Journal of Nanomaterials
Volume 2015 (2015), Article ID 502424, 6 pages
http://dx.doi.org/10.1155/2015/502424

Research Article

Direct Preparation and Characterization of Copper Pentacyanonitrosylferrate Nanoparticles

D. R. Do Carmo, M. M. Souza, U. O. Bicalho, V. S. Dos Santos, J. P. Souza, and D. R. Silvestrini

Departamento de Física e Química, Faculdade de Engenharia de Ilha Solteira, Universidade Estadual Paulista (UNESP), Avenida Brasil Centro 56, 15385-000 Ilha Solteira, SP, Brazil

Received 23 November 2014; Accepted 17 December 2014

Academic Editor: Hassan Karimi-Maleh

Copyright © 2015 D. R. Do Carmo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract.

The present work describes the preparation of nanoparticles of copper pentacyanonitrosyl complexes starting from the compound sodium nitroprusside. Copper pentacyanonitrosylferrate (NCuNP) nanoparticles were successfully synthesized by using deionized water and formamide as solvent. The material was characterized by Fourier-transforming infrared spectroscopy (FT-IR), X-ray diffraction (XRD), ultraviolet-visible (UV-Vis) spectroscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and cyclic voltammetry (CV). The results revealed that the electronic spectra of NCuNP exhibited a broad intervalence charge transfer band at 685 nm. An XRD peak broadening pattern of the NCuNP was verified, indicating a particle decrease when formamide is used. The particle size of NCuNP is estimated to be 80 nm. The cyclic voltammogram of the modified graphite paste electrode with NCuNP showed two redox pairs with formal potentials  V and  V ( mV s⁻¹; KCl 1.0 M), attributed to the redox process and [(CN)₅NO]/[(CN)₅NO], respectively. The graphite paste electrode with NCuNP presents electrocatalytic response for Sulfite determination.

1. Introduction

Metallic nanoparticles (NPs) have attracted considerable attention on account of their intriguing properties and potential applications [1], due to their superior and advantageous functional properties for a wide range of technological applications, including catalysis, optics, microelectronics, and chemical, biological, and electrochemical sensors [1–7].

However, metallic nanoparticles (NPs) are materials that have received much attention due to their potential applications in areas such as chemistry, physics, biology, and engineering because of many magnetic properties, electrical, optical, and chemical properties that are dependent on particle size [1]. An important class of nanoparticles attracting considerable attention for their intriguing properties and potential applications is the hexacyano- and pentacyanonitrosylferrates metalates which are Prussian Blue analogues. Decreasing the size of these above particles plays an important role from an application point of view. The smaller or even nanoscale sizes improve the dispersibility of these cyanometalates in a particular solvent. This helps the thin film formation process of the material, studying the optical properties, electrochromic behavior, and composite preparation. In order to achieve finely controllable synthesis of hexacyano- and pentacyanonitrosylferrate metalates, many synthetic methodologies have been obtained by using a microemulsion method [8]. Metal nitroprussides (MNP) have received much attention from the scientific community as electrochemical sensors due to their versatility and electrocatalytic activity [9–14].

Recently, a new protocol toward the synthesis of cobalt nitroprusside (CoNP) coordination nanoparticles was described based on drop-by-drop (DbD) method without the use of any additives. It was also prepared by sonication as well as by bulk mixing methods for comparison purposes [2]. This paper proposes a new facile and direct synthesis route to obtain nanoparticles of copper pentacyanonitrosylferrate (NCuNP).

The copper pentacyanonitrosylferrate (NCuNP), a Prussian Blue analogue, has been the subject of major investigations because of its excellent chemical and electrochemical [15] stability and due to an presence of the different oxidation states that can be studied by various spectroscopic and electrochemical techniques, these insoluble binuclear complexes provide a wide range of analytical applications [15, 16].

Due to their intriguing properties and potential applications nanoscale size metallic particles are attracting considerable attention [17].

Recently, materials in the nanometer range have shown superior or advantageous functional properties for a wide range of technological applications, including catalysis, optics, microelectronics, and chemical/biological sensors. Metal nanoparticles as catalysts have been vigorously investigated because of their specific properties such as large surface area and their superior properties, which are different from their bulk counterparts [18]. Inorganic nanoparticles are very useful candidates for electrochemical studies [19, 20] owing to their outstanding activity and catalytic power [21–24].

