The paper deals with the testing of microalloyed steels H300LAD and H380LAD under creep conditions. To test the properties of these steels, tensile and creep tests were carried out in the temperature range of 200–500°C. Torn samples were subjected to microscopic and submicroscopic observations. Microalloyed steels were compared with the alloyed steels C16E and 16Mo3 bypasses used at the same temperatures. The results of the experiments highlighted the possibility of application of microalloyed steels in operations within the specified temperature range.
Increasing the strength properties of traditional carbon steels is possible only by increasing either the carbon or manganese content in steel, which caused expressive significant decrease of brittle fracture and technological properties (weldability, flexibility). Alloying of low carbon steels, mainly using Nb, V, Ti (up to 0.15%), or other elements, in combination with thermomechanical processing, enables the obtaining of microalloyed steels; using especially grain and precipitation hardening, the high values of yield stress, up to 600 MPa, were attained, whereas the mechanical and technological properties were the same or even better [
These materials offer economic, environmental, and social benefits, when compared to the more commonly used steel grades, through a reduction in material usage, weight, and section size [
In order for the final product to be properly developed and applied, a number of factors must be considered when manufacturing individual components, including design, processes, inspection, and quality control of the structure [
The quality of steel can be defined, according to [
It is especially important to realize the examination of the quality of a material in relation to its purpose. The aim of this paper is to research the influence of temperature, ranging from 200°C to 500°C, on the strength and failure processes of microalloyed steels, considering the possibilities of application in constructing power equipment working at elevated temperatures of up to 500°C.
To determine the resistance of the examined materials to high temperatures, we have used a test procedure according to ISO 6892-1:2009 [
The reason for examining the resistance of microalloyed steels to high temperatures is because of their potential use in industrial practices, as a high-temperature protection shields for pipelines.
To determine the suitability of using microalloyed steels in operation at elevated temperatures, two types of microalloyed steel, H380LAD and H300LAD, were tested, and their characteristics were then compared to those of two alloyed steels, C16E and 16Mo3.
The structure of microalloyed steels consisting of a substitution-hardened, fine-grained matrix and fine, uniformly distributed precipitates in the matrix provides the precondition that their properties at elevated temperatures will be better than those of usual creep-resisting steels [
Figure
Microstructure microalloyed steels (a) H300LAD and (b) H380LAD.
Microalloyed steels are characterized by a ferrite–pearlite fine-grained structure with small quantities (max. 0.15%) of a combination of Al, Ti, Nb, and V; these elements are bound to C and N [
An increase in strength characteristics can be obtained using grain refinement and precipitation. Current high strength steels mean “steels with a nominal yield stress equal to or above 550 MPa.” The mechanical properties of the microalloyed steels are largely provided by the type of microstructure, which depends on the chemical composition and processing technology [
Experimental tests were performed on the cold rolling samples prepared from strips of steels with a thickness of 8 mm. All samples were cut in the rolling direction. The chemical compositions of the steels are given in Table
Chemical composition of tested microalloyed and standardly-used steels.
Material | C |
Mn |
Si |
P |
S |
Al |
Ti |
Nb |
V |
Mo |
Cr |
---|---|---|---|---|---|---|---|---|---|---|---|
H380LAD | 0.007 | 0.860 | 0.020 | 0.011 | 0.005 | 0.037 | 0.013 | 0.038 | 0.003 | — | — |
H300LAD | 0.008 | 0.730 | 0.020 | 0.013 | 0.004 | 0.028 | 0.009 | 0.039 | 0.005 | — | — |
C16E | 0.150 | 0.500 | 0.150 | 0.040 | 0.040 | 0.150 | — | — | — | — | 0.250 |
16Mo3 | 0.120 | 0.500 | 0.150 | 0.040 | 0.040 | 0.150 | — | — | — | 0.300 | — |
Thermomechanical processing is a metallurgical process that combines mechanical and plastic deformation process. Thermomechanical processing is an effective method for ferrite grain refinement in microalloyed steels [
The testing process was carried out on microalloyed steel samples, H380LAD and H300LAD, according to ISO 6892-2:2011 [
Tested samples were prepared according to the standard ASTM A370 test method, and round bars were made (
The tensile test was initially carried out at room temperature (20°C) according to ISO 6892-1:2009, and at elevated temperatures, in the range of 200–500°C, according to ISO 6892-2:2011. The results are shown in Table
Tensile testing under static conditions at elevated temperatures.
