Effect of Nano-ppy / OMMT on the Physical and Electrochemical Properties of an Ionic Liquid Gel Polymer Electrolyte

A new type of nanopolypyrrole/organically modified montmorillonite-ionic liquid gel polymer electrolyte (ppy/OMMTILGPE) is prepared based on nanopolypyrrole/organically modified montmorillonite (ppy/OMMT), N-butyl-Nmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PP14TFSI), lithium-bis(trifluoromethanesulfonyl) (LiTFSI), polyvinylidene difluoride (PVDF), methyl methacrylate (MMA), and benzoyl peroxide (BPO) by an in situ method. The effect of nano-ppy/OMMT on the physical and electrochemical properties of an ionic liquid gel polymer electrolyte is demonstrated. The results show that nanoppy/OMMT-ILGPE has a porous structure with a large surface area, and the diameter of the pores on the surface is approximately 12μm.TheLi+ transference number of 0.72 is achieved, and the ionic conductivity reaches up to 1.2× 10 S/cm at room temperature. Nano-ppy/OMMT-ILGPE has good thermal stability and mechanical properties. Meanwhile, nano-ppy/OMMT-ILGPE has fine cycle performance in the Li|nano-ppy/OMMT-ILGPE|LiNi1/3Co1/3Mn1/3O2 coin cell. The good electrochemistry performance of nano-ppy/OMMT-ILGPE means that it can act as an ideal gel polymer electrolyte material for lithium ion batteries.


Introduction
The organic electrolyte plays an important part in lithium ion batteries (LIBs).However, the organic electrolyte is volatile, toxic, and explosive to the environment, and the development of LIBs has been limited.Therefore, ionic liquid gel polymer electrolytes (ILGPEs) that do not leak and have good electrochemical stability as well as high conductivity have increasingly drawn the attention of researchers in recent years [1][2][3][4].With respect to ILGPEs, ionic liquids have more advantages than other liquid electrolytes, such as a higher dielectric constant, no combustibility, higher thermal stability, and less volatility [5].PVDF, which has a high degree of crystallization, is a common organic polymer support material in the field of ILGPEs [6].However, the high degree of crystallization may hinder the migration of lithium ions and increase the internal resistance of the LIB [7][8][9].Polymethyl methacrylate (PMMA) also serves as a common organic polymer support material.PMMA with liquid electrolyte can form gel phases.Thus, the PMMA support material can adhere to the electrode and has a high ionic conductivity with liquid electrode well [10,11].However, the crystallization of PMMA is reduced after adding a liquid electrolyte, affecting the mechanical strength of PMMA [9,10].
To improve the mechanical strength and electrochemical properties of the gel polymer electrolyte, nanolayered silicates are added to the gel polymer electrolyte and are called nanocomposites.Nanocomposites that have functional advantages and structures have a more promising future than other conventional gel polymer materials [11].Among the commonly used inorganic layered structures, nanomontmorillonite (MMT) has been preferentially considered due to its special features, such as its length scale (clay channel width = 16 × 10 −10 m), high cation-exchange capacity (CEC ∼ 80 mequiv./100g), high aspect ratio (∼1000), large specific surface area (∼31.82m 2 /g), and appropriate interlayer charge (∼0.55), which makes MMT suitable for nanocomposites [12].During charge/discharge processes, the interaction between MMT and impurities from the polymer electrolyte and electrode improves the interfacial stability of the electrode and electrolyte [13,14].The high cationic exchanges of MMT that act as Lewis acid centres on the surface can retard the transformation of cation and polymer segments into complexes [13], leading to changes of the MMT structure and the formation of conduction pathways.The interaction between the liquid electrolyte and MMT changes the micropore diameter of the polymer, enhancing the mechanical strength and absorbency rate of the liquid electrolyte [15,16].Thus, nano-MMT doped into an ILGPE would be beneficial to enhance the mechanical strength and electrochemical properties of the ILGPE.In this work, under the action of FeCl 3 as the oxidant and sodium p-toluene sulfonate (TSANa) as the swelling agent, pyrrole (py) monomer was polymerized between the molecular layers of nano-organic modified montmorillonite (OMMT) by an in situ method.This method was used to prepare nano-ppy/OMMT, leading to enhanced electrochemical properties.Nano-ppy/OMMT was added to a homogenous solution (PVDF, MMA, BPO, LiTFSI, and PP14TFSI) at different ratios.Composite ionic liquid gel polymer electrolytes were prepared by this in situ method.A PVDF-PMMA copolymer was used as the support material for the ILGPE to reduce the crystallinity and improve the ionic conductivity.The PMMA amorphous phase absorbed the liquid electrolyte.The PVDF crystalline phase improved the mechanical capacity of the gel polymer electrolyte membrane.
