The Scientific World Journal

Volume 2014 (2014), Article ID 847806, 10 pages

http://dx.doi.org/10.1155/2014/847806

Research Article

Synthesis and Optical Enhancement of Amorphous Carbon Nanotubes/Silver Nanohybrids via Chemical Route at Low Temperature

Tan Kim Han, Leo Bey Fen, Ng Meng Nee, and Mohd Rafie Johan

Nanomaterials Engineering Research Group and Advanced Materials Research Group, Department of Mechanical Engineering, University of Malaya, Lembah Pantai, 50603 Kuala Lumpur, Malaysia

Received 6 February 2014; Revised 10 May 2014; Accepted 12 May 2014; Published 5 June 2014

Academic Editor: Bingqing Wei

Copyright © 2014 Tan Kim Han et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract.

We report the synthesis of amorphous carbon nanotubes/silver (αCNTs/Ag) nanohybrids via simple chemical route without additional reactant and surfactant at low temperature. Field emission scanning microscope (FESEM) and transmission electron microscope (TEM) confirmed formation of CNTs. X-ray diffraction (XRD) pattern confirmed the amorphous phase of carbon and the formation of Ag nanoparticles crystalline phase. Raman spectra revealed the amorphous nature of αCNTs. UV-visible spectroscopy showed enhancement of optical properties of αCNTs/Ag nanohybrids.

1. Introduction

Since the discovery of crystalline carbon nanotubes (CNTs) by Iijima [1], they have attracted worldwide interest due to their exceptional properties such as high mechanical strength, high electrical conductivity, and high thermal conductivity. Therefore, CNTs play a great role in a tremendously diverse range of research and application. However, crystalline CNTs pose a challenge for being produced in a large quantity due to their very critical deposition conditions like high operating temperature, expensive cost, long synthesis period, complex processing steps, and others [2]. In that light, amorphous carbon nanotubes (αCNTs) have become alternative to the crystalline CNTs due to their ease of production in large quantities [3]. αCNTs have unique amorphous structures, which are different from crystalline CNTs due to the wall composed of carbon clusters with a short-distance order or long-distance disorder [4]. The properties of CNTs are affected by their amorphous structural arrangement. They can be synthesized by arc discharge [5], chemical vapor deposition (CVD) [6], laser ablation [7], and chemical route [8].

Nevertheless, the αCNTs properties can be improved for various potential applications through hybridization of CNTs with noble metal such as silver [9], gold [10], and platinum [11] or with semiconductors such as cadmium selenide quantum dots [2]. The unique structure of CNTs enables them to be considered as a template for metal nanoparticles to form nanohybrids. In order to deposit nanoparticles on the inert CNTs wall, functional groups such as carboxylic acid, carbonyl, and hydroxyl groups need to be introduced onto the surfaces of CNTs by additional chemical treatment under acidic conditions. The functional groups created will give rise to the preferred nucleation site for metal deposition and also enhance the solubility of the CNT [12, 13]. Nanohybrids possess the combination of advantageous physical, chemical, and optical properties from both CNTs and metal nanoparticles. They could reveal the unexpected quantum effects and alter the band gaps of CNTs [2, 3]. CNTs/Ag nanohybrids received considerable attention due to the outstanding characteristic such as high catalyst activity [14], great optical properties [15], electrochemical sensor [16], and bactericidal properties in biomedical materials [17]. From the approaches reported, the CNTs/Ag nanohybrids can be produced by physical evaporation, solid state reaction, wet chemical reaction, and electroless deposition [18].

In this paper, we report a simple method for the synthesis of αCNTs and for the first time Ag nanoparticles attached on the αCNTs walls. The αCNTs surface was first purified and functionalized by strong acids; carboxyl groups were added on nanotubes wall to create reaction point between Ag nanoparticles. The acid treated nanotubes act as a template and starting point for the formation of nanohybrids. The interactions between αCNTs and Ag nanohybrids such as morphological, structural, elemental, and optical properties were investigated.

2. Experimental

2.1. Materials and Sample Preparation

Ferrocene, Fe(C₅H₅)₂ (98%), and ammonium chloride (NH₄Cl) were purchased from Acros Organics and Fisher Scientific, respectively. Hydrochloric acid, HCl (37%), was purchased from R&M Chemicals and silver nitrate (AgNO₃) was purchased from Fisher Scientific. All chemicals were used without further purification.

