Investigation of Gamma and Neutron Shielding Parameters for Borate Glasses Containing NiO and PbO

Themass attenuation coefficients, μ/ρ, half-value layer, HVL, tenth-value layer, TVL, effective atomic numbers,Z PIeff, and effective electron densities,N e,eff, of borate glass sample systems of (100-x-y) Na2B4O7 :xPbO :yNiO (where x and y = 0, 2, 4, 6, 8, and 10 weight percentage) containing PbO andNiO, with potential gamma ray and neutron shielding applications, have been investigated. The gamma ray interaction parameters, μ/ρ, HVL, TVL, Z PIeff, andNe,eff, were computed for photon energy range 1 keV–100GeV. The macroscopic fast neutron removal cross-sections (Σ R ) have also been calculated. Appreciable variations were noted for all the interaction parameters by varying the photon energy and the chemical composition of the glass samples. The better shielding properties of borate glass samples containing PbOwere found.These results indicated that borate glass samples are a good radiation shielding material.


Introduction
Interaction of energetic radiations X/-ray and neutron with the material is essential in radiation technologies, medical, nuclear engineering, agriculture, space technology, industries, and other shielding applications.Transparent radiation shielding materials have been an interesting area in nuclear engineering to provide the adequate radiation protection as well as visibility through it.Glasses are found to perform the double functions of being transparent to visible light and absorbing the radiations, thus providing radiation shielding to the observer.The silicate glasses are found to be the most commonly commercial glasses owning to ease of fabrication and excellent transparency to the visible light [1].The transparent property of the glass makes it useful for optical windows in nuclear reactors and isotope technology centers.The optical windows play a crucial role in operation and maintenance of nuclear facilities for complete visual inspection without radiation exposure.
Lead and lead glasses are easily available for shielding of the gamma rays and neutrons due to high densities and atomic numbers [2].The high atomic number () offers large gamma ray interaction cross-section for gamma rays and density plays vital role in neutron interaction.Nowadays, bismuth (Bi) and barium (Ba) are playing an analogous role in radiation shielding by replacing lead.The glasses containing low  elements (H, Li, B, C, etc.) are another group of the glasses required for neutron radiation shielding produced specially in nuclear reactors and accelerators.It has been found that gamma photon in reactor is in range of 0.10 to 10 MeV and prompt neutron energy spectrum ranges from 0.18 to 12 MeV with average neutron energy 1 to 2 MeV during uranium fission [3].Therefore boron containing glass materials are found to be a potential candidate for neutron radiation shielding.
The absorption of gamma ray is being represented by the mass attenuation coefficients, atomic cross-sections, effective atomic numbers, and effective electron densities.The attenuation coefficient is defined as the probability of radiation interaction with a material per unit length [4].The effective atomic number is a convenient parameter for evaluation of gamma ray interaction for a compound or mixtures.The other important parameter for interaction is an electron density which is defined as the electrons per unit mass 2 of the absorber.Mass attenuation coefficients of elements, compounds, and mixtures are taken from standard tables [5] developed as XCOM program at energies 1 keV to 100 GeV.

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The XCOM program has been converted to user-friendly windows platform WinXcom [6].
Various investigators have reported gamma ray interaction parameters of phosphate, lead, bismuth, silicate, and flyash glasses [2,[7][8][9][10][11]. NiO is being used for making smoky colored glasses and for decolouring lead crystal glasses [12].The gamma ray attenuation coefficients of borate glasses are found for 1173 and 1332 keV [13].However detailed study on gamma ray and neutron interaction for the colored borate glasses containing NiO is not found in the literatures.This encouraged us to investigate the gamma and neutron interaction parameters of borate glasses, potential shielding materials.Therefore, we have calculated the mass attenuation coefficients, /, half-value layer, HVL, tenth-value layer, TVL, effective atomic numbers,  eff , and effective electron densities,  ,eff , of borate glass samples containing PbO and NiO given in Table 1.The study shall be useful for shielding against gamma ray and neutron applications.

