Dust Explosion Characteristics of Agglomerated 35 nm and 100 nmAluminum Particles

In the experiment, nanoparticles of 35 nm Al and 100 nm Al powders, respectively, formed particles with average sizes of 161 nm and 167 nm in agglomeration. The characteristics of dust cloud explosions with the two powder sizes, 35 nm and 100 nm, revealed considerable differences, as shown here: (dp/dt)max-35 nm = 1254 bar/s, (dp/dt)max-100 nm = 1105 bar/s; Pmax-35 nm = 7.5 bar, Pmax-100 nm = 12.3 bar, and MEC-35 nm = 40 g/m3, MEC-100 nm = 50 g/m3. The reason of Pmax-35 nm value is smaller than Pmax-100 nm may be due to agglomeration. From an analysis of the explosive residue, the study found that nanoparticles of 35 nm Al powder became filamentous strands after an explosion, where most of 100 nm Al nanoparticles maintained a spherical structure, This may be because the initial melting temperature of 35 nm Al is 435.71◦C, while that for 100 nm Al is 523.58◦C, higher by 87.87◦C. This study discovered that explosive property between the 35 nm Al and 100 nm Al powders after agglomeration were different.


Introduction
When the diameter of a particle approaches the nanoscale, the van der Waals force increases.The sound, light, electrical, magnetic, and thermal properties of the particle change.When the agglomeration of particles changes them from the nano-to the microscale, certain nanoscale properties change.For example, if Fe 3 O 4 particles aggregate to form 30-180 nm clusters, the color changes from black to yellow or blue, while the magnetic force increases.There is no optical effect when a Fe 3 O 4 cluster is more than 180 nm [1].
Agglomeration is related to the isoelectric point and pH value of the nanoparticles in a solution.Zhang et al. [2] pointed out that the isoelectric point of ZnO powder in water is 9.2.When initially purchased, ZnO powder is nanometer grade, but once it is transformed into an emulsion, the ZnO nanoparticles coalesce with other particles to form larger diameter particles that are no longer nanometer grade.When the pH is in the range of 7-11, ZnO powders only carry small positive or negative charges.After the addition of a cationic dispersant of polyethyleneimine (PEI), the ZnO powder generates a large number of positive charges when it is dissolved in water to make it effectively disperse [3].Niu et al. [4] applied polyacrylamide, which clings to the surface of the nanoparticles, to keep the SiO 2 nanoparticles uniformly dispersed in water with good stability.
The various interparticle forces give rise agglomeration of powders.The main forces have Van der walls force, electrostatic forces, and interparticle force due to liquids (Eckhoff [5]).Bryant [6] studied the degree of agglomeration of fine boron carbide particle, dispersed as cloud in gas.He generated the cloud by blowing dust through a narrow nozzle and measured the mean effective agglomerated size as function of injection pressure.This phenomenon was investigated in greater detail by Yamamoto and Suganuma [7], their finding are significant to both the actual industrial dust explosion hazard and design of experimental methods to assess ignitability and explosibility of cloud of cohesive dusts.Agglomeration may occur when nanoaluminum comes in contact with moisture in the air.This research investigated the explosive characteristics of nanoaluminum, which formed aggregates with nearly equal diameters from particles with different original diameters.

Experimental Chemicals and Equipment
2.1.Chemicals.The specifications for the aluminum powder used in the study are shown in Table 1.The primary diameter is a projected figure calculated by a transmission electron microscopy (TEM) with a confidence interval of 99%, based on a sample containing 100 particles.The image is shown as (Figure 1).Since both the 35 nm and 100 nm Al nanoparticle powders demonstrated the agglomeration phenomenon, the particle size measurements obtained by the mode 3090 engine exhaust particle sizer (EEPS) were significantly bigger than the data originally provided by the material supplier (Figure 2).Note: a The particle diameter is a projected figure calculated by a TEM (transmission electron microscope) with a confidence interval of 99%, based on a sample containing 100 particles.b The aggregate diameter is based on an analysis by the EEPS 3090.The sampling tube was directly plugged into the 20-l-apparatus.The test was performed in accordance with the standard 20-l-apparatus test procedure.The aluminum powders came from dust container by high pressure air (20 barg) to the steel sphere (−06 barg).Data is collected from all electrometers at rate of 10 times per second.This model reports 16 channels per decade of size, for a total of 32 channels between 5.6 and 560 nm.The sampling tube was directly plugged into the 20l-apparatus.The test was performed in accordance with the standard 20-l-apparatus test procedure.The aluminum powders came from dust container by high pressure air (20 barg) to the steel sphere (−06 barg).

The 20-l-Apparatus.
A 20-l-apparatus was used for the explosion test.This apparatus was manufactured by Kühner AG of Switzerland.The temperature was set at 25 o C.This instrument was used to measure three dust explosion characteristics: the maximum explosion pressure (P max ), maximum rate of pressure rise ((dP/dt) max ), and minimum explosion concentration (MEC).The chemical ignition energy was 10 kJ for the experiments of P max, and 2 kJ for MEC.Al 100 nm-Tm-25-650-G, 3.5 mg

Scanning Electron Microscope (SEM).
A TESCAN Model 7435 was used.Samples of the explosive residue of the 35 nm and 100 nm nanoparticles were taken, which had been dispersed from the 20-l-apparatus after a dust explosion with a dust concentration of 1000 g/m 3 .agglomeration.The mean size of the agglomerates were only marginally larger than the sizes of the primary particle, which means that on average each agglomerate contains only a small number of primary particle.The reason may be the nozzle effect.The aluminum powders came from dust container by high pressure air (20 barg) to the steel sphere (−06 barg).The valve between dust container and steel sphere was like as nozzle that made agglomerate contain a small quantity of primary particle.

