Performance of NiFe 2 O 4-SiO 2-TiO 2 Magnetic Photocatalyst for the Effective Photocatalytic Reduction of Cr ( VI ) in Aqueous Solutions

Investigation into the reduction of Cr(VI) in aqueous solution was carried out through some batch photocatalytic studies. The photocatalysts used were silica coated nickel ferrite nanoparticles (NiFe 2 O 4 -SiO 2 ), nickel ferrite titanium dioxide (NiFe 2 O 4 -TiO 2 ), nickel ferrite silica titanium dioxide (NiFe 2 O 4 -SiO 2 -TiO 2 ), and titanium dioxide (TiO 2 ). The characterization of the materials prepared via stepwise synthesis using coprecipitation and sol-gel methods were carried out with the aid of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, thermal gravimetric analysis (TGA), and vibrating sample magnetometry (VSM). The reduction efficiency was studied as a function of pH, photocatalyst dose, and contact time. The effects of silica interlayer between the magnetic photocatalyst materials reveal that reduction efficiency of NiFe 2 O 4 -SiO 2 -TiO 2 towards Cr(VI) was higher than that of NiFe 2 O 4 -TiO 2 . However, TiO 2 was observed to have the highest reduction efficiency at all batch photocatalytic experiments. Kinetics study shows that photocatalytic reduction of Cr(VI) obeyed Langmuir-Hinshelwood model and first-order rate kinetics. Regenerability study also suggested that the photocatalyst materials can be reused.


Introduction
Heavy metal pollution has become one of the most serious environmental problems today.Their toxicity and persistence have made their treatment and remediation from the environment pertinent.Wastewater containing hazardous metals generated by industries is continually discharged into the environment especially fresh water resources causing severe health risks.These toxic metals unlike organic contaminants are not biodegradable and when accumulated in the body cause severe damage and sometimes death [1].Chromium is one of the most frequently found metals in the environment because of its usage in major industries such as metal plating, petrochemicals, mining, fertilizer, tanneries, batteries, pesticides, and paper industries [2,3] but it is a source of concern and risk to human because of its toxicity, cancer causing tendencies, and free movement in water.
Different valence forms of chromium are known but in water bodies Cr(VI) and Cr(III) forms are most common.The valence state of chromium determines its behavior.Whereas Cr(III) is immobile and nontoxic, Cr(VI) is highly toxic, cancerous, and mobile [4].In the past, extensive studies on various techniques of Cr(VI) removal from wastewater have been reported.These include coagulation [5], membrane separation and ion exchange [6], solvent extraction and electrochemical destruction [7], and ozonation and aerobic/anaerobic microbial degradation [8,9].Despite the availability of these techniques, limitations encountered with these technologies such as cost, high energy requirement, and large use of reducing agents [10] are noticeable drawbacks.Also, semiconductor photocatalysts such as titanium dioxide (TiO 2 ), zinc oxide (ZnO), cadmium sulfide (CdS), tin oxide (SnO), and tungsten oxide (WO 3 ) have been employed for the reduction of Cr(VI) in wastewater.Although titanium 2 Journal of Nanomaterials dioxide photocatalysts have been shown to be the most efficient due to their superior oxidation and reduction capability, nontoxicity, low cost of preparation, and chemical and biological inertness [11][12][13][14], however, problems such as difficulty of separation and recycling of photocatalyst materials from wastewater are encountered.Efforts made to overcome these problems include supporting titania on silica, glass, zeolite, and fibre glass [7,[15][16][17][18][19].Also, magnetic nanoparticles have been reported as supports to aid the recycling and ease the separation of titanium photocatalyst but all these reduce the photocatalytic activity of titanium dioxide to an extremely low point due to the immobility of the photocatalyst and low mass transfer rate.To address these problems, the use of magnetic photocatalysts containing various molar ratios of magnetic nanoparticles and TiO 2 as well as the use of an inert layer such as silica between titania and magnetic nanoparticles allows for easy separation with the aid of an external magnet and recyclability while maintaining the photocatalytic properties of titania [20,21].
In this study, we report on the effectiveness of magnetic titanium dioxide nanocomposite with silica interlayer (NiFe 2 O 4 -SiO 2 -TiO 2 ) to photocatalytically reduce Cr(VI) in aqueous solution.In addition, NiFe 2 O 4 -TiO 2 nanocomposite, TiO 2 photocatalyst, and NiFe 2 O 4 -SiO 2 were synthesized and assessed for Cr(VI) reduction.Furthermore, the photocatalytic activities of the photocatalyst composites were compared to determine if the introduction of silica interlayer enhanced the reduction of Cr(VI) from aqueous solution.The nanocomposites were prepared by stepwise methods starting with coprecipitation followed by the hydrolysis of SiO 2 and TiO 2 for NiFe 2 O 4 -SiO 2 -TiO 2 and hydrolysis of only TiO 2 for NiFe 2 O 4 -TiO 2 .Most published works are on the use of titanium dioxide-carbon nanocomposite and titanium dioxide photocatalysts on the reduction of Cr(VI) in aqueous solutions [4,10] and to the best of our knowledge there has been no report on the use and comparison of the photocatalytic performance of NiFe 2 O 4 -SiO 2 -TiO 2 and NiFe 2 O 4 -TiO 2 nanocomposites for the reduction of toxic Cr(VI) from aqueous solution.The optimum conditions necessary for Cr(VI) reduction were also investigated using batch photocatalytic adsorption processes involving the effect of pH, contact time, and catalyst dose.Regenerability studies using the spent photocatalyst materials were also carried out on the reduction of Cr(VI) in aqueous solution to determine their reusability.

