous publications, this research team has described the methodology and the results achieved in the development work about roofing tiles made form recycled materials [11].In this paper, the purpose is to compare the thermal performance of these components with that of other traditional ones that are used for the same application in our country, such as zinc sheets and ceramic and concrete roofing tiles, in relation to the costs and benefits of each one.
e technology developed in CEVE collaborates in the decontamination of the environment, since it only uses residues that are largely buried in municipal landfills, without any utility, or accumulated and burned in garbage dumps, causing degradation of the environment.

Availability of the Recycled Materials
Used in is Technology.Large quantities of plastic waste are available.According to data provided in 2015 by the Ministry of Health and Environment of the Nation, Argentina produces 1 kg of garbage per day per person, which is equivalent to 12,325,000 tons of garbage per year.Plastic wastes constitute 13.3% of the total weight (1,639 tons/year) [12].Most of plastics are no biodegradable materials, so nature cannot absorb them as other waste.e low-density polyethylene (LDPE) bags take 150 years to degrade in contact with natural agents [13].
Large quantities of rubber from ELTs are also available.According to the National Institute of Industrial Technology data for 2012, more than 100,000 tons are generated annually [14].
e ELTs, which accumulate in landfills, produce visual contamination, have a high flammability, and are not degradable.ey are the ideal refuge for insects, rodents, and reptiles, so their accumulation favors the spread of dengue and other diseases transmitted by mosquitoes.It is proven that when they burn, they emit carcinogenic substances.Only a fraction of ELTs are recycled to produce heat energy in special furnaces such as those used in the cement industry, which have adequate filters to avoid producing atmospheric pollution [15].

Objectives of This Work
In this work, we determined the thermal performance of a house cover built with roo ng tiles made from recycled rubber and plastic, and it is compared with traditional house covers systems (with zinc sheets, concrete, and ceramic roo ng tiles).Moreover, we determine the physical-mechanical properties of the roo ng tiles made from recycled rubber and plastic.en, comparison with traditional roo ng systems was carried out.

Applied Methodology.
e design of a traditional constructive system for a house cover with a wooden structure was carried out, and the calculation of the thermal transmittance, K, was performed for the climatic zone of Córdoba, which is classi ed as a Zone III A (Temperate dry), according to Argentine Institute of Normalization and Certi cation (IRAM) Standard 11603/96, using four di erent types of constructive elements: zinc sheets, concrete tiles, ceramic tiles, and CEVE roo ng tiles [11] made from recycled rubber and plastics.
See in Figure 2 the bioclimatic zones of Argentina, with the location of the province of Córdoba.
Subsequently, the comparison was made between the thermal transmittance of the di erent alternatives and the veri cation of compliance with the standard set in our country by the IRAM Standard 11,605, required by Argentine national law number 13,059.e goal was to meet Level B (average level).
A comparison was also made between the other technical properties and the cost of each one of the alternatives, in order to have the necessary tools when selecting one of them to design a home.

Description of the Construction Technology Used in the
Prototype.For this work, it was used a prototype of house with four di erent covers (Figure 3).e four alternatives were built with the same technology; the only di erence between them was the type of constructive element used in the house covers.
e construction system used on these sloped roofs is a traditional type and consists of these elements: a structure of 3″ × 6″ saligne pine straps, 1.5″ × 2″ saligne pine ribbons, 6 mm pine plywood ceiling, 40 mm expanded polystyrene thermal insulation layer, 40 kg/m 2 waterproof Wichi ® membrane with aluminum, 1″ × 2″ pine cleats, 25 mm air chamber between roo ng tiles and pine cleats, and di erent constructive elements for cover (zinc sheets, ceramic, concrete, or rubber and plastic roo ng tiles), see Figures 4 and 5.

Description of the Technology Used for the Production of
Roo ng Tiles Made from Recycled Material Developed by CEVE 3.3.1.Materials.Recycled materials of two types were used: crushed rubber from ELTs with particle size of 1-2 mm and LDPE from hoses, drums, and discarded pipes, in the form of pellets 2-3 mm long.

Equipment.
A single-screw extruder made by MJ (Martin Jimenez) was used to process the rubber and plastic mixture. is machine has three heating zones (600 watt,  To press the hot paste, the MJ pneumatic pressing machine was used.e maximum pressure is 20 tons.

Process.
e material was mixed in a horizontal mixer for 2 minutes and then added to the hopper of the extruder.
e screw was heated in a gradient between 250 °C and 270 °C; the hot and melted material was placed in the mold   Advances in Civil Engineering  Advances in Civil Engineering with manual aid for material distribution, and a pressure of 20 tons was applied for 4 minutes.e molded roofing tile was then removed from the mold and cooled in a frame to avoid deformation.See manufacturing sequence in Figure 6. Figure 6(b) shows the melted material leaving from die of extruder machine.In this point, we detected the emission of smoke, due to the processing of the LDPE and rubber at high temperatures (270 °C).
erefore, the manufacturing process must be carried out under extractor equipped with filters for volatile organic compounds (particles filter and activate charcoal filter).

