Mechanical and Thermal Properties of RCB Masonry Containing Three Rows of Holes

In order to promote and apply the structures of the recycled concrete block (RCB) masonry, the thermal and mechanical properties of the recycled concrete specimens were tested in this study. The RCB can meet load-bearing and seismic requirements and was prepared through experiments. Concurrently, the mechanical property experiment was conducted on the RCB masonry, and then its failure process and mode were discussed. In addition, a thermal property test was completed on the RCB wall, and the difference in the thermal properties of single-row hole, three-row hole, and solid blocks was analyzed by theoretical calculations. The results indicated that the mechanical properties of the RCB masonry were basically the same as those of the natural concrete block masonry, and they have good compressive stability. The calculation formulas of the compressive and shear strengths of the natural concrete block masonry are applicable to the RCB masonry. The RCB masonry containing three rows of holes owns more outstanding thermal property than natural concrete block masonry and satisfies the requirements for related codes.


Introduction
In recent years, the rapid urbanization development has resulted in a sharp increase in producing the construction and demolition wastes domestically [1]. Concurrently, China is a country with frequent earthquakes, which has resulted in numerous building wastes in a short time [2]. If construction waste is not dealt with appropriately, it leads to not only significant land occupation but also environmental pollution [3].
Construction waste disposal is a problem that has been of extensive concern globally, and it affects the sustainable development of the resources as well as the environment.
e United States of America and the developed European countries have been studying this problem relatively early. According to a national survey conducted by the US Federal Highway Administration in 2004, 41 of the 50 states use recycled aggregates produced from construction waste [4]. According to the statistics from the Netherlands, the recycling rate of construction waste reached 90% in 2000. e demolished concrete in the UK is approximately 28 million tons per year, of which 14.8 million tons are recycled, and the recycling rate is approximately 52% [5]. Recycled concrete aggregate is a kind of aggregate produced by the construction waste, which overcomes the difficulties introduced by construction waste, thus realizing the recycling of construction waste resources. is measure protects natural resources and the human living environment and has good social and environmental benefits.
Over the past decade, researchers from various countries have conducted numerous studies on recycled concrete [6][7][8][9][10]. Poon et al. [11] showed the characteristics of the concrete prepared by the recycled aggregates.
en they reported that, as the recycled aggregate content increased, the concrete's strength decreased, which correspondingly reduced the resistance to the concrete's chloride ion penetration. Xiao et al. [12] investigated the relationship among the compressive strength, density, and splitting tensile strength, as well as flexural strength of the recycled concrete, and it was determined that there might be a significant difference in the mechanical properties between the recycled and normal concretes. Currently, most researches have proved that recycled aggregates tend to degrade the mechanical properties of recycled concrete [13] owing to their characteristics of low apparent density, high water absorption, and large crushing index [14]. However, by reasonably designing or adjusting the mixing ratio, the recycled concrete's performance could be made to satisfy the specific requirements.
us, the recycled concrete can be used in the construction industry to some extent [15]. Rodriguez et al. [16] applied recycled concrete to nonstructural concrete elements and tested their mechanical properties, carbonization resistance, and chloride ingress through experiments.
e results show that the use of recycled aggregate can reduce the performance of concrete. Still, the addition of fly ash and slag can significantly improve most of the performance of recycled concrete elements, including long-term property. It can be found that recycled concrete is mainly used for roadbed and nonload-bearing structural member materials [17][18][19][20]. To expand the application scope of recycled concrete, it should be used in load-bearing structural components, such as structural walls. It is well known that, except for realizing a specific mechanical strength, a structural wall should own outstanding thermal insulation property [21].
In this paper, the mechanical property of RCB was studied. e RCB that meets the load-bearing requirement was prepared by experiment and used in load-bearing structural walls. e compressive and shear strength of the RCB containing three rows of holes and masonry was tested and theoretically analyzed, and the effect factors and failure modes of the strength of RCB were discussed. Considering that the RCB wall should not only meet the load-bearing requirements but also have good thermal insulation performance, the thermal resistance of the RCB wall was tested and calculated theoretically. ese studies will promote the application of RCB masonry in practical engineering.

Cement.
In order to investigate the effect of cement strength on the strength of RCB, PC32.5 and PC42.5 composite Portland cement that were produced by China Shaanxi Qinling Cement Plant were employed in this study. e physical and mechanical properties of cement are shown in Table 1.