Preparation of Nickel Ferrite
Nanoparticles.Nickel ferrite nanoparticles were prepared by the coprecipitation method [22].Molar solutions of FeCl 3 ⋅6H 2 O and NiCl 2 ⋅6H 2 O in ratio 2 : 1 were prepared and 30 cm 3 of each solution was mixed and stirred under nitrogen for 30 min.NaOH of 10 mol dm −3 was slowly added to the reacting mixture until the pH of the mixture attained 11.The temperature of the reaction mixture was taken up to 80 ∘ C and the mixture was allowed to stir for another 90 min under an inert nitrogen condition.The large amount of precipitate generated was filtered, washed twice with ethanol and severally with deionized water with repeated centrifugation at 4000 rpm for 10 min until the pH was about 7, and dried overnight at 80 ∘ C. nanoparticle placed in a 250 cm 3 round bottom flask was dispersed in 25 cm 3 solution of ethanol using a water bath ultrasonicator for 1 h.Diethoxydimethylsilane (0.7 cm 3 ) and 30% NH 3 (0.6 cm 3 ) were both added gradually while stirring in the sonicator bath for 3 h at 25 ∘ C. The resulting precipitate was collected by centrifugation after washing severally with water and dried overnight at 80 ∘ C followed by calcination at 450 ∘ C for 2 h [23].

Preparation of Titanium Dioxide Photocatalyst.
In 200 cm 3 of deionized water placed in an ice bath with vigorous stirring, 11 cm 3 of titanium tetrachloride was added dropwise.The resulting solution was allowed to undergo hydrolysis by heating at 80 ∘ C for 30 min.Sodium hydroxide solution was used to adjust the pH to around 8-9.The white precipitate formed was washed thoroughly with deionized water to remove excess chloride ions and was collected via centrifugation and dried in an oven at 70 ∘ C overnight.The white powder obtained after oven drying was calcined at 450 ∘ C for 2 h.  .Nanocomposites were prepared using the sol-gel method.200 mg of NiFe 2 O 4 -SiO 2 nanoparticles in a round bottom flask was dispersed in 25 cm 3 ethanol and sonicated in an ultrasonic water bath apparatus for 60 min at room temperature.0.1 M HCl solution was used to adjust the pH of the suspension to 4.0.Titanium(IV) isopropoxide (0.2 cm 3 ) in 10 cm 3 ethanol was slowly added into the suspension above and ultrasonicated while stirring for 4 h at 80 ∘ C to ensure uniformity of mixture.The precipitate obtained was filtered and washed with ethanol and then deionized water until the pH was about 7.0.The particles were left to age at room temperature for 1 h and then dried overnight at 80 ∘ C and later calcined at 450 ∘ C for 2 h.For the synthesis of NiFe 2 O 4 -TiO 2 , the same method was followed except that NiFe 2 O 4 was used [23].

