The Variability and Evaluation Method of Recycled Concrete Aggregate Properties

With the same sources and regeneration techniques, given RA’s properties may display large variations. The same single property index of different sets maybe has a large difference of the whole property. How shall we accurately evaluate the whole property of RA? 8 groups of RAs from pavement and building were used to research the method of evaluating the holistic characteristics of RA. After testing and investigating, the parameters of aggregates were analyzed. The data of physical and mechanical properties show a distinct dispersion and instability; thus, it has been difficult to express the whole characteristics in any single property parameter. The Euclidean distance can express the similarity of samples. The closer the distance, the more similar the property. The standard variance of the whole property Euclidean distances for two types of RA is Sk = 7.341 and Sk = 2.208, respectively, which shows that the property of building RA has great fluctuation, while pavement RA is more stable. There are certain correlations among the apparent density, water absorption, and crushed value of RAs, and the Mahalanobis distance method can directly evaluate the whole property by using its parameters: mean, variance, and covariance, and it can provide a grade evaluation model for RAs.


Introduction
Accurate evaluation of RA is beneficial to its rational utilization.The current problems in evaluating the variability of RA are focused on the application of RA mixture only, regardless of the study and conclusion [1].How shall we accurately express the whole property of RA and how shall we effectively evaluate the grade of RA?So far, there is still no reasonable method to be seen, and most of the evaluation methods are the evaluation of mixtures with RAs.
The single properties of aggregates are usually described by the apparent relative density, water absorption, crushed value, wear value, the adhesion index, while the comprehensive property is the whole property of aggregate showed in applications.The single property of different RAs shows a large variability, so the comprehensive evaluation method of each kind of RA needs to be studied.
Over the past decades, the United States, Europe, and other developed countries have promulgated some quality standards and technical specifications of RA according to the RA characteristics of their own countries.Although each of them has their own characteristic, it is still insufficient for the evaluation method.The main problem is that they focused more on the single property index and neglected the whole property evaluation for the RA [2][3][4].For example, the American Society for Testing and Materials (ASTM) made clear provisions for the extremum of the evaluation index of coarse aggregate in different engineering fields.The British Standard (BS) divided RA into three grades based on different sources [3,5].V. W. Y. Tam and C. M. Tam further put forward the RA should be divided into 7 grades in view of the evaluation indices of apparent relative density, water absorption, flakiness content, impact value, the contents of chloride, and sulfate in 2007 [6].The common problem is that the grading standard is too absolute and does 2 Advances in Materials Science and Engineering not give the whole characteristics requirement in different application fields.In 1998 Germany promulgated "Regeneration Aggregate Concrete Application Guide," where the quality requirements of RA must comply with the technical requirements of natural aggregate (NA) [7,8].It ignores the characteristics of RA, and it is not conducive to the application of concrete aggregate.Although Spain and other countries have not given a clear classification and grading standard of the RA, only relevant qualification was performed with recycled coarse aggregate [9,10].The standard did not include many details.The common features are that these specifications only gave a different range of values for a single property index of the RA and did not make provisions for the whole properties.
Because of the complexity of RA sources and regeneration techniques, an RA's properties show large variations in its microstructure and physical, mechanical, and chemical properties [1].The test values show a large variability; the same single property index of different sets maybe has a large difference of the whole property, so the whole property of RA could not be only expressed by a single property index.Adopting the Euclidean distance method and Mahalanobis distance method, respectively, in evaluating the single and whole property of RA is proposed in this paper.The flow chart is demonstrated in Figure 1.The RAs used in the present study were screened into three different sizes (4.75-9.50mm, 4.75-13.2mm, and 9.50-19.0mm) with the same processing method.After sampling, the aggregates were sieved with 4.75 mm standard sieve and then rinsed with water to ensure that they are free of dirt and dust (see Figure 2) [11].

Test and Analysis of the
The properties of the RA and NA, such as apparent relative density, water absorption, crushed value, wear value, and the adhesion, were tested according to the Chinese standard.Table 1 presents the results from the above-described tests.
As indicated in Table 1, the properties of NA tested satisfy all commonly acceptance, while RAs had higher water absorption and lower adhesion to asphalt values than the listed, commonly accepted values.1, the apparent relative densities of RA with different particle sizes are similar, and they are all slightly lower than those of NA.In addition, the water absorption of RA is much higher than that of NA for the same size of aggregate.These may be mainly attributed to the high porosity, or low density, of the mortar adhered on the surface of the aggregate.In addition, during the production process of RA, mechanical crushing, particle collision, and sliding also produce microcracks in the aggregate, and these will result in an increase in the aggregate porosity and a decrease in the apparent relative density.The porous mortar and fine cracks are also responsible for the high water absorption of the RAs.Furthermore, the high silt content on the surface of the RA particles may also help to increase the rate and amount of water absorption.

