Journal of Nanomaterials

Volume 2013 (2013), Article ID 702679, 8 pages

http://dx.doi.org/10.1155/2013/702679

Research Article

Synthesis of h- and α-MoO₃ by Refluxing and Calcination Combination: Phase and Morphology Transformation, Photocatalysis, and Photosensitization

Pannipa Wongkrua,¹ Titipun Thongtem,¹ and Somchai Thongtem2,3,4

¹Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand

²Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand

³Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand

⁴Science and Technology Research Institute, Chiang Mai University, Chiang Mai 50200, Thailand

Received 29 April 2013; Accepted 18 June 2013

Academic Editor: Chunyi Zhi

Copyright © 2013 Pannipa Wongkrua et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract.

Hexagonal molybdenum oxide (h-MoO₃) nano- and microrods were successfully synthesized by refluxing of (NH₄)₆Mo₇O₂₄·4H₂O solutions with the pH 1 at 90°C for 1, 3, 5, and 7 h and were further transformed into orthorhombic molybdenum oxide (α-MoO₃) microplates by calcination at 450°C for 6 h. These selected products were used to determine the degradation of methylene blue dye under 35 W xenon lamp for 0–180 min, due to the photocatalysis and photosensitization processes. In this research, catalytic activity of the metastable h-MoO₃ has higher efficiency than that of the thermodynamically stable α-MoO₃. Their phase and morphology transformation was also explained according to the experimental results.

1. Introduction

MoO₃ is one of the transition metal oxide materials. It has a wide range of applications such as imaging devices, smart windows, electrodes of rechargeable batteries, gas sensors, and supported catalysts [1]. Since MoO₃ is a 3.15 eV wide band gap n-type semiconductor, it is well known as one of the most widely used photocatalysts. Its catalytic efficiency has long been known, for example, in alcohol and methane [2, 3]. Its crystalline structures are known to have three common polymorphs: one thermodynamically stable orthorhombic MoO₃ (α-MoO₃) and two metastable phases hexagonal MoO₃ (h-MoO₃) and monoclinic MoO₃ (β-MoO₃). The MoO₆ octahedrons are the basic building units of all MoO₃ structures. For α-MoO₃, the MoO₆ octahedrons share edges and corners, resulting in zigzag chains and a unique layer structure. But for β-MoO₃, it has a ReO₃-related structure, in which the MoO₆ octahedrons share corners to form distorted cubes. The h-MoO₃ is also composed of the same zigzag chains of MoO₆ octahedrons connecting through the cis-positions [1, 4]. Moreover, h-MoO₃ exhibits phase stability up to 436°C at which the irreversible phase transition occurs to form orthorhombic α-MoO₃ [5]. Various molybdenum oxide structures and morphologies have been synthesized by different methods: hexagonal rod-like h-MoO₃ by liquid phase deposition [1], nanospheres by ultrasonic-assisted synthesis [3], hexagonal rod-like h-MoO₃ by precipitation [4, 6], MoO₃ nanorods by ultrasonic synthesis [5, 7], α-MoO₃ nanobelts by hydrothermal synthesis [8, 9], h-MoO₃ rods by solution precipitation and solvothermal treatment [10], MoO₃ nanostructures by solution combustion [11], α-MoO₃ polycrystalline thin films by spray pyrolysis [12], MoO₃ nanobelts by hydrothermal method [13, 14], h-MoO₃ and α-MoO₃ nanoparticles by hydrothermal synthesis [15], h-MoO₃ nanorods by precipitation [16, 17], α-MoO₃ microplates by microwave plasma process [18], and α-MoO₃ nanocrystals by oil bath heating and sintering combination [19].

In this research, both hexagonal and orthorhombic molybdenum oxide phases were synthesized by refluxing process to form the first and followed by high temperature calcination to form the second. Different phases, phase and morphology transformation (PMT), degradation of methylene blue dye, and mechanisms of photocatalysis and photosensitization are also discussed.

2. Experimental Procedures

To synthesize h-MoO₃ and α-MoO₃ with different morphologies, 0.005 mole ammonium heptamolybdate tetrahydrate ((NH₄)₆Mo₇O₂₄·4H₂O) was dissolved in 40 mL of deionized water with continuous stirring at room temperature for 30 min. Subsequently, 2 M HNO₃ was added to the solution until achieving the pH 1 and forming of the clear solution. The solution was processed by a refluxing method at 90°C for 1, 3, 5, and 7 h. In the end, light-blue precipitates were synthesized, separated by filtration, washed, and dried in an electric oven at 80°C for 24 h. The products were further calcined at 450°C for 6 h to form powders.