Preparation of Nanocomposite
2.6.Characterization.Characterization of the synthesized materials was done using XRD to determine the crystallite size, crystalline phase, and purity of the photocatalysts.This was recorded on a Bruker D8 Advanced, equipped with a proportional counter using Cu K radiation ( = 1.5405Å,  nickel filter).Scanning electron microscope (SEM) images were recorded using JOEL JSM-6390 LVSEM.Transmission electron microscope (TEM) was done to determine the shape and confirm the particle size of the material.Fourier transform infrared (FTIR) spectroscopy was used to observe the vibrations of the composite samples.Perkin-Elmer Universal ATR sampling accessory spectrum 100 FTIR spectrometer was used to collect the IR spectra of the samples.Thermal gravimetric analyzer was used to determine the purity and thermal stability of the materials; thermogravimetric analysis (TGA) was performed using a Perkin-Elmer TGA 4000 analyzer.The magnetic properties of the photocatalyst composites were quantified using a cryogen free physical measurement vibrating sample magnetometer (VSM) at a temperature range of 1.8 to 310 K with a magnetic system of 14 tesla.

Photocatalytic Experiment.
To evaluate the photocatalytic capability of the prepared photocatalyst against the reduction of Cr(VI) in aqueous solution, a photocatalytic reactor made of a 500 cm 3 glass beaker, an orbital shaker, and a mercury (Hg) lamp of a wavelength of 254 nm were employed (Figure 1).Typically, 10 mg/L of potassium dichromate solution was used.Before UV illumination, 200 mg of photocatalyst was suspended in 100 cm 3 potassium dichromate solution in a 500 cm 3 beaker covered with a parafilm to prevent evaporation and subjected to agitation at 120 rpm for 30 minutes in the dark to ensure the attainment of equilibrium of adsorption or desorption between Cr(VI), photocatalyst, and water.This solution was then irradiated with 9 W Hg lamp at room temperature.The mixture was centrifuged and filtered through a 0.22 micrometer membrane filter after 300 min and the final concentration of Cr(VI) was determined using a UV-Vis spectrophotometer at 350 nm.The effect of pH, time, and catalyst dose was studied for each photocatalyst to determine the optimum conditions necessary for photocatalysis.The photocatalytic reduction efficiency (RE) was calculated using where   is the initial concentration of Cr(VI) solution and  is the absorbance of Cr(VI) solution at the irradiation time ().

Regenerability Study.
In a 50 cm 3 beaker, 50 mg of spent photocatalyst materials was agitated with 25 cm 3 of 0.1 N NaOH for 1 h.The titanium dioxide photocatalyst was collected by filtration and the magnetic photocatalyst composites were separated from the solution by an external magnet.The materials were dried in an oven at 105 ∘ C overnight and reused two more times for the photocatalytic reduction of Cr(VI) in aqueous solution.The % reduction of Cr(VI) after 3 runs was calculated using (1).

Results and Discussion
The synthesized photocatalysts were characterized using different techniques to confirm that they will be effective for the reduction of Cr(VI) in aqueous solution.The effect of silica interlayer on the magnetic photocatalyst for the reduction of Cr(VI) was investigated and compared with that of TiO 2 and bare magnetic titanium dioxide composite sample by means of some batch photocatalytic experiments.and TiO 2 , respectively, are listed in Table 1.The analysis shows that as the composite sample is formed, the crystallite size of NiFe 2 O 4 decreases which is evident in the weakening of the line intensities of NiFe 2 O 4 and that nickel ferrite possesses a cubic spinel structure while the titanium dioxide exists in the anatase crystalline phase which is in agreement with recently published report [26].

