Effect of Used Motor Oil and Bitumen as Additive on the Permeability and Mechanical Properties of Low Plastic Soil

Stability of permeable soils near large-scale water reservoirs for paved and unpaved road pavements is all too frequently compromised due to excessive seepage and the climatic conditions of that area. In this research, a multilevel research approach was adopted by conducting a comparative study of the microspectroscopy through Fourier transform infrared (FTIR) spectra to investigate the maximum absorbance correlation along with mechanical investigations (such as the compressive strength, modified proctor test, California bearing ratio test, and swell percentage test). +e native low plastic soil sample (CL) was blended with varying percentages of petroleum additives (bitumen and usedmotor oil) independently at 0%, 4%, 8%, 12%, 16%, and 20%. A comparison of results in the case of bitumen and used motor oil revealed that a decrease in Atterberg’s limits occurred accompanied by an increase of bitumen blending percentage, while used motor oil (UMO) increased the plastic limit. Maximum dry density (MDD) increases while optimum moisture content (OMC) decreases with the increase in bitumen.Usedmotor oil (UMO) initially (up to 4%) increased theMDDand subsequently decreased it. Investigative reports show that bitumen causes a decrease in swell percentage and increases California bearing ratio (CBR), whereas UMO causes a continuous increase in percentage swell and decrease in CBR. +e addition of bitumen in soil resulted in a decrease in the coefficient of permeability (k), while UMO has a significant result of up to 4%. Regarding the control sample, spectrum analysis through FTIR effectively supports the laboratory results as the intensity of peaks increases with the oil, and bitumen concentration reveals that oil and bitumen impart cementitious property to the soil. Moreover, this research work by experiment supported and strengthened the idea of soil pavement stabilization through bitumen, which gives antiwater stability, and facilitates low-cost construction by obtaining raw material on the spot. UMO adversely affects soil properties beyond 4% addition by weight.