2. Experimental

2.1. Instruments and Chemicals

All reagents and solvents were of analytical grade and were used as purchased. The vibrational spectra of materials were obtained by a Nicolet 5DXB FT-IR spectrometer (Nicolet Instruments, Madison, WI). 150 mg of previously dried KBr pellets and 1.5 mg (1.0% (w/w)) of each sample were prepared for the analysis. A minimum of 64 “scans” with a resolution of ±4 cm⁻¹ in a band of 4000 to 400 cm⁻¹ was used. The characterization by X-ray diffraction was performed using Rigaku Ultima IV diffractometer with Cu Ka radiation (λ = 1.5418 Å). Electronic spectra (UV-Vis) were obtained using Guided Wave model 260 spectrophotometer, in 350–1600 nm. The microstructure was observed by field-emission scanning electron microscope (FE-SEM, JSM-6700 F, Japan).

2.2. Preparation of Copper Pentacyanonitrosylferrate Nanoparticles (NCuNP)

The nanoparticles were synthesized according to the procedure described in [8, 25] with some modifications and described as follows: two solutions, A and B; solution A consisted of 0.7 g of Na₂[Fe(CN)₅NO] dissolved in a solution of 30 mL of formamide and water mixture in a 6 : 4 ratio. Solution B was prepared by dissolving 0.7 g of CuCl₂ H₂O in 20 mL of formamide and water mixture in a 6 : 4 ratio. After the solution was prepared, solution A was poured into solution B and stirred for 2 hours. The solid phase was filtered through a sintered plate funnel and washed thoroughly to eliminate the sodium chloride formed during the reaction.

3. Results and Discussion

3.1. The Vibrational Spectroscopy in the Infrared Region (FT-IR)

Figure 1 illustrates the infrared spectra of the sodium nitroprusside (a) and NCuNP (b). The NCuNP exhibited two absorption bands at 2197 cm⁻¹ and 1952 cm⁻¹ (Figure 1(b)) which confirmed the formation of copper pentacyanonitrosylferrate nanoparticles. The absorption bands at 2197 and 1952 cm⁻¹, attributed to stretching of (C≡N) and ν s (NO), were found to be in good agreement with the values for transition metal pentacyanonitrosylferrate [9–11], reported in literature. A close comparison of the and band shifts and those obtained for sodium nitroprusside (NP) confirms a bathochromic (55 cm⁻¹) shift of the former relative to the latter (Figure 1(a)), thus characterizing the formation of the binuclear complex –-(CN)- [20].

(a)

(b)

(c)

Figure 1: FTIR: (a) sodium nitroprusside, (b) NCuNP obtained in water (bulk), and (c) NCuNP obtained in water and formamide mixture (6 : 4).

3.2. X-Ray Diffraction (XRD)

The material was also characterized by XRD technique (Figure 2). The XRD analysis was compared to the crystallographic cards (references 01-0244 and 30-0483) and in accordance with findings in [26, 27]. Therefore, by the Scherrer equation [27], the particle sizes were estimated to be 80 nm. Peak broadening was verified indicating a decrease in particle size when formamide is used [25].

(a)

(b)

(c)

Figure 2: X-ray diffractogram of (a) sodium nitroprusside, (b) NCuNP obtained in water (bulk), and (c) NCuNP obtained in water and formamide mixture (6 : 4).

3.3. The Electronic Spectra (UV-Vis)

Another strong indication of the formation of nanoparticles was verified by electronic spectroscopy. As shown in Figure 3, the NCuNP obtained from formamide (a) and NcuNP (in water) shows two absorption processes with at 655 and 696 nm, respectively, attributed to the intervalence charge transfer, absent in pure sodium nitroprusside, Figure 3(a). Figure 3(b) shows a widening of the band and shift bathochromically by about 51 nm for the NCuNP for the complex prepared in aqueous medium. These indicate that the particles exhibited size-quantization effects [25].

(a)

(b)

Figure 3: Electronic spectrum (UV/Vis): (a) NCuNP obtained in water and formamide mixture (6 : 4) and (b) NCuNP obtained in water (bulk).

3.4. Scanning Electron Microscopy and Energy-Dispersive X-Ray Spectroscopy (SEM and EDX)

Figure 4 illustrates SEM images of NCuNP obtained in water (a) and in formamide mixture (b). The NCuNP in formamide mixture show cubic particles with size in the range of 8.5 nm. Figure 5 shows the energy-dispersive X-ray spectroscopy (EDX) of NCuNP that exhibited the presence of elements (Na, Fe, and Cu) in the nanoparticle, thereby confirming the formation of the binuclear complex.