Characterization of Photocatalysts. X-ray diffraction patterns of NiFe
Figure 3 shows the FTIR spectra of (a) NiFe 2 O 4 -TiO 2 and (b) NiFe 2 O 4 -SiO 2 -TiO 2 .The absorption bands between 3354.08 cm −1 and 3328.40 cm −1 in both spectra are ascribed to the stretching mode of the hydroxyl groups on the surface of the photocatalysts.This is important as it enhances the photocatalytic activity of TiO 2 by providing higher capacity for the adsorption of oxygen [26].Bands observed at 456.84 cm −1 and 430.33 cm −1 for NiFe 2 O 4 -TiO 2 and NiFe 2 O 4 -SiO 2 -TiO 2 , respectively, are assigned to the stretching vibrations of Ti-O in anatase TiO 2 as described by Li et al. [27].However, a band observed at 1068.69 cm −1 corresponding to the Si-O-Si stretching vibration in the FTIR spectra of NiFe 2 O 4 -SiO 2 -TiO 2 confirmed the introduction of SiO 2 in the composite sample and this band was found to be absent in the spectra of NiFe 2 O 4 -TiO 2 photocatalyst.This SiO 2 phase is however not observed in the XRD pattern and the absence is due to the fact that SiO 2 occurs in the amorphous phase and this observation has been reported in recently published results [20,26,28,29].This therefore confirms the successful synthesis of the composite photocatalyst materials.SEM was used to investigate the structural morphology of the photocatalysts and NiFe 2 O 4 -SiO 2 nanoparticles.Figure 4 shows the SEM images of (a) NiFe 2 O 4 -SiO 2 , (b) TiO 2 , (c) NiFe 2 O 4 -TiO 2 , and (d) NiFe 2 O 4 -SiO 2 -TiO 2 at the same magnification.It was observed that spherical nanoparticles were exclusively obtained.However, high degree of agglomeration and different surface morphologies was observed in Figure 4(a) for the NiFe 2 O 4 -SiO 2 .This may be due to the magnetic attraction between nickel ferrite and silica layers.Figures 4(c) and 4(d) show that the nucleation of NiFe 2 O 4 -TiO 2 and NiFe 2 O 4 -SiO 2 -TiO 2 is heterogeneous with high degree of roughness on the surface; this effect is not observed in the pristine or pure photocatalyst (TiO 2 ) (Figure 4(b)) [26].Figure 4(b) indicates that spherical shaped and few TiO 2 aggregate nanoparticles resulting from the hydrolysis of titanium dioxide precursors were obtained.This same observation was reported in a study by Yang and Zeng [30].
Images collected on TEM were used to observe the structure, size, and distribution of the materials produced.shows the TEM image of TiO 2 photocatalyst, the image shows that the synthesized TiO 2 photocatalyst consisted mainly of elementary particles of size ranging from 15 to 26 nm which is consistent with the results obtained from the XRD analysis (Table 1).The thermographs of the NiFe 2 O 4 -SiO 2 and photocatalyst materials are given in Figure 6.NiFe 2 O 4 -SiO 2 is more stable than the photocatalyst materials at all temperatures.The loss of weight observed between 20 and 200 ∘ C for the photocatalyst materials in the thermograph is due to the removal of OH and H 2 O indicating the presence of water molecules as also observed in their FTIR spectra [32].However, above 200 ∘ C, the photocatalyst composites did not show any loss of weight; this confirms the stability of the materials even at higher temperatures suggesting that the presence of magnetic nanoparticles improved the stability of TiO 2 .Weight loss above 200 ∘ C for TiO 2 shows that titanium dioxide can be unstable at higher temperatures.
Figure 7 shows the magnetization curves of the silica coated NiFe 2 O 4 nanoparticles and the magnetic photocatalyst composites.It can be observed that the saturation magnetization value of the silica coated NiFe 2 O 4 is much higher than the magnetic titanium dioxide photocatalyst; this is as a result of the nonmagnetic character of TiO 2 present in the composite samples which decreases the magnetization value of the NiFe 2 O 4 in the composite.Although magnetic photocatalyst with silica interlayer (NiFe 2 O 4 -SiO 2 -TiO 2 ) was observed to have a slightly higher saturation magnetization value than the NiFe 2 O 4 -TiO 2 , this may be due to the presence of the SiO 2 on the NiFe 2 O 4 which reduces the influence of the TiO 2 on the magnetic nanoparticles.This result therefore indicates that both magnetic photocatalyst composite materials exhibit supermagnetic properties at room temperature and it will enable and enhance the separation and recovery