The microstructure and electrochemical performance of nano-ppy/OMMT-ILGPE are discussed in detail.

Modified Principle and Preparation of Nano-ppy/OMMT.
OMMT is prepared by the cationic exchange reaction between octadecyl dimethyl ammonium chloride (ODAC, AR, Tianjin Guangfu), as an organic intercalation agent, and Al 3+ in nano-MMT (AR, Aladdin).The grain diameter of nano-OMMT became smaller and the layer spacing expanded.This enhanced the access of py monomer (AR, Beijing J&K) to the space between the molecular layers.To further expand the OMMT layer spacing, py monomer was polymerized between the molecular layers during the reaction with FeCl 3 (AR, Tianjin Guangfu), as the oxidant, and TSANa (AR, Tianjin Guangfu), as the swelling agent.This method has been applied to prepare nano-ppy/OMMT, as shown in Figure 1(a) [15,17,18].
First, MMT was dissolved and stirred vigorously in deionized water for 12 h at 60 ∘ C until it was fully dispersed.Then, ODAC, an intercalating agent, was added (MMT and ODAC at a ratio of 5 : 1 by mass) and stirred for 15 h at 60 ∘ C until a homogenous solution was formed.Second, the solution TSANa and py monomer were mixed at the appropriate ratio and were dissolved and vigorously stirred for 1 h at room temperature.Thirty millilitres of 1 mol/L FeCl 3 was added and stirred for 6 h at room temperature.Finally, the product was washed, separated by a centrifuge, and then placed into a high vacuum drying oven for 15 h at 80 ∘ C (see Figures 1(b) and 1(c)).

Electrode Preparation and Cell
Assembly.The positive electrode was prepared by adding a LiNi 1/3 Co 1/3 Mn 1/3 O 2 (Shenzhen KeJing Co., Ltd.) active material powder, acetylene black (Shenzhen KeJing Co., Ltd.), and PVDF binder at a mass ratio of 8 : 1 : 1 to NMP with constant stirring for 10 h at 100 ∘ C until a viscous slurry formed.Then, the resulting viscous slurry was cast onto an aluminium foil (14 mm thickness), as a current collector, and dried at 100 ∘ C in a vacuum oven for 10 h.A cell was assembled by sandwiching nano-ppy/OMMT-ILGPE between the LiNi 1/3 Co 1/3 Mn 1/3 O 2 positive electrode and lithium metal negative electrode.Then, the cell was pressed with a hydraulic press at a pressure of 10 MPa.All of the manufactured cells were manufactured in a dry argon atmosphere glove box.