Comparison of Test Results.
A comparison has been made between the properties of the roofing tiles developed by CEVE made from recycled materials and other traditional roofing elements in our country such as zinc sheets and concrete and ceramic tiles acquired from manufacturers of these products in the city of Córdoba, Argentina.e technical properties of the constructive elements are shown in Table 2.

Discussion of Test Results
(1) Weight per unit area: the roofing tile made from recycled materials has a weight per m 2 33% higher than the zinc sheet, 40.3% lower than the concrete roofing tile, and 51.5% lower than the ceramic See Table 3 for the classification of concrete roofing tiles according to the coefficients of permeability to air (Swiss Standard SIA 262/1-E10).e roofing tile made from recycled materials surpasses the ceramic roofing tile in this test, which presents superficial defects such as craters, chipping, and so on after the test.It is known that the ceramic roofing tile does not withstand a strong hail.Place of realization: Laboratory of Structures of the FCEFyN of the UNC.e roofing tile made from recycled materials is very flexible; consequently it resists higher loads than the ceramic and concrete roofing tiles, but with excessive deformation, which is not acceptable due to the conditions of support.e flexural resistant test must be stopped not by the breaking of the piece but by the deformation of the piece.e ceramic roofing tile resists a maximum load of 1000 N. e concrete roofing tile resists a maximum load of 3200 N, complying with the IRAM Standard that states that none of the roofing tiles should break under a load less than or equal to 1200 N. Place of realization: Laboratory of Structures of the FCEFyN of the UNC.(9) Resistance to freezing: all the analyzed constructive elements comply with the IRAM Standard 11632-2 for concrete roofing tiles, which states that no deterioration or surface peeling should be observed after the test.Place of realization: CINTEMAC Laboratory, UTN Córdoba.(10) Water Absorption: the roofing tile made from recycled materials has a lower water absorption rate than the other roofing tiles: 91% less than the concrete roofing tile and 97% less than the ceramic roofing tile.
Both the roofing tiles made from recycled materials and the concrete and the ceramic roofing tiles comply with the IRAM Standard 12528-03, which establishes that the tiles immersed in water for 24 hours shall not absorb a quantity of water greater than 15% of their respective masses in the dry state.e zinc sheet is not water absorbent.Place of realization: Laboratory of Structures of the FCEFyN of the UNC.(11) Resistance to aging: All the analyzed elements are resistant to the action of UV rays and humidity, according to the tests carried out under ASTM D 4329:99 and ASTM G154:04.e postaging flexural resistance and hard impact tests were performed to compare both values (before and after aging).
e test lasted 6 weeks, equivalent to 2 years exposed to the weather elements, in a climatic zone like Córdoba.Place of realization: Laboratory of Structures of the FCEFyN of the UNC.

Calculation of ermal Transmittance, K.
e calculation of the thermal transmittance coefficient, K, was performed for the four considered alternatives, with different types of constructive element for house cover.e calculation was made for the climatic zone of Córdoba, which is classified as Zone III A, Temperate Dry. e K coefficients are shown in Table 4.  condition.For required Level B, the coe cient K must not exceed the value of 0.72.In the case of the cover with zinc sheets, it complies to the limit with the Standard.e thermal transmittance K of the option 4 with roo ng tiles made from recycled materials is slightly higher than the other types of cover.However, we see in Table 1 that the thermal conductivity of the roo ng tile made from recycled materials (0.33 W/m 2 • °C) is much lower than the other constructive elements:
To conclude, the major contribution to thermal resistance of the house cover is given by the thermal insulation layer and its thickness.us, the constructive element of cover (zinc sheets, ceramic roo ng tiles, concrete roo ng tiles, or rubber and plastic roo ng tiles) is not decisive for the thermal performance of the house cover system.
On the other hand, it is recognized that, in many cases, it is not possible for users of social housing to have a ceiling with adequate thermal insulation (usually a layer of expanded polystyrene or glass wool), at an early stage of housing.It is common to begin to inhabit the dwelling with a cover made with zinc sheets, without insulating ceilings, because it is the most economical alternative; and later when the economic situation of the users allows, the thermal insulating ceiling is added.
is economic option does not comply in the initial stage with the current regulations regarding the coe cient of thermal transmittance (this coe cient K should not exceed the value of 0.72 in a climate like that in Córdoba).And it also has the problem of moisture condensation.
In the province of Córdoba, according to data from the National Population Households and Housing Census of 2010 [16], there are a total of 18,181 homes with zinc sheets as house cover; only 8,327 of them have thermal insulation ceilings (46%), and 9,852 do not have thermal insulating ceilings (the remaining 54%).And there are a total of 35,070 homes with roo ng tiles; only 23,985 of them have thermal insulating ceilings (68%), and 11,085 do not have insulating ceilings (the remaining 32%).Please see the data presented in Table 1.
It follows that in an initial stage of housing, in which there is no possibility of having a thermal insulating ceiling, the housing that is covered with roo ng tiles made from recycled materials is more convenient from the point of view of the thermal insulation.When the house is nished, if it has a thermal insulating ceiling, practically the four alternatives have the same thermal insulation: zinc sheets, ceramic roo ng tiles, concrete roo ng tiles, or roo ng tiles made from recycled materials.

