Synthesis of Nanoporous TiO 2 and Its Potential Applicability for Dye-Sensitized Solar Cell Using Antocyanine Black Rice

Nanoporous mesostructure TiO2 powders were synthesized by sol-gel method, with TiCl4 as a precursor in methanol solution. The Pluronic PE 6200 of block copolymer was used as the pores template. It was found from XRD measurements, both at 400◦C and 450◦C calcination temperatures, that the sol-gel technique yielded the nanoporous TiO2 with anatase phase. Based on N2 adsorption characterization using BET method, the TiO2 samples have surface area of 108 m2/g and 88 m2/g for calcination temperatures of 400◦C and of 450◦C, respectively. From small-angle neutron scattering (SANS) patterns, TiO2 samples were observed to have nanoporous structures with pore sizes between 22–24 nm. The TiO2 also have order degree which depends on the calcination temperature. The potential applicability of the resulting TiO2 is confirmed for dye-sensitized solar cell (DSSC), composed of nanoporous anatase TiO2 and natural dye from antocyanine black rice. UV-Vis measurement of dye extracted from the black rice indicated that the antocyanine chelate can propagate into the TiO2 nanoporous network. The short circuit photocurrent density (Jsc) under 100 mWcm−2 reached 1.287 mAcm−2 with open circuit photovoltage (Voc) of 550 mV and the fill factor of 33.4%. The results show that the hybrid organic-inorganic structures are very attractive for future low-cost devices.


Introduction
The dye-sensitized solar cell (DSSC) is one of the potential candidates for next generation solar cells, because its lowcost material and relatively simple production processes.Different from conventional solar cells whose working principle is based on solid state theory, dye-sensitized solar cell is a photoelectrochemical-based solar cell.Photo absorption is done by dye molecule and charge separation by inorganic semiconductor nanocrystals which have a large band gap, and uses electrolytes for dye regeneration.
One of the commonly used wide gap semiconductor for DSSC applications is titanium dioxide (TiO 2 ).Titanium dioxide (TiO 2 ) is a semiconductor material which has wide applications in optical as well as electronics materials.This is because TiO 2 have remarkable physical, chemical, and optical characteristics.It has attracted increased attention for potential applications as gas sensors [1], metal-oxidesemiconductor field effect transistors (MOSFET) gate dielectric [2], anti-microbial coating [3], pigments [3], solar hydrogen generation [4], and photovoltaic cells or well known as dye-sensitized solar cell (DSSC) [5].In energy and environmental fields, much research has been done on TiO 2 characteristics especially on its applications as a main component of DSSC [3].For this application, material with large surface area is preferred to increase the contact area.Indeed the nanostructure of TiO 2 becomes an important characteristic as well as the pore nanosize.A certain class of nanoporous material emerged from the requirements called mesoporous material, which has pore diameters between 2-50 nm [4].This kind of material has attracted much attention because of its wide potential applicability in dye-sensitized solar cells as well as sensor devices [5][6][7][8][9][10].

