Numerical Analysis of the Energy Improvement of Plastering Mortars with Phase Change Materials

1 Construction Technology, Quality and Management (GEQUALTEC), Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal 2 Polytechnic Institute of Viseu-School of Technology & Management, Campus Politécnico de Repeses, 3504-510 Viseu, Portugal 3 Laboratory of Building Physics (LFC), Civil Engineering Department, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal


Introduction
Nanotechnology and nanoproducts offer interesting new opportunities in many civil engineering areas and architecture including design and construction processes, such as the development of novel insulation materials.These novel materials with very good insulation values are already available on the market, enable a thermal rehabilitation of buildings in which conventional insulation is not possible, and can help to improve energy efficiency.On the construction industry not all products that feature the term "nano" actually contain nanomaterials.Often, the term "nano" merely refers to structures in the nanosize range.Nanotechnology in the construction industry is currently concentrated in the following sectors: (i) cement-bound construction materials, (ii) noise reduction and thermal insulation or temperature regulation, (iii) surface coatings to improve the functionality of various materials, (iv) fire protection.
This paper presents the application of nanotechnology, in the construction process, to improve the building energy efficiency.One of the greatest challenges in the construction sector is the thermal renovation of existing buildings; and applying new insulation materials based on nanotechnology could make an important contribution.In the past, energy consumption has increased steadily.However, the energy efficiency of buildings is today a prime objective for energy policy at regional, national, and international levels [1].Innovations attributable to nanotechnology also enable thermally insulating buildings in which a conventional insulation is not possible (e.g., in older buildings with structured facade) and thereby achieve very good insulation values, for example, aerogels, phase change materials (PCMs), and vacuum insulation panels.

Advances in Materials Science and Engineering
A PCM is a substance that changes from one state of matter to another at a certain temperature and represents a technology that may reduce peak loads and HVAC energy consumption in buildings.Building materials with incorporated PCM are meant to increase heat storage capacity and enable stabilization of building interior surface temperature, whereby influencing the thermal comfort sensation and the stabilization of the interior ambient temperatures [2].
Thermal energy storage based on the latent heat of phase change material has attracted attention of researchers and engineers in different fields, and a considerable number of numerical researches on PCMs have attempted to estimate potential energy savings through building energy simulation.To analyse energy and peak load benefits from PCMs a significant number of commercial building energy simulation programs such as CoDyBa, EnergyPlus, ESP-r, and TRNSYS were used.
EnergyPlus PCM algorithm uses a one-dimensional conduction finite difference solution algorithm (CondFD).This algorithm was tested and validated against multiple tests suites [3,4].However, when simulating complex models over extended periods this procedure becomes very time consuming and computationally demanding.In the problem under study the objective is to evaluate and minimize the annual heating load while guaranteeing a good thermal comfort performance.
As far as the organization of this paper is concerned, Sections 2 and 3 deal with the manufacturing methods used for the achievement of the PCM-based plastering mortar, as well as with the characterization of the developed material.Section 4 is dedicated to the numerical analysis of the plastering mortars energy improvement with phase change materials, with the BESTest (Building Energy Simulation Test) of EnergyPlus.Section 5 closes the paper with the main conclusions and prospects of the research work.

Phase Change Materials (PCMs)
2.1.Properties, Groups, and Categories.Thermal comfort of interior building spaces can be achieved using sensible heat form, related to conventional building materials, or via latent heat form, associated with PCMs.PCMs used for latent heat storage in buildings are characterized by an endothermic behaviour (with energy accumulation) during solid-liquid transition and exothermal process (with energy liberation) during liquid-solid phase shift.The solid-liquid PCM group comprises three categories: organic PCMs (paraffins and fatty acids); inorganic PCMs (salt hydrates and metallics); and eutectic mixtures (organic-organic, organic-inorganic, and inorganic-inorganic).
Thermal properties, like melting temperature and phase change enthalpy, are crucial to the process of selecting a suitable PCM for thermal energy storage.The scheme shown in Figure 1 makes a distribution of the existing PCMs trough those two essential thermal properties.
Salt hydrates and eutectic mixtures present the highest phase change enthalpy for the operative temperatures required inside building spaces.However, the set of characteristics presented by paraffins makes of these the most desirable materials to be used in latent heat storage systems.Organic materials, such as paraffins, are chemically stable, offer no supercooling, and are available in a large temperature range with low cost.To avoid incompatibility problems, due to the direct contact between conventional construction materials and PCMs, encapsulation method arises.Encapsulation eases the process of handling and incorporating of PCM into building materials, the leakage problem can be avoided, and the function of the construction structure can be less affected.

