Temperature Dependence of Sensors Based on Silver-Decorated Nitrogen-Doped Multiwalled Carbon Nanotubes

1Department of Physics, Umeå University, 90187 Umeå, Sweden 2Department of Chemistry, Umeå University, 90187 Umeå, Sweden 3Advanced Materials Department, IPICYT, Camino a la Presa San José 2055, Colonia Lomas 4 Sección, 78216 San Luis Potośı, SLP, Mexico 4Instituto Tecnológico Superior de Irapuato, Carretera Irapuato-Silao Km. 12.5 Colonia El Copal, 36821 Irapuato, GTO, Mexico 5Centro de Nanociencias y Micro y Nanotecnologı́as, Instituto Politécnico Nacional, Luis Enrique Erro S/N, Colonia Zacatenco, 07738 Delegación Gustavo A. Madero, DF, Mexico 6Institute of Carbon Science and Technology, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan 7Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY 12180, USA 8Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan 9Department of Physics, Department of Materials Science and Engineering and Materials Research Institute, The Pennsylvania State University, 104 Davey Lab., University Park, PA 16802-6300, USA


Introduction
Carbon nanotubes (CNTs) have proved to be excellent candidates for sensing applications.Multiwalled carbon nanotubes (MWCNTs) based sensors are sensitive to a variety of gases such as NH 3 , NO, NO 2 , H 2 , SF 6 , and Cl 2 [1][2][3].Different devices have been used to fabricate CNTs sensors for the detection of vapors and gases; the most common are field effect transistors [4] and resistors [5][6][7][8].Because of their simplicity and simple fabrication, the resistor is a frequently used arrangement, where the change in electrical conductivity is monitored when the sensor is exposed to various atmospheres.One common disadvantage of carbon nanotubes based gas sensors is the potential interference from 2 Journal of Sensors relative humidity at room temperature, the slow recovery, and poor selectivity.There have been a variety of attempts to overcome these limitations, such as heat treatment, ultraviolet light irradiation, increasing carrier gas flux, and modification of CNTs with functional groups or other additives [9].
Chemically functionalized CNTs have been used as an active component in sensor devices; the addition of functional groups such as carboxylic acid in CNTs has demonstrated enhanced sensitivity to ethanol [10] and nitric oxide gas [11].Other approaches involve the incorporation of carbon nanotubes into polymers to form nanocomposites [12].Nanocomposite materials such as CNTs decorated with metal or metal oxide nanoparticles have been proposed as an active component in gas sensing devices.These nanoparticlesnanotube systems have attracted much attention because of their unique and enhanced sensitivity toward gaseous species such as H 2 , H 2 S [8, 13,14], NO 2 [5,8,15], NH 3 , and CO [15,16] compared to pure nanotube gas sensors [17].
Nitrogen-doped MWNTs (CN  -MWNTs) have also been shown to be an excellent approach to overcoming some limitations which exhibit pure carbon nanotube systems in gas sensing applications [6,18,19] due to their higher chemical reactivity at the surface.The use of CN  -MWNTs avoids the use of hazardous strong acidic treatments and additionally, these materials are better candidates for anchoring diverse nanoparticles [20][21][22] and fabrication of more sensitive sensors.The decoration of CNTs with silver nanoparticles (Ag-NPs) has been extensively explored [23][24][25][26], and the resulting hybrid composites have proved to be an excellent active component for sensing biological materials [27,28].
By taking advantage of the facility to deposit metallic nanoparticles on CN  -MWNTs and the high affinity that Ag exhibits to sulfur containing molecules, we have fabricated a carbon disulfide (CS 2 ) gas sensor.We selected CS 2 as a targeting gas because of its potential hazard to human health.Nowadays, the most feasible and widely accepted technique for the analysis of reduced sulfur compounds (RSC) in air is gas chromatography (GC) [29].CS 2 is one of the most abundant RSCs in the environment [30].Pure CS 2 is highly volatile, the vapor can explode in the air, and the exposure affects the nervous system and developing fetus; its chronic exposure may lead to kidney and liver damage [31].For these reasons and due to the difficulty in the detection and quantification of CS 2 vapor, the developing of portable, sensitive, and selective sensors is needed to overcome the timeconsuming and tedious processes of sampling and offline analytical protocols in the laboratory.Some considerable efforts have been done to detect CS 2 ; some reports use metal oxide nanomaterials such as CeO 2 [32] and doped TiO 2 [33], while others use quartz crystals as a surface acoustic wave sensor [34], often resulting in complex experimental setups.But despite this effort, the CS 2 vapor detection is still a challenge and developing materials used for manufacturing a portable sensor with improved properties is an ongoing investigation.
In the present work, we propose the use of Ag-decorated CN  -MWNTs-Ag as sensor devices.Different fabricated sensors were tested using CS 2 , ethanol, acetone, and chloroform vapors.Thermal effects are also considered on the sensors performance.In addition, first-principles calculations are carried out in order to understand the interaction between carbon nanotubes, Ag-NPs, and the involved organic molecules.