Crystalline phases, morphologies, and vibration modes were characterized by a Philips X’Pert MPD X-ray diffractometer (XRD) at 45 kV and 35 mA with Cu Kα radiation in the 2θ range of 20–80 deg with a scanning rate of 0.04 deg per step, a JEOL JSM-6335F scanning electron microscope (SEM) with an accelerating voltage of 15 kV across the LaB₆ cathode, a JEOL JEM-2100F transmission electron microscope (TEM) and selected area electron diffraction (SAED) at 200 kV, and a Bruker Tensor 27 Fourier transform infrared (FTIR) spectrometer with KBr as a diluting agent operated in the range of 4000–400 cm⁻¹ with the resolution of 4 cm⁻¹. In the end, photoluminescence (PL) of the products was analyzed by a LS50B PerkinElmer fluorescence spectrometer using 337 nm excitation wavelength at room temperature and photoabsorption by a Lambda-25 PerkinElmer UV-visible spectrometer in the wavelength range of 250–800 nm.

The degradation of methylene blue (MB) dye aqueous solutions was investigated. Each 150 mg MoO₃ was added to a 150 mL  M MB solution, which was stirred for 30 min in the dark condition to establish an adsorption-desorption equilibrium. Thus, the MB dye molecules have a chance to adsorb on the MoO₃ surfaces. Degradation was initiated by a 35 W Xe lamp for 0–180 min. The absorbance peak (strongest intensity) at 664 nm wavelength, determined by UV-visible spectrometer, was assumed to be linearly dependent on the concentration of MB solution. Decolorization efficiency (%) was calculated by , where and were the absorbance intensities of the solutions before and after degradation, respectively.

3. Results and Discussion

3.1. XRD

XRD patterns of the products synthesized by a refluxing method for 1, 3, 5, and 7 h are shown in Figure 1. All the diffraction peaks can be indexed to be pure hexagonal (h) MoO₃ phase (JCPDS no. 21-0569) [20]. Their crystalline degrees were improved by increasing the length of reaction time. Upon calcination of the products at 450°C for 6 h in air, they were transformed into the orthorhombic (α) MoO₃ (JCPDS no. 05-0508) [20] (Figure 2) with no impurity detection.

Figure 1: XRD patterns of h-MoO₃ synthesized by refluxing method for ((a)–(d)) 1, 3, 5, and 7 h, respectively.

Figure 2: XRD patterns of α-MoO₃ synthesized by refluxing method for ((a)–(d)) 1, 3, 5, and 7 h and followed by calcination at 450°C for 6 h, respectively.

3.2. FTIR

The functional groups of the products with the best crystalline degree were identified by FTIR (Figure 3) over the range of 4000–400 cm⁻¹ wavenumber. For h-MoO₃, its spectrum shows peaks at 3574 cm⁻¹ and 1620 cm⁻¹ corresponding to the stretching and bending vibrations of O–H bonds of adsorbed water molecules, respectively. Those at 3182 cm⁻¹ and 1400 cm⁻¹ are due to the stretching and bending vibration of N–H of groups, consistent with the previous report [16]. The 1000–400 cm⁻¹ peaks correspond to the stretching and bending vibrations of metal-oxygen characteristic bonds. The peaks at 980 cm⁻¹ and 914 cm⁻¹ are the characteristic of Mo=O stretching vibrations, including those between 600 and 500 cm⁻¹ corresponding to the vibration of Mo–O bonds [15, 17]. But for α-MoO₃, the spectrum shows three strong peaks: 994 cm⁻¹ attributed to the terminal M=O stretching vibration with an indicator of the layered orthorhombic MoO₃ phase, 860 cm⁻¹ to the stretching mode of oxygen in Mo–O–Mo bonds, and a broad band at 558 cm⁻¹ to the bending vibration of oxygen atom linked to three metal atoms [14, 15, 18]. No water was detected in this orthorhombic-structured product.

Figure 3: FTIR spectra of (a) h-MoO₃ and (b) α-MoO₃.

