Microstructures, Mineral Compositions, and Mechanical Properties of Red-Layers in Southern China

In order to reveal the water-induced damage mechanism and mechanical properties of red-layers in Southern China, typical redlayer samples are experimentally studied by scanning electronmicroscope (SEM), energy spectrum analysis, XRD, andmechanical tests. -e results show that some red-layer samples contain a large number of smectite and illite-smectite mixed-layer clay minerals and their microstructures are mainly stacked microaggregates in which mutual agglomeration is formed by flake and tabular clay particles. Widespread distribution micropores and fractures in microaggregates provide the necessary moisture migration channels. -e various cemented materials produce a kind of irreversible structural strength, and this strength is vulnerable for the aqueous medium conditions. -e influence of microstructures and mineral compositions on red-layer mechanical properties is discussed. -e results could provide the reference for further research about the water-induced damage mechanism of red-layers in Southern China.


Introduction
ere are widely distributed red-layers in Southern China, for example, in Yunnan, Guangdong, Guizhou, and Sichuan provinces.e red-layers in those areas are brownish red or brownish yellow clay soil or soft rock, which is the laterized product of carbonate rock.Mainly including expansive clay minerals, soluble minerals, or organic minerals, the redlayers have many special engineering geological properties in comparison with common clay.In general, most redlayers have high water content, high plasticity, large pore ration, and low density, the physical and mechanical properties of red-layers are easily affected by water [1,3].Engineering construction disturbance or water intrusion will induce damage in microstructures or/and change in mineral compositions, which could cause the red-layers rapidly expanse and collapse.Such complex properties bring a serious impact on the safety and stability of major engineering construction in those regions [4][5][6][7][8][9]; for instance, squeezed muck wear formation ahead of shield cutters seriously affected Guangzhou Metro Lines construction speed (Figure 1, [10,13]).
e physical and mechanical characteristics of red-layers or clay soil have been widely studied.Mendes and Toll [14] revealed that the critical state stress ratio is not affected by the initial water content, and the volumetric behavior differences lead to sample property differences when samples are subjected to wetting and drying after compaction.Chavali et al. [15] investigated the alkali-induced swelling in nonswelling kaolinitic clays, and the results showed that the magnitude of alkali-induced swelling in the clays is attributed to dispersion of clay particles and formation of new mineral.Harjupatana et al. [16] developed a noninvasive method for simultaneous measurement of the 3D displacement field and the water content distribution of a wet solid material and applied it in validating models involving transport of water and the resulting swelling deformation of bentonite.Aziz et al. [17] revealed that the observed soil behavior could be critical for embankments constructed with rock-fill materials.Wong et al. [18] reviewed the research of strength and stiffness reduction in rocks attributed to an increase in water content in recent years.Ma et al. [8] conducted a series of constant water content triaxial tests on statically compacted specimens, the results showed that Yunnan red clay failure envelope is affected by its saturation degree, and a new semiempirical shear strength model in terms of degree of saturation could be proposed.Zhao et al.'s [6] experimental results showed that the damage form of the remodeled red clay changed from the ballooning excessive damage to shear failure with the reduction of water content.Zhang et al. [7] proposed and verified a X-ray computed tomography (CT) method to nondestructively measure the water content of red clay cylinders, and the test results showed that the rainfall, ground water level, and degree of compaction are factors that could significantly affect the moisture migration distance and migration rate.Hu et al. [9] investigated the effect of water content on the stable swelling capacities, swelling process, and characteristics of red bed mud-stone, the results revealed that there were three phases exiting in the confined free sweeling test, and vertical loads greatly restrained the confined swelling.However, limited studies have been conducted on the relationship of red-layer mechanical properties and its microstructure and composition changes.Some studies showed that changes in mineral compositions and microstructures yielded macroscopic degradation of mechanical parameters [3,[19][20][21]; therefore, the relationships of mechanical behaviors and microstructure and mineral compositions of red-layers should be fully investigated.
In this study, for investigating mechanical behaviors of red-layers influenced by microstructures and mineral compositions, a series of experimental tests are conducted on redlayer specimens which are sampled in Guangzhou Metro Line.  1.For other details of the samples, see Liu and Zhang [22].