Experimental Details
2.1.CN  -MWNTs-Ag Production and Sensors Fabrication.CN  -MWNTs are synthesized by chemical vapor deposition (CVD) by pyrolyzing a solution containing 2.5 wt% of ferrocene and benzylamine at 825 ∘ C in an Ar atmosphere for 30 min [35].The nitrogen content of these CNTs is around 2% [36,37].Afterwards generating the CN  -MWNTs, the anchorage process of Ag-NPs is carried out as follows: the CN  -MWNTs are heated at 300 ∘ C in air during 5 min, in order to modify its surface by adding some oxygenated functional groups.Afterwards, 35 mg of nanotubes is added to 20 mL of acetone containing silver nitrate (166 L of a solution 0.1 N, J.T. Baker) in a flask.The suspension is dispersed ultrasonically for one hour.Subsequently, the solution is placed in a water bath at ∼50 ∘ C for 60 minutes.Finally, the solution is filtered using a PTFE membrane with 0.2 m pore size, washed with distilled water, and dried at 110 ∘ C in a furnace.The Ag-NPs exhibit an average diameter of 14 nm.
For the sensors fabrication, the following steps are followed.(a) Foils formed by dispersed CN  -MWNTs and CN  -MWNTs with Ag-NPs (CN  -MWNTs-Ag) are obtained by vacuum filtration using acetone as a solvent; the concentration of the suspension is selected to provide a homogeneous foil thickness.(b) The foil sensors are cut to obtain a surface of 0.5 × 4.0 mm.(c) The foils are supported on alumina plates with copper electrodes using silver paint.(d) The electrodes are connected to the source-meter and control system.In order to perform the experiment, the fabricated sensor devices are placed within a quartz tube inside a tubular furnace.The desired vapor is introduced by bubbling Ar gas (Ar flow of 0.3 L/min) into a deposit containing the corresponding liquid.

Material Characterization Techniques.
The characterization of the nanotubes films is carried out using a scanning electron microscope (FEG-SEM, FEI XL30 FEG/SFEG) operated at 3-20 kV.The X-ray powder diffraction patterns of all samples were performed using XRD D8 Advance-Bruker AXS, with Cu K  radiation ( = 1.54060Å).The operating current and voltage were maintained at 25 mA and 35 kV.High resolution images were taken with HRTEMfield emission Tecnai F30 operated at 300 kV.The electrical characterization of each sample was carried out using a SourceMeter (Keithley 2400) with Labview environment.In order to measure the sensing capacity of the foils, these were placed inside a quartz tube with a controlled temperature and atmosphere; a schematic of the experimental setup is shown in Figure S1 in Supplementary Material available online at http://dx.doi.org/10.1155/2016/4319498.Argon gas is used to purge and clean the nanotubes foils.Two different exposure intervals are used: 80 s for the gas to be detected and 120 s to purge the system with Ar gas; this process is repeated for at least five cycles.We then plotted the normalized resistance (  ) which is defined as   = ( −  0 )/ 0 , in which  represents the electrical resistance obtained in the sensing measurement;  0 is the initial value of the resistance.The sensitivity (%Δ) of the sensor is defined as the ratio between electrical resistance variation (Δ = (  −   )/  ) during gas exposure (  ) and the measured resistance before gas exposure (  ).

