Development of Machining Processes for the Use of Multilayer High-Performance Coatings

e development of corrosionand wear-resistant high-performance coatings is important to improve components of mobile and stationary turbines, aerospace undercarriages, combustion engines, and hydraulic modules. New microand nanostructured coating materials and processes to machine these coatings are developed in order to increase the performance of workpieces and components, to enhance durability, and to reduce maintenance andmanufacturing costs. At the Institute of Machining Technology (ISF), milling and grinding procedures have been developed for the preparation of the workpiece surface for the subsequent coating process. In contrast to conventional applications, the workpieces are not manufactured with the aim of achieving a minimized resulting surface roughness. Instead of this, a de�ned and adequate structure has to be generated, providing a good adhesion of the thermal sprayed coating on the workpiece surface. A�er �rst coating of the prepared substrates by a High-Velocity-Oxygen-Fuel (HVOF) coating process, the resulting surface topography does not have the required surface quality for a subsequent (Diamond Like Carbon) DLC coating process. In order to generate a more uniform surface structure, the deteriorated surface resulting from the HVOF coating process also has to be processed.erefore, the application of an adapted grinding process with diamond wheels is used.


Introduction
To increase the wear, erosion, and corrosion resistance of tribologically stressed functional surfaces, the use of thermally sprayed coatings increases.Typical applications for these slide or bearing surfaces are stationary turbines, aerospace undercarriages, combustion engines, and hydraulic modules [1].One of these thermal spraying processes is the High-Velocity Oxygen Fuel (HVOF).Based on the high particle velocity a low porosity, high bond strength, and an increased hardness are the main advantages of this thermal spraying process [2,3].In order to obtain a good adhesion between the coating and the substrate, it is necessary to prepare the substrate surface.Although coinciding with several disadvantages, such as the necessity to clean the workpiece and the costs, a blasting process is usually used to activate the surface.In order to circumvent these disadvantages, other machining processes have to be considered.Obtaining unique surface structures which are similar to blasted surfaces regarding the roughness is also possible with other machining processes.ese machining processes may be milling, grinding, or honing, for example.Depending on the process parameters, they are able to generate different surface structures, too.
Unfortunately, the surface roughness resulting from the HVOF coating process exceeds the acceptable limit for many applications, especially in case of using multilayer coatings.DLC (Diamond Like Carbon) coatings which are more and more applied by a PVD (Physical Vapour Deposition) process on the tungsten carbide coating have a thickness of less than 5 m.In order to gain a more uniform surface structure for a subsequent DLC coating process or to improve the tribological behaviour of the HVOF coating, the workpieces are typically ground [4,5].e HVOF coating material used in this study is a WC-CoCr layer which has been proven for its good performance regarding wear test.Based on this inherent material property, it is a good substitute for hard-chromium coatings which are not favourable due to their toxic production process [6].Furthermore, multilayer systems consisting of tungsten carbide and Diamond Like Carbon are characterized by a singni�cantly increased wear resistance and an improved adhesion of the DLC coating compared to single DLC coatings [7].

Preparation of the Surface Topography by Milling.
Before the thermal spraying process, a preparation of the substrate surface is necessary.is is used to activate the surface and to create a de�ned roughness, thereby a su�cient coating adhesion is guaranteed.For this purpose, milling processes are used because they allow the preparation of almost any surface geometry.e cutting parameters and the contact ratios can be varied.ereby the structures and the roughness parameters can be modi�ed in relatively wide ranges.�ith the material X12Cr13, machinability tests were conducted.Figure 1 shows examples of possible surface topographies.ese were obtained with a toroidal high-feed milling cutter made by Hitachi with a diameter of    mm and a corner radius of    mm.e representations were created by rendering the digitized data, which were acquired with a confocal measuring microscope.e accompanying soware also allows the subsequent extraction of roughness parameters from this data in any direction of the measured surface.e different surface characteristics which are determined by the engagement conditions are clearly visible.is can be obtained by changing the inclination of the milling tool to the surface.e distance between the individual milling scratches can be varied by the feed per tooth and the mutual penetration of the scratches by the width of cut.Due to the small thickness of the tungsten carbide layer of approximately 100 microns or less, �ner structures, as shown in the middle of Figure 1, are appropriate for an interface with good adhesion between substrate and coating.Referring to the experiments, the cutting tools show good suitability for machining used test material, even at very high tooth feeds and cutting widths.As expected, by using low-alloy tool steels, a slightly higher tool wear occurred.Furthermore the used tools had a de�ned tool corner radius and were thereby suitable for the processing of free-form elements.Additionally, they can be used for radial engagement conditions, thus resulting in a greater freedom of surface structure production.