Advances in Materials Science and Engineering
Mesoporous TiO 2 has been developed with various methods, most importantly using organic templates to build porous structures.Synthesis of mesoporous TiO 2 was first reported by Antonelli and Ying in 1995 using an ionic alkyl phosphate surfactant as a template with sol-gel method [11], however the resulting material was not pure TiO 2 because the phosphate molecules were strongly bonded on to the TiO 2 structure.One alternative is to use nonionic surfactants, particularly block copolymers, as a substitute to ionic surfactants.Block copolymers have an advantage of being easily removed from inorganic frameworks by calcination or solvent extraction since the block copolymer only involves H-bonding type rather than the electrostatic interactions found using ionic surfactant [12].Moreover the properties of block copolymers can be continuously tuned by adjusting solvent composition, molecular weight, or polymer architectures of block copolymers [13].
After succeeding in synthesizing mesoporous material using block copolymer templates, publications related to mesoporous TiO 2 has continuously increased, but mostly used titanium alkoxide as Ti source at aqueous solution [14].Large amounts of water inside the solution can cause hydrolysis and condensation as well as difficulties in controlling the mesostructure because the alkoxide is highly reactive with water.In this research we firstly, in our knowledge, prepared mesoporous TiO 2 using triblock copolymer Pluronic PE 6200 as a template and TiCl 4 as a precursor at alcoholic solution.The resulting mesostructure TiO 2 powder is characterized by using X-ray diffraction, SEM, and small-angle neutron scattering (SANS) to confirm the nanostructure of materials.The resulting mesostructure TiO 2 has a nanocrystalline wall, which is necessary to ensure good electron diffusion [15].A DSSC using nanocrystalline TiO 2 film electrode is then fabricated and a DSSC using visible light sensitisation of a nanocrystalline TiO 2 film is developed.
To investigate TiO 2 application in a DSSC system, the use of natural dye extracted from antocyanine black rice was investigated.Natural antocyanine from black rice extraction would be used as the dye since the antocyanin has good chemical bonding with titanium dioxide [16].The I-V curve measurement was performed under direct Xenon HID lamp using multimeter, variable resistor, and pyranometer.

Experimental Method
The triblock copolymer PEO-PPO-PEO Pluronic PE 6200 (PEO 8 -PPO 30 -PEO 8 , M av = 2450 g/mol) was supplied by BASF.The titanium tetrachloride (TiCl 4 ) precursor was purchased from Merck, and methanol was used as a solvent.To obtain TiO 2 paste, polyvinyl alcohol (PVA) was used.The dye was extracted from the black rice.All chemicals were used without further purification.
An initial solution was made by adding 1 gram of Pluronic PE 6200 to 10 gram methanol and stirred for 30 minutes to initiate micelle structure.Then the TiCl 4 was slowly added to the solution under stirring for 30 minutes so that the molar ratio of TiCl 4 : methanol : Pluronic PE6200 was 1 : 21.7 : 0.0408.The ratios used in the synthesis process are as follow; TiCl 4 : methanol : Pluronic PE6200.TiCl 4 reaction with alcoholic solution is exothermic and produces large amount of HCl gas and a collection of chloroalkoxide (TiCl 2 (OCH 3 ) 2 ) [17,18].The solutions were then aged for 4 days at 40-45 • C in a furnace until dry gel was formed.The TiO 2 dry gels were then calcined at 400 • -450 • C for 4 hours with a heating rate of 5-6 • C/minute to remove the block copolymer and promote crystallization.
The TiO 2 paste was made by mixing TiO 2 powder with 10% polyvinyl alcohol (PVA)/water solution, mixed at 80 • C.After that the resulting powder was ground with mortar to obtain the smooth paste for deposition.The paste was deposited onto ITO conductive glass (In:SnO 2 ) using doctor blade technique with area of 0.855 cm 2 , then sintered at 450 • C for 30 minutes.The TiO 2 film was then rinsed in dye solution extracted from black rice for about 30 minutes.
The antocyanine dye was derived from Indonesian black rice extraction using organic solvent which is the combination of alcohol, acetic acid, and water with the molar ratio of 25 : 4 : 21.The black rice as much as 13 gram was grinded using mortar then dissolved by solvent on magnetic stirrer.Finally, the solid filtrate was removed with filtration paper and the dye was kept in tight and dark bottle to prevent evaporation and degradation.
The conductive glass with platinum layer as a catalyst was put on the top of the TiO 2 -dye electrode.This platinumconductive glass acted as a counter electrode.The electrolyte for dye regeneration is composed of 0.5 M potassium iodide (KI), 0.05 M Iodine (I 2 ), and acetonitrile solvent (all obtained from Merck).since the weight-losses are always followed by endothermic or exothermic processes.The X-Ray Diffractometer (XRD) patterns were obtained using Philips Analytical X-Ray with Cu radiation (λ = 0.154056 nm) and the crystallite sizes were calculated using Scherrer equation at Miller indices (101).Wide-angle XRD patterns shown at Figure 2 indicate both samples have wellcrystallized TiO 2 with pure anatase phase according to the JCPDS number 21-1272.As shown at Table 1, higher calcination temperatures resulted in higher crystallite size.More intense and well-resolved peaks observed at higher calcinations temperature indicate the increasing degree of the crystalline.This result correlated with the fact that full crystallization of TiO 2 occurs at 550 • C [20].In accordance with TG-DTA result, TiO 2 sample calcined below 450 • C still contain some residual carbon, which can be observed from black colour of the powder sample, which in turn may contribute to amorphous peak nature at XRD patterns.

