Hydrogen Generation from Al-NiCl2/NaBH4 Mixture Affected by Lanthanum Metal

The effect of La on Al/NaBH4 hydrolysis was elaborated in the present paper. Hydrogen generation amount increases but hydrogen generation rate decreases with La content increasing. There is an optimized composition that Al-15 wt% La-5 wt% NiCl2/NaBH4 mixture (Al-15 wt% La-5 wt% NiCl2/NaBH4 weight ratio, 1 : 3) has 126 mL g−1 min−1 maximum hydrogen generation rate and 1764 mL g−1 hydrogen generation amount within 60 min. The efficiency is 88%. Combined with NiCl2, La has great effect on NaBH4 hydrolysis but has little effect on Al hydrolysis. Increasing La content is helpful to decrease the particle size of Al-La-NiCl2 in the milling process, which induces that the hydrolysis byproduct Ni2B is highly distributed into Al(OH)3 and the catalytic reactivity of Ni2B/Al(OH)3 is increased therefore. But hydrolysis byproduct La(OH)3 deposits on Al surface and leads to some side effect. The Al-La-NiCl2/NaBH4 mixture has good stability in low temperature and its hydrolytic performance can be improved with increasing global temperature. Therefore, the mixture has good safety and can be applied as on board hydrogen generation material.


Introduction
Hydrogen is a nonpolluting fuel and a clean energy which can be consumed and transformed to electricity in proton exchange membrane fuel cell (PEMFC). The development of PEMFC in vehicles and portable electronics requires large amounts of hydrogen storage at moderate temperature with high efficiency and low cost [1]. On board hydrogen generation from reaction of chemical hydrides or metals in aqueous solutions can storage more hydrogen at moderate temperature in comparison to conventional hydrogen storage materials [2]. Among these hydrogen generation materials, sodium borohydride (NaBH 4 ) and aluminum (Al) have been paid attention widely due to high theoretic hydrogen generation density, safe, controllable, and mild operating conditions. Many achievements showed that NaBH 4 -and Al-based hydrogen generation system attached to PEMFC can provide 2 W-10 kW powers [3,4]. Nevertheless, NaBH 4 and Al have many disadvantages. For example, NaBH 4 is an expensive raw material and alumina layer on Al surface reduces Al reactivity in water. The low solubility of NaBH 4 and NaBO 2 reduce hydrogen generation density and catalyst reactivity and durability [5]. So the disadvantages limit the commercial application of these hydrogen generation materials.
Hydrogen generation from solid-stage NaBH 4 or NaBH 4 /Al mixture in little water amount presents a good solution to overcome the disadvantages of traditional NaBH 4 -and Al-based hydrogen generation system. It has high hydrogen generation density and fast hydrolytic kinetic as exothermal reaction proceeds in limited water amount. Liu et al. [6] found that the uniform mixture of solid-state NaBH 4 and Ru-based catalyst has 7.3 wt% hydrogen generation density at 298 K, meeting the required target of USA department of energy (6.5 wt.%). Sodium borohydride/nanoaluminum could supply stable hydrogen generation with about 7 wt.% yield when their mass ratio is 1 : 1 [7]. Dai et al. [8] found that micro-Al/NaBH 4 /NaOH mixture had controllable hydrogen generation performance via regulating the amount and rate of CoCl 2 solution. In 2 The Scientific World Journal such case, water acts as an oxidizer for both aluminum and metal borohydride, thus as a source of hydrogen. There also exists an interaction of Al/NaBH 4 hydrolysis which improves their hydrolytic kinetics. However, there is a great shortcoming that nanoaluminum particle or alkaline solution has to be used to start the hydrolytic reaction. It is necessary to find an environmental-friendly metal which can improve aluminum reactivity in neutral aqueous solution at moderate temperature. Metal lanthanum is a good candidate. It is a good hydrogen generation material and its hydrolysis byproduct presents alkaline, which accelerates the hydrolysis kinetic of magnesium and aluminum [9,10]. Luo et al. [11] found that the addition of rare earth metal into aluminum alloy could effectively damage the dense oxide layer and led to the formation of flower-like nanoflake reaction products, which prevented the byproducts Al(OH) 3 from depositing densely on the surface of composites and stimulated Al hydrolysis.
We herein report a simple but effective method that can control hydrogen generation performance of micro-Al-NiCl 2 /NaBH 4 mixture and reduce the alkali corrosion problems via the lanthanum additive (La). The relative hydrolysis mechanism has been discussed to gain the mechanistic understanding of the effect of La.