Aggregate Characteristic Analysis. As shown in Table
The crush values of RAs are clearly lower than those of NA.And the degree of abrasion of RAs is all lower than that of NA.A main reason for these is that the RAs had already gone through a crushing process during recycling.After crushing, washing, and sieving, the RAs had high pebble content with good integrity.As a result, the RAs used in this study had a higher crushing and abrasion resistance than the NA.This suggests that the lower the strength of the original concrete, the smaller the damage degree in the process of the aggregate regeneration and the better the property of resistance to crushing of the recycled aggregate.Adhesion of aggregate to asphalt is critical for the property of asphalt concrete pavements.Table 1 shows that among three RA samples tested, two had adhesion level values less than 4 as required.It was observed during the adhesion testing that the general peeling area was around 10%, and localized peeling area summed up to 30%.The weak adhesion of RA may be related to the reaction of water soluble ions leaching out from the adhered mortar on the aggregate surface with the carboxylic acids of asphalts.
A scanning electron microscope (SEM) was used to observe the microstructure of RA and NA, as shown in Figure 3.
It can be seen that RA possesses a large number of pores and microcracks internally caused by the accumulated damage during crushing, leading to an increase in the void ratio, water absorption, and crush value (shown in Figure 3).Compared to the surface structure of NA, the asphalt bonding material can penetrate into the RA surface more easily.Further, the strength of interface may be improved.
In summary, for the RA from low strength concrete, except for the water absorption rate, the other properties of RA appear better than that of NA.Perhaps this is a special case; more extensive investigation may need to be done.Sixteen groups of RAs were selected from pavements and buildings, respectively [15,16].Most of the property data were investigated except for groups , , and NAs, which were tested by ourselves in the laboratory.All of the RAs were crushed by the jaw-crush method (see Tables 2 and 3).
As shown in Tables 2 and 3, the basic property data of the NA are generally property density at 2.63 g/cm 3 ; water absorption at 1.6%; needle and flakiness content at 5.2%; and crushing value at 9.6%.

Variability Analysis of the NA Property Data.
As can be seen from Tables 1 and 2, there is a little distinction in apparent relative density between RA and NA.Most of the RA's apparent relative density is 88%∼97% of the NAs, about 2.31-2.61kg/m 3 .The shapes of RA from different sources have a high degree of similarity; some of them are even better than the NA.The shapes of different sources of RA are similar, and for some the quality is better than the NA; the apparent relative density and needle-flakiness content are relatively stable, while the water absorption and crushing values are relatively higher.The water absorption rate of RA is between 2%∼10%; the highest value even is up to 12%, which is 2 to 7 times that of the NA.The crushing value of RA varies greatly, and its crush resistance ability is significantly lower than the NA, as is shown in Figure 4.
After being crushed, the RA might produce a large number of microcracks on the aggregate surface and the interior between aggregate and adhesive cement mortar.
Besides, the RA would be cracked more easily when being pressed, and it contains a variety of impurities on the surface; therefore, the RA strength would be lower than NA.As a result, the water absorption and crushing value of RA were significantly larger [7,17], and the experimental data showed a large variability as well.Since the content of impurities and microcrack is influenced by many factors, such as the types of concrete waste, engineering construction, and crushing method, and the RA from building contains more impurities than that from pavement, its variability would be greater.

Pavement Property with RA.
The conclusions of our previous study about RA's instability are as follows [11].
(1) Compared with NA, the RA recycled from low grade concrete had lower apparent relative density, higher water absorption, and poorer adhesion to asphalt but had probably lower crushing and wearing value.
(2) The rutting deformation of the HMA mixes generally increased with the level of RA replacement, but the low temperature cracking resistance test results showed that the failure load, tensile stress, and modulus of the HMA mixes with RA are all significantly higher than those of the mix with NA.
(3) The water stability measured by immersion compression tests showed a similar trend to that measured by freezethaw splitting strength tests.The water stability of the HMA concrete decreased with increasing RA replacement (up to 50%).When the RA content reached 75%, the water resistance of the HMA concrete increased, rather than decreased further.
Due to instability, a large variability has been indicated by experimental data of RA property index.Therefore, it is inaccurate to illustrate the whole property through a single property index.It is possible that the whole property is better  in the asphalt mixture, while a single property index exhibits poor results.However, the distance method is not affected by the dimension and directly expresses the difference of multiple variables or sample set of indices.According to the distance method, it is feasible to illustrate the whole property of RA.

