Synthesis and Characterization of New Photoluminescent Oxadiazole/Carbazole-Containing Polymers

We report on the synthesis and the characterization of a new class of segmented polyethers POC containing the oxadiazole and carbazole units. The polymers exhibit a high thermal stability, high glass transition temperatures, and good solubility in common organic solvents, despite the extended aromatic portion in the main polymer chain. The synthetic procedures are simple, and no acid side-products are obtained. According to previous reports on oxadiazole/carbazole-containing materials, POCs show high photoluminescence activity in the blue region of the visible spectra. The good solubility in chlorinate solvents allows the preparation of films with homogeneous thickness by spin coating. Glass transition temperature in the range 115–125◦C ensures good stability of film morphology at room temperature. The only exception is POC(6), which shows a poor solubility and higher Tg (170◦C), due to its shorter aliphatic chain portion. For these features, polymers POC are potential candidate materials for fabricating blue light-emitting devices.

To improve the electron transfer in PLEDs, researchers usually spin a p-type polymer on an n-type polymer with electron transport properties. But this kind of multilayer system may suffer difficulties in spinning a polymer solution on an organic film, which can easily dissolve. To deal with this issue, polymers containing both hole-and electrontransporting moieties have been prepared. Recently, polymers with either electron-withdrawing (such as oxadiazole, diphenylquinoline, etc.) or electron-donating groups (such as triphenylamine, carbazole, etc.) have been prepared [14][15][16][17].
Oxadiazole/carbazole derivatives having good solubility, high quality film formation, and a strong blue emission can play a very important role in organic/polymeric optoelectronic materials, and they can be used as single-layer materials for OLEDs.
In this work we report on the synthesis and characterization of a series of oxadiazole/carbazole-containing polymers (POCs), having the formula mentioned in Scheme 1, where n is 12 or 6 for the two homopolymers and 12 and 6 or 8 and 4 for the two copolymers. The synthetic procedures are based on the Williamson condensation reaction. All the polymers show high glass transition temperatures and good solubility in common organic solvents. According to previous reports on oxadiazole/carbazole-containing materials [18], POCs show high photoluminescence activity in the blue region of the visible spectrum. Compared to the low-molecular-weight compounds, the new polymers show higher thermal stability and the possibility to be processed in high-quality thin films by solution casting or spin coating. (DMAc) and N,N-dimethylformamide (DMF) were refluxed on calcium hydride, distilled in vacuum, and stored on 4Å molecular sieves. Other reagents were used without further purification. 2-(4-carbazol-9-yl-butoxy)-terephthalic acid dihydrazide was synthesized according to a previously reported procedure [18].

Synthesis of Compound 1.
To a suspension of compound 2-(4-carbazol-9-yl-butoxy)-terephthalic acid dihydrazide (0.00460 mol, 2.00 g) in dry DMAc (50 mL) at room temperature, the 4-acetoxybenzylchloride (0.0101 mol, 2 : 1 + 10%) was added and the reaction was left to take place overnight under stirring. The reaction mixture was then poured into cold water (600 mL) and the resulting solid product was filtered, washed twice with water, and dried under vacuum. m.p. = 256 • C. The product was used in the subsequent intramolecular ring closure reaction. The proton resonance data are in agreement with the expected values.

Synthesis of Compound 2.
The freshly synthesized azide 1 (1.0 g) was poured in 80 mL of phosphorous oxychloride (POCl 3 ); the reaction was conducted at refluxing temperature for 5 hours. The mixture was then slowly dropped into ice water (600 mL), and a precipitate was collected. The crude product was then hydrolyzed with 500 mL of aqueous KOH (pH = 12-14), under stirring at 50 • C. The clear solution was finally neutralized to pH = 7, and the final product (compound 2, Scheme 2) was purified by crystallization from DMF/water to obtain pale yellow crystals, with m.p. =   Figure 1.
For the other polymers of the series, the spectra are similar, the difference is only in integration of the signals for the -CH 2 -aliphatic group in the interval (1.62-1.32) ppm.

