Experimental Study of Correlation of Mechanical Properties of Al-Si Casts Produced by Pressure Die Casting with Si / Fe / Mn Content and Their Mutual Mass Relations

The submitted contribution addresses problems concerning influence of alloying elements (Si/Fe/Mn) of Al-Si pressure die casts (HPDC) on values of residual deformation. On the basis of results of executed experiments, mutual correlations are analyzed and described, while not onlymeasurements results are evaluated but alsometallographic outputs of obtained compounds from the view of their formation, occurrence, and size. The development of intermetallic phases structures Al(FeMn)Si as well as intermetallic ferritic phase Al 3 FeSi was observed. More verification experiments follow in order to apply obtained knowledge for improvement and/or preservation of casts properties on required level.


Introduction
Parts manufactured by pressure die casting distinguish by suitable properties in relation to their mass.In present, these products/casts are utilized in various spheres of industries, significant share of which is automotive industry [1].An important requirement in this sphere is resultant mass of products, whilst all claimed properties are preserved.The trend of mass reduction leads to application of aluminiumbased materials, while demands on strength, extensibility, and other mechanical properties are on the same level as for Fe-based materials.
The paper describes basic impacts of chosen alloying elements on permanent deformation as a significant mechanical property.Mutual correlations between chosen alloying metals and resulting deformation measured on a group of casts are described.Consecutively these relations are observed during variation of content of the alloying elements in order to increase resulting strength of the cast.Providing stability in casting process is of great importance, since it has direct impact on resulting cast properties [2][3][4].Aluminium alloys are die cast under pressure on casting machines with cold chamber [5,6].Significant factor of the process is corrosive effect of liquid aluminium alloys particularly at higher temperatures, this effect makes it impossible to employ casting machines with hot chamber [6][7][8].Horizontal cold chambers are relatively simple, and it is possible to apply higher specific pressure on the cast metal.Thus, it is possible to cast light-walled casts with smooth surface and high mechanical properties.These advantages of horizontal chamber make it possible to design large casting machines with voluminous loading chamber and closing force   up to 30 MN, with gross cast mass 30 kg or more, in casting of aluminium alloys (charge utilization of 80%) [6,9,10].
The quality of aluminium casts produced by pressure die casting depends closely on the content of alloying elements [5,6,[11][12][13][14][15]. The properties of chosen alloying elements are described in Table 1.
Concentration of alloying elements in the cast is chosen according to requirements on the cast properties; however, the concentrations are limited by recommended ranges [11].
Iron and silicium are very often contained in aluminium alloys.Both of these elements influence mechanical properties of the casts.Theoretical knowledge shows that iron It is alloyed together with B in order to refine structure content higher than 1-1.4% has negative impact on the cast properties [5,6,11].

Preparation of Experimental Casts.
Casting machine CLH 400.01 was applied for the experimental casting.It is horizontal pressure machine with cold chamber, with manual dosing of metal.Other operations of casting process run in semiautomatic cycle, so that all conditions of casting cycle could be replicated.In semiautomatic regime of the machine with horizontal cold chamber, an operator manually scoops up metal with the scoop from the heating furnace and pours it into loading chamber.All other operations including ejection of the cast from the mould are automatic with electrohydraulic safety system for particular operations.Set of 80 specimens were cast at a given technological order (Table 2).Every eighth cast specimen were selected for experimental evaluation, so that the whole range of usable capacity of the heating furnace would be represented.

Evaluation Method by Pressure Tests of Residual Deformation.
This is a type of pressure test which follows residual deformation; the term residual deformation means deformation measured at partial unload discharge.The load is evoked by force  1 .When maximal value of deformation evoked by Residual deformation tests were carried out on device TIRA test 28200.Initial load force was set on value  1 = 86 kN with loading speed 10 mm s −1 .When maximum The analysis of the casts provides mass content percentage of the following elements: Si, Fe, Cu, Mn, Mg, Zn, Ni, Cr, Pb, Sn, Ti, Na, Sr, V, Zr, and Al.Table 3 shows values of boundary intervals of contents for particular elements according to the norm STN EN 42 4331.