PCM in
Macroencapsulation for PCM can present many different shapes, tubes, spheres, or panels, and can be obtained from several materials like aluminium or polymers.Macroencapsulated PCMs can be easily placed in ceilings [10] or underfloor systems [11].It has the disadvantages of poor thermal conductivity and tendency of solidification at the edges (crystallization) [12].Microencapsulation can be described as the technology in which PCM particles are enclosed in a thin, sealed, and high molecular weight polymeric film.Microcapsules, with diameters that can vary from 1 to 1000 m, prevent PCM from leakage during the phase change process.Microencapsulated PCMs are easy to incorporate and do

PCM Plastering Mortar
3.1.Test Methods and Requirements.The main goal of this section is to evaluate the feasibility of a new composite material, with inclusion of microencapsulated paraffin in cement based mortars, to be used in interior coatings for buildings.In order to be marketed within the European Union (EU) plastering mortars should respond to European Norm EN 998-1 [5].Therefore, the development of a plastering mortar should comply with characteristics presented in Table 1 where test parameters and target properties for mortars are identified.In the scope of this work, apart from performing tests on the properties mentioned in Table 1 while developing a PCM-based mortar, complementary properties like enthalpy and specific heat were also evaluated.

Components and Formulation.
The achieved mixture (used later on for further characterization) resulted from a set of preliminary analyses performed with the goal of evaluating the technical viability of the incorporation of microencapsulated PCM (industrially manufactured) into cement/lime based plastering mortar.Due to initial problems associated with the high cracking proneness of mortars containing PCM, the mixture composition was adjusted by an iterative process of trial and error, until the samples of the hardened mortar presented no visible cracking after the first hours of drying in controlled environment (with a temperature of 22 ± 2 ∘ C and a relative humidity of 50% ± 5%).
The trial samples, with 10 cm × 10 cm × 1 cm, resulted from spreading of the fresh mortar over a brick surface.Besides all conventional components used in common plastering mortars,cement, lime, sand, and/or industrial fillers, and different kinds of additions (resins, fibers, cellulose deviants, and others) the trial mortars involved the use of PCM.
The following text provides further information on the several constituents mentioned above, encompassing their main characteristics.The cement used is a type I class 42,5R according to NP-EN 197-1 [6].The industrial aggregate used was calcium carbonate with 0.5-1.5 mm granulometric distribution.Resins (polymer ethyl-vinyl acetate, VAE) were applied in some of the trial formulations, with the primary function of improving adherence to the substrate (brick or concrete substrate) on low cement concentrations.However, they are known to reduce the blend's elasticity.
The added fibers-polyacrylonitrile (PAN) 6 mm fibers-and aluminium powder are meant to compensate and redistribute the internal tension in the mortar, thus turning the shrinkage crack formation invisible.Cellulose deviants (cellulose ether) are used for high consistency development, as they impart good workability and enhance water retention considerably [17].A microencapsulated paraffin powder (based on polymethyl methacrylate, highly cross-linked paraffin mixture), with commercial designation of "Micronal DS5008x, " is used as PCM, with 23 ∘ C of melting point, an enthalpy of 100-110 kJ/kg, and 300 kg/m 3 density, approximately [18].After a trial-and-error procedure that consisted in casting several test specimens (formulations A to L shown in Table 2, together with the corresponding compositions), adequate behaviour (i.e., absence of drying cracks) was obtained with formulations J, K, and L. The formulation of a reference mortar, named as REFM, is also shown in Table 2, to better illustrate the similitude between formulation L and the formulation of a common plastering, which is commercially available for interior coating.

