Potential of Flocculant-Aided Soil Slurry Dewatering in Land Reclamation: Laboratory Investigations

When soil slurry is used as a fill material in land reclamation projects, vacuum preloading or geotextile tube systems are often adopted for the dewatering treatment in a large scale. However, these two methods often suffer from clogging problems and impede further dewatering treatment. In this study, we test the potential of using flocculants to enhance the dewatering efficiency in a vacuum preloading model test and a geotextile tube model test. Experimental results show that, by adding a flocculant into soil slurry, the dewatering efficiency in terms of drainage volumes and rates is significantly improved as compared to that in pure soil slurry. (e amounts of drainage water in the tests with flocculant addition are about 20% and 100% more than those in pure slurry tests in the vacuum preloading and geotextile tube model tests, respectively. (e underlying reason could be the flocculation effect that prevents the movement of small soil grains and the formation of impermeable layers on the filters.


Introduction
To cater the industrial and urban development, large-scale foreshore land reclamation projects have been taking place in coastal regions in many East Asian countries.In the engineering practices in China, seabed soils are widely used as fill materials in land reclamation projects [1].Seabed soils are easily obtained at coastal regions.A common way to facilitate the transportation of seabed soils is to mix soils with large amounts of water using cutter suction dredgers and transport the soil slurry though pipelines.In spite of the convenience and cheapness to obtain fill materials in such a way, the subsequent dewatering process is difficult and time-consuming.
Two techniques are usually used for the dewatering of soil slurry in land reclamation projects: the vacuum preloading and geotextile tube systems [1].e vacuum preloading system is briefly illustrated in Figure 1.It mainly consists of a drainage system and a vacuum pumping system.
e drainage system comprises vertical drains installed vertically in the soil and horizontal drains that can transfer vacuum pressure into the soil ground.Under the vacuum pressure, water and gas in the soil can be taken away, and thus, soil can be compressed like a sponge.e vacuum preloading technique is suitable for the creation of land spaces in large areas.e use of geotextile tubes for the dewatering of soil slurry is illustrated in Figure 2. e material used to fabricate the tubes has high tensile strength and stiffness.It also serves as a filter for the drainage of water.Soil slurry is pumped into the tube first.When the tube is full, further pumping of slurry into the tube can cause high pressure and in turn lead to the drainage of clean water from the tube surface.Several tubes can be stacked together to accelerate the dewatering process.Geotextile tube systems are often used for the construction of dikes, breakwaters, and other temporary and permanent shore protection structures.
In spite of the extensive adoption in engineering practices, a serious problem in these two dewatering techniques is that the drainage capacity can be greatly reduced due to the clogging of vertical drains/geotextiles, as reported by many studies and engineering projects [2,3].During the dewatering processes, small soil grains can flow with water and finally adhere onto the filter.A thin layer of small grain soils on the filter could be the major reason that accounts for the reduction of drainage capacity.
One of the possible solutions to the abovementioned problem is to use flocculants.Flocculants are a type of longchain organic compounds of repeating monomers.Monomers are the single units that consist of flocculant molecules.In the water environment, flocculants can attract fine solid particles and form large aggregates (i.e., flocs), as illustrated in Figure 3. Using flocculants is an effective way to remove small particles in water or to enhance the dewatering efficiency of slurry materials.It is widely used in wastewater treatment facilities.It has also received increasing interests in other applications, such as the management of tailings from oil sand mining [5,6] and the dewatering of dredged sediments [7,8].
e use of flocculants in geotechnical engineering for land reclamation and ground improvement projects has been receiving research interests in recent years [2][3][4].
In this study, attempts were made to evaluate the potential of using flocculants for the dewatering of soil slurry.Two laboratory model tests, vacuum preloading and geotextile tube tests, were carried out.e dewatering effects were evaluated in comparison to those without flocculant addition.e underlying mechanisms are also discussed.

