Effect of Temperature on Concrete Carbonation Performance

School of Civil Engineering, Central South University, 22 Shaoshan Road, Changsha 410075, China National Engineering Laboratory for High Speed Railway Construction, 22 Shaoshan Road, Changsha 410075, China School of Civil Engineering, Central South University of Forestry and Technology, 498 Shaoshan Road, Changsha 410004, China National and Provincial Joint Engineering Laboratory of Road & Bridge Disaster Prevention and Control, Lanzhou Jiaotong University, Lanzhou 730070, China


Introduction
Concrete carbonation is a neutralization reaction between carbon dioxide (CO 2 ) penetrated into concrete from surrounding atmosphere and the alkaline hydration products (e.g., calcium hydroxide) in concrete [1].Concrete carbonation can cause a local fall of alkalinity of pore solution due to the consumption of calcium hydroxide [2].
e reduction of the concrete alkalinity can destroy the passive film initially formed around the steel reinforcement and thus lead to the corrosion of reinforcing steel when both moisture and oxygen are present there [3].During the past few decades, plenty of achievements have been obtained [4,5], which mainly focused on water to cement ratio [6], crack and freeze-thaw [7], admixtures [8,9], loading [10], and initial curing period [11].Meanwhile, the effects of environment factors including temperature, carbon dioxide concentration, relative humidity, and loading on concrete carbonation have also been investigated [12][13][14].In view of the increasing amount of temperature around the world, the deterioration effect of temperature on concrete carbonation becomes even more serious.Carbonation of concrete becomes a different durability problem, which accelerates the degradation of reinforced concrete structures.erefore, it is significant to investigate the effect on concrete carbonation.
e objective of this study is to investigate the effect of temperature on concrete carbonation.Macroperformance (i.e., compressive strength, carbonation depth, and strain) and microcharacteristics (i.e., composition phase, microstructure, and carbonation products) of carbonized concrete under different temperature were measured.Polycarboxylic acid series of the high-efficiency superplasticizer which contained 30% of solid was made by Hunan Changsha Huangteng Co., Ltd. e fly ash was produced by Hunan Xiangtan Power Plant.CO 2 gas was provided by Changsha Fanggang Gas Company. e mix proportion of concrete is listed in Table 1.

Experimental Process. According to GBT 50082-2009
Standards on Test Method of Ordinary Concrete Long-term Performance and Endurance, the concrete specimens with a size of 100 mm × 100 mm × 300 mm and 100 mm × 100 mm × 100 mm were cast and demoulded after 24 h.e specimens were cured at the temperature of (20 ± 1) °C and the relative humidity of (95 ± 5)% for 28 d.Subsequently, specimens were dried for 48 h at 60 °C, and the concrete carbonation test were conducted under different environments (Table 2) provided by the environmental simulation test system.e carbonation depth, compressive strength, and surface strain of concrete were measured, when the carbonation test was lasted for 28 d.
e concrete prisms used to test the carbonation depth were prepared as follows: two opposite sides of concrete prism with a size of 100 mm × 300 mm were reserved, and the rest sides were sealed by using epoxy resin.According to GB/T 50082-2009 Standards for Test Methods of Long-Term of Performance and Durability of Ordinary Concrete, the carbonation depth of concrete was observed by spraying a phenolphthalein solution onto the surface of a split concrete prism.Ten measured points on the cross section of the specimen were measured, and the corresponding average value was set as the carbonation depth with a precision of 0.1 mm.Mechanical properties of concrete were tested according to GB/T50081-2002 Standards on Test Method of Ordinary Concrete Mechanical Properties with the loading rate of 3 kN/s.e prism specimen used to test the concrete surface strain was conducted with the imc data acquisition system, and a strain gage was pasted on the middle of concrete surface.

Test Instruments and Devices.
Test instruments mainly included Quanta-200 environment scanning electron microscope (ESEM) made by FEI Company (USA), BD-86 X-ray diffraction (XRD) produced by Rigaku Company (Japan), WAW-DP Universal tester was provided by Shanghai Sansi Co. Ltd. (China), and the environmental simulation test system was made by Wuhan Jinyatai Instrument Co., Ltd.(China).Moreover, the imc data acquisition system with sixteen channels was provided by Integrated Measurement and Control Co. (Germany).

