Classification and Disintegration Characteristics of the Carboniferous Rocks in Guangxi, China

Guangxi Beitou Transportation Maintenance Technology Group Co., Ltd., Nanning, Guangxi 530029, China Guangxi Communication Design Group Co., Ltd., Nanning, Guangxi 530029, China Faculty of Engineering, China University of Geosciences, Wuhan 430074, China State Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan, Hubei 430071, China School of Civil Engineering, Changsha University of Science & Technology, Changsha 410114, China


Introduction
Carbonaceous rocks are normally defined as hand-soiling black or grayish black claystones containing large quantities of carbonized organic matter as a result of tectonic or sedimentary processes. Carbonaceous rocks are widely found throughout China, particularly in Guangxi, Guizhou, and Yunnan provinces [1]. Its unique geographical location and extensive tectonic and sedimentary history account for the complicated tectonic conditions in Guangxi Province, where carbonaceous rocks have been exposed by many road and bridge construction projects over the past years. Some of the examples include the construction sections along the Liuzhai-Renshui Secondary Highway, the Shuiren-Nanning Expressway, the Yizhou-Liuzhai Expressway, the Liuzhai-Hechi Expressway, the Hechi-Baise Primary Expressway, the Jinchengjiang-Yizhou Primary Highway, and the Yizhou-Liuzhou Expressway. Despite their distinct regional physical properties and mineral contents, the carbonaceous rocks in Guangxi Province are quite similar in terms of their engineering characteristics. Typically, these engineering characteristics include a high initial strength, low weathering and slake durability, vulnerability to disturbance, complicated mineral compositions, and unsuitability for plant growth [2].
Sensitive to the natural environment, easy to shatter, disintegrate, and soften, carbonaceous rock generally refers to a particular clay rock whose engineering properties change greater along with the natural environment [3,4]. In Guangxi, the distribution of carbonaceous rock is not as widely as red clay. However, landslides, collapse, and other geological disasters often occur on the highway and railway slopes composed of carbonaceous rock, attracting the attention of various industries [5,6]. It is well known that failure modes of carbonaceous rock slopes include two categories. e first kind mainly occurs in bedding sliding, the sliding deformation of the upper loose overburden along with the rock, and soil interface after the slope excavation. e second type is the collapse of surface rock mass caused by the changes of its properties after slope excavation, generally manifested as the spalling and disintegration of a surface rock mass [7,8]. After the carbonaceous rock slope is excavated and exposed, the carbonaceous rock is prone to softening and collapse under the action of water immersion, resulting in slope collapse and affecting the stability of the slope (Figure 1). At present, the research on carbonaceous rocks mainly focuses on the material composition, structural characteristics, mineralized composition, physical and mechanical properties as well as deformation and failure mechanism, etc. erefore, it is of greater significance to understand the softening and disintegration of carbonaceous rocks by carrying out relevant laboratory tests.
Rock slaking behavior has been widely studied all over the world. Gamble et al. [9,10] deemed that one factor alone can hardly cause extensive slaking of carbonaceous mudstones. Instead, this is a process jointly controlled by temperature, humidity, and several other factors. Based on slaking tests on soft rock samples, Qu [11] concluded that the slaking rate of soft rocks is related not only to the mineral contents of the rocks but also to the degree of cementation of the rocks. Zhang et al. [12] deemed that the expansibility of these rocks is inversely correlated with the grain sizes of the fraction with the maximum content, effective grain size, and slake durability index of the collapsed scraps of the swelling rock. Liang et al. [13] investigated the changes in the morphology, static disintegration index, and disintegration ratio of four different kinds of soft rocks under slaking based on their mineral compositions and physical parameters. Guo et al. [14] carried out laboratory wetting and disintegration tests on typical red mudstone samples under different conditions. e results revealed that the moisture content during the wetting-drying cycles was the driving factor behind the disintegration of soft red mudstone. Surendra [15] examined the effects of the mineral composition on shale durability and suggested using inorganic salt modifiers to control the slaking of soft rocks. Nara et al. [16] studied the influences of temperature and humidity on subcritical crack growth in sandstone. Bailey [17] analyzed the particle degradation of soft rocks during compaction in subgrade construction. However, previous studies on rock slake durability have mainly focused on soft rocks, with less attention paid to the slaking behavior of carbonaceous rocks.
In view of this, investigating the slaking behavior of the carbonaceous rocks in Guangxi Province is of both engineering and theoretical significance.