Sample Preparation
e samples' lithologies are shown in Figure 2.
e specimens for all mineral XRD tests are prepared as follows: (1) the core of the rock or soil sample block is dried for 48 h in an electric oven below 60 °C, and then the specimens are cooled to room temperature.(2) 1-2 g of the samples is crushed to less than 1 mm particle size by a grinding machine, and then the particles are ground to the whole particle size of less than 40 µm.(3) e aluminum sample frame is closely placed on the flat glass plate, and the sample powder is spooned into the 20 mm × 18 mm framework and is vertically compressed for molding.e lower side is adopted for the test surface.
e sample preparation for XRD tests of the relative clay mineral content is as follows: (1) the air-dried sample is crushed to a particle size of less than 1 mm, the crushed power is placed into the beaker, and then the sample is soaked with distilled water and dispersed by the ultrasonic treatment.(2) e suspension with a particle size of less than 2 µm is drawn and centrifuged for accelerating the clay mineral settlement.(3) e centrifuged sample is then dried for 48 h in an electric drying oven below 60 °C, and the dried sample is ground to finer particles by an agate mortar.(4) 40 mg of the dried sample particle is placed into 10 ml tubes and 0.7 ml of distilled water is added into the tubes; after complete stirring, the clay mineral is fully dispersed by the ultrasonic treatment, the suspension is quickly placed on glass slides and air-dried, and then a natural directional sheet (N) is prepared.(5) After the experiment, the glycol vapor is used to make a glycol saturated tablet (NG) by heating a natural directional sheet (N) at 40-50 °C constant temperature for 7 h, and then the sheet is cooled to room temperature.(6) At the end of the experiment, the glycol saturated tablet (NG) kept at 550 °C constant temperature for 2 h, and then the specimen is cooled to room temperature to make a heating sheet (550 °C).
ere is a time interval between the sampling and the test.For more realistic viewing of microstructures of the redlayers, it is necessary to remake the specimen.e specimens for SEM analysis are prepared as follows: (1) After removing surface, the samples are immersed in pure anhydrous alcohol for 30 minutes, and then the pure anhydrous alcohol is replaced with anhydrous alcohol to ensure the purity of the alcohol before the test.e purpose of using anhydrous alcohol is to ensure original microstructures of the specimen, because anhydrous alcohol is easily evaporated and carries away the residual moisture in the samples.(2) e samples are air-dried and then are cohered on the table, and heavy metal membrane are sprayed on surfaces to avoid discharge phenomenon.(3) 30 mm thickness heavy metal membrane is sprayed on the morphology analysis samples.
e energy spectrum analysis samples are without metal spray coating to avoid the metal film effects on test precision.

Experimental Test
e typical tests for analyzing the microphysical property of red-layers are SEM analysis which include micromorphology

Analysis of Scanning Electron Microscope and Energy Spectrum Test Results.
e mineral compositions are expressed as follows: C � chlorite; I � illite; S � smectite; Na-F � albite; I/S � illite and smectite mixed layer; K � kaolinite; K-F � kaolinite and potash feldspar mixed layer; Q � quartz crystal; I/C � illite and chlorite mixed layer; C/S � chlorite and smectite mixed layer.
e SEM images of Tiyu west road station red clay samples are shown in Figure 3, which shows that the soil samples are relatively loose and the larger pores between the particles are about 100-200 µm with the great connectivity.
e samples contained a lot of honeycomb and flaky illite and smectite mixed layer, a small amount of needle-like chlorite and flake-flocculent chlorite and smectite mixed layer, and authigenic polyhedral quartz and strip albite crystal existing in particles.
e SEM images of Zhujiang new city station red clay samples are shown in Figure 4.It could be known from Figure 4 that the soil samples are relatively loose, and the larger pores between the particles are with the diameter of 30-100 µm with the good connectivity.e samples contain a large number of flake-flocculent illite and smectite mixed layer, illite and chlorite mixed layer, layered illite, and flake kaolinite.
e local parts of the samples contain leached surface potash feldspar crystals.Under the magnification of 9440-20,000 times, a large number of flake aggregates could be observed.
e SEM images of Wushan road station red clay samples are shown in Figure 5.One could see from Figure 5 that the red  e energy spectrum analysis of red clay samples are carried out by the LINKISIS-type energy spectrometer; for simplicity of consideration, only the scanning images of Tiyu west road station red clay samples are given (Figure 6).Tiyu west road station red clay samples contain a large number of illite and smectite mixed layer, chlorite and smectite mixed layer, massive albite crystals, and filamentous chlorite.ere are massive authigenic quartz crystals spreading between the particles.Zhujiang new city station red clay samples contain a lot of orderly flake, disorderly