Computational Details
The electronic calculations are performed using density functional theory (DFT) [38,39] in the framework of general gradient approximation (GGA) with Perdew-Burke-Ernzerhof as exchange-correlation functional [40,41] as implemented in the SIESTA code [42].We use a double- basis set with additional polarization orbitals [43].The real-space grid used for charge and potential integration is equivalent to a plane wave cutoff energy of 150 Ry and 350 Ry for Ag(111) systems.The pseudopotentials were constructed from 4, 5, 6, 6, 7, and 11 valence electrons for the carbon, nitrogen, oxygen, sulfur, chloride, and silver atoms, respectively (C: 2s 2 2p 2 , N: 2s 2 2p 3 , O: 2s 2 2p 4 , S: 3s 2 3p 4 , Cl: 3s 2 3p 5 , and Ag: 5s 1 4d 10 ).The nitrogen-doped (5,5) single walled carbon nanotubes are constructed by using a supercell of 100 atoms (5 unit cells) and 3 nitrogen atoms with a pyridine-like doping configuration.Periodic boundary conditions are used and the intertube distance is kept to a minimum of 30 Å to avoid lateral interactions.For the case of Ag(111) surface, the systems are represented by (4 × 4) Ag(111) slab consisting of 4 layers, where the top two layers are freely relaxed.An 8 × 8 × 1 Monkhorst-Pack grid is used to sample the Brillouin zone.A Methfessel-Paxton smearing of 0.1 eV and a Pulay mixing are employed to aid convergence on the selfconsistent electron density.All the structures are relaxed by the conjugated gradient minimization until the maximum force is less than 0.04 eV/ Å.The adsorption energy (Δ ads ) is defined as Δ ads =  total −  surf −  mol , where  total is the energy of the total system (adsorbent + adsorbate). surf is the energy of the adsorbent (i.e., a nanotube or Ag(111) surface) and  mol is the energy of the adsorbate.Finally, the thermal stability of the adsorption process is verified by molecular dynamics (MD) using a time step of 1 fs for the integration of the equations of motion, for a minimum of 1000 steps.The temperature of 200 and 350 K is controlled by the Nose thermostat, using a Nose mass of 10.0 Ry⋅fs 2 [44].