Characterization and Classification: Thermal Properties.
The characterization of the developed plastering mortar had two main goals: the compliance with normative required values and consequent classification of the PCM mortar and the identification of the thermal complementary properties given by the presence of the PCM (like enthalpy and specific heat).The hardened mortars of the selected formulation L, now renamed as PCMM (PCM mortar), were submitted to a set of characterization tests required by European Norm EN 998-1 [5].The measured properties for PCMM are summarized in Table 3, where the corresponding test method/normalization is shown (the normalizations required for the developed tests are EN 1015 [19] and EN 1745 [20]).In regard to the properties shown in Table 3, it should be remarked that the water vapor permeability coefficient and the specific heat were estimated from the values presented in Table A.12 of EN 1745:2002 [20], as a function of the measured density of the composite mortar (1170 kg/m 3 ).
A heat flow meter apparatus was used to determine thermal conductivity of the new composite material according to ISO8301:1991 [21].The thermal conductivity measured   with this experimental technique was 0.295 W/m K. Also, the melting temperature and the fusion enthalpy were experimentally determined through differential scanning calorimetry (DSC) tests with recourse to a Diamond DSC from Perkin Elmer.A sample of the supplied PCM mortar (powder) of approximately 7.7 mg was tested and an enthalpy of 22.6 kJ/kg was registered.This result came close to what would be expected (25 kJ/kg), assuming that the enthalpy is linearly proportional to the fraction of paraffin amount in the sample (25%), bearing in mind that the PCM is the only material in the mixture to experiment phase transition (from solid to liquid) in the range of studied temperatures (5-50 ∘ C).From these results it may be concluded that the PCM keeps its characteristics when integrated into hardened cement based mortars.Therefore, from now on, it will be considered that the composite mortar containing 25% of PCM has a melting point of 23 ∘ C and a melting enthalpy of 25 kJ/kg in a 2 ∘ C temperature range.The comparison of characteristics between PCMM and REFM is presented in Table 3.These results confirm the expected similarity in behaviour for the developed plastering mortar in view of the PCM chemically inert characteristics, which was introduced in the mix by replacing aggregates.

Numerical Simulation
4.1.Field Equations: PCM Model with EnergyPlus.Traditionally EnergyPlus uses conduction transfer functions (CTF) to simulate surface constructions.These are linear equations, relatively simple, which allow the calculation of the conduction heat transfer through a completed layered building surface.However, with this method, it is impossible to include temperature dependent thermal properties, and thus modelling behaviours such as phase change enthalpy become unmanageable [22].
The inclusion of a new solution algorithm that utilizes an implicit finite difference procedure (CondFD) upgraded EnergyPlus to simulate the effect of PCM.This new model was tested and validated against multiple test suites [3,4].The CondFD algorithm in EnergyPlus uses an implicit finite difference scheme coupled with an enthalpy-temperature function.This function is the users' input to accurately account for energy transfer during phase change.EnergyPlus includes two different options for the specific scheme or formulation used for the finite difference model.Before version 7, EnergyPlus used Crank-Nicholson solution scheme and then a new algorithm was added and is referred to as fully implicit.Both algorithms are based on an Adams-Moulton solution approach but the fully implicit one is considered of first order in time (Crank-Nicholson solution scheme is considered of second order).The model equation for the fully implicit scheme is described in [23] where  is the node temperature;  is the node being modelled; +1 is the adjacent node to interior of construction; −1 is the adjacent node to exterior of construction; +1 is the new time step;  is the previous time step; Δ is the calculation time step; Δ is the finite difference layer thickness (always less than construction layer thickness);   is the specific heat of material;   is the thermal conductivity for interface between  node and  + 1 node;   is the thermal conductivity for interface between  node and −1 node; and  is the density of material.This equation is complemented by ( 2) that relates enthalpy and temperature and is used to develop an equivalent specific heat at each time step: where HTF is an enthalpy-temperature function that uses data from user input.The algorithm also permits including a temperature dependent thermal conductivity: where  0 is the 20 ∘ C thermal conductivity value and  1 is the change in conductivity per degree temperature difference from 20 ∘ C.

Geometry Model and Parameters.
In this research the effect of introducing PCM in a plastering mortar on the external walls of a simple office cell located in Portugal is explored.
A sensitivity analysis was performed, which included the study of the influence of material properties variation, such as melting temperature ranges and enthalpy, and the study of the influence of installing the office cell in different climatic regions.Discomfort due to overheating and cooling energy demand were the outputs used in the analysis.The geometry adopted was an office cell like the one of ASHRAE Standard 140-Bestest Case 900 [24] as well as the internal gains and ventilation.The introduction of PCM on a plastering mortar in the building envelope (PCMM) and the use of a reference mortar (REFM) were compared.Figure 2 shows the main configuration used to model the walls and Table 4 provides the thermal conductivity, density, specific heat, and thickness of each layer.
Simulations were performed in two cities of Portugal, Lisbon and Porto, which represent different climatic regions.Both cities are located near the coast but, especially during summer, Lisbon is warmer than Porto.Figure 3 presents the monthly mean air temperature ( air ), the sol-air temperature ( sol-air ), and the total solar radiation (direct and diffuse) of Lisbon and Porto [23].
All the simulations were performed with software Ener-gyPlus, for the cooling season, between 01/04 and 30/09, on an hourly basis and considering 60 time steps per hour.