Preparation of Al-La-NiCl 2
Mixture. Elemental aluminum powder (99.9% purity and particle size of about 10 μm; Angang Group Aluminum Powder Co., Ltd., China), La powder (99.0% purity), NiCl 2 (99.0% purity), and NaBH 4 (98% purity; China Chemical Company, Ltd.) were used as starting materials. The composites of the Al-15 wt.% La-5 wt.% NiCl 2 mixture (if not specially noted) were weighed and mixed in an argon-filled glove box. The total weight of the mixture was 2 g, and ball milling was performed by a QM-ISP3 planetary ball miller under 0.2-0.3 MPa argon atmosphere. Ball-to-powder mass ratio corresponded to 30 : 1 at a milling time of 15 h and a rotation speed of 400 r/min.

Hydrolytic Performances and Microstructure of Al-La-
Hydrolytic performances of the Al-La-NiCl 2 /NaBH 4 mixture with different weight ratios were carried out in pure water at 323 K. The total weight of the Al-La-NiCl 2 /NaBH 4 was 0.4 g, while the volume of pure water was 100 mL. Weight ratio of the Al-La-NiCl 2 /NaBH 4 was 1 : 1, unless otherwise stated. At the set temperature, the mixture was placed in water and the produced gas flowed through a condenser prior to measurement of the hydrogen volume. The produced hydrogen volume was measured by monitoring the water displaced from a graduated cylinder at 273 K and 1 atm as the reaction proceeded, in accordance with the experiment conducted by Soler et al. [12]. The reaction time began with the first bubble, and the final volume of the produced hydrogen was collected after 60 min of reaction. Conversion efficiency was calculated according to the following equation: % = experimental hydrogen generation amount/theoretical hydrogen generation amount × 100%. Impurities were involved in the calculations. Powder X-ray diffraction (XRD) studies were carried out in an X-ray diffractometer (RIGAKU, Japan, model D/MAX2550V/PC).