Photocatalytic Experiment. The photocatalytic reduction of Cr(VI) by NiFe
and TiO 2 was studied for its efficient reduction in contaminated wastewater.The reduction efficiencies of the photocatalysts were compared to determine the photocatalyst with the best capability to reduce Cr(VI).The effects of pH, time, and catalyst dose were studied to determine the optimum conditions for Cr(VI) reduction.Desorption studies were also studied for all the photocatalysts to ascertain the reusability of the photocatalysts.

Effect of Solution pH. Solution pH in photocatalytic
experiments is a vital factor to be considered as it can affect the surface charge of the photocatalyst.It has been reported that TiO 2 surface has three different species in water, TiOH + , TiOH, and TiO − [10].At pH values higher than 5.5 (point of zero charge of TiO 2 photocatalyst), the surface of TiO 2 will have TiO − species which repels Cr(VI) thereby affecting its adsorption on the surface of TiO 2 and with pH value less than 5.5 the surface will be positively charged and Cr(OH) 3 will be formed as a precipitate on the surface of TiO 2 which therefore aids the adsorption of Cr(VI) so that Cr(III) is deposited on the TiO 2 surface [33,34].Consequently, the effect of solution pH was carried out by exposing to UV light a known concentration of dichromate solution for 1 h with photocatalyst at room temperature.The solutions were adjusted to obtain an initial pH range of 2-10 using 0.1 mol dm −3 HCl or NaOH as the case may be.The effect of pH on the photocatalytic reduction of Cr(VI) using NiFe reduction efficiency is favoured in acidic solutions.Although the reduction of Cr(VI) was best in TiO 2 photocatalyst, for the composite samples, reduction efficiency was observed to be higher for NiFe 2 O 4 -SiO 2 -TiO 2 than in NiFe 2 O 4 -TiO 2 at all pH levels (Figure 8); this could be attributed to the SiO 2 interlayer present in the former.Similar result has been reported by Álvarez et al. [24].All other photocatalytic reduction studies were conducted at a pH value of 4, since this value is within the reduction range for all the photocatalysts considered in this study.

Effect of Irradiation Time.
In order to ascertain the irradiation time required to achieve maximum reduction, the photocatalytic reduction of Cr(VI) in aqueous solution using NiFe 2 O 4 -SiO 2 , NiFe 2 O 4 -TiO 2 , NiFe 2 O 4 -SiO 2 -TiO 2 , and TiO 2 photocatalyst was conducted for different time intervals.Figure 9 shows that photocatalytic reduction efficiency increases as the irradiation time increases for NiFe 2 O 4 -TiO 2 , NiFe 2 O 4 -SiO 2 -TiO 2 , and TiO 2 photocatalysts while no reduction was observed for NiFe 2 O 4 -SiO 2 .Also, Cr(VI) solution reached 96.5% photocatalytic reduction using NiFe 2 O 4 -SiO 2 -TiO 2 within 300 min of UV irradiation compared to the 60% photocatalytic reduction using NiFe 2 O 4 -TiO 2 in 300 min.This higher photocatalytic reduction can be attributed to the SiO 2 interlayer covering and preventing the NiFe 2 O 4 core from reducing the photocatalytic property of TiO 2 in the composite of NiFe 2 O 4 -SiO 2 -TiO 2 .This result is similar to the result obtained in a reported study [24].This result reveals that the introduction of SiO 2 as an interlayer between magnetic titanium dioxide photocatalysts improved its photocatalytic properties and aids magnetic separation from aqueous solution.It is worthy of note that the best photocatalytic reduction was obtained within 240 min with TiO 2 photocatalyst (96.7% reduction efficiency).NiFe 2 O 4 -SiO 2 and blank did not show any reduction in Cr(VI) after 300 min; this implies that NiFe 2 O 4 -SiO 2 and UV irradiation without photocatalyst cannot reduce Cr(VI) in aqueous solution.

