A Damage Constitutive Model of Rock under Hydrochemical Cyclic Invasion

In order to analyze the stability of water-related materials, the deterioration and damage of rock strength due to circulating water intrusion in an open tailings pond were studied. Uniaxial compression tests were carried out for rocks under different hydrochemical environments and varying numbers of invasion cycles. Results show that, with increasing number of cycle times, rock peak strength and elastic modulus gradually decrease and the acidity and alkalinity of the soaking solution also degrades rock strength. *e curve of the number of cycles, acidity, alkalinity, peak strength, and elastic modulus is fit numerically. Based on the principle of damage mechanics, a hydraulic-chemistry-mechanics (HCM) coupling damage variable is defined. Based on the theory of microbody strength distribution, the constitutive equation for rock damage under the coupled effect of water chemistry and cyclic water invasion is established. *e results verify the validity of the established damage constitutive model.


Introduction
Abandoned open pits are geological bodies with increased safety risks when the original support system fails. In order to make abandoned open pits reusable and avoid wasting land resources on new tailings storage, some open pits are used as tailings ponds for nearby dressing plants [1][2][3][4][5].
Using an open-pit mine as a tailings pond raises two main problems. First, the waste tailings liquid contains a large amount of tailings sand and is discharged into the pit through a pipe or tanker, which causes the water level in the open pit to continuously rise. Increased groundwater flow and precipitation can also cause the water level to significantly increase. Secondly, the tailings liquid in the open pit undergoes long-term precipitation, and the tailings sand consolidates and settles. e ore pit uses the water in the pit for secondary use at various times, resulting in a decrease in water level. erefore, after the open-pit mine is used as a tailings pond, the stability of the slope rock mass needs to be analyzed and the influence of the rock environment and water level fluctuation on the rock strength needs to be considered. At present, many researchers have examined the strength of engineering rock masses affected by water level fluctuations, primarily including the static and dynamic rocks characteristics such as compressive strength and elastic modulus. ere are numerous research results on the variation in macroscopic strength of rocks under the effect of cyclic water invasion [6][7][8][9][10][11][12]. e weakening of rock strength under the effect of cyclic water intrusion is the damage of the micro-meso rock structure inside. Structural control theory in engineering geology indicates that cyclic water intrusion causes the expansion of primary defects such as microcracks and micropores and also causes the development of secondary defects, eventually leading to the formation of macrocracks inside the rock mass, which affects the macrostrength of the rock. Presently, for rock mesodamage characteristics under cyclic water intrusion, scanning electron microscopy and Computed Tomography (CT) tests are primarily used. Fractured sections of the rock are examined using advanced instruments such as nuclear magnetic resonance imagers to obtain mesostructural changes for different cyclic invasion conditions and produce a qualitative analysis of the mesodamage. Using digital image recognition technology, mesostructural information, such as fractal dimension and porosity, is extracted to quantitatively characterize the mesostructural damage [3,[13][14][15][16]. Results show that cyclic water intrusion affects the strength and structure of rocks and adversely affects the stability of the project. However, the rocks on the bank slope of the tailings reservoir are immersed in acidic or alkaline tailings for a long time. e tailings with different acidity and alkalinity will have a nonnegligible degradation effect on the macrodamage and mesodamage of the rock. For different water chemical environmental conditions, there is still a lack of necessary research on rock damage characteristics. erefore, examining the degradation and damage characteristics of rock strength relative to water chemistry and cyclic invasion is significant, especially for wading geotechnical and coastal geotechnical engineering.
Taking the open pit as the tailings pond, the change in rock strength under the influence is examined, considering the degradation and damage to rock strength due to the coupled effect of water chemistry and cyclic invasion. Using the uniaxial compression of rocks under different hydrochemical environments, the experiment focused on analyzing the rock strength damage and established a multiparameter variation plane equation. Based on the principle of Hydraulic-Chemistry-Mechanics (HCM), coupling damage variables were defined and constructed.