Euclidean Distance Comparison Method of RA
in which   ,   , , , and  are the same as formulation (1).(3) The whole property Euclidean distance standard variance of RA   is generally in which type   is the standard variance of whole property Euclidean distance for building RA and pavement RA;   is the arithmetic mean value of whole property Euclidean distance for the different number of RA;   , , and  are the same as formulation (1).

The Comparison and Analysis of Euclidean Distance of RA Property.
According to the Euclidean distance formula (1)-( 3), for the two types of RA, the Euclidean distances of single property and whole property are shown in Tables 4 and  5 and Figures 5 and 6, respectively.The greater the value of the properties, the greater the difference between the RA and the NA; otherwise, the smaller the value, the closer the difference.The standard variance of the whole property Euclidean distance of building RA and pavement RA was calculated to be 7.341 and 2.208, respectively.Table 4 and Figure 5 show slightly differences of the property density and flakiness content of RA compared with the NA, while the crushing value and water absorption are obvious differences.In addition, pavement RA was significantly better than building RA in terms of single property index.As shown in Table 5 and Figure 6, the whole property of RA with better single property may be poor, while the whole property of RA with poor property may be better.
From the size of Euclidean distance, it can be seen that the comprehensive properties of group , group , and group  are the best, whereas group  shows the worst results.The Euclidean distance of crushing value and water absorption is the largest, which shows a primary need to improve the property index of the RA.
The standard variances of the whole property Euclidean distances are 7.341 and 2.208, respectively, which shows that the property of building RA has great fluctuation, while pavement RA is more stable.
The global 1 is defined by the vector  and the global 2 as ; then the distance from a sample point of global 1 to global 2 is equal to the distance from a point of vector  to vector : is a normalized distance of nonuniform distribution, and it can reflect the comprehensive index of RA property without the need to consider the dimension of each index and the choice of unit.Based on the characteristic distribution condition in the whole space,  can express the effect of correlation among indices of RA.Therefore,  can better describe the similarity between RA and the set, so as to provide a basis to determine the level of RA.The smaller the  value, the better the property and vice versa.

Mahalanobis Distance
in which    ,    ,    are the water absorption, crushing value, and adhesion of different grades of NA. , ,  are the average value of water absorption, crushing value, and adhesion of a certain RA. 2  ,  2  ,  2  are the standard deviation of water absorption, crushing value, and adhesion of a certain RA.

Grading Method of Mahalanobis Distance. When the 𝐷(𝑝 󸀠
1 ), (  2 ), (  3 ) represent, respectively, Mahalanobis distance grade 1, grade 2, and grade 3, the RA can be graded by the methods of Table 6; therefore, Mahalanobis distance comprehensive evaluation method can be applied to evaluate some cases which are difficult to compare each other.

Figure 2 :
Figure 2: RA before and after washing.

)Figure 4 :
Figure 4: Contrast charts of NA and RA properties.

Figure 5 :
Figure 5: Single property of RA.

Table 1 :
Properties of RA and NA.
Figure 1: RA property evaluation flow chart.

Table 2 :
Property data of RA from buildings.

Table 3 :
Property data of RA from pavement.

Table 4 :
Euclidean distance of single property of building and pavement RA.

Table 5 :
Euclidean distance of whole property of building and pavement RA.Suppose that there are two variables 1 and 2, which obey the state distribution,  ∈   is a new sample point, and the distance from  to 1 and 2 is defined as follows:

Table 6 :
Grading methods of RA.
Calculation and Grading Method 5.2.1.Mahalanobis Distance Calculation.Water absorption, crushing value, and adhesion are represented by , , and , respectively.The evaluation index of RA comprehensive property can be considered as a three-dimensional vector (, , ), and assuming that the value of the three indicators is   (   ,    ,    ), we can calculate the distance  between any RA and NA and then distinguish the whole property of RA.