Figure 4: FE-SEM images of the (a) NCuNP obtained in water and (b) formamide mixture (6 : 4).

Figure 5: Energy-dispersive X-ray spectroscopy (EDX) of the NcuNP obtained in formamide mixture (6 : 4).

3.5. Cyclic Voltammetry (CV)

NCuNP was characterized by cyclic voltammetry as shown in Figure 6. With the voltammogram of NCuNP (20% w/w), a redox pair (peak I) was observed with a midi potential = 0.36 V and a redox pair (peak II) was observed with a midi potential = 0.78 V (ν = 20 mV s⁻¹; KCl 1.0 M), attributed to the redox process and .

Figure 6: Cyclic voltammogram of graphite electrode modified with NCuNP (KCl 1.0 mol L⁻¹; = 20 mV s⁻¹; 20% (w/w)).

Figure 7 illustrates the voltammetric behavior of the graphite paste electrode modified with NCuNP for the electrooxidation of Sulfite in 1.0 mol L⁻¹ KCl. The unmodified graphite paste electrode in a solution of KCl 1.0 mol L⁻¹ in the absence (curve A) and presence of Sulfite (curve B) did not show a redox pair in the potential range studied between −0.2 and 1.2 V. After the addition of Sulfite there was an increase in the anodic peak current intensity (curve D) when compared with the graphite paste electrode modified with NCuNP in the absence of Sulfite (curve C). There was an increase in the anodic current intensity of the peak at 0.80 V. Thus, it was determined that, by adding aliquots of the Sulfite, the analite was oxidized at the electrode surface by an electrocatalyst oxidation process.

Figure 7: Cyclic voltammograms of (A) the graphite paste electrode; (B) graphite paste electrode and 4.0 × 10−2 mol L⁻¹ of Sulfite; (C) graphite paste electrode modified with NCuNP; and (D) graphite paste electrode modified with NCuNP and 4.0 × 10−2 mol L⁻¹ of Sulfite (KCl 1.0 mol L⁻¹; 20 mV s⁻¹; 20% (w/w)).

The electrocatalytic oxidation of Sulfite occurs as follows: Fe³⁺ is produced during anodic scan, and the Sulfite molecule is chemically oxidized when it is reduced to Fe²⁺, which will again be electrochemically oxidized to Fe³⁺.

The electrocatalytic process in this system can also be represented according to (1) and (2):

Thus Sulfite is oxidized at the electrode surface, and this process occurs in the potential of 0.80 V. The oxidation process does not occur in this potential when glassy carbon electrode or unmodified graphite paste is used (Figure 7(B)).

The peak potential is not affected by the concentration of Sulfite and the catalytic current is also linear with the square root of scan rate. Figure 8 illustrates the analytical curve used to determine Sulfite. The modified electrode showed a linear response from 7.0 × 10⁻⁴ to 4.0 × 10−2 mol L⁻¹ with the corresponding equation = 0.112 + 134.187 (Sulfite) and a correlation coefficient of . The method showed a detection limit of 3.20 × 10−4 mol L⁻¹ with a relative standard deviation of ±2% () and amperometric sensitivity of 0.134 mA mol L⁻¹.

Figure 8: Analytical curve for the determination of Sulfite using the graphite paste electrode modified with NCuNP (KCl 1.0 mol L⁻¹; 20 mV s⁻¹; 20% (w/w)).

3.5.1. Interference Study

Interferences in the determination of 56 ppm sulfite using the graphite paste electrode modified with NCuNP were examined by testing the effect of several species frequently found with Sulfite. The effects of several organic acids such as citric acid, oxalic acid, and ascorbic acid, the sugars such as glucose, fructose, and sucrose, and some inorganic ions such as thiosulfate, persulfate, nitrite, nitrate, and chloride were carried out by adding 300-fold of sulfite concentration (1.0 × 10⁻² mmol L⁻¹) of some of the compounds mentioned. Of the compounds tested only ascorbic acid caused a negative interference in the electrode response. The other compounds did not show any interference (at 300-fold of sulfite concentration) to detect Sulfite using the modified electrode.