Aggregates.
e recycled concrete was originated from the construction waste, which was removed from an abandoned factory locally, and subsequently, it was squashed, swashed, and then screened to prepare recycled concrete aggregates in a waste recycling plant. e recycled concrete aggregates were classified as recycled fine and coarse aggregates, whose particle size is 0-5 mm as well as 5-10 mm, respectively. Figure 1 shows the components of the recycled concrete aggregates. In Figure 1, the aggregates with a wrapping mortar percentage of less than 10% were undisturbed stones, and those with 10%-100% are secondary aggregates. e mortar lump comprised a pure mortar block as well as small stones, which were completely wrapped with the mortar, and other components including tiles, glass, and wood crumbs. e natural aggregates included pebbles as well as river sands. e particle sizes of the pebbles ranged from 5 mm to 10 mm, and the fineness modulus of the natural sand was 2.18. e primary materials' physical properties were tested, as shown in Table 2. It was found that, compared with the apparent and bulk densities of the natural aggregates, those of the recycled concrete aggregates were significantly lower. erefore, it could be concluded that the recycled concrete aggregates' water absorption was significantly greater than that of the natural aggregates, and that of the recycled fine aggregates was 3.1 times larger than that of the recycled coarse aggregates.

Specimens and Mixture Proportions.
A type of RCB with a porosity of 36% was developed, whose length is 390 mm, width is 240 mm, and height is 190 mm, as shown in Figure 2. To best utilize the recycled concrete aggregates, the recycled coarse aggregate's replacement ratio was 100%. Based on previous research [22], in this test, the unit water consumption as well as the water-cement ratio was set as 150 kg/m 3 and 0.4, respectively. e sand rate, the replacement rate of recycled fine aggregate, and the strength grading of cement were changed. Among them, the recycled fine aggregates replacement ratio was 0%, 40%, and 100%, respectively. e sand rate was 45%, 50%, and 55%, and the strength grading of cement was PC32.5 and PC42.5, respectively. e details of the concrete mixtures as well as their mixture proportions are summarized in Table 3. ere were six groups in the test and five blocks in each group.

Experimental Procedures.
A material machine (TYE-2000E) was used to test an RCB, as shown in Figure 3. e compressive strength test was carried out in accordance with "Test methods for the concrete block and brick" (GB/T 4111-2013) [23], and the load was applied using a force-controlled load actuator at a rate of 10 kN/s. In the early loading stage, as the load increased, the reading from the material testing machine steadily increased, and the surface of the RCB did not change. When the load was approximately 70% of the ultimate load of the RCB, some fine cracks appeared on its surface, and the reading from the material testing machine increased slowly. As the load further increased, the number of cracks on the surface of the RCB increased. However, when there was an ultimate load, the deformation of the RCB increased rapidly, the reading of the material testing machine decreased, and the RCB was destroyed. Figure 4 shows the specimens' failure process.     Advances in Materials Science and Engineering

Experimental Results and Discussion.
During the test process, the maximum load, P, of each RCB was recorded. Later, the compressive strength was calculated. en the average compressive strength of five blocks was determined for each mixture proportion. Table 4 shows the test results. Figures 5 and 6 show the effects of the sand and replacement ratios between the recycled fine aggregates and the compressive strength of the RCB, respectively. It was inferred that, for the recycled fine aggregates' same sand or replacement ratio, the compressive strength of the blocks with cement PC 42.5 was higher than that of the RCB with cement PC 32.5. It was also found that, with the increase of the sand ratio as well as the decrease of the recycled fine aggregates' replacement rate, the compressive strength of the RCB increased. e effects of the recycled fine aggregates' replacement ratio on the recycled concrete blocks' compressive strength were mainly focused on in this study. e brick strength grade in the masonry structure was represented by MU, and MU5 means that the average compressive strength of the block is not less than 5 MPa [23].
For groups R1 and R4, the recycled aggregates were adopted to replace the entire coarse and fine aggregates, and it could be observed that the compressive strength of the RCB, which were prepared by using PC32.5 and PC42.5 cement, both reached the strength level of MU5.0, which satisfied the minimum requirements of the loadbearing block in the Chinese standard (the strength grade of load-bearing blocks is not less than MU5.0) [24]. e allowable compressive stress of hollow load-bearing block is 4.83 MPa in "Building Code Requirements and Specification for Masonry Structures" (ACI 530/530.1-13) of the United States [25], which is similar to the Chinese Code.  For groups R2 and R5, the recycled fine aggregate's replacement ratio was 40%. en the blocks' compressive strength grew to the strength level of MU7.5, which satisfied the seismic requirements (the strength grade of the block used for the seismic structure is not less than MU7.5) [26].
However, the ACI code does not make requirements for the strength of hollow blocks in terms of seismic design.
For groups R3 and R6, the coarse aggregates were the recycled coarse aggregates, and the fine aggregates were only the natural fine aggregates. e strength grades of the blocks prepared by PC32.5 and PC42.5 cement reach those of MU7.5 and MU10.0, respectively. Figure 7 shows the strength variation coefficient of the RCB. It was found that, as the recycled fine aggregates' replacement ratio increased, the variation coefficient also increased. When their replacement ratio reached 0, the variation coefficient was 4%-6%, and when the former was 100%, the variation coefficient increased to 14%-18%. is indicated that the recycled fine aggregates would increase the difficulty of the quality control of the RCB.