αCNTs were prepared by mixing 2 g of Fe(C₅H₅)₂ and 4 g of NH₄Cl together in a covered crucible. The sample was heated in the furnace at 200°C for 30 min and allowed to cool at room temperature. The as-produced αCNTs were washed consecutively with diluted HCl and deionized water for several times and dried at 40°C for 24 h. The purified sample was functionalized by immersing in HNO₃ at room temperature. The samples then were washed several times with deionized water and then dried at 40°C for 24 h. The functionalized αCNTs were hybridized with Ag nanoparticles.

100 mg of αCNTs was soaked in 200 mL deionized water for 5 min under ultrasonic dispersion. Different concentrations of AgNO₃ (0.01 M, 0.05 M, 0.1 M, 0.5 M, and 1 M) were added into the αCNTs aqueous solution and continuously stirred at room temperature for 20 h. The product was filtered and washed with deionized water sequentially and dried at 40°C for 24 h. The nanohybrids functionalized by HCl and HNO₃ were denoted as αCNTH/Ag and αCNTN/Ag, respectively.

2.2. Characterizations

The morphological structures of all samples were observed using field emission scanning electron microscope (FESEM, AURIGA Zeiss) and transmission electron microscope (TEM, Philips CM12) operated at 10 and 200 kV, respectively. Structural characterization was performed using X-ray diffractometer (XRD, Siemen D500) with Cu Kα radiation (40 kV, 40 mA). The optical absorption spectra were recorded using UV/VIS spectrophotometry (Varian CARY 50 Series). Raman spectra for all samples were recorded using inVia Raman microscope (RENISHAW, United Kingdom).

3. Results and Discussion

The FESEM images of αCNTH/Ag and αCNTN/Ag nanohybrids at different molars of AgNO₃ were shown in Figures 1 and 2, respectively. Figures 1(a) and 2(a) present FESEM images of the HCl and HNO₃ functionalized αCNTs prior to hybridization. Both images show tubular structures and are present in a bundle form due to van der Waals forces. Meanwhile, Figures 1(b)–1(f) and 2(b)–2(f) show the FESEM images of hybridized HCl and HNO₃ functionalized αCNTs at different molars of AgNO₃. The walls of αCNT were randomly coated with Ag nanoparticles. The interaction sites of αCNT and Ag nanoparticles vary with increasing molarity of AgNO₃. It was found that Ag nanoparticles tend to aggregate at higher molar of AgNO₃.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 1: FESEM images of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 2: FESEM images of HNO₃ functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

Figures 3 and 4 show the TEM images of HCl and HNO₃ functionalized αCNTs/Ag at different molars of AgNO₃. It is clearly observed that Ag nanoparticles are attached heterogeneously on the nanotubes wall. For HCl functionalized αCNTH/Ag, Ag nanoparticles are highly concentrated at specific sites on the CNTs wall at higher molar of AgNOs. Meanwhile, for HNO₃ functionalized αCNTN/Ag, Ag nanoparticles are more scattered on the CNTs wall and not influenced by the various molars of AgNO₃. This evidence confirmed that HNO₃ manages to create more the reaction side than HCl.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 3: TEM images of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

(a)

(b)

(c)

(d)

(e)

(f)

Figure 4: TEM images of HNO₃ functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

The XRD patterns of all samples obtained are illustrated in Figures 5-6. The as-synthesized αCNTs are amorphous with the broad peak at around 26° corresponding to (002) Bragg’s reflections plane of graphite. The XRD patterns of the hybridized samples show diffraction peaks at angles of 38°, 44°, 64°, 77°, and 82° corresponding to (111), (200), (220), (311), and (222) planes of Ag nanoparticles structure. This result indicates that Ag nanoparticles are well crystallized on αCNTs wall. Meanwhile, additional peaks at angles of 28°, 32°, 46°, 55°, 58°, 68°, and 77° are also observed corresponding to the face-centered cubic (FCC) structure of AgCl. The formation of AgCl is resulted from the reaction of Ag⁺ with Cl⁻ during purification process [19]. However, AgCl peaks decrease significantly at higher molar of AgNO₃. The trend is similar for HNO₃ functionalized αCNTN/Ag nanohybrids.