Chemical Composition.
The results of chemical composition measurements have shown decrease in the content of observed elements in casting process.Particular casts indicate variations of the contents with decreasing tendency.The results directly correspond to the results of observation of content changes in heating furnace that are described in contributions dealing with casting process variations [21,22].The results are given in Table 4.
From measurements of the chemical composition of each sample (Table 4), the track of changes to the content of the particular elements, depending on the time, can be kept.These changes are directly reflected in the element content of castings, and interval of the change is 7.04% for Si, 15.19% for Fe, and 27.27% for Mn.
On the basis of the analysis, it was suggested to stabilize or slightly increase iron content and to directly increase manganese content.An iron content should be up to one percent because-as it is given in the theory and also prescribed by the norm-exceeding of iron content above 1.4% causes strong negative effects [6,11].Relation of iron and manganese content was determined on the basis of measurements to 3.15 : 1.According to this relation and to cast manufacturer requirements, also taking into account possibilities to change alloy composition, the iron content for further experimental evaluation was set on value 0.90 to 0.95% Fe, and the manganese content was set 0.35% to 0.38% Mn.
The experiment that followed was based on suggested iron and manganese content values.The set of casts was produced with the same methodology as in previous case.Six casts from the set were selected for residual deformation and chemical composition analyses.Obtained values are shown in Table 5.
Dependence courses of particular casts on chemical composition on casting order of the casts are given in Figure 1.

Residual Deformation.
In this part, dependence courses of residual deformation on chemical composition of the casts are observed.Particular influences of chosen alloying elements are given in introductory part of the paper.An influence of iron and manganese on resulting residual deformation was observed, at the same time, a possible influence of silicium content variation was evaluated.Considering that Si influences fluidity, all observed casts were X-ray tested, and no internal defects were detected.Also, visual and dimensional inspections did not show any negative changes of the casts.Figure 2 gives dependence courses of residual deformation on chosen elements content.

Influence of Iron and Manganese Contents on Values of Residual Deformation.
For increasing values of iron content, it is possible to see the decrease of residual deformation values (Figure 2, Fe (wt.), exp.I).The decrease is also observed at the manganese content increase (Figure 2, Mn (wt.), exp.I).In proposal for iron content in aluminium alloy, the content intervals were suggested, and these intervals were not exceeded during analyses.In one case, the iron content value (0.98%) exceeded recommended range (0.90 to 0.95% Fe); however, no negative effect was observed.Figure 2 shows diagrams representing whole range of observed iron and manganese contents and residual deformations which depend on those contents.From the diagrams, the decrease in residual deformations in dependence on alloying elements increase is apparent.The recorded decrease for residual deformation was 19.85% for the observed samples.The coupling of the iron content and manganese content can be observed also; this is represented by residual deformation.The test of functional dependences was carried out.At first, the correlations between iron and manganese contents in aluminium alloy and residual deformation were observed independently.In the following, the complex dependences between the parameters were described.For analyzed places A and B, the value of correlation coefficient for measuring of iron content and residual deformation was determined on −0.868, and for manganese content and residual deformation, it was determined on −0.838.The mutual correlation between iron and manganese content was determined on 0.944.Values of correlation coefficients indicate indirect functional dependences between iron content, manganese content, and residual deformation.Values approach significantly the value −1, so the high degree of the correlation can be noted.