Testing Materials.
Testing soil was obtained from a staging ground used for the placement of dredging sediments from Baimahu Lake, Jiangsu Province, China.Basic physical and geotechnical properties of the soil are given in Table 1.e experiments for the determination of these index properties followed the Chinese standard for soil testing [9].An SEM image of the soil is presented in Figure 4. Based on the X-ray diffraction analysis, the chemical composition of the soil was 84.23% SiO 2 , 7.12% Al 2 O 3 , 5.32% Fe 3 O 4 , and 3.33% CaO. e soil mainly consisted of quartz and vermiculite.
In this study, polyacrylamide (PAM) was used for the treatment of soil slurry.PAM is a commonly used flocculant in wastewater treatment facilities.
e PAM used in the experiments was nonionic.
e molecular weight was 12 million.ere are many types of flocculants with different parameters, including the types of charge (cationic, anionic, or neutral), the charge density (quantity of positive or negative charge), the molecular weight, the molecular structure, and the type of monomers [10,11]. is flocculant was selected because it was the most effective one in accelerating the settlement of soil slurry compared with several other flocculants with different parameters.Details of the methods for the selection of a proper flocculant in a particular condition were given in [4].

Preparation of Soil Slurry.
Soil slurry was prepared by adding ultrapure water into the soil and mixing them to a uniform state.e flocculant should be used in the solution form.Dry granules of the flocculant were added into ultrapure water at 0.4% concentration, and mixing was carried out for 1 hour to ensure complete dissolving.For the treatment of soil slurry, flocculant solution was added into e initial water contents were 100% for both pure slurry and flocculant-added slurry.e methods and procedures of applying flocculants into soil slurry also followed our previous study [4].

Vacuum Preloading Model
Test. e setup of the vacuum preloading model is illustrated in Figure 5. e prefabricated vertical drain was produced by Quansheng Electronics Co. Ltd. (China).It had a maximum drainage capacity of 50 cm 3 /s.e inner diameter of the test container was 43 cm.Both pure soil slurry and flocculant-added soil slurry were prepared before placing into the container.After the preparation, the soil slurry was carefully poured into the container to avoid any inclusion of gas bubbles.e slurry was filled to a height of 55 cm.A piston was placed on top of the slurry surface.e piston could move freely up and down to adjust to the settlement of soil slurry.A vertical drain was inserted into the slurry sample for transferring vacuum pressure.e top end of the vertical drain was connected to a sealed water tank.A vacuum pump was also connected to the water tank for the application of vacuum pressure into the vertical drain and soil slurry.During the application of vacuum pressure, soil slurry experienced compression and consolidation under the pressure difference below and above the piston.e settlement of the slurry was measured using the ruler attached to the container.Water flowed out of the slurry was collected in the water tank.
e volume of drainage water can be measured using a balance during the tests.

Geotextile Tube Model Test.
e setup of the geotextile tube test is illustrated in Figure 6. e geotextile tube was SoilTain PP 105 produced by Huesker Synthetic GmbH.
e tensile strength was larger than 105 kN/m.e permeability in the vertical direction was 20 × 10 −3 m/s.e size of the geotextile tube was 110 × 72 cm 2 .During the test, slurry was pumped into the tube until it became completely full.en, the slurry underwent drainage and settlement under its self-weight for around 1 day.After 1 day, 60 kg sand bags were placed on top of the geotextile tube to further compress the slurry for several days until there was no more water drained out.e settlement of the geotextile tube at its top point was measured.
e drainage water could be collected, and its weight could be measured using a balance during the tests.