4. Conclusions

The nanoparticles were synthesized by using deionized water and formamide as solvent. The structure of NCuNP and its composites were confirmed by FT-IR, XRD, UV-Vis, FE-SEM, and EDX techniques. The nanoparticle sizes can be influenced according to the solvent used. It is concluded that the use of formamide as solvent and water is much more advantageous than using only water as solvent. A smaller size of the material with the use of formamide was observed. The cyclic voltammogram of the graphite paste electrode modified with NCuNP showed two redox pairs with formal potentials = 0.36 V and = 0.78 V (ν = 20 mV s⁻¹; KCl 1.0 M), attributed to the redox process and [(CN)₅NO]/[(CN)₅NO], respectively. The redox pair [(CN)₅NO]/[(CN)₅NO] presents a notable electrocatalytic response for the determination of Sulfite. The modified electrode gives a linear range from 7.0 × 10⁻⁴ to 4.0 × 10−2 mol L⁻¹   for the determination of Sulfite with detection limit of 3.20 × 10−4 mol L⁻¹ with a relative standard deviation of ±2% () and amperometric sensitivity of 0.134 mA mol L⁻¹ for Sulfite.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgments

Financial support for this research was provided by Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP, Processes 2012/05438-1, 2003/12882-6, and 2012/11306-0) and Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Process 306087/2012-0.

References

M. G. Lines, “Nanomaterials for practical functional uses,” Journal of Alloys and Compounds, vol. 449, no. 1-2, pp. 242–245, 2008.

S. Devaramani and P. Malingappa, “Synthesis and characterization of cobalt nitroprusside nano particles: application to sulfite sensing in food and water samples,” Electrochimica Acta, vol. 85, pp. 579–587, 2012.

D. D. Guo, C. H. Wu, X. M. Wang, and B. A. Chen, “Electrochemical study of the effect of functionalized nickel nanoparticles on cellular uptake of leukemia cancer cells in vitro,” Chinese Chemical Letters, vol. 19, no. 5, pp. 577–588, 2008.

M. Najafi, M. A. Khalilzadeh, and H. Karimi-Maleh, “A new strategy for determination of bisphenol A in the presence of Sudan I using a ZnO/CNTs/ionic liquid paste electrode in food samples,” Food Chemistry, vol. 158, pp. 125–131, 2014.

M. Elyasi, M. A. Khalilzadeh, and H. Karimi-Maleh, “High sensitive voltammetric sensor based on Pt/CNTs nanocomposite modified ionic liquid carbon paste electrode for determination of Sudan I in food samples,” Food Chemistry, vol. 141, no. 4, pp. 4311–4317, 2013.

M. Bijad, H. Karimi-Maleh, and M. A. Khalilzadeh, “Application of ZnO/CNTs nanocomposite ionic liquid paste electrode as a sensitive voltammetric sensor for determination of ascorbic acid in food samples,” Food Analytical Methods, vol. 6, no. 6, pp. 1639–1647, 2013.

S. Kharian, N. Teymoori, and M. A. Khalilzadeh, “Multi-wall carbon nanotubes and TiO₂ as a sensor for electrocatalytic determination of epinephrinein the presence of p-chloranil as a mediator,” Journal of Solid State Electrochemistry, vol. 16, no. 2, pp. 563–568, 2012.

Y. Ding, Y.-L. Hu, G. Gu, and X.-H. Xia, “Controllable synthesis and formation mechanism investigation of prussian blue nanocrystals by using the polysaccharide hydrolysis method,” Journal of Physical Chemistry C, vol. 113, no. 33, pp. 14838–14843, 2009.

L. L. Paim and N. R. Stradiotto, “Electrooxidation of sulfide by cobalt pentacyanonitrosylferrate film on glassy carbon electrode by cyclic voltammetry,” Electrochimica Acta, vol. 55, no. 13, pp. 4144–4147, 2010.

H. Razmi and H. Heidari, “Nafion/lead nitroprusside nanoparticles modified carbon ceramic electrode as a novel amperometric sensor for l-cysteine,” Analytical Biochemistry, vol. 388, no. 1, pp. 15–22, 2009.

Z. Xun, C. Cai, and T. Lu, “Effects of a surfactant on the electrocatalytic activity of cobalt hexacyanoferrate modified glassy carbon electrode towards the oxidation of Dopamine,” Electroanalysis, vol. 16, no. 8, pp. 674–683, 2004.