Results and Discussion
Figure 1(a) depicts scanning electron microscopy (SEM) image of CN  -MWNTs-Ag.Note that the sample exhibits a good distribution of Ag-NPs along the nanotube surface.The monocrystalline structure of the Ag-NPs can be clearly observed by transmission electron microscopy (TEM) images as it is depicted in Figures 1(b) and 1(c), with an average diameter of 14 nm.High resolution TEM analysis (see Figure 1(c) and Figure S2) shows that Ag-NPs exhibit a well atomic arrangement indicating the formation of a single crystal with a thin amorphous layer on its surface (probably formed of carbonaceous material derived from the decoration process).X-ray diffraction analysis (Figure 1(d)) also confirms the crystallinity of the Ag-NPs and indicates that the nanoparticles exhibit a face centered cubic structure (fcc).After the decoration process, we fabricated diverse sensors, and Figure 1(e) depicts a SEM image of the nanotube foil used as the active sensor material; here, it can be appreciated that the foil is composed by well-dispersed CNTs. Figure 1(f) depicts a photograph of the fabricated sensor device showing the millimetric nanotube foils collocated between the copper electrodes.
The change in electrical resistance of the nanotube foils is monitored continuously during the entire sensing test in the presence of CS 2 , acetone ((CH 3 ) 2 CO), ethanol (C 2 H 5 OH), and chloroform (CHCl 3 ).The sensor sensitivity is obtained by analyzing the change in electrical resistance (%Δ) before and after vapor exposure.We have also estimated the response and recovery time of the sensing devices, where the response time is defined as the necessary time to reach the maximum electrical resistance after the vapor exposure.On the other hand, the recovery time is defined as the time needed to recover approximately 95% of its initial electrical resistance.In order to easily compare our results, we fabricated two different sensing devices: one is based on pure CN  -MWNTs, while the second one is fabricated using Ag-decorated CN  -MWNTs (CN  -MWNTs-Ag).Both nanotube sensors are exposed to CS 2 vapor, and the results are reported in Figure 2. The sensing experiments are carried out at three different temperatures (25,40, and 80 ∘ C).First, at room temperature (25 ∘ C) when the sensors are in contact with CS 2 vapor, their electrical resistance increases rapidly until saturation and it remains almost constant until the next purging cycle is applied.These results are depicted in Figure 2(a), where the shadow areas indicate the vapor exposure cycles.During the purging time, the electrical resistance decreases and returns nearly to the original value before vapor exposure.This behavior suggests that most of the adsorbed molecules on the nanotubes surface are removed during the contact with the purge gas.We also noted that the baseline is continuously decreasing after each purging cycle; this fact is related to the long-time molecule desorption.Pure and Ag-decorated CN  -MWNTs based sensors exhibit similar behavior with small response and recovery times (∼10 s), which are better than previously published reports [32][33][34]; see Table S1 in Supplementary Information.However, the increment in electrical resistance (%Δ) generated by the exposure to the organic vapor is larger for CN  -MWNTs-Ag (Δ = 36%) compared to pure CN  -MWNTs (Δ = 22%); these results indicate better sensitivity for CS 2 vapor in the case of the Ag-NPs-nanotube system.This increment may be related to the presence of Ag-NPs on the CN  -MWNTs, thus having more sites to attach foreign molecules, which could increase the electrical resistance.Our results are in good agreement with the previous reported data, where metal decorated nanotube systems exhibit an improvement in sensor sensitivity [7,8,[13][14][15][16].
The fast decrease in resistivity shown in Figure 2(a) suggests a weak interaction between the CS 2 molecules and the sensors at room temperature.This relative weak interaction could be understood for foils made only of CN  -MWNTs due to the typical low reactivity.However, for CN  -MWNTs-Ag sensor device, the change in electrical resistance (%Δ) is expected to be larger after each exposure cycle (i.e., the baseline should increase) since it is anticipated that sulfur atoms (from CS 2 vapor) interact in a stronger way with the Ag-NPs than with the carbon nanotube surface [7].Our observations could be explained by suggesting that Ag-NPs do not interact directly with the CS 2 molecules.
The nondirect interaction could be demonstrated by TEM characterization (see Figure 1(c) and Figure S2), where Ag-NPs exhibit small amorphous layer on their surface.At 40 ∘ C (Figure 2(b)), the baseline (in both sensor devices) remains practically constant after each exposure cycle, suggesting that chemisorption may become relevant as adsorption process.At this temperature, also the CN  -MWNTs-Ag composite displays the best performance and sensitivity; it exhibits a larger change in electrical resistance during vapor exposure compared to pure CN  -MWNTs device.At higher temperature (80 ∘ C, Figure 3(c)), both baselines (pure and Agdecorated CN  -MWNTs) increase slightly after each CS 2 exposure cycle, suggesting that chemisorption of CS 2 vapor is the main adsorption process.This event may also be related with the amorphous layer surrounding the Ag-NPs, which could be removed by thermal effects, and temporally allows that CS 2 molecules could be covalently attached to Ag-NPs.In Figure 3, the sensor devices are also tested at room temperature (25 ∘ C) using acetone, ethanol, and chloroform vapors.Similar to the CS 2 case, these results indicate that, at room temperature, the adsorption process is dominated by physisorption.The sensors based on CN  -MWNTs-Ag exhibit larger signal than sensors made of only CN  -MWNTs.We also tested the sensors at higher temperatures (70 ∘ C or more); the results (not shown) demonstrate that sensors present chemisorption effects; that is, the baseline of electrical resistance increased monotonously with the number of cycles of exposure; in this case the purge gas does not remove completely previously attached molecules in the nanotube surfaces.The response time for both nanostructured sensors, with and without Ag-NPs, is in the range of 10-20 s and the recovery time around 10-15 s.
The sensitivity (%Δ) of the sensor based on CN  -MWNTs-Ag for four different organic vapors is summarized in Figure 4; here the sensitivity (%Δ) is plotted versus operation temperature.Typically, for all gases and vapors, the sensor shows an enhanced sensitivity at higher operation temperature.However, at a certain temperature the sensor sensitivity decreases.These critical temperatures depend on the targeted analyte, being the lowest for ethanol, followed by chloroform, acetone, and finally CS 2 vapors.This critical temperature is also an indication in how strong is the interaction between the analyte and the nanocomposite, suggesting weaker interaction energies for ethanol and chloroform and larger for acetone and CS 2 .For ethanol, after 40 ∘ C the sensitivity decreases substantially; then after 50 ∘ C there is no clear response, which also indicates that the interaction energy with the nanosensors is easily overcome by the thermal energy.On the other hand, at 50 ∘ C the sensor sensitivity is the highest for chloroform vapor, but if the operation temperature reaches 80 ∘ C, the electrical change generated by introduction of chloroform is negligible.In the case of acetone or CS 2 , the CN  -MWNTs-Ag sensor at 80 ∘ C still exhibits a clear response and good sensitivity, and only after 130 ∘ C the response for acetone and CS 2 decreases considerably (not showed).These results suggest that, by varying the operating temperature, it is possible to control the detection of the desired vapor and improve the selectivity of the sensor device.