Discomfort Analysis due to
Overheating.The first performed analysis was the evaluation of the discomfort due to overheating, assuming a "free-floating" scenario (without cooling system).The discomfort was assessed by computing the degree-hours.The degree-hours (DH 25 ) can be defined as the sum of the differences between air temperature and a reference value as follows: where   is the interior temperature.It performed a sensitivity analysis that aimed to understand if overheating minimization can be achieved by the increasing of enthalpy amount in the mortar or by changing the PCM melting temperature range.A numerical simulation was carried out, which included 13 cases resulting from the combination of different phase change ranges (melting temperatures from 23/25 ∘ C to 26/28 ∘ C) with varied enthalpy values of 25, 100, and 200 kJ/kg, as well as the reference case without PCM, as can be observed in Figure 4 and Table 5.

Analysis of the Effect of Introducing an HVAC System.
In the second analysis, the effect of introducing an HVAC system in the office cell was evaluated by computing the energy demand for cooling assuming a temperature set point of 25 ∘ C. For this sensitivity analysis only two melting temperature ranges were considered, resulting in 7 cases (Table 6).

Simulation Results
. The comfort sensation is guaranteed by temperature level and stabilization inside a building space   [25].PCM contributes to interior temperature stabilization being an interesting solution to improve comfort conditions and to minimize energy consumption [1,12,26].

Results for the Discomfort Analysis due to Overheating.
The first approach of the sensitivity analysis was for the "freefloating" situation.Degree-hours for 25 ∘ C basis were used as the evaluation parameter to assess the discomfort due to overheating.As an example, Figure 5 shows the simulation result of a daily temperature profile in Lisbon for different scenarios: the effect of enthalpy variation is exposed in Figure 5(a), where the same melting temperature, of 24-26 ∘ C, for three different enthalpies, was calculated, and in Figure 5(b), where the same enthalpy, of 200 kJ/kg, for four different melting temperature ranges, was studied.Attending to the results shown in Figure 5(a) the peak temperature for the reference case REFM was 30.4 ∘ C, dropping to 28.7 ∘ C when considering a PCMM with 24-26 ∘ C and an enthalpy of 200 kJ/kg (PCM24/26 200).With this plastering mortar, PCM24/26 200, the interior temperature of the office cell varied between 24.5 and 28.7 ∘ C, reaching a temperature interval of Δ PCM24/26 200 = 3.3 ∘ C inside the building.On the other hand, with the REFM (without PCM), an interval of Δ REFM = 5.3 ∘ C, between 25.1 and 30.4 ∘ C, was achieved.The presence of the PCM was observed lowering the interior temperature peak, reducing the temperature variation within the building, and increasing the period of time during which the temperature is maintained within the melting range near 25 ∘ C (i.e., comfort temperatures).
Regarding Figure 5(b) the most interesting performance was obtained with PCM25/27 200 and PCM24/26 200 with a temperature variation between 24.7 and 28.4 ∘ C, with Δ PCM25/27 200 = 3.7 ∘ C, and 24.5 and 28.7 ∘ C, with Δ PCM24/26 200 = 4.2 ∘ C, respectively.However, it is important to underline that all the simulated scenarios correspond to an improvement when compared to the reference case without PCM (REFM).It is clear that PCM incorporated in plastering mortars changed the interior temperature profile, helping to stabilize them and dropping temperature peaks.
The "overheating improvement" was evaluated by a percentage resulting from the difference of degree-hours DH 25 between the use of REFM as plastering in the office cell and the use of different PCMM.Attending to the analysis for "free-floating" situation, with a 25 ∘ C basis for DH to assess the discomfort due to overheating, with results plotted in Figure 6, maximum overheating improvement was 12%, obtained for the office cell placed in Porto with PCM25/27 200.The lowest value was registered for the office cell placed in Lisbon for PCM23/25 25 (a PCM with an enthalpy of 25 kJ/kg and a fusion temperature range between 23 and 25 ∘ C).Still, the overheating improvement was 2%.
These results are in line with other authors [1,12,26,27].Some additional improvement would be expected if some changes were made in the building envelope and ventilation.Indeed, the model used in this analysis is very exposed to overheating problems, due to a combination of large solar heat gains (no adequate solar shading device is used), lack of insulation in the roof, and poor ventilation rates especially during the night (no night ventilation procedure is established).This situation leads to very high interior temperatures (situations with interior temperatures over 30 ∘ C were regularly observed) and, therefore, there is a large untapped potential in the PCM.The lower overheating improvements obtained in Lisbon are also explained by this situation since the exterior climate conditions are more aggressive than in Porto (higher temperatures and more intense solar radiation).