2.4.Characterization.IR spectra were effective at describing the characteristics and interactions of different groups.These were recorded in the spectral range of 4000 to 400 cm −1 at room temperature.The chemical structures of MMT and nano-ppy/OMMT were investigated using the IR spectrometer (FTIR-1500) and Raman spectrometer (RENISHAW-inVia reflex).The interlayer spacing and crystallization of MMT, OMMT, and nano-ppy/OMMT were studied by X-ray diffraction (XRD) using an automatic Japanese D/MAX-2500 powder diffractometer with monochromatic Cu K radiation under the following conditions: voltage and current of 30 kV and 30 mA, respectively; scanning range of 1 ∘ ≤ 2 ≤ 15 ∘ ; scanning speed of 3 ∘ /min; and incident X-ray wavelength of 0.154 nm.Scanning electron microscopy (SEM, Nano SEM 430) and transmission electron microscopy (TEM, JEM-2100F) were used to study the structure and surface morphology of MMT, nano-ppy/OMMT, ILGPE, and nanoppy/OMMT-ILGPE.The tensile properties of ILGPE and nano-ppy/OMMT-ILGPE were evaluated at room temperature following ASTM D 638 type V method, using the universal material testing machine (WDW5000).The crosshead speed is 10 mm/min and the load cell capacity is 5000 N.For two specimens (10 mm × 5 mm), the measurements were taken and the values of tensile strength were calculated [22].Thermogravimetric analysis (TGA, STA409EP, Netzsch) was performed to investigate the thermal characteristics of ILGPE and nano-ppy/OMMT-ILGPE from room temperature to 700 ∘ C at a heating rate of 10 ∘ C/min in a nitrogen atmosphere.AC impedance spectroscopy was used to test ionic conductivity of ILGPE and nano-ppy/OMMT-ILGPE with two stainless steel blocking electrodes over a frequency range from 0.01 Hz to 10 5 Hz at 20 ∘ C. Both the Li-ion transference number determination and cyclic voltammetry (CV) were important in evaluating the performance of the electrolyte membrane.A combination of the amperometric I-t curve and AC impedance was applied to determine the Li-ion transference number.CV was used to measure the range of oxidation potential and reduction potential in the reversible electrode reaction.Electrochemical impedance spectroscopy (EIS) was used to investigate the interfacial behavior of the cells over a frequency range of 0.01 Hz to 10 5 Hz with an amplitude of 10 mV.The above experiments were used with CHI660E.The charge/discharge performances and cycling behavior of the Li|nano-ppy/OMMT-ILGPE|LiNi 1/3 Co 1/3 Mn 1/3 O 2 and Li|ILGPE|LiNi 1/3 Co 1/3 Mn 1/3 O 2 cells were tested by battery testing equipment (CT2001A) with a testing voltage between 2.7 V and 4.2 V.

Results and Discussion
In Figure 2(a), 1020.98 and 1026.07 cm −1 represent the vibration absorption of Si-O; 472.09 and 469.31 cm −1 represent the bending vibration of O-Al in the MMT lattice.The polymerization reaction of the py monomer (Figure S1) between the layers of MMT has a small effect on the vibration absorption peaks.This indicates that the structure of MMT cannot be changed after organic modification [23].ppy has the characteristic peaks of N-H and C=C.The vibration absorptions of N-H appear at 3460.22 and 1460.12cm −1 , and the stretch vibration of C=C appears at 1640.23 cm −1 .This suggests that py monomer becomes ppy between the MMT layers.
Figure 2(b) shows the obvious differences of the MMT and nano-ppy/OMMT samples in the Raman spectra, which confirm the organic modification of the MMT.The several characteristic peaks at 1156, 1577, and 971 cm −1 are ascribed to ring-stretching mode in the curve of nano-ppy/OMMT.They corresponded to the D-band (C-C, the disordered graphite structure), G-band (C=C, sp 2 -hybridized carbon), and C-H in-plane deformation of ppy, respectively [24,25].It is in line with the result of FTIR (Figure 2(a)).
The interlayer spacing is calculated by using the following Bragg equation: where  is the layer spacing,  is the semi-diffraction angle, and  is the incident X-ray wavelength.
Figure 2(c) shows the XRD patterns of MMT, OMMT, and nano-ppy/OMMT.MMT exhibits the (0 0 1) diffraction peak at 2 = 6.18 ∘ , corresponding to an interlayer spacing of 1.42 nm.The (0 0 1) diffraction reflection shifts to 2 = 4.78 ∘ for OMMT and corresponds to an interlayer spacing of 1.84 nm.This can be explained by the cationic exchange reaction between ODAC and MMT.The long alkyl chain of ODAC can increase the interlayer spacing of OMMT by up to 1.84 nm.The shape of the OMMT peak is broader, meaning that the crystallization of OMMT is weakened.Thus, it is easier for the py monomer to gain access between the layers of OMMT.Via interactions with FeCl 3 , as the oxidant, and TSANa, as the swelling agent, py monomer undergoes the polymerization reaction in situ between the molecular layers.For nano-ppy/OMMT, the (0 0 1) diffraction reflection shifts to 2 = 2.68 ∘ , corresponding to an interlayer spacing of 3.61 nm.Meanwhile, the diffraction peaks are substantially broader, indicating that the amorphous state of nano-ppy/OMMT is enhanced.This can improve the ionic conductivity and other electrochemical properties of the ionic liquid gel polymer electrolyte [26][27][28].