Results and Discussion
Small-angle Neutron Scattering (SANS) measurements were carried out to confirm the porous structure of the resulting TiO 2 at Neutron Scattering Laboratory, BATAN Indonesia using SMARTer.The neutron wavelength of SANS  was λ = 0.566 nm.Sample to detector distances were varied at 2, 8, and 18 meter to obtain the vector of transfer momentum (q) range about 0.02-1.5 nm −1 .The SANS patterns as shown in Figure 3 confirm that the correlation peak formed at both samples indicated that mesoporous structures were preserved.The peak formed at low angle can be attributed to the distance between the center of pores [20].According to the calculations, the average pore distances (d = 2π/q peak ) are about 22 nm (Ti-a) and 24 nm (Ti-b) which is typical of the pore to pore distance of mesoporous materials.Average pore distance was increased with increasing calcination temperatures because of structure contraction observed from the heat treatment.SANS patterns also show that the peak intensity of lower calcination temperature sample (Ti-a) was slightly larger.This indicating that sample with lower calcinations temperature has higher pore ordering than sample with higher calcinations temperature (Ti-b).Scanning Electron Microscope (SEM) images were obtained from JEOL operated at 20 kV.The morphology of the samples was observed with SEM images as shown at Figure 4.The structure morphology contains large amount of close packed particles which is typical of porous material.The mesoporosity of samples was partially due to both intrastructure porosity and interstructure porosity of the materials.
Nitrogen adsorption measurements were carried out on a NOVA 1000 High Speed Gas Sorption Analyzer to determine Brunau-Emmett-Teller (BET) surface area.Before these measurements, the samples were degassed at 200 • C for 2 hours in vacuum conditions to eliminate water and oil.According to N 2 adsorption measurements, the BET surface area are 108 m 2 /g and 88 m 2 /g for Ti-a sample and Ti-b sample, respectively (Table 1).Higher calcination temperatures produced a lower surface area since the crystallization of TiO 2 is usually followed by some collapse and destruction of the mesostructure [21].These surface areas are larger than commercial Degussa P-25 which is mainly used as a nano TiO 2 reference which has BET surface area at about 50 m 2 /g [22].
The DSSC performance of the Ti-a sample was investigated using illumination from a solar simulator.Photocurrent-photovoltage characteristic of the black rice adsorbed on a nanocrystalline TiO 2 electrode was measured with a sandwich type cell.The working electrode with the black rice dye adsorbed on a nanocrystalline TiO 2 film was gently squeezed together with a platinum-coated ITO glass electrode and irradiated from the substrate side of working electrode.The I-V curve was characterized using a 10 kΩ potentiometer and digital multimeter (Fluke 77 III and Advantest) to get maximum power output (see Figure 5).Irradiation of 100 mW/cm 2 by a 35 W Xenon HID lamp was measured using Precision Spectral Pyranometer (Eppley Radiometer) to get the intensity.The fill factor (FF) and efficiency (η) are calculated as [1] Figure 6 shows the photocurrent-photovoltage characteristics of a sandwich solar cell based on the black rice dye adsorbed on a nanoporous TiO 2 film electrode irradiated with a light intensity of 100 mW/cm 2 as a light source.The I sc , V oc , I max , V max , and the point of P max also are indicated in Figure 6.The I max and V max , which indicate the photocurrent and photovoltage at P max , are estimated to be 0.69 mAcm −2 and 343 mV.The J sc and V oc values of solar cell were estimated to be 1.287 mAcm −2 and 550 mV.The η value was estimated to be 0.236% and the P max was 236.7 μWcm −2 .
The FF value was estimated to be 33.4% using (1).The low efficiency of DSSC could be caused by the black rice dyes extraction which could be improved by better extraction process such as purification and enrichment.
To investigate the absorption process of sunlight into the black rice dye, the UV-VIS measurement is performed between 200-700 nm of the wavelength.The Figure 7 shows the UV-Vis absorbance spectrum of black rice dye extract which is characterized by three peaks located at 242, 282, and 530 nm, with absorbance 0.72, 0.80, and 0.62, respectively (in arbitrary unit).Those peaks indicate the higher possibility to absorb sunlight, especially at 530 nm.Because of the peak of sunlight spectra at 550 nm [1], the dyes can receive maximum sunlight absorption.When the antocyanine dyes from black rice chemically bonded with TiO 2 , it can be chemical adsorption or chelation as described before; the LUMO-HOMO of dyes will be affected so that the bandgap energy change.Finally, the changing of bandgap energy will shift the peak of absorbance spectra and broaden the peak.Some reports state that the shifting goes to the lower energy or red shifting [5,9].As a result, the black rice dyes absorbance will approach the sunlight maxima spectra, which yield higher possibility of light harvesting.

