Corrosion Activity on CFRP-Strengthened RC Piles of High-Pile Wharf in a Simulated Marine Environment

We report test results from an experimental study to investigate the effectiveness of carbon fiber-reinforced polymer (CFRP) against reinforcing steel bar corrosion. Twelve reinforced-concrete pile specimens of 180mm square by 1,600mm long were cast. Three pile specimens were corroded to 5% steel mass loss and then strengthened with CFRP sheets; four specimens were strengthened by using CFRP sheets, whereas the remaining five specimens were not strengthened. The specimens were placed in a simulated marine environment, and corrosion was induced by an impressed current technique. At different theoretical corrosion degrees, nondestructive tests were performed to investigate the corrosion activity of the pile specimens, and destructive tests were performed to determine reinforcing steel bar mass loss. Based on the findings, the effectiveness of the CFRP-strengthened RC piles under aggressive marine environmental conditions was established.


Introduction
The deterioration of marine reinforced-concrete (RC) structures induced by reinforcing steel bar corrosion is a global problem [1].In general, concrete provides a highly alkaline environment, which results in the formation of a passivation membrane that protects steel bars from being corroded.Reinforcing steel bars in concrete structures are depassivated as chloride concentrations reach threshold levels on the rebar surface or when the pH of the concrete cover is reduced below critical levels because of carbonation [2].Marine structures, especially RC pile foundation of high-pile wharf, experience reinforcement corrosion, because their concrete face is often wetted periodically by tidal levels, and dry-wet environments supply reinforcement corrosion with three necessary conditions: sufficient chloride ions, moisture, and oxygen.Temperature variations make it easy for chloride ions to reach the reinforcement or to decrease the pH of the concrete cover.As reinforcement corrosion is initiated, it progresses by volumetric expansion of the rust around the rebar.
Traditionally, reinforcement corrosion damage has been repaired by "chip and patch" methods in which the deteriorated concrete is removed; then the corroded steel bar is cleaned, and patching mortar is applied.After repair, rerepair is common for the poor corrosion resistance of mortar materials.
Because of the aggressive marine environment, the deterioration of concrete pile for high-pile wharfs usually does not occur from one harsh condition type only.However, no detailed information exists in the literature on reinforcement corrosion that is caused by multiple harsh conditions in the marine environment.We conducted an accelerated corrosion experiment to investigate the behavior of concrete piles that are encased with CFRP sheets when subjected to multiple 2 Advances in Materials Science and Engineering Notes.CF5-10 denotes that a pile specimen firstly corroded to 5% steel mass loss, then was strengthened by CFRP, and corroded to 10% steel mass loss.N10 denotes an unstrengthened pile specimen that was subjected to 10% steel mass loss.simulated environmental conditions of temperature variations, high chloride concentrations, and wet-dry cycles.

Experimental Program
Twelve one-fifth scale models of 1,600 mm long and 180 mm square RC piles were cast.These prototype piles are used widely in South China coastal port engineering (Figure 1).Four 10 mm diameter longitudinal reinforcing bars were used for compression reinforcement with a clear cover of 40 mm, and 6 mm diameter plain stirrups were spaced at 120 mm.The tidal range zone of the pile specimen was 400 mm in the middle of the pile.A 9.53 mm diameter hollow stainless steel bar was provided at the center of the pile cross section to serve as an internal cathode for an impressed current to accelerate corrosion.
Specimens were divided into three groups: strengthened, unstrengthened, and poststrengthened specimens, as shown in Table 1.The reinforcing steel bar of the pile specimens in the poststrengthened group was corroded to 5% steel mass loss, then strengthened with CFFRP sheet, and subjected to further corrosion.The pile specimen of N0 that was not corroded in the unstrengthened group was the control pile in the test.Specimens that were strengthened or poststrengthened were encased over a 400 mm length by using CFRP sheet in the middle tidal range zone.Each pile specimen contained seven mounted strain gauges to monitor the deformation by expansion of the reinforcement corrosion, as shown in Figure 2.

Material Properties
The concrete mix proportion by weight was cement : sand : gravel : w/c = 1 : 1.11 : 2.72 : 0.38.The 28-day concrete compressive strength was 31 ± 1.2 MPa.The compression reinforcement in all pile specimens was 10 mm nominal diameter steel with a yield strength of 335 MPa and an ultimate strength of 445 MPa.The 6 mm diameter plain bars used for stirrups had a yield strength of 240 MPa and an ultimate strength of 380 MPa.The cured CFRP strips have a modulus of elasticity of 65 GPa, an ultimate tensile strength of 894 MPa, and an elongation of 1.33% at the breakage point, as reported by the manufacturer.