Figures 3(a) and 3(b) shows the surface morphologies of MMT and nano-ppy/OMMT by TEM.SEM images of the ILGPE and nano-ppy/OMMT-ILGPE are shown in Figures 3(c) and 3(d).In Figure 3(a), MMT has a particle size, with a diameter of 1-2 m.However, the lamellar structure of nano-ppy/OMMT, which has a diameter of approximately 50-100 nm, is evident in Figure 3(b).This provides the basis to construct the porous structure of the gel-type composite electrolyte.As shown in Figures 3(c) and 3(e), the sizes of the pores on the ILGPE surface are approximately 5-15 m.The sizes and the number of pores are affected by the content and properties of the additive in the casting solution [29,30].Figures S2, 3 the proportion of amorphous region increases.Meanwhile, many micropores are formed among aggregates, which are staggered and interconnect into the membrane [30].Thereby, nano-ppy/OMMT can decrease the diameter of pores and create a porous structure.Nano-ppy/OMMT-ILGPE could effectively promote Li + migration and avoid negative effects on the surface of nano-ppy/OMMT-ILGPE [31].Thus nanoppy/OMMT has a significant effect on the average diameter of the pores, which would be beneficial to the migration of Li + and further enhance the ionic conductivity.
To test the mechanical capacity of nano-ppy/OMMT-ILGPE, the tensile test is used to separately test nanoppy/OMMT-ILGPE and the ILGPE.The mechanical parameters derived from Figure 4(a) are listed in Table 1.From Table 1, the tensile strength of nano-ppy/OMMT-ILGPE (1.82 MPa) is higher than that of ILGPE (0.88 MPa) without nano-ppy/OMMT.The elongation at sample breakage of nano-ppy/OMMT-ILGPE (5.87 mm) is shorter than that of  It can be seen from Figure 4(b) that ILGPE decomposes in two steps.From 100 ∘ C to approximately 300 ∘ C, the curves of ILGPE and nano-ppy/OMMT-ILGPE show the evaporation of the NMP solvent.For the curve of ILGPE, the decomposition of both the copolymer and LiTFSI starts at approximately 310 ∘ C, and 90% weight loss is detected at 410 ∘ C. For the nano-ppy/OMMT-ILGPE, the decomposition of ppy ranges from 350 ∘ C to 410 ∘ C [32].The copolymer and LiTFSI of nano-ppy/OMMT-ILGPE begin to decompose at approximately 350 ∘ C, and 70% weight loss is detected at 500 ∘ C [33,34].Because of the addition of nano-ppy/OMMT, the intermolecular force between macromolecular chains and nano-ppy/OMMT is larger than that between individual chains; nano-ppy/OMMT is fully dispersed in the electrolyte membrane.As external heat is transmitted to the inner region of the electrolyte membrane, the layer structure of nanoppy/OMMT can block the heat transmission.Therefore, ILGPE with nano-ppy/OMMT can delay the evaporation of the NMP solvent and decomposition of the copolymer and LiTFSI.The thermal decomposition temperature of nano-ppy/OMMT-ILGPE is increased, which means that nano-ppy/OMMT-ILGPE has good thermal stability for the preparation of LIBs.
The ionic conductivity of the electrolyte membrane strongly depends on Li + migration.The AC impedance technique at room temperature reveals that different addition ratios of nano-ppy/OMMT affect the ionic conductivity of nano-ppy/OMMT-ILGPE. Figure 5(a) shows the Nyquist plots of gel polymer electrolyte with different addition ratios of nano-ppy/OMMT, and the values are less than those of ILGPE without nano-ppy/OMMT.Equation ( 2) is used to calculate the ionic conductivity: where   is the bulk resistance,  is the film thickness,  is the surface area of the electrode, and  is the ionic conductivity.