3.3. EM and PMT

Figures 4(a)–4(e) show SEM and TEM images of h-MoO₃ synthesized by refluxing method for different lengths of reaction time. The products shaped like clusters of hexagonal rods with the most complete at 7 h processing. The rods were 83.82, 143.57, 182.58, and 220.84 nm in diameter for 1, 3, 5, and 7 h processing, respectively. They became enlarged, by transforming from nanosized to microsized rods, with increasing the processing time. In this research, the rods grew out of a center [21], appearing as clusters/flowers of hexagonal rod-like petals and becoming the most complete flowers for 7 h processing. A SAED pattern of h-MoO₃ (Figure 4(f)) reveal as single crystalline h-MoO₃. When these products were calcined at 450°C for 6 h, h-MoO₃ structure ( Å,  Å, α = β = 90 deg, and γ = 120 deg) [20] transformed into α-MoO₃ ( Å,  Å,  Å, and α = β = γ = 90 deg) [20]. Concurrently, their morphology transformed from flowers of hexagonal rods (Figures 4(a)–4(e)) into assemblies of microplates (Figures 5(a)–5(e)), due to the arrangement of Mo and O atoms to achieve the lowest energy. During 450°C calcination, flowers of h-MoO₃ rod-like petals were separated into a number of rods. All atoms of these individual rods were at high energy, leading to the vibration and diffusion process. The strength of vibration and diffusion of the solid was controlled by the calcination temperature, bond strength, type of bonds, and others. Thus, the rods were no longerable to retain their original morphologies. When the calcination process was complete at 6 h, the solid was cooled down to room temperature. During cooling, the vibration and diffusion of all atoms slowed down. The atoms returned to their new lattice sites which were at the lowest energy. In the end, the atoms formed a orthorhombic crystalline structure (α-MoO₃) of which the unit cells arranged themselves into assemblies of microplates. SAED pattern (Figure 5(f)) of the Figure 5(e) product was indexed to be α-MoO₃ with the direction as zone axis.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 4: SEM images of h-MoO₃ synthesized by refluxing method for ((a)–(d)) 1, 3, 5, and 7 h, respectively. (e) TEM image and (f) SAED pattern of h-MoO₃ processed for 7 h.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 5: SEM images of α-MoO₃ synthesized by refluxing method for ((a)–(d)) 1, 3, 5, and 7 h and followed by 450°C and 6 h calcination. (e) TEM image and (f) SAED pattern of (d).

In this research, h-MoO₃ flowers with 5 and 7 h refluxing were more perfect than those synthesized by ultrasonic synthesis [7] and chemical precipitation [16, 17], including the corresponding α-MoO₃ microplates which were more systematic than those synthesized by microwave plasma [18].

3.4. Photocatalysis, Photosensitization, and Mechanisms

The MB solution containing metastable h-MoO₃ phase with 7 h refluxing was studied and became colorless by 30 min stirring during establishing adsorption-desorption equilibrium. Possibly, the solution containing h-MoO₃ was exposed to UV radiation.

Photocalytic properties of α-MoO₃ containing methylene blue (MB) solution irradiated by xenon light for 0–180 min (Figure 6) were investigated. For cationic MB dye aqueous solution, there are two absorption bands at 293 nm or 4.23 eV () and 664 nm or 1.87 eV () [19]. In this research, intensities of absorption peaks at 664 nm were decreased with the increase in the lengths of irradiation time. Comparing to the catalyst-free solution, the 180 min degradation of MB solution (Figure 7) containing α-MoO₃ catalyst synthesized by 90°C refluxing for 7 h in combination with 450°C calcination for 6 h was 88%. During photocatalysis or changing of a chemical reaction rate by photons, electrons in valence band of α-MoO₃ were excited and transferred to its conduction band under xenon light radiation, leaving holes in valence band behind. Holes combined with H₂O to form •H and •OH radicals. Concurrently, the electrons in conduction band diffused to the adsorbed O₂ to form activated • with subsequent transforming of H₂O molecules into •OH radicals. These oxidative species could mineralize MB dye back into original chemical forms of CO₂ and H₂O creating a cleaner and safer environment [22]. If the processes were not possible, electron-hole pairs would recombine together to generate heat on the materials. Photocatalytic activity was controlled by various factors, including structure, particle size, surface area, crystalline degree, surface-adsorbed water molecules, and hydroxyl groups [23]. The present results show that catalytic activity of the metastable h-MoO₃ phase has higher efficiency than that of the thermodynamically stable α-MoO₃ one.

Figure 6: UV-visible spectra of MB solution containing α-MoO₃, synthesized by 90°C refluxing for 7 h in combination with 450°C calcination for 6 h and irradiated by xenon light for different lengths of time.