Preparation of the Surface Topography by Short-Stroke
Honing.In contrast to the milling process, the aim of the short-stroke honing process, also called micro�nishing, is the generation of smooth surface topographies with variable material ratios.e machining kinematic of the �nishing process, as shown in Figure 2, is characterized by a superposition of different tools and workpiece motions.e tangential motion is realized by a rotating workpiece.It has the most signi�cant in�uence on the cutting velocity, while the axial velocity which is generated by the oscillating �nishing tool has a less signi�cant in�uence on the cutting velocity.Nevertheless, the axial motion is needed to obtain a smooth surface topography without pro�le peaks and variable pro�le valleys.e contact between the �nishing tool and workpiece is guaranteed by the infeed force which has a substantial in�uence on the generated surface topography as well as the machining time and the grain size of the �nishing �lm [8,9].By using �nishing �lms with different grain sizes and bond structure in subsequent process steps, a speci�c surface structure regarding the peak height and valley depth occurs [10][11][12].
In order to generate different surface structures, two types of �nishing �lms have been used.�n the one hand, an electrostatic ad�usted �nishing �lm with a grain size of   = 30 m and on the other hand muddled �nishing �lms with a grain size of    3, 9, and 3 m.As shown in Figure 2 these �nishing �lms have been combined in two different process strategies.e type of premachining (  = 30 m� has a signi�cant in�uence on the resulting surface topography.�y using an electrostatic adjusted �nishing �lm, an aggressive machining process occurs because of the sharp grain edges which reach out of the bond.As shown in Figure 3, aer the �rst process step with an adjusted �nishing �lm and a machining time of  = 0 s, a mean roughness depth of  =  m occurs.�y using two subse�uent �nishing steps with a grain size of   = 9 m and   = 3 m, the mean roughness depth can be decreased to  =  m.Regarding the tribological behaviour of the surface, it is insufficient to classify the surface topographies only by the mean roughness depth [13,14]. A surface with an increased peak height and a low valley depth probably will have the same mean roughness depth as a surface with low peak height and increased valley depth.To describe the differences between the generated surfaces in detail, the relation between peak height and valley depth can be used.As shown in Figure 3, the typical surface topography generated by micro�nishing is characterized by a greater valley depth compared to the peak height (pk/vk <  for all �nishing steps�.�sing a combination of adjusted and muddled �nishing �lms leads to an increased valley depth on the surface topography because the muddled �nishing �lms with smaller grain sizes are just decreasing the peak height.Accordingly, aer a three-process steps, a plateau-like surface occurs with peak/valley relation of pk/vk < 0..Compared to this, a micro�nishing process with only muddled �nishing �lms is less aggressive and a smooth surface topography occurs.Even with premachining with a grain size of   = 30 m, the mean roughness depth does not exceed  = 0 m.In case of using two subsequent �nishing steps with smaller grain size (  = 9; 3 m), it is possible to decrease the mean roughness depth below  = 05 m.Regarding the material ratio, there is no signi�cant change in the relation between peak height and valley depth.Both are decreased homogeneously and the peak/valley relation stays at pk/vk = 03.
us, by combining the mentioned properties of the �nishing �lms in one process chain, it is possible to generate a smooth structure with little pro�le valleys or a plateau structure with a de�ned valley depth.Regarding slide faces, it o�en is better to have a plateau structure with de�ned pro�le valleys instead of a smoother surface without valleys.Moreover, also for coating substrates, it is necessary to provide a surface which supports a good adhesion between coating and substrate.In order to replace the conventionally used blasting process, a detailed description of the workpiece topography has to be made and further surface characteristics have to be considered.By using conventional machining processes like milling, grinding, and honing with the aim to structure the surface topography instead of just increasing the stock removal rate, the blasting process can be replaced.
First results concerning the quality of the interface between coating and substrate are shown in Figure 4.As shown on the le� side, the originally �nished steel surface is smooth and regular.With the subsequent tungsten carbide coating (in the middle of Figure 4), the smooth surface has been roughened through the kinetic energy of the powder particles.Nevertheless, the interface is characterized by a regular structure without cracks and failures.In contrast, the interface between the coating and the initial blasted surface is characterized by an irregular structure with several deeper grooves which are �lled with particls from the blasting process.Such inhomogeneous grooves and material artifacts can act as crack initiators under speci�c loading situations.us, the interface between the steel substrate and the tungsten carbide coating can rather be improved by �nishing the substrate compared to blasting the substrate.