Introduction
Considering the material quality, plus transport, economic, and political issues, engineers sometimes must use lowquality soil during road construction. ese low-quality soil materials are prone to show unattractive engineering behavior, such as low bearing capacity, susceptibility to differential settlement, high percentage swell, high moisture susceptibility, and poor permeability or seepage behavior.
is type of unwanted soil behavior is generally attributed to the nature of the soil and the fine-grained components present in the soil material. us, fine-grained soils such as silts and clays proved to be the most problematic materials [1]. Stabilizing such type of local material has millions of years of history [2].
is research attempted to improve certain desired geotechnical properties such as shear strength parameters (c-ϕ), permeability, CBR, and the compaction behavior of locally available soil of Peshawar, Pakistan, through used motor oil (UMO) and bitumen.
UMO, also known as waste crankcase oil or waste engine oil, is a lubricating oil used in the crankcase of an internal combustion engine [3].
is UMO is a mixture of 90% hydrocarbons and some other metals such as sulphur, chlorine, and magnesium for about 10%. It cannot be easily differentiated in chemical components other than to say that the major part is either aliphatic or aromatic hydrocarbons [4,5]. After use, it loses its original desired properties due to the breakdown of the additives during the combustion process. It is considered as the main source of environmental pollution if contaminated or burnt in the air because it contains a high level of heavy metals [6]. Pakistan produces 11246 tons of UMO annually. If most of the quantity does not recycle, it will pollute the environment because the waste recycling concept and circular economy is a positive approach to analyse economic, social, and environmental impacts [7]. In this present research, impacts of waste UMO have been studied to reuse in the stabilization of low plastic soil.  [11]. e behavior of motor oil on cohesion and CBR was studied by Nazir who stated that cohesion decreases while the angle of internal friction v increases with an increase in the tendency of motor oil in soil [12]. Bitumen, a by-product of crude petroleum, had also been used for soil stabilization for a very long time in the form of cutback, emulsified, and foamed bitumen [13]. Bitumen, when mixed with soil, helps in binding of the soil particles thereby increasing the cohesive strength of the soil [14]. Nicholson stated that bitumen and its products are mostly used in the soil as an additive, to provide water repulsion and/or adding cohesive strength to the soil [15]. Grouting with hot bitumen for the remedial measure was first introduced in the end of the 19 th century [16]. Dr. Erich Schonian is one of those scientists who wrote first about the behavior of hot bitumen's penetration in cracks and voids [17]. Bituminous substances are used to stabilize the soil, particularly for stabilizing subgrade, subbase, or even base course of road carrying higher traffic load [18]. is research paper expostulated upon hot bitumen in soil stabilization for the stability of road embankment.
Bitumen is a viscous elastic material mostly produced by the crude oil distillation process. It is frequently used in the asphalt pavement with some other civil works such as waterproofing, insulating material, tank material, and flooring material. Bitumen, if mixed in soil, will affect its geotechnical properties [19]. Nasr, in his research, investigates the behavior of strip footing on bitumen-contaminated sand (0-5%) by weight [20]. Michael studied contaminants in the soil stabilization process in soil stabilization using emulsified bitumen following bench-scale evaluation [21]. Vishal Kumar uses emulsified bitumen with a small amount of cement, for gravel road soil stabilization by considering CBR as a key factor in his experimental work [22].
Research on low plastic soil shows that the Phi "v" angle of internal friction increases while cohesion "C" decreases when the oil content increases [14]. Initially, soils had been stabilized by cement and lime, but this trend was changed by the innovation known as foamed bitumen stabilization [23]. Paul and Gnanendran suggest that soil stabilization as an aggregate and bitumen mixture could make a waterproof layer in sublayers of a road embankment [24]. Jones et al. follow indirect tensile stabilization for experimental work on cement-bitumen showing that soil achieves early strength, thereby allowing traffic in the curing stage [25].
Dr. Arora explained that bitumen are hydrocarbons, readily soluble in carbon disulphide (CS 2 ) and are obtained from refined petroleum products. It can be used as a cutback, emulsified, and even directly. Any inorganic soil can be stabilized through bitumen. It makes soil waterproof by plugging its voids and helps cohesive soil in lower moisture content and higher bearing capacity [26].
is research has the potential to minimize the failures of local road and highways in Pakistan by imparting strength and stability to the poor material used in the road construction and reduce the water seepage effect, both of which cause serious damage to the roads. is research will help to investigate the geotechnical properties and internal chemical spectroscopy (Atterberg's limits, compaction test, shear strength parameters, CBR, permeability, and FTIR) of low plastic soil with the hope of stabilization with UMO and bitumen. Stabilization of the native soil has been seriously felt acutely because of the premature failure of the local roads due to population growth, environmental factors, and minimum resources that collectively lead to huge economic and environmental losses to the country. Figure 1 shows work scheme followed in this research work from soil collection, stabilization with bitumen, and UMO to independent investigation for the expected change in geotechnical properties. Continuous and gentle mixing was applied for both the liquid additives to ensure proper mixing. At room temperature, the mixing of bitumen with soil is quite difficult, so bitumen was heated to a temperature of 140°C with constant stirring. en the dry soil was weighed, and the required % of bitumen was added and mixed at 110-115°C by weight at 4% increment rate.

Collection of Materials.
In this research, a soil sample was collected from the Warsak road area situated in the northeast of Peshawar, Pakistan. To ensure satisfactory results, the sample was collected at 1 meter depth below the ground surface in airtight bags to minimize the natural moisture loss. is soil sample then was placed in an oven for drying to measure the natural moistures contents at 105°C for a 24-hour time interval. After the sieve analysis test, sieve # 40 down material was stored for testing. Eighty (80) kilograms of two samples were separated for testing the stabilization by UMO and bitumen independently. UMO was collected from a local auto workshop. Bitumen (60 grade) was taken from the National Highway Authority (NHA) construction material laboratory. In this paper, authors restrict their research to 0%, 4%, 8%, 12%, 16%, and 20% for both UMO and bitumen as soil stabilization independently. e unified soil classification system' (USCS') soil classification Chart Method D-2487 found that testing soil is inorganic clay of low plasticity or lean clay (CL) in nature.

Preparation of Samples.
Oven-dried samples were used for each investigation, at a 4% increment of UMO and bitumen independently. Bitumen was added after heating it up to 140°C so that it can be poured and mixed easily without any hard lumps or air contents. Mixing was carefully done using spades until uniformity of color was perceived at 110-115°C. Mixing in the case of UMO was easy as oil is less viscous as compared to bitumen even if heated. e sticking property of bitumen with soil particles makes flocculants in the soil sample.