Kinetic Study.
The photoreduction of Cr(VI) in aqueous solution over different photocatalyst materials was plotted against irradiation time.Experimental data were fitted to the Langmuir-Hinshelwood (L-H) kinetic model: where  is the rate of photoreduction (mg L −1 min −1 ),  is the concentration of the reactant (mg L −1 ),  is the equilibrium constant for the adsorption of Cr(VI) onto photocatalyst surface,  represents the equilibrium time, and   represents the specific reaction rate constant for the oxidation of the reactants (mg L −1 min −1 ) [36].Consequently, using pseudofirst-order kinetics, (2) can be simplified with an apparent first-order rate constant,  app , and, by integrating it, (3) is obtained: where   represents the initial Cr(VI) concentration.When ln(  /) is plotted against time (), a straight line obtained indicates that the data obtained from the photocatalytic reduction of Cr(VI) using photocatalyst materials obeyed Langmuir-Hinshelwood (L-H) kinetic equation and the slope is the apparent first-order rate constant,  app .Since  2 helps to determine how exact the actual value is to the mean value, it can be observed in Figure 10   reduction decreases; this is attributed to the fact that as the mass of photocatalyst is increased, the total number of active sites on the photocatalyst surface also increases thereby resulting in an increase in the amount of electrons which can be used for the photoreduction of Cr(VI).In increasing the photocatalyst dose beyond 200 mg, there exists a turbidity of the suspension which therefore reduces the penetration of light.Also, catalyst amount beyond 200 mg resulted in an aggregation; these cause a decrease in the number of active sites on the TiO 2 surface available for Cr(VI) reduction thereby resulting into a decrease in the performance of the photocatalysts [10].
However, NiFe 2 O 4 -SiO 2 did not reduce Cr(VI) in aqueous solutions for all photocatalyst dose confirming again its nonphotocatalytic capabilities towards Cr(VI) reduction in wastewater.

Regenerability and Reusability Study.
For the use of the synthesized photocatalysts in the industry, it is important to test for the reusability potential of the spent photocatalysts for cost reduction and availability of photocatalysts for photocatalysis and environmental safety by limiting the disposal of secondary pollutants into the environment.In order to ascertain the reusability of these photocatalyst materials, 0.1 M NaOH was used to treat photocatalyst materials by agitating for 1 h.The choice of 0.1 M NaOH as the eluent for regeneration is attributed to the fact that the favourable pH for the reduction of Cr(VI) in aqueous solutions is the acidic pH range as earlier observed.Therefore, basic pH was not favourable for the adsorption of Cr(VI) on the photocatalysts surfaces and invariably weakens the force of adsorption under basic conditions.The results for the reuse of the photocatalyst materials for the reduction of Cr(VI) in 10 mg/L Cr(VI) solution after 3 cycles or runs are presented in Table 2.The result indicates that although the time for which the reduction of Cr(VI) occurred was slightly higher, the regenerated photocatalysts were still effective for the reduction of Cr(VI) in aqueous solution after 3 cycles or runs.TiO 2 showed better regenerability after 3 cycles or runs as it was able to reduce Cr(VI) completely after 270 min while NiFe

Conclusion
The successful preparation of magnetic photocatalyst (NiFe

Figure 1 :
Figure 1: Photocatalytic setup for the reduction of Cr(VI) using 9 W Hg lamp.

Figure 8 :
Figure 8: Effect of solution pH on the photocatalytic reduction of Cr(VI) (10 mg/L) for NiFe 2 O 4 -SiO 2 and photocatalysts at 20 ∘ C, 120 rpm for 1 h irradiation time under UV light.