Accelerated Corrosion Technique
To complete the corrosion within a reasonable time, an accelerated corrosion technique based on Faraday's law was used [20].A constant-current system was built, and a direct current galvanostatic power supply was used to provide the desired current of ∼190 A/cm 2 .The times to various degree of corrosion (steel mass loss) were estimated according to Faraday's law (e.g., the time to reach 10% mass loss was 45 days).Figure 3 shows the electrical connections of the accelerated corrosion system.

Simulated Marine Environment
To simulate tidal ranges in the marine environment, sea water levels were varied between the high and low tidal levels over 6 h, as shown in Figure 4. Pile specimens were kept in the tank and were subjected to wet-dry cycles by artificially manufactured sea water with the chemical compositions in Table 2.A heater on top of the tank varied the temperature from 25 ∘ C to 40 ∘ C in 24 h to simulate average marine temperatures of the South China Sea region, as shown in Figure 5.

Corrosion Potential.
Half-cell potential measurements are one of the most widely used nondestructive methods to monitor and assess steel bar corrosion in concrete structures [21,22].It is generally agreed that the half-cell potential measurements can be interpreted according to ASTM C 876-80 [23] in Table 3.In the test, all half-cell potential values of reinforcing bar were increased with the degree of corrosion as shown in Figure 6.
In the unstrengthened group, the corrosion potentials in tidal range zone were about −350 mv, −612 mv, −705 mv, and −810 mv at 5%, 10%, 15%, and 20% theoretical corrosion degree, which indicated that the rebar was in corrosion state from the corrosion degree of 5%.In contrast, the atmosphere and full submersible zone were in active corrosion state from For strengthened group, the CFRP repair has pronounced effect on slowing down corrosion velocity of piles.The potentials of tidal range zone were −160 mV, −190 mV, −245 mV, and −389 mV and 54%, 69%, 65%, and 52% greater compared to unstrengthened group piles at 5%, 10%, 15%, and 20% corrosion degree, respectively.The analysis showed that the tidal range zone was greater than 90% probability of no active corrosion at 5% and 10% corrosion degree, active corrosion uncertain at 15% corrosion degree, and greater than 90% probability of active corrosion at 20% corrosion degree.Unlike the unstrengthened group, the potentials were positive compared to those of atmosphere and full submersible zone from 15% corrosion degree.It is because that the externally bonded CFRP effectively slowed down the corrosion velocity of the tidal range zone by preventing air and chloride ions from entering the concrete, which caused the potential curves to be flatter compared to the unstrengthened piles.As the tidal zone was encased with CFRP sheet, the atmosphere and the full submersible zone replaced casing tidal zone as the active region to suffer accelerating corrosion according to the mechanism of electrochemical corrosion.But because of the lack of aggressive medium in atmosphere and the full submersible zone, the average potentials of the atmosphere and the full submersible zone were also positive compared to those of unstrengthened group piles.
For poststrengthened group at 10%, 15%, and 20% corrosion degree, corrosion potentials in the tidal range zone for poststrengthened piles were 26%, 36%, and 44% more positive compared with unstrengthened group piles and 57%, 46%, and 14% more negative than those of strengthened group piles, respectively.The potentials increased more rapidly in the atmosphere and the full submersible zone than that of the tidal range zone as the piles were poststrengthened.The potentials for the poststrengthened group gradually reached those of the strengthened piles with increasing corrosion.The corrosion potentials for the atmosphere and the full submersible zone were more negative than the tidal range zone for a 15% corrosion degree, which is similar to   the strengthened group piles.Based on the variation characteristics of corrosion potentials during the whole period of accelerated corrosion, we could see that the speed of negative growth of poststrengthened specimens' corrosion potentials slowed down immediately compared with corresponding unstrengthened piles just after CFRP repaired.This made the unbalance potentials among atmosphere, tidal range, and full submersible zones tend towards equilibrium.And such homogenization of corrosion potentials occurring inside the poststrengthened specimens would reduce the galvanic corrosion current of reinforcement due to the potential difference and then slow down the corrosion of reinforcement steel.This indicated that external bonded CFRP also had a very good effect on the piles that had already suffered nonuniform corrosion in some extent.