Laboratory Tests.
is research study was supported by various laboratory tests. e physical properties of both UMO and bitumen were investigated and listed in Table 1. For this purpose, unit mass density, viscosity, flash, and fire points were calculated. e bitumen penetrometer test (ASTM D-5), the flash and fire point test (ASTM D-92), the weight density test (ASTM D-4052), and kinematic viscosity tests for oil (ASTM D-445) and for bitumen (ASTM D-2170) were performed. Table 2 summarizes the corresponding physical and chemical properties of the local soil sample. Table 3 describes the overall performed testing summary on the soil sample stabilized with UMO and bitumen at a 4% increment rate. Tests such as the specific gravity test (ASTM D854-00), the particle size distribution test (ASTM D-422), Atterberg's limit test (ASTM D-4318), the modified proctor test (ASTM D-1557), the CBR test (ASTM D-1883-99), the direct shear test (ASTM D-3080), and the falling head permeability test (ASTM D-5084) were performed. Along with these basic geotechnical investigation tests, some microscopic analysis was also performed to visualize the basic internal changes due to the two types of additives.

Particle Size Distribution Test.
Oven-dried weighed sample is poured on the sieve column with largest opening at the top (2̋sieve) to lower sieves with smaller openings (#200 sieve) having a pan at the base. It was mechanically shaken for 12 minutes using mechanical shakers. After shaking, material received by each sieve was weighed with the digital balance having up to 0.1 gram sensitivity. Weight retained on every sieve is divided by total sample weight to get the percentage value of each sieve. To get a specific size range, each passing percentage value was analyzed and drawn as shown in Figure 2.

Compaction Test.
e oven-dried soil sample was investigated to check the effects of UMO and bitumen on MDD and OMC, as presented in Figures 3 and 4. After each soil sample was divided into different suitable quantities, water was added in the probable OMC range. After three or four trials, we obtained the required OMC value. While calculating MDD and OMC, Figures 3 and 4 show that MDD increases by increasing bitumen up to 20%. In the case of UMO, MDD increases up to 4% by 1.94%, and thereafter inversely decreases. Normally, dry density decreases when increasing the rate of used motor oil [10,27]. UMO shows this trend up to 4%. On further addition of used oil above 4%, the clusters of soil particles lose their cohesion due to a higher oil absorption rate causing reduction of soil unit    MDD, maximum dry density, C, cohesion, OMC, optimum moisture content, "ɸ," angle of internal friction, PL, plastic limit, CBR, California bearing ratio, "k," coefficient of permeability, LL, liquid limit, and PI, plasticity index.   On the other hand, bitumen as a stabilizer in soil shows an ascending approach and increases the MDD as high as 17.47%. Because bitumen holds the soil particles in clusters which increases the compressibility of soil, bitumen increases the soil density. Further, bitumen itself is cohesive in nature at low temperature; hence, it causes the particles of the soil to cohere, leading to an increase in the effective cohesion and maximum density. Figure 4 shows the OMC value, and it reveals that that OMC in bitumen-stabilized soil initially increases up to 4% and thereafter decreases. Bitumen increased OMC in the first 4% increment because of bunches formation in the soil, which increase the absorbing characteristic of soil. On further addition of UMO in soil, OMC continuously decreases for 39%. According to Al-Homoud et al., cutback bitumen decreases MDD and increases OMC up to 7% [28]. e declination in OMC is due to the repelling property of oil and bitumen. While UMO plays a part in decreasing the moisture content, UMO has itself low viscosity, which acts like water, so extra water than OMC will make the water film thicker, in consequence of which binding of particles does not take place that cause reduction in MDD [29]. Ojuri et al. studied the effect of UMO in soil stabilization and found that MDD and OMC decrease when increasing UMO contents [30]. Figure 5 shows the effect of UMO and the bitumen effect on soaked CBR. It is clear from the figure that the soaked CBR increased by increasing bitumen rate and decreased with increasing UMO. Zumrawi et al. worked on expansive soil stabilization with bitumen and fly ash. eir results are quite in line with our experimental results [30,31]. Andavan et al. illustrated that bitumen emulsion brings considerable improvement in the CBR value if properly mixed [32]. e similar result was found by carrying a number of tests on bitumen-stabilized expansive soil by Krishnaiah et al. [33]. On the other hand, as the swell percentage increases with used motor oil, it shows no resistance to standard piston penetration that gives zero CBR above 8% oil addition [27].