|
Material | |||||||
---|---|---|---|---|---|---|---|---|
H300LAD | H380LAD | 16Mo3 | C16E | |||||
|
|
|
|
|
|
|
| |
20 | 301 | 425 | 385 | 492 | 270 | 450 | 215 | 390 |
200 | 297 | 444 | 363 | 496 | 255 | 421 | 202 | 372 |
300 | 273 | 403 | 282 | 460 | 203 | 402 | 183 | 351 |
350 | 253 | 363 | 246 | 452 | 196 | 351 | 171 | 322 |
400 | 242 | 359 | 257 | 425 | 185 | 346 | 152 | 285 |
450 | 202 | 303 | 229 | 374 | 177 | 302 | 142 | 268 |
500 | 190 | 250 | 204 | 328 | 167 | 272 | 131 | 232 |
Uniaxial creep testing in tension involves a tensile specimen under a constant load at a constant temperature. Stress rupture testing is like creeps testing aside from the stresses being higher than those utilized within a creep testing. Stress rupture tests are utilized to find out the time it takes for failure, so stress rupture testing always continues until failure of the material occurs. The stress rupture test is used to determine the time to failure. Creep testing at the specified strain rates and temperature is carried out using HTC-50B Stress Rupture and Creep Testing Machine.
Then, creep tests were performed according to ISO 204:2009 [
To assess the creep properties of alloyed steels, stress rupture tests were performed. The duration of the tests was between 102 and 104 hours.
For metallographic analysis of the microstructure of fracture surface, an Olympus optical microscope (Vanox-TAH2) was used. The test results are shown in Figures
For a detailed analysis of the samples, metallographic analysis using a scanning electron microscope (JEOL JSM35-CF) was used. Test results are shown in Figures
The patterns of microalloyed steels precipitates (Figures
The specimens for microstructural studies were mechanically polished using standard metallographic procedures (according ASTM E3–11 Standard Guide for Preparation of Metallographic Specimens) and were etched with a 4 vol.% Nital solution.
The results of the creep test are the determination of the time to fracture (
Dependence of the time to fracture (
Dependence of the time to fracture (
The creep limit to tensile strength ratio is considered to be a creep-resistance characteristic of steels [
Ratio of
Experiments showed that the microalloyed steels tested favorably under creep conditions. The failure development stages of metal materials during high-temperature loading do not differ from a common fracture process, which is characterized by gradual local and time accumulation of individual forms of failure [
Fractures of steel. (a) Tensile specimens of C16E steel after creep exposition at 450°C; (b) fracture of H300LAD steel after creep exposition at 450°C.
Dependence of the contraction (
Close to fracture microstructure. (a) C16E after creep exposition at 450°C, 7120 h; (b) H300LAD after creep exposition at 450°C, 8930 h.
Fracture surface. (a) C16E after creep exposition at 450°C, 7120 h; (b) H300LAD after creep exposition at 450°C, 8930 h.
Substructure of (a) H300LAD and (b) H380LAD.
The failure process of C16E steel is presented in Figure
At fracture times, that is, under high stress, the fracture has a transcrystalline, or predominantly transcrystalline, character, as the high stress allows plastic deformation of the entire volume (Figures
The growth of V-shaped cracks takes place due to slippage along grain boundaries, which results in an intercrystalline fracture. The substructure of H300LAD, with precipitation, is shown in Figure
Hardening by the grain boundaries, which represents a crucial contribution of hardening of microalloyed steels at higher temperatures (up to 500°C) only, has an effect in short-time loading. In the creep conditions, the effect of this hardening on the stress rupture strength is neglected hardening.
This paper analyzes the influence of temperature, ranging from 200°C to 500°C, on the strength and the failure processes of microalloyed steels and compares it to standard-use, higher-quality alloyed steels. Based on the experiments and their analyses, the following can be stated: The failure characteristics of the tested microalloyed steels under creep conditions change depending on the fracture time. At short fracture times, cup-shaped fractures are formed, and, at longer fracture times, the fractures can be considered brittle. The fractures of C16E steel have a cup characteristic, up to the time to fracture of 104 hours. A crucial influence on the heat resistance of microalloyed steels is the contribution of precipitation. The creep limit ( On the basis of these test results and analyses, it can be stated that microalloyed steels can be well used to construct power equipment that works at elevated temperatures of up to 500°C.
A limitation of this research was the small number of test materials due to the time and energy intensity.
After the completion of the research, the studied materials were used for shields that prevent the escape of heat while protecting a pipeline against the adverse effects of high temperatures. Our experience shows that H380LAD is suitable for use, up to a temperature of 500°C, for the above-mentioned application in constructing power equipment.
The authors declare that there are no conflicts of interest regarding the publication of this paper.
Mária Mihaliková conceived and designed the study; Mária Mihaliková and Anna Lišková performed the experiments and analyzed the data; Kristína Zgodavová performed the theoretical analysis. All authors read and approved the manuscript.
This paper was developed within two projects supported by the Ministry of Education, Science, Research and Sport of the Slovak Republic: VEGA 1/0549/14 “The analysis of local properties of automotive steel in dynamic conditions” and VEGA 1/0904/16 “The utilization of processes capability and performance and products dimensional tolerances in the management of material consumption and related economic, energy and environmental consequences (MINIMAX-3E).”