Maximum Explosion Pressure (P max
) and Maximum Rate of Pressure Rise ((dP/dt) max ).The experiment was based on 35 nm and 100 nm Al powders.Under different dust concentrations, the characteristics of dust explosions using these 2 particle sizes were demonstrated through measurements of the explosion pressure (P ex,c ) and maximum rate of pressure rise ((dP/dt) max ), as shown in Figures 3 and 4.
The test results for the 35 nm Al nanoparticles were recorded during the dust explosion.Its maximum explosion pressure (P max ) was 7.5 bars with a dust concentration of 1300 to 1800 g/m 3 , and the maximum pressure stepup rate ((dP/dt) max ) was 1254 bar/sec, with a dust concentration of 1800 g/m 3 .For nanoparticles of the 100 nm Al powder, the maximum explosion pressure (P max ) was 12.3 bars, with a dust concentration from 1500 to 2000 g/m 3 , and the highest rate of pressure stepup ((dP/dt) max ) was 1105 bar/sec, with a dust concentration of 2000 g/m 3 .The explosive characteristics of the nanoaluminum powders are shown in Table 2.
The smaller size of microparticles could generate larger P max and (dP/dt) max values (Bartknecht and Cashdollar [8,9]); however, there are different tendency on P max value in this study.It may result from agglomeration.In the future, this kinds of experiments need to do for identifying the property.

Minimum Explosion Concentration (MEC).
This study was based on BS EN 14034-3, which states that if one of three test explosions with the same dust concentration is successfully fired with a recorded pressure (P ex,e ) larger than or equal to 0.5 bar, this confirms that the dust cloud has been ignited, where P ex,e is directly obtained with a pressure gauge without data correction.The P ex,e test results for the two powders, 35 nm Al and 100 nm Al, with different dust concentrations for the dust explosion test are charted in Figure 5. Based on BS EN 14034-3, the MEC for the two samples of different particle sizes were 40 g/m 3 and 50 g/m 3 .
From the microperspective, the MEC results for these 2 samples showed a significant difference.Under the condition that the experiment only used 35 nm and 100 nm Al powders, the relationship between the particle size of the aluminum powder and MEC was directly proportional, with the MEC decreasing as the particle size decreased.The test results corresponded with the findings of Cashdollar and Amyotte et al. [9,10].

The Melting Point Experiment for Nanoaluminum.
Using differential scanning calorimetry, the melting points of the 35 nm Al (Figure 6) and 100 nm Al (Figure 7

The Residue Analysis after the Dust Explosion.
After the dust explosion, particles of the 35 nm Al powder were changed into filamentous strands.A clear pattern can be seen from these test results.On the other hand, since the 100 nm Al powder contained larger particles, most of the residue after the explosion still maintained its spherical structure, with only a small amount of filamentous strands (as shown Figure 8).The highest explosion temperature had melted 30 nm Al particle with smaller diameter and lower melting point.

Conclusions
The A residue analysis after the dust explosions showed that particles of 35 nm Al powder were changed into filamentous strands by the explosion, but that most of the 100 nm Al particles after the explosion still had a spherical structure, with only a small amount of filamentous strands.
This study discovered that the particle sizes of 35 nm and 100 nm Al powders were comparable after agglomeration, yet their explosive characteristics were different.

Figure 1 :
Figure 1: The image of primary particle Al powder (measured with TEM) (a) 35 nm (b) 100 nm.

3. 1 .Figure 8 :
Figure 8: The residues of the 35 nm and 100 nm Al powders after the explosions.
) were measured.The initial melt temperature of the 35 nm Al was 435.7 o C, and that of the 100 nm Al was 523.5 o C.This represents a difference of about 87.8 o C. The melt point of the 35 nm Al was 529 o C, and that of the 100 nm Al was 537.7 o C.

Table 1 :
The specifications for the aluminum powders.

Table 2 :
The characteristics of aluminum powder in a dust cloud explosion.
nanoparticles of 35 nm Al and 100 nm Al powders, respectively, formed particles with average sizes of 161.3 nm International Journal of Chemical Engineering and 167.5 nm in agglomeration.The dust explosion characteristics for 35 nm and 100 nm Al aggregate particles are, respectively: (dp/dt) max-35 nm = 1254 bar/s, (dp/dt) max-100 nm = 1105 bar/s; P max-35 nm = 7.5 bar, P max-100 nm = 12.3 bar; and MEC = 40 g/m 3 , MEC = 50 g/m 3 .The reason of P max-35 nm value is smaller than P max-100 nm may be due to agglomeration.The initial melt temperature of 35 nm Al is 435.7 o C, while that of 100 nm Al is 523.5 o C.This is a difference of about 87.8 o C. 35 nm Al powder is readily melted under extreme heat, but 100 nm particles have demonstrated that they can sustain relatively high temperatures.