Swell Percentage Index Test.
Prior to the soaking CBR test, percentage swell was measured for various UMO and bitumen contents from 0% to 20% at a 4% increment interval rate. Figure 6 shows that heated bitumen causes a reduction in swell percentage rate, while UMO increases in the swell index. Singh et al. reported a significant increase in swell percentage in CL soil with UMO that ultimately increases differential settlement [27].
Bitumen imparts cohesive property to the soil and does not allow water to enter; hence, the swell index decreases [32]. Al-Homoud et al. found a significant reduction in the swell index by treating soil with bitumen [28]. On the other hand, the UMO makes a thin film around the soil individual particle or sum of particles and makes it even coarser. us, when soil is stabilized with UMO, moisture and oil contents stored in the void spaces developed internal stresses that cause free void spaces and leads to decrease in the cohesion and increase in the swell percentage.

Direct Shear Test.
e reduction in the shear strength of soil sample due to water can be minimized by introducing a waterproofing material such as bitumen in the soil sample. e best way to do this is by providing a layer coating of a waterproofing agent [34]. Figures 7 and 8 show the direct shear parameters that are cohesive (attractive force between soil particles) and the angle of internal friction v (resistance to shearing movement) based on Coulomb's shear strength theory. Results show that cohesion increases by increasing the rate of bitumen. e angle of internal fraction increases to a peak value for UMO concentration of 20%. While it gives the lowest value at 20% bitumen concentration as shown in Figure 8.
Conversely, cohesion decreases with increased rate of bitumen, which is obviously a sign of losing shear strength.
ere is less cohesion between the soil particles and the particles of oil; hence, UMO, the shear strength, decreases. Figure 8 shows the angle of internal friction "phi" that decreases in the case of bitumen, while it increases in the UMO case.

Atterberg's Limit Test.
A higher variation in the case of consistency limits is observed in both bitumen and used motor oil used as a soil stabilizer. Figure 9 shows that both bitumen and used motor oil decrease the rate of liquid limit. e decrease in the liquid limit (both oil and bitumen case) and plastic limit (bitumen case only) is because of the flocculation and agglomeration of the minerals present in the soil due to isomorphous substitution of cations at the surface of soil particles that resembles previous findings [35][36][37]. However, increases in the plastic limit with UMO might be due to the particle thickness due to the cation effect between soil particles and used oil ( Figure 10). Salih et al. found that UMO not only increases the PL but also LL and PI [38]. Rasheed et al. reported that Atterberg's value of overconsolidated clay decreases by increasing UMO contents [11]. LL and PL decrease by increasing UMO contents [19,27]. Figure 11 shows that the plasticity index of the soil decreases while increasing both Bitumen and UMO.

Permeability Test.
For safe operation of traffic and long life period, remote water and hinterland water which intercept the road embankment is an important element [39]. Figure 12 describes the coefficient of the permeability "k" test, conducted on the used motor oil and bituminous stabilized soil. It is observed that up to 8% UMO addition causes a decrease in the permeability effect of the local soil and beyond great increases because of the coarser effect of the soil. It is observed that the coefficient of permeability "k" fell by 5.83%, but on further addition of UMO, the permeability increases up to 4.5% as the soil sample coarsens with the addition of UMO as a soil stabilizer. e increasing rate of bitumen from 0% to 20% reduces the coefficient of permeability to go as low as 40% and thus minimizes the deleterious impact of percolated water. e reason is that the strong adhesive force of bitumen prevented the water from percolating through the voids by blocking the pathways. Venkatesh demonstrated that bitumen causes reduction in the permeability of soil [40]. Resistance to water or impermeability is mostly estimated by the value of water absorption or penetration. According to Fang, if bitumen in liquid form is mixed with soil up to 5-6%, irrespective of the type of soil, the absorption will be less than 2% [41].