Machining of the Coated Surface
In this study, the workpieces have been coated with �ne WC-CoCr powders with a particle size between 2 and 10 m.e main advantages of these �ne powders are the reduced porosity of less than 1 percent and a thin layer thickness of 100-140 m.e surface roughness "as-sprayed" is also lower when using �ne powders [15].e quality of the coating "as-sprayed" has a mean roughness depth above   0 m.Regarding the subsequent DLC coating with a thickness of less than 5 m, the "as-sprayed" condition does not provide the requirements for a good interface between tungsten carbide and DLC coating.In order to improve the surface quality, the workpieces were ground.Many studies outlined that a subsequent grinding process directly affects the tribological behaviour of the coating.On the one hand, there is an improved erosion resistance realized by compressive residual stresses which are induced into the surface by grinding [16][17][18].On the other hand, in case of sliding contact, the decreased surface roughness leads to less friction and a lower wear level [19].Furthermore, it has been shown that the wear rate of the DLC coating will signi�cantly increase, if the substrate surface roughness exceeds the speci�c roughness value    m.is increase is based on a change in wear mechanisms [20].Based on these �ndings, the approach in this study was to examine the in�uence of different process parameters like cutting speed, workspeed, and cutting depth on the resulting surface topography.To avoid several problems concerning surface cracking, which can occur in case of using CBN-wheels, only diamond grinding wheels were used in this study [21].e grain size of   = 64 m was similar for all three grinding wheels.e wheels differed regarding the bond type and the grain concentration.As shown in Figure 5, it is possible to machine these coatings with all three bond types, although there are several differences regarding the surface roughness.Similar for all three grinding wheels, a better surface quality is achieved by using lower work speed.is effect is based on the fact that a lower workspeed is proportional to a decreased undeformed chip thickness.In case of having a decreased chip thickness, the surface roughness decreases as well [22].e same effect occurs when increasing the cutting speed.
Beside the parameter value cutting speed and workspeed, the grain concentration has a signi�cant in�uence on the surface quality.Based on the good damping properties, typically it is the resinoid bond which is responsible for high quality surfaces [22].In this case, it is the bond type with the worst surface quality compared to the results achieved by a grinding wheel with metallic or vitri�ed bond.Additionally, there is a remarkable decrease in surface roughness by increasing the grain concentration.e reason for this functional relation is the dependence between the grain concentration and the undeformed chip thickness.By increasing the grain concentration, the chip thickness decreases and the same effect, as beforehand mentioned, occurs.

Conclusion
Summarizing we can conclude that, in this study, alternative machining processes were developed, in order to prepare a workpiece surface for a subsequent thermal coating process with tungsten carbide.Furthermore, the in�uence of different process parameters on grinding of the coated surface was examined.To avoid several disadvantages of a blasting process, which is usually used to activate the surface, a milling process and a short-stroke honing process were considered to achieve the needed surface structure.Based on their speci�c process kinematic, both processes are able to generate surface structures with variable material ratios.e preparation of the surface by honing especially was successful regarding the interface between the coating and the substrate.e interface between the honed substrate and the coating showed a regular structure opposite to the interface between the blasted substrate and the coating which is characterized by several deeper grooves and blasting particles.In order to achieve a smooth surface topography of the coated surface, the used grinding process was optimized regarding the speci�cation of the diamond wheels and the relevant in�uencing variables.With this subsequent machining of the coating, the requirements for the use as a slide face or an optional subsequent DLC (Diamond Like Carbon) coating were achieved.

F 1 :
Selection of manufacturable surface structures by milling.

3 F 4 :
Interface between coating and substrate depending on the surface preparation.