Engineering Background
e Cangshang open pit was closed in 2005 and has remained idle. Due to the construction of an 8,000-ton ore dressing plant adjacent to the Sanshandao Gold Mine, the Cangshang open pit was converted to a tailings pond for the Sanshandao Gold Mine Concentrator in 2009. With the discharge of abandoned tailings fluids, the water level in the open-pit mine continues to rise, which severely affects the stability of the slope (Figure 1). e main sliding area is located on the north side of the slope. Obvious cracks are visible at the top of the slope, and there is significant slip on the local sliding surface as well as a substantial collapse of the adjacent house wall. e open pit water level rise and fall cycles cause irreversible deterioration to the rock strength and internal structure of the slope, especially for slopes containing weak structural planes, such alteration zones are formed during gold mineralization. e alteration zone has a certain strength, and the slope is in a relatively stable state. When the water invades, the rock strength decreases or the rock mass fails, which causes the pit slope to slip and even causes sudden slope instabilities. e cyclic water invasion-dehydration effect weakens the rock mass strength and causes the open pit slope to slip. e YCY-3 water level automatic measuring instrument is used to monitor the surface displacement of the open pit north side and the open pit water level change ( Figure 2). e water level of the tailings dam in the figure shows an increasing trend of first falling and then rising. When the water level falls rapidly or rises rapidly, the slope structure of the bank slope is likely to be unstable, causing serious landslides, displacements, and other disasters.

Uniaxial Compression Test Curve.
e rock samples are taken from the typical rock samples of the tailings dam slope of Sanshan Island Gold Mine. e method is to use on-thespot sampling with the method of combining the core and the block on the slope surface. e drilled cores are encapsulated with plastic wrap in time to ensure their original moisture content. e rock sampled on-site is cut into standard rock specimens of 100 mm × 50 mm. Here, one cycle of water infiltration is defined as the rock being soaked in the soaking box for 24 hours and then dried in the drying box at 105°C for 24 hours. e test consists of three sets of rock samples, each group of 4 rock samples; the rock samples were subjected to 0, 5, 15, and 30 cycles of water infiltration test, and then the samples were then immersed in a solution of pH � 5, pH � 7, and pH � 9 for 24 hours. A uniaxial compression test machine is used to conduct uniaxial compression tests on rocks treated with different water chemical environments at varying cycles. e basic mechanical parameters of the rock under different conditions can be obtained based on the rock stress-strain curve ( Figure 3).
According to the uniaxial compression test results, the various hydrochemical environments and cyclic states have varying degrees of influence on rock mechanical properties. e stress-strain curves show four stages, including the compaction stage, elastic stage, plastic deformation stage, and yield stage. Affected by different pH levels and cyclic water invasion, the peak strength of the rock shows a significant decrease, which is closely related to the pH and the number of cyclic water intrusions. e peak strength and elastic modulus of the rock are obtained according to the uniaxial compressive stress-strain curve. e quantitative mechanical parameters are given in Table 1: With the increase of the number of cycles, the peak strength and elastic modulus of the rock showed an overall downward trend. e degradation rate of the rock was faster during the first 5 cycles of water intrusion, and the degradation rate after 15 cycles was relatively slow. Acid and alkali also have obvious degradation effect on rock peak strength and elastic modulus. e degradation effect of acid solution on rock is stronger than that of alkaline solution, and neutral solution has the weakest degradation effect on rock.

Degradation of Uniaxial Compressive Strength.
Parameters such as rock strength weakening coefficient and elastic modulus degradation under different conditions are obtained from the uniaxial compression test results. e changes in the abovementioned mechanical parameters can be used to quantitatively characterize the degree of rock damage. Define the rock weakening coefficient and the deterioration degree of elastic modulus shown as follows: 2 Advances in Civil Engineering where λ is the rock weakening coefficient, R t0 is the initial peak strength of the rock in the natural state, R tn is the peak strength when the number of cycles of water intrusion is n; D E is the degree of degradation of the elastic modulus, E 0 is the initial elastic modulus of the rock in the natural state, and E n is the modulus of elasticity when the number of cycles of water intrusion is n. e rock damage parameters for different hydrochemical environments and different cyclic states were obtained. e rock damage parameters under different cyclic states are shown in Table 2.
According to Table 2 and Figure 4, for the same water chemical environment, rock strength gradually decreases with increasing number of cycles. Similarly, for the same cycle number of cycles, rock strength gradually decreases under different pH levels. However, for acidic and alkaline environments, the decrease in rock strength in acidic environments is higher than in alkaline environments because the rocks are primarily carbonate rocks, and acidic ions easily breakdown carbonate, resulting in a reduction in rock strength.
By analyzing the effects of different water chemical environments and different cyclic states on the peak rock strength and elastic modulus, a mathematical fit was used to achieve a flat fit of the test results. e fitting results are shown in Figure 5 and the corresponding fitting formula is as follows.
Data were fit using the fitting toolbox in MATLAB to get the fitting formula: (2)