Prices of the Compared Constructive
Elements for House Cover Table 5 shows the prices of the compared constructive elements for house cover.e prices of the zinc sheet and the concrete and ceramic tiles were consulted to Zarate trade (of Córdoba).Date: 13/01/2017.e price of the roo ng tile made from recycled materials was calculated in CEVE.Direct costs (materials and labor), indirect costs (administration, taxes and services, equipment amortization, and maintenance), and a pro t (pro t for the entrepreneur) have been considered in this calculation.
Data of local materials and labor prices were used for the calculation.
e used equipment was of low performance, appropriated for a laboratory scale production, consisting of an extruder and press of molding that allows making a roo ng tile every 15 minutes.Using this equipment, the unit price of this roo ng tile is USD $ 3.3, value updated at January 2017.
But if adequate equipment would be used for a larger scale, with an extruder and mold press that would allow a production of 4 roo ng tiles every 15 minutes (simply with Advances in Civil Engineering a larger molding tray), the unit price of this roo ng tile drops signi cantly, to USD $ 2.0, value updated at January 2017.In Table 5 this value has been used.See the comparison of prices in Figure 8.

Conclusions about the Prices of the Compared Constructive
Elements for House Cover.e price per m 2 of the roo ng tile made from recycled materials is 14% lower than that of the glazed black ceramic roo ng tile (the most similar in traditional roo ng tiles), 72% higher than that of the zinc sheet, 65% higher than that of the concrete tile, and 27% higher than that of the glazed red ceramic roo ng tile.
e most economical option is to use the zinc sheet, but it has some technical disadvantages in the initial stage of social housing, in which in general there is no ceiling that provides the necessary thermal and acoustic insulation and that avoids the problem of condensation of moisture.
Because of its low cost, this option is generally used in a ordable housing or in large roofs, for example in industrial sheds.But with a ceiling with adequate thermoacoustic insulation, it is also used in housing for the middle and upper social classes.Type of constructive elements for house cover

Final Conclusions
e thermal performance of a house cover with the roofing tile made from recycled materials developed in CEVE is better than that of other alternatives with traditional roofing (zinc sheets and ceramic or concrete roofing tiles) at an early stage of the house, when is not possible to have an insulating ceiling.e reason of this better performance is that its thermal conductivity is low (99.4% lower than the zinc sheet, 72% lower than the concrete roofing tile, and 50.7% lower than the ceramic roofing tile).When the houses are finished, if they have a thermal insulating ceiling, they have practically the same thermal insulation in the four alternatives: with zinc sheets, with ceramic roofing tiles, with concrete roofing tiles, or with roofing tiles made from recycled materials.
With regard to the price of the components, the price per m 2 of the roofing tile made from recycled materials developed in CEVE is 14% lower than the glazed black ceramic roofing tile (the most similar in traditional roofing tiles), but higher than other options such as the zinc sheet.It should be taken into account, when choosing the option of constructive element for a house cover, that the roofing tile made from recycled materials developed in CEVE has several advantages over the other compared traditional components, technical advantages.Since it has more thermal insulation, it is more resistant to flexion, hail, and freezing, it is less permeable to water and to air, it is less water absorbent, and it has a lower specific weight; and it also has ecological advantages because it is made from recycled waste, collaborating in the decontamination of the environment.

Figure 1 :
Figure 1: Comparative graphic of the types of house cover used in the province of Córdoba, Argentina [16].

Figure 3 :
Figure 3: Picture of the prototype used to carry out this study (a).Plant and views of this prototype (b).
e properties of the constructive elements have been established in the following standardized laboratories of Argentina: (i) Laboratory of the Center for Research, Development and Transfer of Materials and Quality-CINTEMAC, National Technological University-UTN, Córdoba Regional Faculty.(ii) Laboratory of Structures of the Faculty of Exact, Physical and Natural Sciences of the National University of Córdoba-FCEFyN, UNC.

Figure 6 :
Figure 6: Extruder and pressing machine (a), filling the mold with the mixture (b), thermomolding of the component (c), and finished roofing tile (d).

( 8 )
Flexural resistance: all the analyzed constructive elements have a satisfactory result in this test, performed under the IRAM 12528-2 Standard for concrete roofing tiles.

Figure 8 :
Figure 8: Comparative price chart of construction elements for house cover.

Table 1 :
[16]s of house cover used in the province of Córdoba, Argentina[16].

Table 2 :
Technical properties of constructive elements for house cover.

Table 3 :
Classi cation of concrete roo ng tiles according to the coe cients of permeability to air (Swiss Standard SIA 262/1-E10).Figure 7: Coe cients of permeability to air in constructive elements for house cover.Zinc sheet, roo ng tile from recycled materials (CEVE), concrete roo ng tile with terracotta pigment integral with water-based resin, ceramic roo ng tile unglazed colonial, and ceramic roo ng tile unglazed French have a kT value close to zero.

Table 4 :
ermal transmittance coe cients, K, for di erent types of house cover.