Vacuum Preloading Tests. Two vacuum preloading tests
were carried out on pure slurry and flocculant-added slurry, respectively.During the tests, vacuum pressure was maintained higher than 90 kPa. Figure 7 shows the weight of drainage water during the tests.
e test with flocculant addition showed a larger drainage amount and a faster drainage rate than that without flocculant.At the end of the tests, the amount of drainage water in the flocculated slurry was about 20% more than that in the pure slurry.e settlement curves are shown in Figure 8. Flocculant-added slurry showed a larger and faster settlement than pure slurry.e settlement curves (Figure 8) did not match water drainage curves (Figure 7).
is could be due to the development of cracks in the slurry samples.
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Geotextile Tube Tests.
When geotextile tubes are used for the dewatering of slurry, the addition of flocculant into the slurry also has beneficial effects in terms of dewatering volume and rate.Figure 9 shows the amount of drainage water during the tests.e amount of drainage water in the flocculant-added test was about twice that in the pure slurry test.e settlement of the flocculant-added geotextile tube was also much larger than that of the pure slurry tube, as can be seen in Figure 10.

Discussions
It has been presented above that the use of flocculants can significantly improve the performance of slurry dewatering in the vacuum preloading and geotextile tube systems.e mechanisms are discussed here.When a flocculant is added into soil slurry, small grains in the slurry tend to attract together and form flocs (assemblage of grains).One example is given here [4].As can be seen in Figure 11, when adding a flocculant into soil slurry, flocs can be formed which are much larger than single soil grains.As for the use of vacuum preloading or geotextile tubes, smaller soil grains tend to flow with water and finally attach to the filter.As a result, an impermeable layer consisting of fine grain soils can be formed on the filter, leading to the reduction in the drainage capacity. is process is explained in Figure 12(a).However, when a flocculant is added into the slurry, small soil grains can be captured by flocculant chains, and thereby, the An interesting finding from comparisons between the two tests is that when a flocculant is added, the dewatering effects in the geotextile tube are much more significant than those in the vacuum preloading.Such a difference could be because of the pressure on the drainage boundaries.In the geotextile tube, excess pore pressure generated in the soil can be dissipated easily at the drainage boundary.In the vacuum preloading, negative vacuum pressure is maintained at the boundary, which could lead to the migration of soil grains onto the drains and finally cause the degradation of drainage capacity, in spite of the use of flocculants.An indirect evidence provided in [12] shows that, in the vacuum preloading method, by increasing the vacuum pressure stepwise to the maximum value instead of applying it instantaneously, the drain clogging problem can be alleviated.In future studies, attempts can be made by adding more flocculants in soil slurry or applying vacuum pressure slowly and stepwise to explore whether the drainage efficiency can be improved.
It is worth taking a note that although flocculants can enhance the dewatering efficiency of soil slurry, the mechanical behaviour and geotechnical properties of flocculant-amended soil after the sedimentation are different from those of soil without any flocculant addition [5,6].

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Flocculant-amended soil starts to develop shear strength at a water content higher than pure soil during the sedimentation process.
e sensitivity of flocculant-amended soil is also higher than that of pure soil.ese issues should be addressed in the subsequent ground improvement works.

Conclusions
In this paper, we study the potential of using flocculants to enhance the dewatering efficiency in the vacuum preloading and geotextile tube systems.In the vacuum preloading model test, by adding a flocculant into soil slurry, the volume of drainage water can be increased by 20% and the drainage rate can also be improved as compared with the pure slurry test.In the geotextile tube model test, the volume of drainage water in flocculant-added slurry doubles as compared with that of pure slurry.e settlement is also much larger than that of pure slurry tube.
e improved performance of flocculant-aided dewatering can be explained by the flocculation effect.Without the addition of flocculant, small soil grains tend to move to the filter and finally form an impermeable layer on the filter.e addition of flocculant into soil slurry leads to the formation of flocs (assemblage of soil grains), and thereby, the movement of small soil grains can be restricted.e drainage capacity can thus be maintained for a much longer period.

Figure 4 :
Figure 4: SEM image of the testing soil.

Table 1 :
Properties of the testing soil.values of compression index and permeability were obtained from the oedometer tests on the resedimenting soil with the initial water content of 134.0%. e