Characterization.
Thermal measurements were performed by a DSC-7 Perkin Elmer calorimeter under nitrogen flow at 10 • C/min rate.
Thermogravimetric analysis was performed with a TA Instruments SDT 2960 apparatus, in air at 20 • C/min. X-ray diffraction spectra were recorded using a flat camera with a sample-to-film distance of 90.0 mm (uni-filtered Cu K α radiation). The Fujifilm MS 2025 imaging plate and a Fuji Bio-imaging Analyzer System, mod. BAS-1800, were used for recording and digitizing the diffraction patterns. 1 H NMR spectra were recorded with a Brucker DRX/400 Spectrometer. Chemical shifts are reported relative to the residual solvent peak.
UV-Vis measurements were performed by a Perkin Elmer Lambda 800 Spectrophotometer and photoluminescence was recorded by a Jasco FP-750 Spectrofluorometer.

Structural and Calorimetric Characterization.
The structure of all polymers POC was confirmed by proton NMR analysis. The NMR spectrum of POC (12,6) in deuterated chloroform solution is reported in Figure 1 as a representative example. Thermodynamic data of POC are listed in Table 1. From the DSC analysis only the glass transition temperature is observed, which indicates that POCs, as obtained from the synthesis, are amorphous polymers, with glass transition temperatures depending on the length of aliphatic segments in the main chain. As expected, shorter aliphatic chains lead to higher T g while intermediate values are observed for the copolymers with mixed length of chains.
Glass transition temperature in the range 115-125 • C ensures good stability of film morphology at room temperature. The only exception is POC(6), which shows a poor solubility and higher T g (170 • C), due to its shorter aliphatic chain portion. As an example, DSC trace of POC(8,4) is reported in Figure 2. The X-ray diffraction pattern of virgin samples of POC, recorded at room temperature is reported in Figure 3. It shows a broad halo, confirming the amorphous nature of the polymers.   In the thermogravimetric plots of POC, the degradation process, indicated with a single shoulder, is observed starting at a temperature of about 400 • C. This indicates stability of POC at temperatures lower than about 350 • C ( Table 1). As an example, thermogravimetric trace of POC (12,6) is reported in Figure 4.
POCs are easily soluble in a series of organic solvents; in particular, good-optical-quality films are obtained from chloroform or DMF (Table 1).

Optical and Photoluminescence Characterization.
All POC polymers show similar absorption and emission spectra. As a representative example, UV and fluorescence spectra of POC (12,6) in chloroform solution are reported in Figure 5.
In analogy with our previous paper on low-molecularweight carbazole/oxadiazole compounds [18] and on oxadiazole-containing polymers [19][20][21], the carbazole moiety absorbs at lower wavelength (strong peak at 292 nm) with International Journal of Polymer Science  respect to the oxadiazole unit (two strong and broad peaks at 322 and 345 nm) and emits in the wavelength range (two strong peaks at 354 and 369 nm) where the oxadiazole unit strongly absorbs. The result is that POCs show a strong blue emission, identical to that of analogue oxadiazole-containing polymers; in particular, the emission occurs at 407 nm (main peak, sharp) and at 460 nm (lower peak, broad band). The good solubility in chlorinate solvents and DMF allows the preparation of films with homogeneous thickness by spin coating.

Conclusions
The new synthesized carbazole/oxadiazole-containing polymers (POCs) are blue photoluminescent materials. Taking advantage of the steric constraints due to the side insertion of carbazole unit to the oxadiazole moiety and to the insertion of flexible aliphatic segments in the main polymer chain, POCs are soluble in chlorinate organic solvents or DMF and they can be easily processed to homogenous films. The synthesized polymers show strong photoemission in the blue region of the visible spectrum. Taking advantage from these features, POC could be good candidate materials for the realization of single-layer organic LED.