Conclusions
Nanoporous TiO 2 with mesostructure anatase wall have been successfully prepared using a combination of sol-gel method and block copolymer as a template.TiCl 4 was used as a Ti precursor and Pluronic PE6200 acted well as mesoporous template although only short-range pore ordering is observed.Calcination temperature was observed to be an important parameter for mesostructure formation as well as crystallization process.The biophotovoltaic conversion device based on DSSC using black rice dye adsorbed nanoporous anatase TiO 2 film electrode was prepared and the DSSC using visible light sensitisation of a nanocrystalline TiO 2 film was developed.The I-V curve of the solar cell using black rice adsorbed on a nanocrystalline TiO 2 electrode is characterized under light intensity of 100 mWcm −2 .It is estimated that η value was 0.236% and the FF value was 33.4%.

Figure 1 Figure 1 :Figure 2 :
Figure1shows Thermo Gravimetric-Differential Thermal Analysis (TG-DTA) results for TiO 2 dry gel after 4 days aging at 45 • C. The TG-DTA was performed at the temperature range between 50 • -600 • C with 10 • C/minute of heating rate.From the TGA curve, which shows sample weight loss as the function of temperature, the sample weight decreased by about 75% when heated up to 460 • C. The TGA curve also shows three weight-loss regions.The first region of temperatures below 200 • C resulted from -OH groups evaporation.The second region between 200 • -325 • C was attributed to organic decomposition.The third region from 325 • C to 460 • C is due to residual block copolymer oxidation and decomposition of chlorine bonded to the Ti-OH.The TGA curve also shows that the block copolymer was completely removed at calcination temperatures above 450 • C.The DTA curve clearly shows two peaks, the endothermic peak at region of 100 • C-200 • C which is attributed to solvent evaporation, and broad exothermic peak at 325 • C-460 • C which is attributed to the decomposition of block copolymer and chlorine and phase transformation from amorphous to anatase TiO 2 .The phase transformation actually starts from 350 • C[19].As shown in the full TG-DTA curve, the data from TGA curve correlates directly to the DTA record

Figure 5 :Figure 6 :
Figure 5: The circuit for the measurement of photocurrentphotovoltage characterization of DSSC using black rice adsorbed on a nanocrystalline TiO 2 film electrode with 35 W HID lamp.

Figure 7 :
Figure 7: Absorbance spectra of black rice dyes extract.
a Calculated from Scherrer equation at Miller indices (101).