Exploration on Mechanical Behaviours of Hyacinth Fibre Particles Reinforced Polymer Matrix-Based Hybrid Composites for Electronic Applications

Department of Packaging, Yonsei University, Wonju-Si 26493, Gangwon-Do, Republic of Korea Department of Electronics and Communication Engineering, Jeppiaar Engineering College, Chennai 641407, Tamil Nadu, India Department of Mechanical Engineering, Bharath Institute of Higher Education and Research, Chennai 641407, Tamil Nadu, India Department of Electronics and Communication Engineering, Malla Reddy Engineering College, Secunderabad 500100, Telangana, India Department of Mechanical Engineering, Lincoln University College, Petaling Jaya, Selangor, Malaysia Department of Physiology, College of Medicine and King Khalid University Hospital, King Saud University, Medical City, P.O. Box-2925, Riyadh 11461, Saudi Arabia Zoology Department, College of Science King Saud University, Riyadh 11451, Saudi Arabia College of Environmental & Bioresource Sciences, Chonbuk National University, Iksan 570752, Republic of Korea Department of Mechanics, Seenu Atoll School, Hulhumeedhoo, Addu City 19060, Maldives


Introduction
Researchers have become particularly concerned with reducing their use of synthetic plastics because of environmental problems caused by plastic waste, not biodegradable. Synthetic mixing with biological (hybrid) materials and using fully biodegradable materials have been included in recent innovations. Bioplastics have been developing in the last ten years to replace synthetic plastics [1]. In most modern engineering fields, composites' most advanced physical features are more used against conventional metallic and alloying materials. Despite the high technical and physical features of the alloys, scientists are still trying to detect the new composite material due to its high strength to rigidity ratio, resistance to corrosion, and cost factors. Consistent positive deterministic factors have also been found in the enhanced polymer materials (FRPs) [2], such as low weight, high stiffness-to-weight ratios, good chemical resistance, and corrosion resistance. Generally polymer matrix composites are widely used in aerospace, automobile, and electronic applications. e manufacture of printed circuit boards (PCBs) reached an all-time high of $51 billion in 2009, thanks to the rising demand for electronic devices. However, the PCB industry's rapid growth encourages it to focus on circuit innovation rather than the environmental impact of the materials used. It is necessary to take a fresh approach to the creation of more environmentally friendly foundation materials. Most commercial PCB materials are glass fibre cloth reinforced epoxy composites because they provide a suitable combination of mechanical and electrical qualities. Figure 1 reveals the schematic diagram of printed circuit boards. Figure 2 reveals the types of fibre. Water hyacinth is a possible source of low-cost, nontoxic, and abundant natural fibre in Indonesia. e fibre content is comparable to that from other sources [3] and has approximately 40% cellulose content. e content of cellulose has a considerable impact on biocomposite properties. Like the previous study [4,5], the high content of cellulose leads to better mechanical and thermal properties. e commonly used natural fibres are microfibers of a diameter of 1-1000 μm (micron metre) or nanofibers of a diameter of 1-100 nanometres [6,7]. In previous research studies, microfibers from kenaf [8], water hyacinth [9,10], ramie [11,12], vacuous palm oil bunches [13], and microalgae's [14] were used. However, when dispersed in a stretch matrix, these microfibers usually form agglomerations or porosities, which produce low mechanical characteristics. Fibre must be nanosized to reduce agglomeration. Due to the high contact surface area, lower density, and good mechanical properties, smaller fibres result in better biocomposites [6,15,16]. Different cheap filler materials have been attempted in conjunction with these to reduce the cost to the total composite output to increase the strength of the FRPs. In most research publications [17,18], silica has played a role in this sequence of filler materials such as calcium carbonate. A novel approach was to produce tough epoxy resin made from rice husk with a particle size distribution of 40-80 nm [19]. is study will discuss the Charpy impact comportment of composites based on WH fibre. is research shows that the impact strength of polymer composites is based on WH fibre compounds. It is sufficiently competitive compared to other composites based on natural fibre [20]. ere was an increase in the tensile characteristics, impact strength, and fatigue life of reinforced glass-fiber composites by adding silica nanoparticles to the contents [21]. e incorporation of silica particles reveals a beneficial effect on the elasticity module, flexural modulus, and hardness of 2 wt% threshold value. However, silica's tensile and bending strength are reduced by a slightly higher bending strength than their tensile parts [22]. Increased interfacial bonding for Basalt fibre reinforced epoxy composite is added by adding SiO2 nanoparticles to the fibre surface [23]. Epoxy/silica/kenaf composites with different concentrations have been manufactured with silica particles. Untreated kenaf fibres with modified silica epoxy composites have increased their flexural and impact strength [24]. Aquatic plants like water hyacinth (Eichhornia crassipes) have a rapid growth rate, making them undesirable as garden plants. Water hyacinth's rapid growth has led to low levels of dissolved oxygen in the water, and it can spread across large areas. Water hyacinth is not all bad. It absorbs heavy metals and provides livestock feed, and its fibre can be used to make handicrafts [25,26]. It is found that for water hyacinth-polypropylene composites, except traction strength, all mechanical properties are improved adequately. In the course of this study, water hyacinth fibre was chosen as a refurbishment, and nanosilica particles were chosen as the filler materials for polylactic acid (PLA). e execution methodology of this experimental research work is shown in Figure 3.