Figure 5: XRD patterns of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

Figure 6: XRD pattern of HNO₃ functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

Figures 7-8 show the Raman spectra of HCl and HNO₃ functionalized αCNTs/Ag nanohybrids at different molars of AgNO₃ which are characterized by D and G bands at 1380 and 1583 cm⁻¹, respectively. The G-band is attributed to the vibration of sp² bonded carbon atoms [20] and D band is corresponding to the disordered carbon [21, 22]. The intensity of G () band is increased significantly compared to D band () for all molars of AgNO₃. The similar trend is observed in HNO₃ functionalized αCNTN/Ag nanohybrids. The decrease of / ratio indicated the increase of crystallinity in nanohybrids’ samples. The D and G bands are enhanced significantly after the deposition of Ag nanoparticles on α-CNTs. This can attribute to the plasmonic properties of Ag nanoparticles [23]. The depositions of Ag nanoparticles on α-CNTs wall directly affected the disorder degree in nanotubes due to the presence of crystalline Ag nanoparticles. This will enhance the G band significantly. The results are consistent with the previous XRD patterns.

Figure 7: Raman spectra of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

Figure 8: Raman spectra of HNO₃ functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M.

Figures 9-10 show the absorption spectra for all samples. The absorption peak at around 260 nm is corresponding to the αCNTs [24]. It was found that the absorbance increases with the increase of molarity of AgNO₃. The linear increase of absorbance indicates that the Ag nanoparticles are well bonded on nanotubes’ walls [25]. In addition, there is another band observed in the visible region at 440 nm. This excitonic feature indicates a monodispersed collection of Ag nanoparticles in the nanotubes during hybridization. Thus, the introduction of Ag nanoparticles had relatively enhanced the optical properties of αCNTs [15, 26].

Figure 9: Absorption spectra of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃.

Figure 10: Absorption spectra of HNO₃ functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃.

The optical band gap can be evaluated using the Tauc relation [27, 28]. Consider

where is a constant, is a molar extinction coefficient, is the optical band gap of material, and depends on the type of transition. Figures 11-12 show the values obtained from the interception of linear portion in the Tauc plots [28]. Table 1 summarizes the details of values. decreases significantly after the attachment of Ag nanoparticles on nanotubes wall. However, the increase molarity of AgNO₃ did not further affect the band gap energy. Thus, the attachment of Ag nanoparticles on the nanotubes wall had enhanced the electrical conductivity of the αCNTs.

Table 1: The optical band gap energy () of all samples HNO₃ purified αCNTN/Ag nanohybrids.

Samples at different molars of AgNO₃ (M)
Optical band gap energy (eV)

HCl functionalized α-CNTN/Ag
HNO₃ functionalized α-CNTN/Ag

0.00
2.09
2.30

0.01
1.55
1.56

0.05
1.65
1.55

0.10
1.55
1.55

0.50
1.55
1.55

1.00
1.55
1.56

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(b)

(c)

(d)

(e)

(f)

Figure 11: Optical absorbance spectra of HCl functionalized αCNTH/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M. Inset shows Tauc plot for each spectrum.

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(b)

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(f)

Figure 12: Optical absorbance spectra of functionalized αCNTN/Ag nanohybrids at different molars of AgNO₃: (a) 0 M, (b) 0.01 M, (c) 0.05 M, (d) 0.1 M, (e) 0.5 M, and (f) 1 M. Inset shows Tauc plot for each spectrum.

4. Conclusions

αCNTs/Ag nanohybrids were successfully synthesized by using a simple chemical technique. FESEM and TEM images showed that Ag nanoparticles were successfully anchored on the nanotubes’ walls. They were found to have the tendency to agglomerate at a higher Ag concentration especially for HCl functionalized αCNTH/Ag nanohybrids. The peaks of newly introduced Ag crystalline structure were detected in XRD spectra. Besides that, peaks which refer to AgCl were also found in the nanohybrids system. The attachment of Ag nanoparticles on nanotubes wall enhanced the G band in Raman spectra significantly. As a result, / ratio was gradually decreased, indicating a higher crystallinity degree in nanohybrids samples. The attachment of Ag nanoparticles on αCNTs was found to enhance their optical properties. The optical band gap energy of nanohybrids decreased after the loading of Ag nanoparticles which prove that the Ag nanoparticles had improved the conductivity properties of αCNTs themselves. These unique properties from αCNTs/Ag nanohybrids system may find their advantages and usefulness for potential applications in various fields, such as medical [29], electronic [30], and waste water treatment [31].

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgments

The authors gratefully acknowledge University of Malaya and Ministry of Higher Education of Malaysia for supporting this work under UM/MOHE HIR Research Grant (UM. C/HIR/MOHE/ENG/12).

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