Specimens and Mixture Proportions.
As indicated by the experimental results of the recycled concrete blocks, the mixture proportions of groups R5 and R6 were chosen to produce two types of recycled concrete blocks of strength grades MU7.5 and MU10.0. e mortar strength had the following grades, including M5, M7.5, M10, and M15 (according to Chinese Code "standard for test method of basic properties of construction mortar" (JGJ/T70-2009), M5 means that the average compressive strength of cube mortar blocks of side 70.7 mm is not less than 5 MPa). Table 5 shows the six groups of recycled concrete block masonries that were produced. ere were three pieces of masonry in each group. e size of each RCB masonry is shown in Figure 8, and the mortar's thickness is 10 mm.

Experimental Procedures.
A YE-200A machine was used to test the RCB masonries' compressive and shear strengths, which are shown in Figures 9 and 10, respectively. e specimens underwent three stages during the compression test. e first stage was from the start of the loading to the appearance of the initial crack. During this stage, with the increase in the load, the readings of the mechanical dial indicator for measuring the horizontal and longitudinal deformations of the masonry increased smoothly. When the first fine crack appeared on the surface of the specimen, the initial load was recorded. e second stage was from the initial crack load to the ultimate load. During this stage, there were fine vertical cracks first appearing on the lateral surface along the masonry's width direction, and subsequently with the increase in the load,  Advances in Materials Science and Engineering vertical or oblique ones appeared on the lateral surface along the length direction. en the cracks gradually propagated and penetrated. e readings from the mechanical dial indicator showed a rapid increase. e third stage was from the ultimate load to the failure of the masonry. Penetrating cracks were formed, and the specimen broke into several small block columns. Finally, the specimen was crushed and failed. e shear strength tests were carried out on the RCB masonries under constant-speed continuous loading, and the loading time was approximately 1-3 min. Each specimen presented no abnormal phenomena from the beginning of the loading to the failure, which is a typical brittle failure. e shear failure of the masonries occurred at the mortar surface, and the RCB remained intact. It can be considered that the mortar strength played a major role in the RCB masonries' shear strength and that the single shear failure of the masonries was more than double the shear failure. As indicated by the Standard for "Test Method of Basic Mechanical Properties of Masonry" (GB/T50129-2011) [27], it can be known that the RCB masonries' compressive and shear strengths were calculated, as shown in Table 6.