Theoretical Background and
Computational Work , where   is the proportion by weight and (/)  is mass attenuation coefficient of the th element by using WinXcom [6].The quantity   is given by   =     / ∑       with condition ∑     = 1, where   is the atomic weight of the th element and   is the number of formula units in the compounds.The half-value layer, HVL (HVL = 0.6932/), and tenth-value layer, TVL (TVL = 2.303/), are inversely proportional to  values.
The effective atomic numbers ( eff ) for total photon interaction are given by [14] where   is molar fraction in the mixture,  is linear attenuation coefficient,  is density, / is mass attenuation coefficient,  is atomic weight,  is atomic number, and the ratio, /, between the atomic mass and the atomic number is approximately constant.The electron density is given by  ,eff =   / which is generalized as where   is the number of atoms of the th constituent element,  is the total number of atoms, and ⟨⟩ is average atomic mass of the glass samples.

Macroscopic Fast Neutron
Removal Cross-Sections.The effective removal cross-section of compounds and homogenous mixtures is calculated using the value of Σ  (cm −1 ) or Σ  / (cm 2 /g) of the elements in the compounds by mixture rule [4].The detailed calculation procedure for Σ  can be found various recent literatures for alloys [15], fly-ash brick materials [16], bismuth borosilicate glasses [17], oxide dispersion strengthened steels [18] and building materials [19].The Σ  / values of elements have been taken from Kaplan and Chilton [20,21].

Results and Discussion
In the present investigation, the mass attenuation coefficients, /, half-value layer, HVL, tenth-value layer, TVL, effective atomic numbers,  eff , and effective electron densities,  ,eff , of borate glasses containing PbO and NiO were calculated.The variation of /, HVL, TVL,  eff , and  ,eff is shown in Figures 1-5 respectively.The macroscopic fast neutron removal cross section of the borate glasses is given in the Table 5.

Mass Attenuation
Coefficients.The variation of mass attenuation coefficients, /, of the borate glass samples with photon energy ranging from 1 keV to 100 GeV is shown in Figure 1.From Figure 1     multiple peaks due to , , and  absorption edges whereas borate glass sample without PbO and NiO (S 1 ) is found to be with single peak due to Na element.These variations can be explained by the partial photon interactions such as photoelectric absorption for low-energy, Compton scattering for intermediate-energy, and pair production (nuclear and electric) for high-energy regions.Initially at 1 keV energy, the values of / are very large (order of 10 3 ) which decrease sharply.At low-energy range (0.01 MeV <  < 0.1 MeV), the maximum value of / was found.The values of / of all the borate glass samples become of order of 10 −1 as photon energy reaches 100 keV.Hence the / values decrease rapidly in low-energy region.This shows the dominance of photoelectric absorption in lowphoton energy region.It can also be observed that there is slight variation of / of all the selected borate glass samples at particular photon energy.It is due to the reason that photoelectric absorption is dependent on photon energy and atomic number as  of the elements and  4.5 / With increase in photon energy (above 100 keV), the reduction rate of the / is observed to be very slow (10 −1 to 10 −2 ).It was observed that the variation is negligible between 0.5 and 5 MeV where Compton scattering dominates.It is because the interaction cross-section is linearly dependent on .With further increase in photon energy (above 50 MeV), it was found that the / values start increasing and become constant at around 100 MeV.This is because the pair production process in nuclear field, / (npp) , and electron field, / (epp) , starts at threshold energies of 1.022 MeV and 2.044 MeV and thereafter increases with increase in the incident photon energy.In this high-energy region, a slight variation at particular incident photon energy was again observed due to their different chemical compositions.It may be due to the cross-sections for pair production process in nuclear field and for triplet production depending on atomic numbers  2 and , respectively.It is to be noted that although pair production processes initiate at photon energy 1.022 MeV, they require more incident photon energy to overcome Compton scattering.