Materials and Methods
Matrix material, one of the reinforcement materials which is used in this experimental work, i.e., polylactic acid (PLA) and nanosilica powder, was purchased from Covai Seenu and Company Ltd, Coimbatore, Tamil Nadu, India. e green unit Coimbatore, Tamil Nadu, India, provides further reinforcing material, i.e., water hyacinth fibres. e nanoparticles known as silicon dioxide, also known as nanosilicas, are the base of a large degree of biomedical research due to their stability, low toxicity, and ability to operate with multiple molecules and polymers. Nanoparticles of silicon dioxide appear in white powder form. e physical properties of these nanoparticles are provided in the table below. Table 1 shows the various basic physical, chemical, and thermal properties of nanoparticles with silicon dioxide. P1 consists of pure PLA particulates of 100 wt percent. P2 is made of 80 wt% pure PLA particles, 0 wt% silica powder, and 20 wt% water hyacinth fibre. P3 contains 80 percent wt of pure PLA particles and 20 percent wt of powder of silica and 0 percent wt of powder of water hyacinth. P4 consists of 80% by weight of PLA pure, 2% by weight of silicon powder, and 18% by weight of hyacinth powder. P5 consists of pure PLA particles of 80% wt, silicone powder of 4% wt, and water hyacinth powder of 16% wt. P6 includes 80% wt of pure PLA, 60% wt of silica powder, and 14% wt of powder of hyacinth water. P7 comprises 80 wt% of the pure part of PLA, eight wt % of the silica, and 128 wt% of the water powder hyacinth. e particle size of silica obtained at first does not match the size required. To comply with the requirement, silica powder was processed in a ball mill. e measured nanosilica particle diameter in the range of 75 to 100 nm was used as a reinforcement content. Before feeding these mixtures into the double screw extruder machine, PLA particles were heated above the melting temperature. Following heating, the PLA particles were transformed into a liquid stage. e weight percent of enhancement materials, i.e., nanosilica powder and short water hyacinth fibres, was added to liquid state PLA. After 45 minutes of adding filler and refill material to the fluid state PLA matrix, the entire mixture was thoroughly misled in one blender. e composite mix of the 2 Advances in Materials Science and Engineering array and the reinforcing and the filler materials of smaller pieces (3 cm to 5 cm) in length was prepared by a double screw extruder. Figure 4 reveals the double screw extrusion process arrangement. e composition of the rectangular bars from wellprepared, hybrid-based composite parts was prepared by a hydraulic injection moulding machine. e combined water hyacinth fibre, PLA, and silica particles had allowed the compression moulding machine to heat up to 100°C at a specific hydraulic pressure for up to thirty minutes. e required composite plates had been collected and cooled at room temperature after the processing time of 30 minutes. Figure 5 reveals the advantages of injection moulding. e composite plates were transferred after the cooling process to the water jet machining process, and the necessary composite components were separated from the composite compound according to ASTM standards. For the remaining compositions, the same process was repeated. Figure 6 reveals the tensile test sample. Tensile, flexural, and impact tests for establishing the mechanical properties of composites were permitted for the well-prepared composite specimens. e tensile test (ASTMD638), compression test (ASTM-D695 M), and flexural test (ASTMD790-10) of the composites at a load rating of 1 mm/min were used with a computerised 400 kN universal testing machine. Figure 7 reveals the universal testing machine. A Charpy impact test was also performed on the composite impact test specimens in the Impact Testing machine as defined by the ASTM D6110-97 standards. Figure 8 reveals the Impact Testing machine. A water absorption test was also performed in composite specimens of the water absorption test, according to the ASTM D5229 pure water standards. e tensile, compressive, bending, impact, toughness, and water absorption tests were given in different sample dimensions as given in Table 2.
e results of mechanical and water absorption tests, such as ultimate tensile strength, flexural strength, flexural strength, impact strength, and water absorption percentage, have been shown in the results and the discussions as a graphical colour plot.  Advances in Materials Science and Engineering 3