Results for the Effect Analysis of Introducing an HVAC
System.A similar analysis can be made for the improvement in the cooling energy demand when using PCM in the office cell with an HVAC system.The "energy savings" are evaluated by a percentage resulting from the difference in the annual cooling energy demand between the use of REFM as plastering in the office cell and the use of different PCMM.Attending to the results, shown in Figure 7, plastering mortar PCM24/26 200 used in an office cell placed at Porto can reduce cooling energy demand by 15%.The same solution for the climatic conditions set for Lisbon resulted in 8% of energy savings.
On the analysis of the effect of introducing an HVAC system, the PCM presence was observed lowering the cooling energy demand necessary to maintain the temperatures inside the office cell close to the comfort temperature, 25 ∘ C.
Both sensitivity analyses produced very encouraging results that sustain future works on this research in order to optimize the use of PCM, adapting enthalpy and melting temperature ranges to climatic conditions and building's envelope.

Conclusions and Future Works
The main conclusions of this study are as follows.
(i) PCM can be incorporated into mortars without compromising the properties that are desirable for their application as plastering materials.
(ii) The potential of advanced simulation tools to evaluate and optimize the usage of PCM materials in the indoor temperature control, allowing for an improvement in the comfort conditions and/or in the cooling energy demand, was explored in this paper.
(iii) A sensitivity analysis regarding the enthalpy and melting temperature effect was performed and the temperature stabilization potential of the plastering PCM has been demonstrated.It was found that changes in the enthalpy value can produce a higher impact than varying the melting temperature of the PCM.
(iv) Considering a "free-floating" space, the inclusion of a plastering mortar containing PCM with an enthalpy of 200 kJ/kg and a fusion temperature range between 25 and 27 ∘ C can improve the comfort conditions by 12%.For the office with an HVAC system, the inclusion of a plastering mortar containing PCM with an enthalpy of 200 kJ/kg and a fusion temperature range between 24 and 26 ∘ C can improve the cooling energy demand by 15%.

Figure 5 :Figure 6 :
Figure 5: Assessed interior temperatures for the office cell located in Lisbon: (a) enthalpy effect, (b) melting temperature effect.

Figure 7 :
Figure 7: Energy savings analysis of the inside of an office cell placed in (a) Lisbon and (b) Porto.

Table 1 :
Required tests for hardened mortars of general purpose (GP) and of lightweight (LW).

Table 2 :
Mix proportions of formulations A to L and REFM and surface appearance of samples A to L.
Appearance: fissuring/cracking without evident direction (aprox.⊥).Causes: high cement dosage induces low ductility.A narrow particle sizes distribution with high percentage of fines due to the presence of PCM.Appearance: fissuring/cracking without evident direction (aprox.⊥).Causes: a narrow particle sizes distribution with high percentage of fines.Appearance: better appearance with less fissuring.Causes: better particle size distribution.Reduction on fines content.Appearance: better appearance with less fissuring.Causes: use of industrial filler.Better particle size distribution.Reduction on fines content.Appearance: fissuring/cracking without evident direction (aprox.⊥).Causes: the addition of a water repellent could have affected relaxation and shrinkage.
Appearance: better appearance with less fissuring.Causes: higher ductility mainly due to the addition of lime.The use of dispersed fibers and resins that improves cracking susceptibility.Appearance: better performance concerning cracking.Causes: higher ductility mainly due to the addition of lime.The use of dispersed fibers and resins that improves cracking susceptibility.Appearance: adequate behavior (i.e., absence of drying cracks).Results: very low tensile resistance:   ≪ 1500 MPa.Causes: higher ductility mainly due to the addition of lime.

Table 2 :
Continued.  ≪ 1500 MPa.Causes: higher ductility mainly due to the addition of lime.

Table 3 :
Results of the test performed to the composite mortar with formulation L (PCMM) and comparison to reference mortars (REFM).