Steel Mass Loss.
All specimens were tested gravimetrically to determine the actual degree of corrosion.Longitudinal cuts were made on the concrete surface with a diamondtipped saw, and the cover was chipped off with a hammer.Later, in accordance with ASTM Standard G1-90, the mass loss of reinforcing steel bars analysis was performed for each specimen in a different corrosion phase.The measured and predicted mass losses based on Faraday's law were compared in Figure 7 for all pile specimens at different corrosion degrees.
In the tidal range zone of the unstrengthened group, the measured steel mass loss for pile N5 was 6.2%, which was slightly greater than the theoretical steel mass loss of 5%, whereas the measured steel mass loss of piles N10, N15, and N20 was 9.3%, 13.2%, and 16.5%, which is lower than the theoretical steel mass losses of 10%, 15%, and 20%, respectively.This occurs because of the penetration of corrosion products that build up around the reinforcing bar surface through surrounding concrete pores and form a physical barrier to prevent water and oxygen ingress, which slows their movement towards the bar surface [20].The measured mass loss within the tidal range zone agrees well with Faraday's law for steel mass loss below 5%, possibly because of the sufficient supply of humidity and oxygen needed for corrosion and because minimal physical barriers are formed in this region.The steel mass loss for the atmospheric and full submersible zone was smaller than that of the tidal range zone at the initial stage of corrosion and gradually approximated the value of the tidal range zone with an increase in corrosion.
The measured mass loss for poststrengthened piles of CF5-10, CF5-15, and CF5-20 in a tidal range zone was 27%, 29%, and 34% lower than that of unstrengthened piles of N10, N15, and N20 and was 92%, 80%, and 63% greater than that of strengthened piles of CF10, CF15, and CF20, respectively.As the piles are strengthened with CFRP sheet in the tidal zone, the depolarization of chloride ion would decrease due to the isolation of chloride ion.This caused a sharp decrease in measured mass loss at a subsequent corrosion phase of 10%, 15%, and 20% compared with the unstrengthened specimens.As the ion channel was sealed by CFRP sheet in the tidal range zone of strengthened piles, the steel mass loss induced by corrosion was much smaller compared with poststrengthened and unstrengthened piles.The mass of strengthened pile CF20 was 66% lower than that of unstrengthened pile N20 at the end of the corrosion.The steel mass loss of the atmospheric and full submersible zone was also lower compared with unstrengthened group piles because of CFRP strengthening.These results indicate that the effect of improving pile corrosion occurred by strengthening the piles with a CFRP sheet.

Corrosion Expansion.
As the reinforcement corroded, the rust expanded more than six times in volume compared with the steel, as shown in Figure 8.
Due to the corrosion-induced expansive pressure in the unstrengthened piles, the strains of tidal zone were most severe, followed by the submersible zone and then the atmospheric zone (Figure 9), which is consistent with the process, its strain is much greater than that of the atmospheric and full submersible zones.And the strain in the atmospheric zone was slightly lower than that of the submersible zone during the corrosion stage because of the high concentration of chloride ion in seawater.
To strengthen the piles, the tidal range zone was covered by CFRP sheet and cut off from the corrosive medium, which delayed its corrosion.So the strains of the strengthened piles were smaller compared with the unstrengthened piles during the corrosion stage.At a steel mass loss of 10%, 15%, and 20%, the strain in the tidal zone was 29%, 36%, and 34% smaller than that of the unstrengthened piles and 17%, 12%, and 9% smaller than that of the poststrengthened piles, respectively.The strain in the tidal range zone was on average 5.6% and 11.6% smaller than that of the atmospheric and submersible zones, respectively, at the end of the corrosion because of the constraining force of the CFRP sheet that limited concrete expansion in the tidal zone.
For poststrengthened piles, the strain of the tidal range zone was smaller than that of the unstrengthened piles as the corrosion degree exceeded 10% because of the CFRP casing.The barrier formed by CFRP strengthening system in the tidal zone would significantly reduce the formation of the electrochemical system when the tidal zone was encased with CFRP at 5% corrosion degree.So the tidal zone exhibited a decreased strain growth compared with the strains of the full submersible and atmospheric zone.
The strain in the tidal range zone was smaller than that of the atmospheric and submersible zone at the end of the corrosion degree of 20% because of the confinement of CFRP sheet, like that of the strengthened group piles.As the corrosion increased, the strain value of the poststrengthened piles approached that of the strengthened piles.This indicates that CFRP strengthening is also an effective method to repair RC piles that had served for several years in marine environment.

Figure 3 :
Figure 3: Marine environment simulation system and electrical connection.

Figure 4 :
Figure 4: Tidal cycle of marine environment.

Figure 5 :
Figure 5: Temperature cycle of marine environment.

Figure 7 :
Figure 7: Theoretical and measured steel mass loss.

Table 2 :
Chemical compounds in sea water.
the corrosion degree of 10%.Rebar in the tidal range zone was in more active corrosion state compared with other two zones because it was wetted by cyclic tidal level which could provide an adequate source of chloride ions, water, and oxygen compared to other zones.

Table 3 :
Dependence between potential and corrosion probability.