Multiple coefficient of correlation for analyses in places
A and B has value 0.0954.Cummulative characteristic of residual deformation dependence on Mn and Fe content is shown in Figure 3. Differences between measured-out points and theoretical area fall within supposed range, whilst mutual relations of Mn and Fe changes can be observed.The behaviour can be explained from metallurgy point of view by formation of structures on the Al-Fe-Mn-Si basis and their variations, with an assumption that structures with lesser content of alloying elements contain more massive formations of intermetallic phases Al(FeMn)Si and lower content of Mn causes more frequent occurrence of intermetallic ferritic phase Al 3 FeSi [11].This was the reason to carry out analysis to evaluate the samples.Therefore, the metallographic analysis was carried out to evaluate the particular samples in terms of the formation of structures as well as their possible effect on the mechanical properties of the casts.
From the analysis of microscopic images, it follows that structures of A1, A2, B1, and B2 samples (Figure 4) contain fine structural zones of intermetallic phases Al(FeMn)Si and defects in the form of bubbles in dimensional range ⟨8; 11⟩ m.Structures of A8, A9, B8, and B9 (Figure 4), on the other side, contain more massive structural zones of intermetallic phases Al(FeMn)Si and internal defects in greater dimensional interval ⟨10; 30⟩ m.Also the structures  of ferritic phase Al 3 FeSi and intermetallic phase FeSiAl 5 are observed as more massive needles.In the case of FeSiAl 5 , long needles are forming; these can cause defects due to the notch effect.Variations of ferritic phase Al 3 FeSi from massive and more frequent in samples A8, A9, B8, and B9 to finer and less frequent in samples A1, A2, B1, and B2 correspond to the increase in Mn content.All images also show particles of undissolved silicium in a form of irregular objects.
More massive structural zones of ferritic phase Al 3 FeSi have negative effects on values of residual deformation,   In the case of manganese, it is necessary to observe the correlation, because if it is not saturated, and it is eventually deposited as a thermal compound AlMnSi.

Conclusions
Realized experiments and discussions show several important aspects of obtained and verified knowledge.Experiments were focused on a group of three elements (Si, Fe, and Mn) occurring in subeutectic Al-Si alloy.Selection of the group was based on knowledge of realized measurements obtained within monitoring of processes in heating furnaces, where variations of elements concentration have been observed.The variations relate to silicium, iron, and manganese, all in decreasing trends.
Described results also show that in casting process, concentration variation of silicium, iron, and manganese may occur, whilst these variations in the conditions of real experiment have reached values for Fe 15%, for Mn 27%, and for Si 7%.Also, an influence of these variations on values of residual deformation was confirmed; theoretical approach was proved.The change of deformation in such a case is 16% from observed interval.At the same time, it is possible to evaluate correlation coupling of Si/Fe/Mn with regard to the metallographic tests results.
From verification measurements and from overall behaviour of particular ingredients, it can be concluded that even though the iron is an impurity, it can be used to increase compression strength for loads in incomplete unload discharge.The mean deformation value of standard meltage presents value 0.313 mm with standard deviation 0.0163 and variance of residual deformation 2.69 − 4. Repeated tests with increased values of Fe and Mn contents showed decrease in mean deformation value to 0.2905 mm with standard deviation 0.0053 and variance of residual deformation 2.826 − 5.
Results demonstrated decrease in deformation on an average 7.6%.In such a case, it is suitable to apply interval of Fe content up to 0.95% of mass content.However, it is vital to proportionally increase amount of manganese too, in order to refine structures.If the growth of needle-shape structures is significant, there is a chance of local defects in form of slipping planes; that is, why refined structures are sought for.
Taking into account the variations of alloy content comparing to commercial alloys, it is possible to ensure alloying elements content increase during melting process by subsidizing the particular ingredients or by proper combination of recurrent material.

Figure 1 :
Figure 1: Values of chemical composition (Si/Fe/Mn) for the experiments.

Figure 2 :
Figure 2: Dependence courses of residual deformation on change of Fe and Mn content.

Figure 3 :
Figure 3: Dependence of permanent deformation on iron and manganese.
while they are compensated by increasing manganese content which causes refining of Al 3 FeSi phase and formation of intermetallic Al(FeMn)Si phases.These structures are more beneficial in terms of exposure to residual deformation.

Table 2 :
Technological order and casting parameters.
this force is reached, the value of the force is decreased to value  2 .Time of force  2 effect is usually 10 s.It holds true that

Table 4 :
Values of chemical compositions of particular cast samples and values of residual deformation.

Table 5 :
Obtained content values of chosen elements (Si/Fe/Mn) of particular samples of the casts and values of residual deformation after content correction of Fe-Mn.