Analysis of X-Ray Diffraction
Results. e three clay minerals and three nonclay minerals samples are tested by the XRD.e results are analyzed in accordance with "X-ray diffraction analysis of the relative content of clay minerals in sedimentary rocks" and "X-ray diffraction quantitative analysis of the clay mineral aggregate and common nonclay minerals in sedimentary rocks" [23,24].For the clay mineral XRD test, each soil sample has three piece directional diffraction and three diffraction patterns named "natural directional sheet" (N), "ethylene glycol" (NG), and "saturated tablet 550 °C heating plate" [25,27].
e clay mineral compositions can be identified according to the diffraction characteristics of three diffraction patterns such as diffraction peak or diffraction angle and peak value.
e relative content can be determined by diffraction intensity.If the pattern is not very standard characteristic, or the diffraction patterns are between the two components, it can be identified as a mixed layer of illite and smectite, or chlorite and smectite mixed layer.
For simplicity of consideration, only diffraction pattern of Tiyu west road station red clay samples is shown in Figure 7.It is revealed that the soil samples mainly contain smectite and illite, and the relative content of smectite and illite is 54% and 46%, respectively.Other clay mineral components in the diffraction are not found.
e XRD results of the remaining samples are shown in Table 2.
e XRD results of typical nonclay minerals of Zhujiang new city station samples are shown in Figure 8.It is shown that the content of clay minerals is 39.9%, and the main nonclay minerals are 45.7% quartz and 10.9% plagioclase, respectively.e hematite content is 3.5%, and other nonclay minerals are not found.e test results are shown in Table 3.

Conclusion and Discussion
e typical Southern China red-layers rock and soil samples are experimentally studied by SEM, energy spectrum analysis, XRD, and mechanical tests, and then the results are analyzed.rough this research, we can draw the following conclusions: (1) e local area of red-layers in Southern China contains a large amount of smectite, illite, and smectite mixedlayer clay minerals.e microstructures are mainly layered or stacked microaggregates which are formed by the agglomeration of flaky and flat clay particles.e penetrated or partially penetrated cracks separate the lamellar structures.e stacked microaggregates are the main structural basic units which make up the microstructures and determine the swelling and shrinkage properties of the complex red-layers.e large amount of fine-grained expansion clay minerals is the main material basis for determining the complex red-clays properties.It is also an important internal factor which impacts its engineering properties such as water swelling, easily sliming, and strong viscosity [21,[28][29][30].
(2) e cohesion of various cemented materials in the stacked microaggregates enhances the structural connection between microaggregates of complex red soils, and the cohesion results in a certain structural strength.is structural strength is also a kind of irreversible bond strength which is formed by the physical and chemical connection.While disturbed by construction or intruded by water, or the solution medium conditions in the rock or soil changed, the physical and chemical properties of cemented material will be very different, the structural strength of microaggregates will be lost, the total strength of the complex red-layers will decrease, and the rate of expansion will increase.
Influence of water content on the red-layer specimens is a complex phenomenon.e water-induced changes in microstructures and mineral compositions yield degradation of physical and mechanical parameters.erefore, it is important to analyze the effects of water content on the degradation mechanisms of the specimens, as those conditions are considered during the aforementioned experiments.
e typical red-layers samples have layered or honeycomb microstructures and easily water swelling and weakening minerals such as chlorite and smectite.e pores between the particles have good connectivity which provides the water invasion tunnels.With the lower water content, the particles and layers make good contact with each other and the contact surface is flat and smooth, forming good microstructures which induce relatively good physical and mechanical properties.
During the process of water content increasing, the water infiltrates inside the specimen.e chemical reactions such as dissolution and corrosion occur in the mineral particles, and the chemical migration and dissolution occur at the cemented Advances in Materials Science and Engineering or contact surfaces between mineral particles, which can make the mineral compositions and microstructures change and the macro physical and mechanical degradation of the specimens.Since the red-layers specimens comprises many minerals which can easily expand in the water, under water invasion the cracks would likely propagate by the stress concentrated at the crack endpoints [31].It is favorable for the formation of infiltration channels and water molecules seepage within the specimens.e reactions between minerals and aqueous solution are accelerated, which increase the change in microstructures and promote the extension and coalescence of cracks and microtunnels.ese factors are the mechanism of water content effect on the red-layer properties like shear strength, swelling, creep, and so on.
(3) e swelling behavior of microaggregates affects water migration, water-induced damage, and rheological properties.e test results show that the complex redlayers comprise a large amount of lamellar microaggregates formed by flaky and flat clay particles.e thickness of the monolithic slice is about 10 Å, the length of the monolith is 1-2 µm and the width is 2-5 µm, and the lamellar microfracture width is 0.1-0.5 µm.ere are the electrostatic repulsion, Van der Waals force, and hydration force existing between the stacking layers.e microaggregates structure arrangement state and the distance between the two relatively independent slices play a major role in the red clay hydration (volumetric chemical potential) at certain water content.
e strong viscosity of redlayers under certain water content is due to its surface to surface microstructures in layered microaggregates.

Figure 7 :
Figure 7: X-ray diffraction pattern of red clay in Tiyu west road station.

Figure 8 :
Figure 8: Total mineral X-ray diffraction pattern of red clay samples in Zhujiang new city station.

Table 1 :
Microexperimental soil samples of typical red-layers.

Table 2 :
XRD results of the remaining samples.

Table 3 :
All mineral XRD test results.