Theoretical Description of CN 𝑋 -MWNTs-Ag Gas Sensors.
Additionally, we performed density functional theory (DFT) calculations in order to understand the interaction between nitrogen-doped nanotubes and CS 2 , ethanol, acetone, and chloroform molecules.For the calculations a pyridine-like nitrogen-doped (5,5) single-walled carbon nanotube (CN  -SWNT) is considered.The pyridine-like doping consists in creating a vacancy and then substituting the carbon atoms surrounding the vacancy by three nitrogen ones; this site is one of the most common doping configurations [21,35].The organic molecules are set around the doping site and relaxed using the conjugated gradient method.After geometrical relaxation, in all cases, any covalent bond is observed between the CN  -SWNT and the analytes (see Figure S3 in the Supplementary Information), indicating a weak interaction in agreement with the experimental observations.In order to analyze the adsorption energies on Ag-NPs, we used an fcc Ag surface where the (111) crystal plane is used as adsorption site.This approach has been widely used to accurately determine adsorption energies for nanoparticle systems [45].Figure 5 summarizes the adsorption energy ( ads ) for all systems; here a negative energy is associated with stable configurations.Notice that %Δ increases with the operating temperature; however, in all systems, there exists a critical temperature where %Δ starts to decrease.This behavior suggests that controlling the working temperature, it is possible to discriminate the gas vapor to be detected, improving the selectivity of the sensor material.Figure 5: Adsorption energy ( ads ) of different molecules interacting with (a) (5,5)-single walled carbon nanotubes doped with nitrogen (note that all molecules exhibit a poor interaction with the nanotube surface, thus suggesting a physisorption), (b) Ag(111) surface, showing large values of  ads ; these results suggest that, in this case, chemisorption may be the main adsorption mechanism.Note that negative values of  ads are associated with stable configurations.that the involved organic molecules are weakly attached to the nanotube surface.The calculated  ads for acetone and chloroform are 0.08 and 0.05 eV, respectively, indicating a low interaction.In the case of CS 2 and ethanol the resulting  ads are −0.12 and −0.20 eV, respectively.When the bare Ag(111) surface is set in contact with the molecules (see Figure 5(b) and Figure S4 in the Supplementary Information), all values of  ads are negative and larger than those obtained from the nanotube system.Here, the oxygenated species such as acetone and ethanol exhibit the lowest values of  ads , −0.66 and −0.59 eV, respectively, whereas chloroform and CS 2 exhibit larger  ads equal to −0.70 and −0.88 eV, respectively.These  ads values can be classified as chemisorption, since typically a physisorption event exhibits energies > −0.5 eV.Our results are in good agreement with previous publications, where a low interaction with oxygenated species on Ag surfaces is observed [45].Now considering the results for CS 2 , we observe that CS 2 exhibit a weak interaction with pure carbon nanotubes, inferring that the molecules are joined via a physisorption mechanism, which is in qualitative agreement with the experimental sensing capacity at room temperature of foils made of pristine CN  -MWNTs.However, when the adsorption process is performed on the Ag(111) surface, the CS 2 molecule exhibits multiple covalent bonds with the substrate.These results imply a strong interaction when Ag-NPs are used as substrates, thus suggesting chemisorption mechanism as a main adsorption process in the sensor activity.In order to complement the results, we also performed DFT calculations on using an icosahedral Ag 13 cluster attached to a (5,5)-CN  -SWCNT and similar trends are found when compared with the Ag(111) surface, indicating that the nanotubes have a negligible effect on the adsorption properties of the composite.Similar results are obtained when acetone, ethanol, or chloroform is used on all systems.
Keeping our attention on the CS 2 case, the experimental evidence on the sensor response at room temperature suggests that the CS 2 vapor weakly interacts with CN  -MWNTs-Ag based foils (physisorption).Once the foil detects the gas vapor, this is easily removed by the purging gas.However, one would expect that the S atoms could be easily linked to Ag atoms due to the chemical affinity between these two elements, as indicated by our DFT data.Then, why CS 2 molecules exhibit a weak interaction with the foils avoiding chemisorption?In order to answer this question, we performed molecular dynamics simulations of the interaction between Ag clusters and CS 2 molecules.Firstly, it is noticed that, from the TEM images (see Figure 1(d)), the CN  -MWNTs decorated with Ag nanoparticles exhibit a covering layer composed of amorphous carbon.In order to understand the role of this amorphous layer on Ag-NPs in the sensing capacity, we constructed an Ag 55 icosahedral nanoparticle surrounded by a carbon layer (C 80 ).Each carbon atom was three-coordinated with Ag atoms; the initial structure and the relaxed geometry can be seen in Figures 6(a) and 6(b).Subsequently, we placed seven CS 2 molecules near the surface of the Ag 55 C 80 nanoparticle, the entire system was relaxed by conjugate gradient, and the resulting geometry is depicted in Figure 6(c).Then, using the latest geometry of the 7CS 2 -Ag 55 C 80 system, a molecular dynamics simulation was performed at 200 K during 1 ps with 1-femtosecond steps (Figure 6(d)), and it is observed that two CS 2 molecules are covalently attached to the Ag 55 C 80 .The relaxed structure at 350 K is shown in Figure 6(e); here the 7CS 2 -Ag 55 C 80 system exhibits five CS 2 molecules covalently attached to the Ag 55 C 80 cluster, suggesting that an increment of the temperature promotes the bond formation between the CS 2 molecules and the silver cluster decorated by carbon atoms; thus a chemisorption mechanism becomes relevant which are in accordance with the experimental evidence.