Results and Discussions
3.1. Tensile Test. Figure 9 illustrates the tensile strength and tensile behaviour of the water hyacinth reinforced PLA-filled particulate composites containing different ratios of loaded nanosilica and water hyacinth. Without any water hyacinth fibre or nanosilicone (P1 composite), the pure PLA composite showed a tensile strength of 31.45 MPa and the corresponding tensile strain rate was 0.34 percent. During the test, both ends were very strongly fixed on the grips of the universal test machine and the fracture test was performed with the gradual load at the speed of the crosshead to about 1 mm/min. e PLA matrix with 20 wt% nanosilica and 0 wt % water-enhanced fibre composite (P2 composites) had a tensile strength value of 32.95 MPa, and the respective stress rate was 0.35%. With a tensile strength value of 33.68 MPa and a tensile pressure rate of 0.36 percent, the PLA matrix with 0 wt percent nanosilica particles and 20 wt percent hyacinth water fibre enhanced composites (P3 composites). After the test, the specimen was broken down at specimen length, and the fibre-pull-out fracture initially burns the load by fibre when it exceeds its load capacity, when the load was transferred to the matrix with the loss of interfacial strength from fibre to the matrix, thus losing the power interface between the fibre and the matrix. e addition of composites of 2 percent nanosilica particles (P4 composites) showed the tensile strength of 34.93 MPa; the tensile strength of the P1, P2, and P3 composites is almost 3.7, 6.09, and 11.06 percent higher. Its corresponding pressure rate was 0.32 percent higher than P1, P2, and P3 composites. e mixed specimens (P5 composites) of 4% nanosilica particles had shown a tensile stress value of 35.67 MPa, nearly 2.11% higher than the mixed specimens of 2% nanosilica (P4 composites). e tensile strength of 6% nanosilica mixed specimens (P6 composites) showed the highest tensile stress rate as 36.93 MPa; the value was nearly 3.5% higher than the 4% nanosilica mixed specimens (P5 composites), and the tensile pressure rate was 0.37%. e tensile strength of the 8% mixed specimens of nanosilica particles (P7 composites) has shown the stress value as 34.61 MPa; this value was almost 6.28% less than the 6% mixed particulate matter (P6 composites) for nanosilica, and the corresponding tensile strain rate was 0.35%. In addition, the 6% nanosilica particles, which had 14% water hyacinth in PLA composite samples, showed the highest pressure value for a tensile of 36.93 MPa, which was almost 12.07 higher than their corresponding strain rate which was respected to 0.39%. Similarly, given the tensile stress value of 4%, the jacinth was as high as the other five combinations, with the exception of P6 composite specimens. It is much higher than the other five. e combined or mixed cumulative tensile strength was also 36.30 MPa of 4% nanosilica particles and 6% water hyacinths higher. e respective strain rate was 0.38%, which was equally higher than all mixed proportions. Compared to the pure PLA composites, this experiment demonstrates the greater strength of the particulate composite. e stress rate also decreases in the case of the particulate addition to the matrix material. e stiffness increases so that the value of the tensile strength rises substantially. Figure 10 shows the flexural strength conduct of water hyacinth fibre reinforced PLA filling composites of nanosilica particles and water fibre loaded. First, the specimen was placed over two supports in the standard fixture    en, using the universal test machine with standard crosshead speed, the centre of the specimen is permitted with the gradual load. With the aid of a digital device and a UTM device, the fracture load was noted.

Flexural Test.
As mentioned in the tensile strength analysis, the flexural strain value of 27.12 MPa for PLA pure composites (P1 composite) with a strain rate of 4.9 percent was given in bending strength. With a bending value of 26 Figure 11. e results demonstrated an additional 160.39, 46.21, 64.95, 24.77, and 10.88 percent in composites P2, P3, P4, and P5, respectively, and 6 wt percent of nanosilica particles in the composite P6. is is due to the fillers used by silica particles, which strengthened the PLA matrix less than 56 nm in the particle stage. e microparticle fillers (silica particles) helped increase the surface-to-volume ratio by providing a larger surface area. us, the stress transfer between the filler matrix was increased. In addition, the fillers showed good interfacial adhesion in the polymer matrix, which helped to increase stress transfer between the filler and the matrix.

Impact Test. e impact strength of composites examined by the Charpy impact test is shown in
Composite P6, compared with P1 composite ES, had a higher impact strength due to the presence of water hyacinth fibre and nanosilica particles that allowed greater power absorption in the event of an impact. Made of water hyacinth and nano silica are composites P4, P5, P6, and P7. e results enhance the impact strength of PLA from P4 to P6 composites. Compared to all other composites, pure PLA (P1 composites) also provided a small impact strength (P2 to P7). e highest impact strength of composite P6 was 9.27 kJ/m2, improving by 160.4% compared to pure PLA, because the water hyacinth and nanosilica continuous fibre provide additional energy absorption at impact. However, with the performance of the composite P2, impact to composites P3 to P7 was the lowest. e lack of water hyacinth fibre probably resulted. e result agreed with the finding from earlier studies of the subsequently reduced interaction among the fibres and the matrix by the formation of a crack and byproducts resulting from the reaction of nanosilica particles. Finally, because of the absence of reinforcement and filling materials in the PLA matrix, the impact properties of the composite material were reduced.