Classification of the Carbonaceous Rocks in Guangxi Province
In engineering practice, hand-soiling rocks containing large quantities of dispersed carbonized organic matter are often collectively called carbonaceous rocks, which we do not think is appropriate because carbonaceous rocks containing different mineral components differ in terms of their physical-chemical properties, strengths, and slaking behaviors. Whole-rock mineral analysis and clay mineral quantification were conducted on carbonaceous rock samples from the Hechi-Baise Expressway (HBE) using powder X-ray diffraction (XRD, Figure 2). To classify the carbonaceous rock samples from the HBE, first, the mineral compositions of these samples were investigated. e carbonaceous rock outcroppings at stakes K19-K22 were sampled and prepared (ground) for X-ray diffraction analysis (Figures 3 and 4). Table 1 lists the main mineral components and their percentage contents in the samples.
As shown in Table 1, the mineral contents of samples A1 and A2 are quartz, calcite, and a trace amount of dolostone, with quartz accounting for 69.63% and calcite accounting for 28.66%. Neither of these samples contains clay minerals. e main mineral contents of samples A3, B2, C2, and C3 are calcite, quartz, illite, and a lesser amount of pyrite, with calcite accounting for 43.30%-66.06% and quartz accounting for 5.90%-37.74%. In addition, the clay minerals, which are primarily illite, account for approximately 10%. Smectite was found in some of the samples, and the pyrite contents of all of these samples are less than 2.30%. e main mineral contents of samples C4, C5, D, E, F, and H are quartz, calcite, dolostone, illite, and pyrite, with quartz accounting for 45.69%-64.31%. Clay minerals, which are primarily illite, account for 20.65%-27.18%, and dolostone accounts for 7.12%-15.13%. Some of these samples contain calcite, which accounts for a maximum of 17.92%, and a minimal amount of pyrite, which accounts for a maximum of 2.64%.
Based on the mineral components and their percentage contents in the carbonaceous rock samples from the HBE, the main clay mineral in the carbonaceous rocks is illite, which generally accounts for less than 24.74%. Smectite is also present in a few of the rock samples. Except for sample B, all of the other samples have high quartz contents. Some of the samples contain small amounts of dolostone, pyrite, and other minerals.
Considering the external characteristics, mineral compositions, and contents of the rock samples, according to the Classification and Nomenclature Schemes of Sedimentary Rock (GB-T17412. , the rock samples from the HBE are named as follows: (i) Samples A1 and A2 are carbonate-bearing cherts (ii) Samples A3, B2, C2, and C3 are carbonaceous mudbearing limestones (iii) Samples C4, C5, and D are carbonaceous illite claystones (iv) Samples E, F, and H are carbonaceous illite clay shales 2

Advances in Civil Engineering
To facilitate discrimination during the subsequent experiments, the carbonaceous mud-bearing limestone samples were renumbered B1, B2, B3, and B4; the carbonaceous illite claystone samples were renumbered C1, C2, and C3; and the other samples were not renumbered.

Slake Durability Testing of the Carbonaceous Rocks in Guangxi Province
To establish the slake durability of the carbonaceous rock samples from the HBE, laboratory slaking tests were conducted on the samples under wetting-drying cycles according to the recommendations of the Standard for Tests Method of Engineering Rock Masses (GB/T 50266-2013) for the slake durability testing of rocks.

Test Equipment.
Oven: an LY-660 precision industrial thermostatic air-dry oven was used ( Figure 5). In our experiment, the drying temperature was maintained at approximately 105°C, as recommended by the standard. (2) Slake durability apparatus: the disintegrating tester at the Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, was used ( Figure 6). During operation, the speed of the apparatus was maintained at 20 r/min. e cylindrical screen drum is 100 mm (long) by 140 mm (diameter), with a mesh diameter of 2 mm. (3) Double-face rock grinder: an SCM-200 double-face rock grinder was used. e automatic grinding feed rate was 0.04-0.12 mm. In addition to these apparatus, electronic balances (with a precision of 0.01 g) and thermometers were also used as needed.

Sample Preparation.
e rock samples were collected from the HBE and sealed with industrial parafilm (Figure 7). en, the samples were placed in a plastic wrap to preserve their natural moisture content. e rock samples were reshaped into a rounded form.
e mass of each of the specimens was maintained at 40-60 g using the rock grinder. Each specimen group contained at least 10 specimens ( Figure 8). All four types of carbonaceous rocks were prepared into specimens and were tested separately.