Conclusions
Vapor sensor devices based on Ag-NPs anchored on the surface of CN  -MWCNTs were fabricated and tested with different chemical substances: CS 2 , acetone, chloroform, and ethanol.Our results are compared to sensors made of pure nitrogen-doped multiwalled carbon nanotubes.The temperature dependence of the sensor performances was monitored; the results revealed that the sensor response and selectivity depend strongly on the temperature, promoting in some cases that vapor molecules are attached to the nanotubes surface via a covalent bond.We showed using density functional calculations that CS 2 , ethanol, acetone, and chloroform are weakly linked to the nitrogen-doped carbon nanotubes.However, when these molecules are set in by CONACYT-México Grant 60218-F1 (FLU).Eduardo Gracia-Espino acknowledges support from the Artificial Leaf Project Umeå (Knut and Alice Wallenberg Foundation) and the ÅForsk Foundation (14-541).Mauricio Terrones thanks JST-Japan for funding the Research Center for Exotic NanoCarbons, under the Japanese regional Innovation Strategy Program by the Excellence.The theoretical simulations were partially performed on resources provided by the Swedish National Infrastructure for Computing (SNIC) at the High Performance Computing Center North (HPC2N).

Figure 1 :
Figure 1: Ag-NPs anchored on the surface of CN  -MWNTs-Ag.(a) Scanning electron microscopy (SEM) image.((b) and (c)) Transmission electron microscopy (TEM) images.(d) X-ray diffraction pattern of decorated and nondecorated CN  -MWNTs.The C(002) peak is characteristic of MWCNTs; peaks at ∼43 degrees correspond to encapsulated FeC 3 , normally observed in MWCNTs.(e) Scanning electron microscopy (SEM) image of the sensor device which consists of a foil formed by CN  -MWNTs-Ag.(f) Sensor device photograph showing the nanotube foil over the copper electrodes.

Figure 2 :
Figure 2: Normalized electrical resistance of nanotube foils exposed to CS 2 vapors at three different operation temperatures for CN  -MWNTs (black line) and CN  -MWNTs-Ag (cyan thin line).(a) At 25 ∘ C a good performance in both sensor devices is observed; notice that after each purge cycle, the baseline remains constant, suggesting a weak interaction between vapor and sensor material (physisorption).(b) At 40 ∘ C, chemisorption and physisorption are both important; both devices still exhibit a good performance.(c) At 80 ∘ C the CN  -MWNTs-Ag still shows better performance than the pristine CN  -MWNTs device, but now the chemisorption process is the main detection mechanism.Notice that, in all operating temperatures, the CN  -MWNTs-Ag exhibits larger change in electrical resistance when it is exposed to the CS 2 vapor.The shadow areas indicate the exposure cycles to the CS 2 vapor, equivalent to 80 s.

Figure 5 (
a) shows results for the CN  -SWNT revealing

Figure 3 :Figure 4 :
Figure 3: Normalized electrical resistance of both CN  -MWNT and CN  -MWNT-Ag sensor devices exposed to (a) ethanol, (b) acetone, and (c) chloroform at room temperature (25 ∘ C).The shadow areas are exposure cycles of the different gases, equivalent to 80 s.The dashed (solid) line corresponds to sensors based on CN  -MWNTs decorated with Ag nanoparticles (pure CN  -MWCNTs).