Experimental Results and Discussion.
As indicated by the Standard for "Test Method of Basic Mechanical Properties of Masonry" (GB/T50129-2011) [27], it can be known that the RCB masonries' compressive and shear strengths were calculated, as shown in Table 6. Figure 11 shows the effect of the ultimate load on the cracking load of the RCB masonry. A significantly linear relationship between the ultimate load and cracking load was observed, with the ratio fluctuating around 0.69, and the cracking load increases with the increase in the ultimate load. is trend is basically the same as that for the natural aggregate concrete, indicating that the recycled concrete's compressive performance has good stability and can be widely used in practical engineering.
As it was difficult to measure the descent section of the RCB masonries' stress-strain curves on the YE-200A machine, so only the ascending sections were discussed. Because the slope of each stress-strain curve represents the elastic modulus; therefore, the larger the masonry's elastic modulus was, the higher its compressive strength would be. It can be seen from Figure 12 that regardless of group A or group B with the increase of the mortar strength, the masonries' compressive strength would also increase. However, their deformation decreases. Figure 13 shows the effect of RCB strength and mortar strength on the RCB masonry strength. Figure 13 shows that the strength of the RCB masonry was positively correlated with mortar strength and RCB strength. For the compressive strength of RCB masonry, the strength of the block increased by 39%, and the strength of masonry can be increased by 48%. e strength of mortar increased by 50%, and the strength of the block only increases by 8.3%, which indicates that the RCB strength is the main factor affecting the compressive strength of the RCB. However, the effect of mortar strength on the shear strength of RCB masonry was reversed. e strength of the block increased by 39%, and the strength of RCB masonry can be increased by 9.1%. e strength of mortar strength only increased by 23%, and the strength of the RCB increases by 10.7%, which shows that the mortar strength is the main factor affecting the RCB masonry shear strength. e results may be because connection between the RCB is done by mortar. e change rate in the RCB masonry strength can be described by the slope of the fitted line. It can be observed      [24], the compressive and shear strengths are expressed as follows: where f m represents the calculated masonry compressive strength, f v,m represents the calculated masonry shear strength, f 1 denotes the blocks' average compressive strength, and f 2 represents the mortars' average compressive strength, while α and k 1 are the influence values of the block appearance, dimension, and masonry modus of masonry blocks with different types, and k 2 is the mortar's influence       Advances in Materials Science and Engineering coefficient on the masonry's compressive strength. Besides, k 5 represents the coefficient related to the masonry type. For concrete blocks, α � 0.9, k 1 � 0.46, and k 5 � 0.069. When f 2 ≠ 0, k 2 � 1.0. Considering the discreteness of the RCB strength, it increased the reliability of the parameter values in the code. e results that were calculated by using equations (1) and (2) are shown in Table 7.
As shown in the test results, it could be seen that the RCB masonries' compressive and shear strengths were higher than the results calculated by the equation. e ratio of the test and calculated results was concentrated between 1.1 and 1.2, which indicates that the natural aggregate concrete block masonries' compressive and shear strength formulas can be adapted to obtain the RCB masonries' mechanical strength.
e design of a masonry structure requires to satisfy the material strength's standard as well as the design values. A normal distribution should be adopted in the material strength's probability distribution, and the probability distribution of 0.05 quantile can determine its standard value. As the masonry strength follows a normal distribution [28], f k , the compressive strength's standard value, can be expressed by the following formula: where f m is the calculated masonry compressive strength, σ f is the compressive strength's standard deviation, and δ f is the strength variation coefficient. As shown in Table 5, the average variation coefficients of the masonries in groups A and B are 0.1 and 0.21, respectively. Considering structural safety, the coefficient variation of masonry's compressive strength is 0.21. f, the strength used in the design of masonry structural components in accordance with the final bearing state, is called the masonries' strength design value. When the influence of the factors is considered, such as the variation in the geometric parameters and uncertainty of the calculation mode on the reliability, f can be expressed by the following formula: where c f is the partial coefficient of the material property of the masonry structure. In general, it should be considered based on the construction quality level as B, and c f � 1.6 [24]. e RCB required high water absorption and had porous recycled aggregates; therefore, their construction quality was difficult to control. If a reliable strength design wants to be guaranteed, c f can be increased to 1.7. e standard and design values for the calculation formulas of the shear strength of the RCB masonry were the same as equations (3) and (4), and the variation coefficient of the shear strength was chosen as 0.19. Table 8 summarizes the standard as well as the design values of the recycled concrete block masonries' compressive and shear strengths.

Specimens.
In general, the walls were built by using the RCB, and the insulation performance of the walls is of extreme importance for engineering applications. By adding a heat preservation material to masonry to form a composite wall for energy conservation and heat preservation, we can satisfy the relevant indexes of the "Design Standard for Energy Efficiency of Public Buildings" (GB50189-2015) [29], thus realizing a broad application prospect. In this study, two walls were built using the designed blocks mentioned in Section 4.1: one (W1) with an extruded PS foam insulation board (EPS) and the other (W2) without EPS. e sizes of the specimens are shown in Figure 14.

Experimental Procedures.
e test instrument was a JW-I heat transfer coefficient tester of the RCB walls and a JW-II building thermal temperature and heat flow automatic test system containing hot and cold boxes, a specimen shelf, and temperature sensors. e tests of two specimens were conducted with reference to a Chinese standard (GB/T 10295-2008) [30], which is shown in Figure 15. Each specimen was placed for a month until the RCB wall was dry. e hot and cold boxes were attached to the specimen frame. e instrument was started, and the test was conducted continuously for eight hours.