Rock Damage Constitutive Model
Uniaxial compression tests have shown that the coupling of water chemistry and cyclic water intrusion can cause rock strength degradation, and different environmental conditions have different degrees of impact on rock strength. Advances in Civil Engineering erefore, the coupling effect of water chemistry and cyclic water intrusion is affected by the coupling of cyclic water intrusion. erefore, the damage variable in this paper is defined as the cyclic water invasion Hydraulic-Chemistry-Mechanics (HCM) coupling damage variable. Among them, the cyclic hydraulic (chemistry) damage variable primarily affects mechanical parameters by affecting the internal structure of the rock. According to the principle of damage mechanics, the damage variable is defined by the elastic modulus and the damage caused by mechanical loading. Since the damage is primarily due to the influence of the strength of the unit body inside the rock, the damage

Advances in Civil Engineering
where D e denotes the hydraulic-chemical damage variable; E n is the elastic modulus at n number of cycles; and E 0 is the elastic modulus at 0 cycles. (2) Mechanical damage variable: during the uniaxial compression test, the external load will cause random damage to the internal unit of the test rock. e strength of the unit body is mainly distributed within a certain range, and the strength of the unit body smaller or larger than this range gradually decreases with increasing distance. erefore, based on the knowledge of probability theory, it is assumed that the failure of the internal microunits in the rock as a whole obeys a certain probability statistical distribution, such as the Weibull distribution or Gaussian distribution [15]. Assuming that the strength of the rock microelements obeys the Weibull distribution, the distribution probability density function is [17,18] f where m and λ are Weibull distribution parameters. e mechanical damage variable D m is defined as the strength failure probability of rock microelements: Under the coupling effect of water chemistry and cyclic invasion, rocks are affected by HCM coupling of cyclic intrusion. According to formulas (3) and (5), the cyclic invasion HCM coupling damage variable is defined as follows: According to the above formula, the comprehensive damage variable under the HCM coupling is Damage mechanics is a recently developed discipline for studying the failure process of materials based on continuum thermodynamics. Damage mechanics focuses on the development of defects such as micropores in rocks and is the study of the formation of macroscopic cracks in materials. e principle of damage mechanics proposes the strain equivalent principle combined with the effective stress principle, in which the basic form of the damage constitutive relationship does not change before and after the damage caused by the coupling of water chemistry and cyclic water invasion. However, the effective stress in the constitutive model will change. erefore, based on the principle of damage mechanics, the basic form of the material's damage constitutive equation is [19][20][21] where ε is the rock strain in different states, σ is the nominal stress on the rock, σ is the effective stress on the rock, E is the initial elastic modulus of the material, and D is the damage variable. By combining formulas (7) and (8), a constitutive model of rock damage under the coupling of water chemistry and cyclic invasion can be deduced:

Evaluation of Rock Damage Constitutive Model.
According to the uniaxial compression test results of rock under the coupling of water chemistry and cyclic invasion, the comparative analysis of the statistical damage constitutive model under the coupling of water chemistry and cyclic invasion is carried out (Figure 6). e damage constitutive model established in the paper can effectively describe the characteristics of the test curve, and the description accuracy is greater than 90%, which illustrates the effectiveness of the established model ( Figure 6). Because the damage constitutive model was built without considering the initial compaction stage, some model curves show deviations during the compaction stage of the stress-strain curve, which limits the accuracy of the constitutive model to some extent. However, the damage constitutive model considering the coupling effect of water chemistry and cyclic invasion and can describe the characteristics of rock deformation curve.

Conclusion
Taking an open pit as the tailings pond, the change in rock strength considering the degradation and damage caused by the coupling effect of water chemistry and cyclic invasion was analyzed using uniaxial compression tests. A constitutive model for rock damage under the coupling of water chemistry and cyclic invasion was introduced. e main research conclusions include (1) e coupling effect of water chemistry and cyclic invasion decreases rock strength. Test results show that the peak strength and elastic modulus of the rock gradually decrease as the number of cycles increases. Specifically, the more the number of cycles is, the more obvious the damage of the peak strength and elastic modulus of the rock is. e weakening speed of the peak strength is higher than that of the elastic modulus. (2) e acidity and alkalinity of the fluid also degrade rock strength, acidic and alkaline conditions have a significant weakening effect on the peak strength and elastic modulus of the rock, and the weakening effect of the neutral condition on the rock is slightly weaker; acidic fluids degrade rock strength more that alkaline solutions. e change curve relative to the number of cycles, pH level, peak strength, and elastic modulus of the rock was fit. (3) Based on the principle of damage mechanics, the HCM coupling damage variable is defined. Based on the Weibull distribution theory and the strain equivalent principle, a coupling that considers water chemistry and cyclic water intrusion is constructed. e effect of the constitutive model of rock damage is verified by comparison with experimental results.
Data Availability e processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

Conflicts of Interest
e authors declare that they have no conflicts of interest.