Effect of Temperature on Macroperformance of Carbonized
Concrete.Due to temperature accelerating the carbonation rate, the effect of different temperatures (i.e., 10 °C, 20 °C, and 30 °C) on concrete compressive strength after carbonation for 28 d was investigated.Figure 1 shows the change of concrete compressive strength with temperature.e corresponding test was set with the carbon dioxide concentration of 20% and relative humidity of 70%. Figure 1 indicates that there was a significant relation between carbonation temperature and concrete compressive strength after carbonation, which could be described by a linear function.
e concrete compressive strength after carbonation decreased with the increase of temperature, which may be a result of carbonation reaction of CO 2 with hydration products, such as calcium hydroxide (i.e., CH), calcium silicate hydrate (i.e., C-S-H), ettringite (i.e., AFt), and calcium aluminate hydrate (i.e., C-A-H) in concretes.With carbonation, the hydration products of concrete were gradually decomposed, and new substances without cementitious property were generated.Composition change of concrete induced the deterioration of microstructure, which manifested as the degradation of mechanical property in macroperspective.In brief, the carbonation of concrete was the change of hydration products and the destruction of chemical-state equilibrium of the cementitious system.Moreover, the reduction rate of concrete compressive strength after carbonation was also affected by concrete strength grade, and it may be caused by the compactness of microstructure, which could affect the transmission coefficient of CO 2 in concrete.
Macroperformance of carbonized concrete can also be represented by carbonation depth.Hence, the influence on concrete carbonation depth was measured, and Figure 2 shows the change of concrete carbonation depth with temperature.
Figure 2 shows the relation between concrete carbonation depth and temperature could also be characterized by a linear function, which manifested as the concrete carbonation depth increased with temperature.Under the same carbonation condition, the concrete carbonation depth decreased with the increase of concrete strength.
at is due to high temperature enhancing the transmission coefficient and reaction rate of carbon dioxide, so the carbonation degree and depth of concrete specimens were more significant.With the increase of concrete strength, the concrete manifested as denser microstructure, lower porosity, more sinuosity, and smaller openness of pores.erefore, CO 2 transmitted in concrete with difficultly.Moreover, the carbonation products generated in pore of concrete could fill some pores, which improved the characteristic of pore and decreased the carbonation reaction in concrete.
Due to the carbonation that reacted from concrete surface to the inside, the change of concrete surface can be used to represent the characteristic of concrete carbonation.Using C20 as an example, the influence of temperature on concrete surface strain was investigated.e prism concrete specimens were used to measure the surface strain according to Section 2.2. Figure 3 shows the curves of concrete surface strain with temperature.
As seen from Figure 3, the effect of carbonation temperature on concrete surface strain was obvious, which manifested as the strain value and slope of linear segment of the strain curve.Compared with noncarbonation concrete, the absolute value of slope of the concrete strain curve after carbonation notably decreased with carbonation temperature.Carbonation could induce the degeneration of 2 Advances in Materials Science and Engineering mechanical performance, decomposition of hydration product, and looseness of microstructure, so the elastic modulus and bearing capacity of concrete after carbonation significantly decreased.e higher the carbonation temperature was, the more significant the concrete carbonation was.erefore, the concrete surface strain was more obvious with carbonation temperature.

Effect of Temperature on Microcharacteristic of Carbonized Concrete.
In order to investigate the characteristic of carbonation, the microcharacteristic of carbonized concrete was studied.Figure 4 is the phase composition and hydration products of samples analyzed by XRD.
Figure 4 indicates that there was a significant difference of concrete samples before and after the carbonation.e XRD spectrum of noncarbonation specimens indicated the main hydration products were CH, AFt, C-S-H, and C-A-H.
Temperature had an observable effect on carbonation products and phase composition, which manifested as the disappearance and attenuation of some products' diffraction     Advances in Materials Science and Engineering peaks (i.e., CH and AFt) and the generation and enhancement of the carbonation product (i.e., CaCO 3 ).As seen from Figure 4, the intensity of diffraction peaks of carbonation products enhanced with temperature.at may be caused by the temperature inducing the rise of carbonation rate, and more carbonation products were generated.Microstructure, morphology, and carbonation product of samples under different temperatures were also measured, as shown in Figure 5.
Figure 5 implied the carbonation temperature had a significant effect on phase composition, microstructure, morphology, and hydration products.Hydration products of noncarbonation sample were mainly hexagonal platelike CH, rod-like AFt, flocculent C-S-H, and C-A-H (Figure 5 e above results implied the temperature could determine the crystal form of carbonation product.In addition, the particle size of carbonation products of the sample was different.

Conclusions
(1) e effect of environmental temperature on concrete carbonation was investigated.e experimental results showed the carbonation depth and compressive strength of concrete manifested as a linear relationship with temperature.Concrete carbonation depth increased with the increase of temperature, but the compressive strength of concrete after carbonation decreased with the strength grade of concrete.is was because CO 2 transmission coefficient and chemical reaction coefficient may increase with temperature.
(2) e effects of temperature on concrete surface strain after carbonation manifested as the strain value and the slope of linear segment of strain curve.Phase composition, hydration products, and microstructure of concrete changed significantly before and after the carbonation.Such changes were mainly manifested by disappearance and weakening of diffraction peak of some hydration products.XRD and ESEM spectral analysis revealed that the carbonation product was mainly calcium carbonate.Temperature affected the crystal form of carbonation products.Polyhedral spherical vaterite was major  Advances in Materials Science and Engineering carbonation products at 10 °C and 20 °C, whereas aragonite was the major carbonation products at 30 °C.

Figure 1 :Fitted
Figure 1: Curves of concrete compressive strength with temperature.

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(a)).Nevertheless, there were few gelling hydration products in microstructure of carbonized specimens and particulate CaCO 3 in pores (Figures 5(b)-5(d)).EDS analysis indicated the carbonation product of the sample at 10 °C and 20 °C was polyhedral vaterite (Figures 5(b) and 5(c)).However, the hydration product of carbonized samples was aragonite at a temperature of 30 °C.