C.-X. Cai, K.-H. Xue, and S.-M. Xu, “Electrocatalytic activity of a cobalt hexacyanoferrate modified glassy carbon electrode toward ascorbic acid oxidation,” Journal of Electroanalytical Chemistry, vol. 486, no. 2, pp. 111–118, 2000.

D.-M. Zhou, H.-X. Ju, and H.-Y. Chen, “Catalytic oxidation of dopamine at a microdisk platinum electrode modified by electrodeposition of nickel hexacyanoferrate and Nafion,” Journal of Electroanalytical Chemistry, vol. 408, no. 1-2, pp. 219–223, 1996.

D. R. Do Carmo, R. M. Da Silva, and N. R. Stradiotto, “Electrochemical behaviour of copper nitroprusside generated in situ onto the grafite paste electrode surfasse, and its application in the determination of N-Acethylcysteine,” Portugaliae Electrochimica Acta, vol. 23, pp. 457–470, 2005.

B. J. Sanghavi, S. M. Mobin, P. Mathur, G. K. Lahiri, and A. K. Srivastava, “Biomimetic sensor for certain catecholamines employing copper(II) complex and silver nanoparticle modified glassy carbon paste electrode,” Biosensors and Bioelectronics, vol. 39, no. 1, pp. 124–132, 2013.

R. C. Ashoori, “Electrons in artificial atoms,” Nature, vol. 379, no. 6564, pp. 413–419, 1996.

G. M. Whitesides, J. P. Mathias, and C. T. Seto, “Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures,” Science, vol. 254, no. 5036, pp. 1312–1319, 1991.

B. J. Sanghavi, W. Varhue, J. L. Chávez, C.-F. Chou, and N. S. Swami, “Electrokinetic preconcentration and detection of neuropeptides at patterned graphene-modified electrodes in a nanochannel,” Analytical Chemistry, vol. 86, no. 9, pp. 4120–4125, 2014.

B. J. Sanghavi, S. Sitaula, M. H. Griep, S. P. Karna, M. F. Ali, and N. S. Swami, “Real-time electrochemical monitoring of adenosine triphosphate in the picomolar to micromolar range using graphene-modified electrodes,” Analytical Chemistry, vol. 85, no. 17, pp. 8158–8165, 2013.

M. Yoshinaga, H. Takahashi, K. Yamamoto, A. Muramatsu, and T. Morikawa, “Formation of metallic Ni nanoparticles on titania surfaces by chemical vapor reductive deposition method,” Journal of Colloid and Interface Science, vol. 309, no. 1, pp. 149–154, 2007.

J. M. Domínguez-Vera and E. Colacio, “Nanoparticles of Prussian Blue Ferritin: a new route for obtaining nanomaterials,” Inorganic Chemistry, vol. 42, no. 22, pp. 6983–6985, 2003.

S. Vaucher, J. Fielden, M. Li, E. Dujardin, and S. Mann, “Molecule-based magnetic nanoparticles: synthesis of cobalt hexacyanoferrate, cobalt pentacyanonitrosylferrate, and chromium hexacyanochromate coordination polymers in water-in-oil microemulsions,” Nano Letters, vol. 2, no. 3, pp. 225–229, 2002.

S.-Q. Liu, J.-J. Xu, and H.-Y. Chen, “Electrochemical behavior of nanosized Prussian blue self-assembled on Au electrode surface,” Electrochemistry Communications, vol. 4, no. 5, pp. 421–425, 2002.

V. Vo, M. N. Van, H. I. Lee, J. M. Kim, Y. Kim, and S. J. Kim, “A new route for obtaining prussian blue nanoparticles,” Materials Chemistry and Physics, vol. 107, no. 1, pp. 6–8, 2008.

J. Hanawalt, H. Rinn, and L. Prevel, “Chemical analysis by X-ray diffraction,” Analytical Chemistry, vol. 10, pp. 457–512, 1938.

D. B. Brown, “Nitrogen- and oxygen-bonded nitrosyl. Metal complexes of the nitroprusside ion,” Inorganic Chemistry, vol. 14, no. 10, pp. 2582–2584, 1975.

P. H. Klung and E. L. Alexander, X-Ray Diffraction Procedures for Polycystalline and Amorphous Materials, John Wiley & Sons, Hoboken, NJ, USA, 2nd edition, 1974.