Figure 7: Decolorization efficiency of MB: (a) catalyst-free solution and (b) the solution containing α-MoO₃ catalyst synthesized by 90°C refluxing for 7 h in combination with 450°C and 6 h calcination and irradiated by xenon light for different lengths of time.

Photosensitization or the process of initiating reaction by a photonic absorber and transfer of energy to reactants was also possible. Upon irradiation of the solutions by xenon light, the MB dye absorbed photon energy and induced the transition (4.23 eV [19]) [14], including transition (1.87 eV [19]). The excited electrons of the MB dye diffused to conduction band (d-orbital) of MoO₃ and reacted with adsorbed oxygen to form • oxidants which further mineralized the MB dye back into CO₂ and H₂O. Photolysis or chemical decomposition of dye induced by photon relates to its structural stability [14], which leads to the mineralization process.

In summary, decolorization of MB dye was able to proceed by the photocatalysis and photosensitization processes or either of the two, influenced by photonic energy, energy gap of MoO₃ catalyst, gaps of and states of MB dye, and others.

3.5. PL

Figure 8 shows photoluminescence of h-MoO₃ and α-MoO₃ excited by 337 nm wavelength at room temperature. Photons with energy exceeding their energy gaps reflected on the products and generated photoexcited electrons, which are not stable. Thus, they jumped back to a basic state and emitted fluorescence photons with lower energy. They both show strong emission peaks at 436 nm in accordance with other reports [9, 10, 18, 19], due to the electron-hole recombination. Moreover, h-MoO₃ has another extra peak at 606 nm specified as the presence of adsorbed oxygen on the material [10].

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(b)

Figure 8: Fluorescence spectra of (a) h-MoO₃ and (b) α-MoO₃.

3.6. UV-Visible Absorption

UV-visible absorption spectroscopy has been used to study photonic properties of materials. Experimentally, the following equation has usually been used to estimate their energy gaps:

where , , , and are the photonic absorbance, the Planck constant, photon frequency, and energy gap, respectively. The parameter is a constant associated with different types of electronic transition: = 1/2,  2,  3/2, or 3 for direct allowed, indirect allowed, direct forbidden, and indirect forbidden transitions, respectively, [9, 12, 21, 24]. UV-visible spectra (Figure 9) of α-MoO₃ and h-MoO₃ show a photonic energy attenuated through the solids. The versus plots were used to estimate energy gaps of α-MoO₃ and h-MoO₃ to be 3.18 and 3.05 eV, respectively. These energy gaps are in accordance with those of 3.35 eV for polycrystalline α-MoO₃ thin film [12], 3.75 eV α-MoO₃ nanobelts [9], 3.15 eV for α-MoO₃ layered structure and 3.01 eV for h-MoO₃ hexagonal rods [15], and 2.99 eV for h-MoO₃ hexagonal nanorods [16]. Shape, size, size distribution, phase, crystalline degree, and defects can play a role in the energy gaps of materials. Generally, becomes wider by using smaller particles but narrower by the presence of defects.

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Figure 9: UV-visible absorbance and the versus plots of ((a), (b)) α-MoO₃ and ((c), (d)) h-MoO₃.

4. Conclusions

In this research, h-MoO₃ rods with the shape of flowers were successfully synthesized by refluxing process and further calcination of the flower-like product to form α-MoO₃ microplates. Their phases, morphologies, and vibration modes were characterized by XRD, SEM, TEM, SAED, and FTIR. Degradation of MB dye under xenon light was proceeding by the photocatalysis and photosensitization processes. Catalytic activity of the metastable h-MoO₃ phase has higher efficiency than that of the thermodynamically stable α-MoO₃ one. PL emissions were determined to be 436 nm for α-MoO₃ microplates, and 436 and 606 nm for h-MoO₃ rods, including of 3.18 eV for α-MoO₃ microplates, and 3.05 eV for h-MoO₃ rods. Their phase and morphology transformation was also explained according to the experimental results.

Acknowledgments

The authors wish to thank the National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), for providing financial support through Project P-10-11345, the Thailand’s Office of the Higher Education Commission through the National Research University (NRU) Project for Chiang Mai University (CMU), the National Research Council of Thailand (NRCT) through the research project for fiscal year 2556, and the Center for Innovation in Chemistry (PERCH-CIC), including the Graduate School of CMU through a general support.

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