Test Procedure
. First, the screen drum was dried and weighed. Next, the rock specimen was placed into the screen drum and dried at 105°C-110°C for 24 h. en, the screen drum with the rock specimen was taken out of the oven and placed into the dryer to cool to room temperature before it was weighed again. e screen drum with the rock specimen was placed in the water flume. en, distilled water was poured into the flume to approximately 20 mm below the rotary shaft. e slake durability apparatus was started. e screen drum was run at a constant velocity of 20 r/min for 10 min, and then, the screen drum with the residual specimen was dried in the oven at 105°C-110°C for 24 h to a constant mass, cooled in the dryer to room temperature, and weighed. e second      Advances in Civil Engineering step was repeated for the number of cycles required by the experiment, and the experimental data were recorded. e water temperature was maintained at 20°C ± 2°C during the experiment. At the end of the experiment, the colors of the residual specimen and the water and the characteristics of any precipitate left in the water were described.

Results and
Analysis. e rock slake durability index was calculated using the following equation: where I di is the slake durability index of the rock after the ith wetting-drying cycle (%); m s is the dried mass of the original sample (g); and m r is the dried mass of the residual specimen (g). e rock slake durability index is defined as the mass percentage after each standard wetting-drying cycle relative to the mass of the previous cycle: where I di is the slake durability index of the rock after the ith wetting-drying cycle (%); m i is the mass of the residue after the ith standard wetting-drying cycle (g); and m i−1 is the mass of the residue after the (i − 1)th standard wettingdrying cycle (g).

Slake Durability Indexes of the Carbonaceous Rocks.
Separate slaking tests were conducted on the different types of carbonaceous rock samples from the HBE. Each type was tested under six wetting-drying cycles, and their respective slake durability indexes were obtained. Tables 2 and 3 present the slake durability indexes of the rock samples.
To facilitate observation, the data in these tables are also plotted in Figures 9 and 10. From Figures 9 and 10, for the carbonate-bearing cherts (A1 and A2) and the carbonaceous mud-bearing limestones (B1, B2, B3, and B4), after six standard wetting-drying cycles, the slaking residues and slake durability indexes were linearly related to the number of cycles in all cases. e slake durability indexes remained higher than 90% after six wetting-drying cycles. e slaking of both types of rocks (i.e., the mass reduction of the samples after the experiment) can be understood as a uniform mass reduction of the carbonatebearing chert or carbonaceous mud-bearing limestone resulting from water erosion of the sample and the centrifugal pull from the rotation of the screen drum under laboratory wetting-drying cycles. e relationship between the residual mass of a specimen and the number of wettingdrying cycles is fitted by the following linear equations: A2: y � −1.3786x + 472.95, B1: y � −2.8386x + 297.96, B2: y � −8.905x + 597.12, B3: y � −2.9411x + 486.63, B4: y � −3.415x + 374.18, where y is the specimen's residual mass after slaking, and x is the number of wetting-drying cycles. As can be seen from equations (3)-(8), the slaking residual mass of the carbonate-bearing cherts and carbonaceous mud-bearing limestones decreased linearly as the number of laboratory wetting-drying cycles increased. Except for specimen B2 (which had a slightly higher clay mineral content than the other specimens), which showed a mass reduction of 8-9 g after each wetting-drying cycle, all of the other specimens showed a mass reduction of less than 5 g. More importantly, the specimens showed virtually no cracks on the surface, and all of the specimens remained intact after six laboratory wetting-drying cycles. As such, we can assume that in the natural state, the carbonate-bearing  Advances in Civil Engineering chert and carbonaceous mud-bearing limestone from the HBE are very weakly slakable or not slakable at all. In Figure 10, as the number of standard wetting-drying cycles increased, the slake durability index of the carbonaceous illite clay mudstones (C1, C2, and C3) and the carbonaceous illite clay shales (E, F, and H) from the HBE gradually decreased, with a 43%-66% reduction for the former and a 21%-33% reduction for the latter. e relationship between the number of standard wetting-drying cycles and the slake durability index of the specimen is fitted by the following equations: where y is the slake durability index; and x is the number of wetting-drying cycles. In Figure 11, the specimen's slake durability under different numbers of cycles was close to the fitted curvilinear equation, suggesting that the slake durability of the specimen agrees well with equations (9)- (14), with modest data discretization and very little fluctuation about the curve. Based on the fitting formulas, the slake durability index of the carbonaceous illite clay mudstones and carbonaceous illite clay shales decreased exponentially as the number of wetting-drying cycles increased. Furthermore, as the number of wetting-drying cycles increased, the slake durability index curve gradually flattened until the specimens had completed slaking. Figure 11 shows the relationship between the slake durability indexes and the number of wetting-drying cycles. As can be seen from this diagram, compared with the carbonaceous illite clay shales, the carbonate-bearing cherts and the mud-bearing limestones are very weakly slakable or not slakable at all. e carbonaceous illite clay shales appear to be quite slakable, and the carbonaceous illite mudstones are even more slakable. Figures 12 and 13 show the dependence of the grain size content of these rocks on the number of wetting-drying cycles. An analysis of these figures reveals the following.