Results and Discussion
NiCl 2 is a good promoter for NaBH 4 hydrolysis. In the present study, we firstly examined effect of NiCl 2 on hydrogen generation performance of Al/NaBH 4 hydrolysis. As seen in Figure 1, increasing NiCl 2 content results in an increasingly favorable hydrogen generation rate and amount of Al/NaBH 4 mixture. The Al-15 wt. %La-2 wt.% NiCl 2 /NaBH 4 (weight ratio, 1 : 1) mixture shows 68 mL g −1 min −1 maximum hydrogen generation rate and yields 1293 mL g −1 within 60 min. Upon increasing NiCl 2 content to 15 wt%, hydrogen generation maximum rate and amount of the mixture include 122 mL g −1 min −1 and 1362 mL g −1 , respectively. Reaction (1) of NiCl 2 and NaBH 4 generates Ni 2 B in the hydrolysis process. Ni 2 B has high catalytic reactivity on NaBH 4 hydrolysis, especially distributed into Al(OH) 3 particle [13].
Meanwhile, Ni 2 B deposits on Al surface and acts as a cathode of a microgalvanic cell (Al-Ni 2 B), which stimulates the electrochemical corrosion of Al according to (2). Therefore, higher NiCl 2 content leads to more Ni 2 B amount, which accelerates Al/NaBH 4 hydrolysis correspondingly.
At the anode: The Scientific World Journal The addition of a small amount of La metal causes a remarkable increase of hydrogen generation performance of Al/NaBH 4 mixture. The observation provides new possibilities for practical composition designs. In our preliminary study of Al-La-NiCl 2 /NaBH 4 mixture, we develop sets of control experiments to optimize the composition design. For comparison purposes, the composition of Al-x wt% La-5 wt% NiCl 2 /NaBH 4 (weight ratio, 1 : 1) was fixed except Al and La contents. The La content was fixed at 0, 5, 10, 15, and 20 wt%. We examined the impact of La content on hydrogen generation performance of the mixture. The results are shown in Figure 2. The hydrogen generation amount increase with increasing La content and reach maximum values of 1360 mL g −1 within 60 min at 15 wt% La content. The efficiency is 82%. Further increasing La content deteriorates hydrogen generation performance. It can be explained from the microstructure change in Figure 3, which shows XRD results of Al-5 wt% NiCl 2 with different La content. The peaks of La, Al, and AlNi alloy are identified, reflected that La and Al have not formed alloy compound in the milling process. However, broadened lines are observed with increasing La content. Combined with the Scherrer equation (D hkl = kλ/β cos θ hkl ), the crystal size can be roughly calculated. Its value decreases from 238Å to 190Å with La content increasing from 5 to 15 wt%, but further increases to 197Å with La content further increasing to 20 wt%. In addition, La metal has high reactivity and reacts with water to produce some hydrogen at 298 K. However, the hydrogen generation rate is conversely proportional to La content, which can be obviously obtained in Figure 4. At same set temperature, the maximum hydrogen generation rate decreases from with La content increasing. For example, the value of maximum hydrogen generation rate decreases from 267 to 230, 201, and 187 mL g −1 min −1 with La content increasing from 5 to 10, 15, and 20 wt%, respectively. It is known that hydrolysis byproduct La(OH) 3 has low solubility in water and deposits on Al surface. So the contact area of Al and H 2 O is decreased and hydrogen generation rate is reduced therefore.
Al-La-NiCl 2 /NaBH 4 mixture has low reactivity in low temperature. The results in Figure 4 show that the mixture only yields approximate 500 mL g −1 with about 30% efficiency at 303 K. In practical application, the mixture seldom reacts with water and has good stability at 298 K. But with increasing global temperature, hydrogen generation performance can be improved. In order to further understand the effect of La on hydrogen generation performance of Al/NaBH 4 mixture, the relationship of activation energy and La content was analyzed. Using the Arrhenius equation (3): The equation (2) gives the dependence of a rate constant (k) on the temperature (T) and the activation energy (Ea). The values of k can be determined from the maximum hydrogen generation rate at different temperatures. Using the linear relationship of In k ∼ 1/T in Figure 5, the activation energy of Al/NaBH 4 mixture with different La content can be calculated. It can be found that activation energy is increased with increasing La content in Figure 6. The activation energy values are 50.9, 62.4, 67.5, and 75.2 kJ/mol when the La content are corresponded to 5, 10, 15, and 20 wt % of Table 1 shows hydrogen generation amount and maximum rate of Al-15 wt% La-5 wt% NiCl 2 /NaBH 4 with different weight ratios. Al-15 wt% La-5 wt% NiCl 2 has low hydrogen generation rate and amount, but the hydrogen generation performance is increased with decreasing weight ratios of Al-15 wt.% La-5 wt.% NiCl 2 /NaBH 4 , especially that Al-15 wt.% La-5 wt.% NiCl 2 /NaBH 4 with weight ratio of 1 : 3 has best hydrogen generationperformance. Its maximum hydrogen 4 The Scientific World Journal  generation rate and amount are up to 126 mL g −1 min −1 and 1764 mL g −1 within 60 min. The efficiency reaches 88%. La and NiCl 2 have little effect on Al hydrolysis, but seriously affect NaBH 4 hydrolysis. The hydrolysis byproducts of NaBH 4 hydrolysis stimulate Al hydrolysis in some degree, according to reactions (2).

Conclusions
La additive has greatly affects hydrogen generation performance of Al/NaBH 4 mixture. Hydrogen generation amount increases but hydrogen generation rate decreases with La content increasing. There is an optimized composition that The Scientific World Journal  Al-15 wt% La-5 wt% NiCl 2 /NaBH 4 mixture (weight ratio, 1 : 3) has 126 mL g −1 min −1 maximum hydrogen generation rate and 1764 mL g −1 hydrogen generation amount within 60 min. The addition of La has great effect on NaBH 4 hydrolysis but little effect on Al hydrolysis at 323 K. Increasing La content is helpful to decrease the particle size of A-La-NiCl 2 in the milling process, which induces that the hydrolysis byproduct Ni 2 B is highly distributed into Al(OH) 3 and the catalytic reactivity of Ni 2 B/Al(OH) 3 is increased therefore. Meanwhile, there exists a synergistic effect of hydrolysis byproduct NaBO 2 and Ni 2 B to simulate Al hydrolysis. The Al-La-NiCl 2 /NaBH 4 mixture has good stability in low temperature and its hydrolytic performance can be improved with increasing global temperature. So the mixture has good safety and can be applied as on board hydrogen generation material.

6
The Scientific World Journal