HVL and TVL Values.
The variation of half-value layer, HVL, and tenth-value layer, TVL, of the borate glass samples with photon energy ranging from 1 keV to 100 GeV is shown in Figures 2 and 3. We have plotted HVL and TVL of ordinary (OR), hematite-serpentine (HS), ilmenite-limonite (IL), basalt-magnetite (BM), and ilmenite (IT) [22] along with borate glass samples for comparison.3.At low-energy range (0.01 MeV <  < 0.05 MeV), the maximum value of  eff was found.At intermediate energies (0.05 MeV <  < 5 MeV), where Compton scattering is the main photon interaction process,  eff is approximately equal to the arithmetic mean of the atomic number calculated from the chemical formula of the glass samples, ⟨⟩ = (1/) ∑      .At high energies, ( > 50 MeV),  eff is again constant but smaller than in the low-energy region.It is observed that there is a good agreement between  eff at 10 MeV (Table 3) and the mean atomic number, ⟨⟩, derived from the chemical composition of the glass samples, where Compton scattering is the main photon interaction process.

Effective Electron
Densities.The variation of effective electron densities,  ,eff , for total interaction and noncoherent interaction of the borate glass samples with photon energy ranging from 1 keV to 100 GeV is shown in Figures 5(a) and 5(b).The average effective electron density, ⟨  ⟩, lower and upper values of effective electron densities at specific energies as 10 −3 , 10 −2 , 10 −1 , 10 0 , 10 1 , 10 2 , 10 3 , 10 4 , and 10 5 are given in Table 4.The variations of  ,eff with photon energy for total interaction processes (Figures 5(a) and 5(b)) were similar to that of  eff and can be explained in similar manner.

Macroscopic Fast Neutron
Removal Cross-Section.The macroscopic fast neutron removal cross-sections Σ  (cm −1 ) of the borate glass samples are given in Table 5.It was    are having roughly constant Σ  , borate glass containing 10% PbO (S 7 ) would be preferable gamma ray as well as neutron shielding.The Σ  value of borate glass sample (S 1 ) was found to be higher than ordinary concrete whereas other borate glass samples (S 2 ⋅ ⋅ ⋅ S 7 ) were lower than it.

Conclusions
In the present investigation, the mass attenuation coefficients, /, half-value layer, HVL, tenth-value layer, TVL, effective atomic numbers,  eff , and effective electron densities,  ,eff , of borate glass samples containing PbO and NiO were calculated for photon energy 1 keV to 100 GeV.The macroscopic fast neutron removal cross-sections were calculated for neutron energy 2−12 MeV.These parameters were found to be varying with the photon energy and chemical compositions of the glass samples.These results shall be useful for shielding applications against gamma ray and neutron.

Figure 1 :
Figure 1: Variation of mass attenuation coefficients of the borate glasses containing PbO and NiO with photon energy for range 1 keV to 100 GeV.

Figure 5 :
Figure 5: Variation of effective electron densities of the borate glasses containing PbO and NiO with photon energy for range 1 keV to 100 GeV.

Table 1 :
Borate glass samples containing PbO and NiO for shielding.

Table 2 :
Photon energies (in keV) of absorption edges of , , and .

Table 3 :
Effective atomic numbers ( eff ) of borate glasses at different energies (MeV) for total photon interaction.

Table 4 :
Effective electron densities ( ,eff ) of borate glasses at different energies (MeV) for total photon interaction.

Table 5 :
Macroscopic fast neutron removal cross-section of the borate glasses.
3.5.All the borate glass samples under investigation contain different constituent elements ( 5 B, 8 O, 11 Na, 28 Ni, and 82 Pb) with different weight fractions of elements.The slight differences in the weight fraction of elements result in insignificant variation of / values in photoelectric absorption region.
for S 1 was observed due to zero contribution of Pb and Ni elements.It can be concluded that borate glass sample (S 1 ) is a superior neutron shielding material.Moreover, the borate glass alone may not be suitable for gamma ray shielding; therefore borate glasses containing PbO and NiO are suitable glass shielding materials for gamma ray and neutron.Since oxide containing glasses