Rockwell Hardness.
Hardness is a feature that measures the surface indentation and abrasion resistance of the material. Hardness is also a critical parameter that indicates the composite's durability and life span. e hardness of the various composition composites and PLA composite specimens is shown in Figure 12. All the composites produced were highly harder than the clean epoxy. is increased hardness was associated with the high rigidity and hardness of the distended stage parts, which can be reinforced due to their load carrying capacity. e results indicate that adding 6 wt% of nanosilica particles in the P6 composite improves hardness by 55.88, 43.24, 51.43, 17.78, and 8.16 percent, in P1, P2, P3, P4, and P5.  Advances in Materials Science and Engineering e plot observed that P6 composites have the highest hardness, 56% better than pure PLA composites (P1 composites). However, the hardness of a composite depends on the homogenous distribution of the reinforced particles and fibre into the matrix. Due to the increasing hardness of this composite, the silica content and water hyacinth fibres are increased by 6 wt%, but the loading of the particles increases slightly and gradually. e increase of the hardness value at lower particles charging can be attributed to the homogenous distribution of silica particles and water hyacinth fibre within the matrix, with a depreciation of the vacuums and a stronger interfacial adhesion between the matrix and the particles. It is worth noting that while silica has reduced the composition's tensile strength, it has increased the PLA matrix's hardness. e loading conditions are different. e low interfacial adhesion between both the tensile cargo conditions tends to cause the silica particles to debond from the PLA matrix. In the case of a hardness test, the composite is loaded vertically and downwards.
is causes silica particles to be firmly pressed into the matrix. e pressure action causes a smooth transfer, although their interfacial adhesion has been poor, of the load from the matrix to the silica and water hyacinth. All of these lead to better composite hardness.

Water Absorption
Properties. e durability of the water hyacinth fibre reinforced nanosilica particles filled PLA matrix biocomposites can be predicted through the water absorption tests. e weight of each specimen was measured before this test. Weight measured composite specimens are then immersed in normal water for 72 hours (three days). After this duration, the immersed specimens are taken away from the water container for the weight measuring purpose. Based on the weight of the specimen after the test, the percentage of water absorption has been calculated. e water absorption test results are illustrated in Figure 13 for all composite specimens.  e minimum weight gained by the composite specimens after the water absorption test was found in 6% nanosilica particles filled composites (P6 composites). e percentage of the water absorption has found a very lesser amount at 6% nanosilica particles weight percentage added to the composites. e maximum percentage of water absorption (4.89%) has been found at composites without the nanosilica particles and water hyacinth particles. e water absorption of the specimens has significantly reduced to increasing weight percentages of the nanosilica particles, which are added to the water hyacinth fibre PLA composites. Superior water absorption behaviour, due to removal of lignin, cellulose, and hemicellulose in the water hyacinth fibre, has been found in 14 wt% water hyacinth fibre enhanced composite specimens, and spaces may be made in the water hyacinth fibre molecules. e addition of limited filler content (6 wt percent), i.e., nanosilica particles in water hyacinth fibre voids, has been filled in and enhances the good quantity of water interface between water hyacinth fluid and PLA matrix.

Conclusions
Mechanical tests were carried out on the water hyacinth fibre which enhanced PLA matrix composites, nanosilica particles, and water hyacinth particulate matter. After the standard tests, the following observations are noted.
(1) e water hyacinth fibre enhanced epoxy composite is successfully produced by loading nanosilica particles with various proportions of hyacinth fibre particles.
(2) Tests such as tensile, bending, impact, hardness, and water absorption are conducted in different proportions. Based on tests, nanosilica particles and water hyacinth particles increase the specimens strengths considerably. (3) e combinations of the two particles (6% nanosilica and 14% water hyacinth) nevertheless demonstrated their extraordinary efficiency in every test. (4) It is suggested that both water hyacinth fibre and nanosilica particles reinforced PLA hybrid composites can be used as an alternate material for materials reinforced with natural fibre. (5) Moreover, the most valuable aspect of this research is that water hyacinth, which is considered a waste and environmental pollutant, makes products that may replace high-cost glass fibre-based composites and help grow a healthier aquatic environment for the fishes and other aquatic plants.

Data Availability
e data used to support the findings of this study are included within the article.

Conflicts of Interest
e authors declare that there are no conflicts of interest regarding the publication of this article.  Advances in Materials Science and Engineering 9