The results are listed in Table 2. ILGPE without nano-ppy/OMMT has an ionic conductivity of 9.1 × 10 −5 S/cm, while the conductivity of the ILGPE  5(b) and 5(c), it can be concluded that nano-ppy/OMMT, with its high surface area and layer structure, can inhibit accumulation and crystallization of polymer segments, as well as the closure of pores.More conducting pathways are formed and the ionic transfer ability is enhanced by expanding the free volume, reducing the crystallinity and increasing the amorphous region [31].By contrast, the ionic conductivity of 10% nano-ppy/OMMT is lower than that of the 8% nano-ppy/OMMT-ILGPE.The former is attributed to the presence of excess nano-ppy/OMMT, and a denser structure of nano-ppy/OMMT-ILGPE is formed, impeding the conducting pathways and retarding ion migration.When 8% nano-ppy/OMMT is added, the ionic conductivity of nano-ppy/OMMT-ILGPE is optimized.The conductivity of ILGE mainly depends on the migration of the free ions produced in the electrolyte.The lower the apparent activation energy is, the easier the free Li + migration is.The bulk resistance (  ) of nano-ppy/OMMT-ILGPE is tested by electrochemical impedance spectroscopy (EIS) from 20 ∘ C to 80 ∘ C. Conductivities () at different temperatures are obtained according to (2).The detailed parameters are listed in Table 3, and the linear relationship of log  value and 1000/T conforms to Arrhenius conductive behavior presented in Figure 6 [33].The correlation coefficient  2 = 0.96 of the straight line is obtained: where   is apparent activation energy,  is the absolute test temperature,  is the gas constant, and  is the ionic conductivity.
From Figure 6, the fitting result of nano-ppy/OMMT-ILGPE is extracted from the Arrhenius equation;   is 30.10 kJ/mol.The apparent activation energy is lower than the values ever reported [33], which is conducive to the free migration of Li + .This demonstrates that nano-ppy/OMMT-ILGPE is good for lithium ion batteries.Meanwhile, the linear relationship of  and temperature conforms to the Vogel-Tamman-Fulcher (VTF).The detailed parameters and fitted curve are exhibited in Table S1 and Figure S3. between the electrode and electrolyte is calculated using the line at low frequency [35,36].There is no significant change in   before and after the test.However,   clearly increased after the test, which may be related to passive film forming between the electrolyte membrane and lithium electrode.The diameter expansion of the   -  semicircles shows an increase in the interface resistance after polarization, thereby restraining the diffusion of lithium ions and the subsequent transfer reaction.The Li-ion transference number ( Li + ) represents the charge of the interface resistance before and after polarization and is calculated using (4).The values of the parameters are listed in Table 4.In Figure 7 and Table 4, when nano-ppy/OMMT is doped into ILGPE, the 1-2 m pores appear on the surface which stagger and interconnect into the membrane in Figure 3(f).The porous structure of nano-ppy/OMMT-ILGPE can get a high surface area.In some way, the Li-ion intercalation and deintercalation abilities are increased, and the transfer resistance of nano-ppy/OMMT-ILGPE is decreased [31].The Li-ion transport of nano-ppy/OMMT-ILGPE is effectively improved.The porous structure of nano-ppy/OMMT-ILGPE increases  Li + up to 0.72, which is approximately twice that of ILGPE without nano-ppy/OMMT.Therefore, nanoppy/OMMT-ILGPE can contribute to the improvement of Liion transport in the LIBs.
In Figure 8(a), the reduction peak and oxidation peak appear at 3.4 V and 4.2 V in the 1st cycle, respectively.The cathodic peak shifts to a lower potential in the 2nd cycle, which indicates that a passive film is formed between the electrolyte membrane and cathode material during the 1st cycle [37].After activation and formation of the passive film in the 1st cycle, the reduction peak shifts to 3.25 V, which could be ascribed to the diffusive phenomena between the cathode and membrane during the 2nd cycle.The peak positions are invariable in the 3rd and 4th cycles.In the following cycles, nano-ppy/OMMT-ILGPE exhibits better compatibility, stability, and reversibility.