Figure 9 :
Figure 9: Effect of irradiation time on the photocatalytic reduction of Cr(VI) (10 mg/L) for blank, NiFe 2 O 4 -SiO 2 , and photocatalyst materials at 20 ∘ C, pH 4, and 120 rpm and under UV light.

Figure 10 :
Figure 10: Linear plot of ln   / against time () for the reduction of Cr(VI) using 200 mg of NiFe 2 O 4 -SiO 2 and photocatalysts.

Figure 11 :
Figure 11: Effect of catalyst dose on the photocatalytic reduction of 100 cm 3 10 mg/L Cr(VI) at 120 rpm in the presence of (a) 50 mg, (b) 100 mg, (c) 150 mg, and (d) 200 mg of NiFe 2 O 4 -SiO 2 and photocatalysts under UV light at room temperature and 300 min irradiation time.
NiFe 2 O 4 -SiO 2 .SiO 2 was used to coat the surface of NiFe 2 O 4 using the method of Laohhasurayotin et al. (2012) with slight modification.300 mg of NiFe 2 O 4
4 in the XRD pattern of NiFe 2 O 4 -SiO 2 -TiO 2 and NiFe 2 O 4 -TiO 2 composite samples show the successful incorporation of NiFe 2 O 4 -SiO 2 and NiFe 2 O 4 , respectively, in the composite catalysts [24, 25].The crystallite sizes of NiFe 2 O 4 , NiFe 2 O 4 -TiO 2 , NiFe 2 O 4 -SiO 2 -TiO 2 , and TiO 2 obtained using Scherrer formula with (311) and (101) diffraction peaks for NiFe 2 O 4 [37,38]straight line was obtained from the data with  2 values of 0.96136, 0.94901, and 0.97108 and corresponding  app values of 0.00289 min −1 , 0.01049 min −1 , and 0.01371 min −1 for NiFe 2 O 4 -SiO 2 , NiFe 2 O 4 -SiO 2 -TiO 2 , and TiO 2 , respectively, indicating that all the data fitted well into the linear equation for the photocatalytic reduction of Cr(VI) solution conducted at pH 4.0 and 200 mg of NiFe 2 O 4 -SiO 2 and photocatalyst materials.The photocatalytic experiments successfully fitted well into the Langmuir-Hinshelwood (L-H) kinetic model and are described by the pseudo-first-order kinetics suggesting a surface reaction where Cr(VI) was absorbed at the rate determining step for the process.Similar results have been reported by Ku and Jung and Sun et al.[37,38].
the photocatalytic reduction of Cr(VI) in aqueous solution under UV light.An increase in the reduction capacity of Cr(VI) was observed for all photocatalysts from 50 mg, 100 mg, 150 mg, and 200 mg catalyst dose (Figures 11(a), 11(b), 11(c), and 11(d)).Also, as the photocatalyst dose increases from 50 mg to 200 mg; the time for complete photocatalytic 2 O 4 -SiO 2 -TiO 2 had 68.92% reduction efficiency after 300 min and NiFe 2 O 4 -TiO 2 50.36% reduction efficiency.These results signify that the photocatalyst materials can be regenerated for reuse and that NiFe 2 O 4 -SiO 2 -TiO 2 again performed better than NiFe 2 O 4 -TiO 2 showing better reusability.It is worth knowing that NiFe 2 O 4 -SiO 2 was not tested for its reusability in this study since it did not show any photocatalytic activity towards the reduction of Cr(VI) in aqueous solution.
2 O 4 -SiO 2 -TiO 2 ) by coating NiFe 2 O 4 , a magnetic core with a SiO 2 interlayer and hydrolyzing with photocatalytic TiO 2 was achieved.In addition, TiO 2 in an anatase phase, NiFe 2 O 4 -TiO 2 , and NiFe 2 O 4 -SiO 2 were also synthesized for the reduction of Cr(VI) in aqueous solution.FTIR and XRD analysis confirmed the formation and coexistence of anatase TiO 2 and spinel NiFe 2 O 4 while microscopic studies revealed that TiO 2 photocatalyst was deposited on ferrite nanoparticle in the composites.Photocatalytic