Slaking Grain Size Analysis of the Carbonaceous Rocks.
As the number of wetting-drying cycles increased, the content of the 20-40 mm fraction in the slaking product of the carbonaceous illite clay mudstones gradually decreased, whereas the contents of all of the other grain sizes gradually increased. e content of the <2 mm fraction increased the fastest relative to all of the other grain sizes. e slaking product of the carbonaceous illite clay mudstones after the laboratory slaking test was mainly composed of grains <2 mm. e carbonaceous illite clay shales were weakly slakable, with a low slaking speed and a lower slakability than the carbonaceous illite clay mudstones. Other than the content of the <2 mm fraction, which increased comparatively quickly, the contents of all of the other grain sizes changed slowly, with even smaller variations after the first two cycles. e carbonaceous illite clay shales were less slakable than the carbonaceous illite clay mudstones. e slaking of the carbonaceous illite clay shales typically occurred along the textures, resulting in many schistose structures in the slaking residues that could hardly pass through the smallsize sieve holes. e larger sized grains were the main contributors.
Because the carbonaceous illite clay mudstones were more slakable than the carbonaceous illite clay shales, they slaked noticeably faster than the carbonaceous illite clay shales. e variations in the contents of the larger and smaller grain sizes were also greater. us, under the same conditions, the carbonaceous illite clay mudstones required fewer wetting-drying cycles to completely slake compared to the carbonaceous illite clay shales.

Conclusions
e slaking phenomena and the behaviors of typical outcropping carbonaceous rock in the HBE in Guangxi under different numbers of wetting-drying cycles were investigated through laboratory slaking tests. e residual slaking grains of the rock samples were also analyzed for gradation. e following conclusions were drawn: (1) As the carbonate-bearing cherts contained no clay minerals and the mud-bearing limestones had a very low clay contents, both rock types appeared to be very weakly slakable or not slakable at all. e carbonaceous illite clay mudstones and carbonaceous illite clay shales, both of which contained more than 20% clay minerals, were highly slakable. us, the clay content constitutes the main driving factor behind the slaking behavior of carbonaceous rocks. Furthermore, despite their similar clay contents, the carbonaceous illite clay mudstones and carbonaceous illite clay shales also differed from each other in terms of their slaking behavior (the carbonaceous illite clay mudstone was more slakable) as a result of their different structural forms. ese phenomena suggest that the slaking behavior of the carbonaceous rocks from the HBE was primarily determined by the clay content. e structural form also played a nonnegligible role.
(2) As the number of wetting-drying cycles increased, the grain size contents of the slaking products of the carbonaceous illite clay mudstones and carbonaceous illite clay shales changed continuously, with similarities as well as differences between the two rocks. e carbonaceous illite clay mudstones slaked more quickly. e chunky specimen gradually slaked into smaller fragments and elliptical grains, with the 20-40 mm chunky fraction decreasing quickly, and the <2 mm granular fraction increasing quickly. Like the carbonaceous illite clay mudstones, as the number of wetting-drying cycles increased, the <2 mm fraction also prevailed in the slaking product of the carbonaceous illite clay shales. e unique stratification of this rock also resulted in the 20-40 mm schistose fraction predominating in the  20~40 mm 10~20 mm 5~10 mm 2~5 mm <2 mm Figure 13: e change in the particle contents of the carbonaceous illite clay shales as the number of wetting-drying cycles increases. 8 Advances in Civil Engineering residue, while all of the other grain size fractions increased slowly.

Data Availability
e data used to support the findings of the study are available from the corresponding author upon request.

Conflicts of Interest
e authors declare that there are no conflicts of interest regarding the publication of this paper.