To confirm the difference in the thicknesses of the passive films on the surfaces of nano-ppy/OMMT-ILGPE and ILGPE subjected to charge and discharge tests at room temperature, the EIS values of the cells before and after 100 cycles at 0.5 C are shown in Figures 8(d) and 8(e).In Figure 8(d), the bulk resistance (  ) and charge transfer resistance ( ct ) of the cell assembled with nano-ppy/OMMT-ILGPE are smaller than those of the cell with ILGPE before 100 cycles because the porous structure of the electrolyte membrane is improved when nano-ppy/OMMT is doped into ILGPE.The porous structure of nano-ppy/OMMT-ILGPE with a high surface area can absorb more electrolyte and form more conducting pathways, thus improving the ability of lithium to migrate.Therefore, the porous structure of nano-ppy/OMMT-ILGPE can reduce the   and  ct of nano-ppy/OMMT-ILGPE.After 100 cycles, nano-ppy/OMMT-ILGPE and ILGPE present two separate semicircles at the high and low frequencies, which are caused by the solid electrolyte interface resistance ( SEI ) and  ct (see Figure 8(e)) [40].Compared with the  SEI of ILGPE, the  SEI of nano-ppy/OMMT-ILGPE is significantly low because nano-ppy/OMMT reacts with impurities to inhibit any negative effects between the surfaces of the electrode and membrane.The Li-ion deintercalation ability increases, which could reduce  and make the passive film thinner [41]. ct of the nano-ppy/OMMT-ILGPE is substantially smaller than that of ILGPE because the improved porous structure of nano-ppy/OMMT-ILGPE increases the Li-ion deintercalation ability and reduces  ct to some extent.This reveals that the porous structure of nano-ppy/OMMT-ILGPE is beneficial to the increase of the transfer ability of lithium ions and to the improvement of the cycle stability of the lithium ion battery.
To confirm the electrochemistry performance of nanoppy/OMMT-ILGPE, the reversible discharge capabilities of the cells with nano-ppy/OMMT-ILGPE and ILGPE at different C-rates are evaluated, as shown in Figure 8(f).The testing voltage is between 2.7 V and 4.2 V, and the charge/discharge current density ranges from 0.2 C to 2 C. The reversible discharge capacities of the cells with nano-ppy/OMMT-ILGPE and ILGPE are 129.1 and 120.1 mAh/g (0.2 C), 114.6 and 103.5 mAh/g (0.5 C), 106.3 and 88.9 mAh/g (1 C), and 96.2 and 71.3 mAh/g (2 C), respectively.The reversible discharge capacity gradually decreases, while the current density increases.The differences between the electrolyte membranes become more evident at the higher current densities.The reversible discharge capacity of the cell with nanoppy/OMMT-ILGPE is 96.2 mAh/g (2 C), meaning that the discharge performance of nano-ppy/OMMT-ILGPE is better at a high current density.When the current density is further decreased to 0.2 C, the reversible discharge capacity of the cell with nano-ppy/OMMT-ILGPE is 118.7 mAh/g.However, the reversible discharge capacity of the cell with ILGPE is 91.6 mAh/g.It is found that the discharge performance of the cell with ILGPE is optimized after the addition of nanoppy/OMMT [42].

Conclusions
Nano-ppy/OMMT is prepared in situ during the polymerization reaction of the py monomers between the molecular layers of MMT.The diameter of nano-ppy/OMMT is approximately 50-100 nm, and it has a flake structure and large interlayer spacing.Nano-ppy/OMMT is considered to be a good inorganic doping agent for the preparation of a composite gel polymer electrolyte with a porous structure.Nano-ppy/OMMT-ILGPE has a porous structure with an approximately 1-2 m aperture, relatively high transference number of lithium ion (0.72), and high conductivity (1.2 × 10 −3 S/cm) at room temperature.The good electrochemical stability of nano-ppy/OMMT-ILGPE is favourable for use in Li/LiNi 1/3 Co 1/3 Mn 1/3 O 2 cells.Nano-ppy/OMMT-ILGPE exhibits better charge/discharge cycling at 0.5 C and is superior to ILGPE in specific capacity and cycle stability.Therefore, nano-ppy/OMMT-ILGPE has many advantages, such as good thermal stability, mechanical performance, and environmental friendliness, as well as a high energy density and cycling stability, and can be used as an ideal gel polymer electrolyte material for lithium ion batteries.
are many large pores in ILGPE, the polymer segment can stretch and shift under the action of external force.When nano-ppy/OMMT is uniformly distributed in the electrolyte membrane, the distance between molecular chains is decreased.The structure of nano-ppy/OMMT-ILGPE gets tighter.When the sample of nano-ppy/OMMT-ILGPE is

Table 3 :
The resistance of nano-ppy/OMMT-ILGPE and related data in different temperature.
where  0 and   are initial and steady-state current values, Δ is the applied potential difference (10 mV), and  0 and   are the initial interfacial resistance and steady-state interfacial resistance, respectively.