Experimental Results and Discussion.
e test yielded that the surface temperature of the hot chamber wall and the cold chamber wall was 26.4°C and −1.8°C, respectively. W1 had a heat transfer coefficient of 1.41 W/(m 2 ·K) as well as a thermal resistance of 0.559 m 2 ·K/W. Meanwhile, W2 had a heat transfer coefficient of 1.62 W/(m 2 ·K) and thermal resistance of 0.467 m 2 ·K/W.
It can be found that the thermal resistance of the concrete block containing three rows of holes is higher than that of the concrete block with a single-row hole after a comparison based on the "Technical Specification for Concrete Small-sized Hollow Block Masonry Buildings" (JGJ/T14-2011) [31], as summarized in Table 9. e thermal insulation of the RCB is 52.3% higher than that of the natural concrete block containing three rows of holes. e thermal resistance increases by 0.092 m 2 ·K/W after adding EPS to the recycled concrete block, making it 20% higher than that previously reported, and the thermal insulation become more significant. e calculation formula in the " ermal Design Code for Civil Building" (GB50176-2016) [32] cannot be directly used because the recycled concrete and holes in the hollow block are not merely superimposed. us, the thermal resistance of the hollow blocks was calculated by the formula when there is a combination wall [23]. en a composite wall's average thermal resistance can be calculated by the following formula: Advances in Materials Science and Engineering

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Advances in Materials Science and Engineering where R represents the average thermal resistance; F 0 represents the complete heat transfer area which is vertical to the heat flow direction. Meanwhile, F 1 , F 2 , . . ., F n are the heat transfer areas that are parallel to the heat flow direction, while R 0,1 , R 0,2 , . . ., R 0,n are the heat transfer resistance at the heat transfer surface; R i represents the inner surface's heat transfer resistance, and it is taken as 0.11 m 2 ·K/W; R e represents the outer surface's heat transfer resistance, and it is taken as 0.04 m 2 ·K/W. Finally, φ denotes a correction coefficient. It is shown in Figure 16 that the total heat transfer surface which is vertical to the heat flow direction is divided into 13 heat transfer surfaces, of which 12 and 13 are mortars of 5 mm on the block's left and right sides. e thermal resistance of RCB containing three rows of holes was calculated by formula (5) as 0.63 m 2 ·K/W, which was slightly higher than the experimental results. e results due to the holes of the three-row hole block had chamfers, and the chamfers are not converted into square holes of the same area in the simplified calculation, which makes the air area of the holes extremely large.
In the same calculation method, the calculated thermal resistance of the RCB containing a single row of holes (porosity is 48%) with the same thickness is 0.59 m 2 ·K/W. It can be found that, though the RCB containing three rows of holes (porosity is 36%) have less porosity, they have a higher thermal resistance. is is because the staggered-array holes appeared in the blocks, which expands the heat conduction path. Meanwhile, it can be compared by calculation that the thermal resistance of recycled concrete solid brick is much smaller than that of hollow block, which is only 0.23 m 2 ·K/ W, indicating that hollow block has excellent thermal insulation performance. In addition, the three-row hole block can reduce material consumption while making its strength meet MU7.5, which is suitable for load-bearing walls.

Conclusions
is study aimed to survey the mechanical and thermal properties of an RCB masonry containing three rows of holes, and then the following conclusions were drawn: (1) As the recycled fine aggregate's replacement rate increased, the RCB's compressive strength reduced. e strength grade of the prepared RCB masonry containing three rows of holes ranged from MU5.0 to MU10.0, which could meet the load-bearing and seismic requirements.
(2) Based on the compression test of the RCB masonry containing three rows of holes, the cracking load had a high correlation with the ultimate load, and their ratio remained basically unchanged. erefore, there was an outstanding stable compressive property in the RCB masonry. (3) e test results of the RCB masonry's compressive strength and shear strength were greater than the calculated results. e ratio of the test and calculated results lies within 1.1-1.2, which indicated that the mechanical strength of RCB masonry could be calculated by the compressive and shear strength formulas of the natural aggregate concrete block masonry. erefore, the RCB masonry' strength standard and design values were calculated. (4) e thermal resistance of the RCB wall containing three rows of holes was tested and determined as 0.467 W/m 2 ·K. At the same time, the RCB's thermal insulation was 52.3% higher than that of the natural concrete blocks, so the thermal insulation performance increased by 20% after adding EPS. (5) Compared to the single-row RCB, there is less porosity but higher thermal resistance in the RCB masonry containing three rows of holes; therefore, it is a better thermal property while meeting the loadbearing and seismic requirements.

Data Availability
e data used to support the findings of this study are available from the corresponding author upon request.

Disclosure
Hanquan Yuan and Lihua Zhu are the co-first authors of this paper. Advances in Materials Science and Engineering 11