FTIR Test.
Functional groups and molecular structures have different absorptions rate of infrared radiation. erefore, chemical compositions of control and modified soil samples were identified through the analysis of infrared absorption spectrum. Spectrometry was performed having a wavenumber 500-4000 cm −1 with 0.1 accuracy wavelength. FTIR tests were performed for the soil sample at which maximum dry density (strength) was obtained in the stabilization process. As seen in Figure 3, UMO gives maximum dry density at 4%, while bitumen does so at 20%.
rough FTIR tests, we compared the changing spectrum of 4% UMO stabilized soil sample and 20% bitumen-stabilized soil sample to that of control soil sample.
FTIR results for control soil and stabilized soil with UMO and bitumen were observed with tremendous changes in the peaks values. e difference in transmission or absorbance usually arises due to difference in concentration, as described by Lambert's law [42], which states that absorption depends on path length, concentration, and strength of absorbance band. In Figure 13, different peaks can be seen: a very broad peak at 3600 cm −1 shows that the OH group is present, a very small peak at 3000 cm −1 shows that the CH group is present at lowest intensity, the peak at 2500 cm −1 shows the SH group, the peak at 1500 cm −1 shows the N-O group, and a very sharp and intense peak at 1000 cm −1 represents C-O. So, it is clear from Figure 13 that natural soil contained compounds having C-O, NO, SH, and CH functional groups, but the concentration of S-H and N-O containing compounds are low. In Figure 13, the position of the peak is identical but the intensity of peaks varies, peaks at 3600 cm −1 become broad and increase in length, which shows that more absorbance occurs in this case due to increase in the concentration of compounds, while the intensity of peaks at 3000 cm −1 and 1500 cm −1 increases, which is an indication of the concentration of CH and NO containing compounds increment after addition of used oil into the soil. Similarly, in Figure 13, the intensity of peaks increase, and peaks at 3600 cm −1 , 3000 cm −1 , and 1500 cm −1 become more intense, which show the concentration of CH, and NO containing compounds increased after the addition of bitumen to the soil. e peaks at 2500 cm −1 and 1000 cm −1 did not show more increase in intensity, which confirm that when bitumen is added to soil, the amount of SH and C-O containing compounds are not increased. Figure 12 shows that oil and bitumen are organic compounds, and they increase the intensity of soil by leaving the hydrocarbons and sulphur content in the soil mix, which impart cementitious properties to the soil mix. UMO contains a lesser amount of hydrocarbons but more carbonyl groups from ketones or acids, while bitumen contains a greater number of hydrocarbons. A large number of hydrocarbons makes the soil hard and gives antiwater characteristic to the soil, decreases the ability to absorb water, and makes it waterproof. So far, from the FTIR result, it is confirmed that bituminous is more effective instead of waste oil in soil stabilization.

Conclusions
In this research work, the stabilizing effect of UMO and bitumen was studied by mixing it with a local soil sample to evaluate its geotechnical properties and specifying the application of that soil in embankment layers. Mechanical and chemical laboratory tests were performed, and graphical tools were used to reach the following conclusions: (1) e local roads and district highways condition can be improved by using the waste motor oil up to 4% effectively. is research work illustrates that 4% of UMO is the effective percentage for soil stabilization. Above 4%, it has an inverse effect on soil stabilization. (2) Bitumen as a stabilizer agent was proved to be more effective than UMO. Native soil can be stabilized up to 20% bitumen and used in the embankment layers. (3) CBR results show that bitumen is a better stabilizer to give strength to the soil as compared to UMO. (4) Swell percentage in the case of UMO shows a tremendous rise that reduces the soaked CBR to 0%.  Petroleum additives (%) Figure 12: Relationship between coefficient of permeability "k" with bitumen and UMO contents. 8 Advances in Materials Science and Engineering (5) Bitumen reduces the permeability of the soil more effectively as compared to motor oil. (6) e liquid limit tends to decrease with the addition of bitumen and UMO. Similarly, plasticity decreases with bitumen increasing. It initially increases and then decreases with UMO increasing. (7) e variation in graph peaks from the FTIR test indicates that bitumen impart more cementing characteristic than UMO because of more hydrocarbons, which give higher concentration.

Data Availability
e data used to support this study are available from the corresponding author upon request.

Conflicts of Interest
e authors declare that they have no conflicts of interest.

Authors' Contributions
Kamran Iqbal designed and executed the laboratory test plan, developed the methodology and empirical data, contributed to conceptualization of the research, and drafted the manuscript. Prof. Dr. Xu Chengshun provided guidance and suggestions to improve this study. Prof. Dr. Hassan Nazir analyzed the test results and checked the validity of the data. Prof. Dr. Muhammad Alam contributed to the review process, enhanced the methodology, and helped in technical writing. Asst. Prof. Dr. Asim Farooq contributed to conceptualization and presented the discussion along with illustrative examples in the manuscript. Prof. Dr. Edward J. Williams, being a native speaker and experienced writer, improved and tightened the English writing of the manuscript.