Nanosized TiO 2 Photocatalyst Powder via Sol-Gel Method : Effect of Hydrolysis Degree on Powder Properties

Nanosized TiO2 powder was synthesized via sol-gel method using titanium tetraisopoxide (TPT) as the precursor. Mol ratios of water to TPT were varied from 1 (Powder A), 2 (Powder B), 3 (Powder C), and 4 (Powder D) to evaluate effect of hydrolysis degree. TG/DTA curves showed that amorphous phase turned to anatase crystal structure at ca. 415, 337, 310, and 339◦C for Powders A, B, C, and D, respectively. XRD analysis showed that all the synthesized TiO2 powders were 100% in anatase form with Powders B and C showing considerably higher crystallinities. The powders obtained at lower water to TPT mol ratios were spherical in shape and they became bar-like shapes higher mol ratios. The lower hydrolysis degree led to higher surface area of the Powder A (24.8 m2/g) compared to Powder B (14.6 m2/g). From phenol photocatalytic measurement, Powder B was the most efficient attributed to its higher crystallinity.


Introduction
The rapid growth of industries especially in developed countries has lead to the expansion of environmental problems.An awful amount of hazardous waste are continuously released from factories into the uncontaminated river or ground water.An appropriate and a cheap technique to purify the contaminated waste water needs to be developed.Some conventional methods used to purify polluted waste water from the industries are by [1] (1) adsorption on activated carbon technique and (2) oxidative treatment by chlorine.In oxidative treatment, using chlorine is inefficient due to the formation of other toxic products due to the oxidation process such as desethylatrazine which is a degradation product from pesticide type of pollutant known as atrazine [1].Other methods to remove organic pollutants in the water reported by Kansal et al. [2] were by employing chemical and physical processes such as precipitation, air stripping, flocculation, reverse osmosis, and ultrafiltration [2,3].Still, these techniques are nondestructive because they only transfer the nonbiodegradable matter into sludge that will only lead to formation of a new type of pollutant [2][3][4].
Other than these two conventional methods; a chemical oxidation method such as addition of potassium permanganate has also considerable potential to act as an oxidant to control biological growth in treatment plants, odor and taste as well as to remove colour.However, potassium permanganate is a poor disinfectant.It is also not advisable to leave a residual of potassium permanganate in purified water after the treatment as it can cause the colour of the water to turn to pink [5].Potassium permanganate should also be handled with full body protection as it can cause serious injury to the eyes and can generate skin and inhalation irritant if direct contact is occurred.Thus, utilization of semiconductor photocatalyst is a promising approach and has been widely studied for treating the waste water containing harmful chemicals over the past three decades [6,7].
Photocatalyst TiO 2 has been extensively used for environmental applications because of its high oxidative power, nontoxicity, photostability, and water insolubility properties under most conditions [6,[8][9][10].Photocatalysis process uses ambient oxygen from air and irradiation, basically UV light, to generate oxidation and reduction which can degrade almost all harmful organic and inorganic compounds to International Journal of Photoenergy nontoxic substances.It is initiated when the amount of UV irradiation absorbs by TiO 2 transcends its band gap energy to induce the separation of electron from the valence band to the conduction band [11].The electrons will react with the oxygen to produce superoxide anions and parallelly holes will react with water to produce the hydroxyl radicals to degrade and mineralize the organic compound [11].TiO 2 with anatase crystal structure is more favorable than rutile as it is more active with band gap energy of 3.2 eV than rutile (3.0 eV) [12][13][14].Higher surface area of TiO 2 anatase than rutile is another factor affecting its higher photocatalytic activity efficiency.
Several parameters need to be controlled in order to obtain a highly efficient degradation of organic molecules utilizing TiO 2 photocatalyst.Habibi et al. [15] have developed an efficient way to achieve the optimized photocatalyst process.The most optimal photocatalysis operational parameters such as oxygen, temperature, catalyst loading, UV-light irradiation time, solution pH, and inorganic ions were investigated for the complete decolorization of dyes.Vosooghian and Habibi [16] explained that the photooxidation process of organic sulfides using TiO 2 photocatalyst was better in the presence of pure oxygen rather than in atmospheric oxygen or in the absence of oxygen.The study proved that a specific and controlled oxidative chemistry in organic substrates adsorbed on TiO 2 surface was needed to achieve higher photodegradation rate of the pollutants.In another work, Habibi et al. [17] have also managed to develop TiO 2 thin film for dyes degradation.Investigation on the effect of annealing temperature on the dyes degradation rate found that the annealing temperature of thin film and the substrate nature on which TiO 2 films were deposited played important roles in enhancing the photocatalytic degradation rate of dyes.However, TiO 2 is not the only potential photocatalyst to carry out photodegradation process.Indium tin oxide thin film was one of the promising photocatalysts to degrade textile dyes to replace TiO 2 if the degradation process was done at the optimum condition [18].
In this work we have developed TiO 2 powder photocatalyst via sol-gel method using titanium tetraisopropoxide (TPT) as the precursor.TiO 2 photocatalyst powders with water-to-TPT mol ratios of 1, 2, 3, and 4 were synthesized.The effects of hydrolysis degree on the formation of powders particles were physicochemically investigated.It is expected that the amount of added water will affect the monomer hydrolysis rate resulting in formation of powder particles with different size and shape.The sol-gel derived TiO 2 powders were then tested to evaluate their photocatalytic efficiency in degradation of aqueous phenol solution as a representative model for polluted water.

Experimental
2.1.Synthesis of TiO 2 Powder.TiO 2 powders with waterto-TPT mol ratios of 1 (Powder A), 2 (Powder B), 3 (Powder C), and 4 (Powder D) were synthesized via sol-gel method.The synthesis was done by hydrolysis of titanium (IV) isopropoxide (TPT) (Sigma-Aldrich) as a precursor in methanol (R&M chemicals).Both chemicals were used as received.TPT and methanol were mixed and heated until boiling point of methanol was reached.Then, distilled water was added dropwise and it was left for several minutes to let the hydrolysis-polymerization process take place.The obtained white solution was filtered to get the precipitate of TiO 2 gel powder and dried at 200 • C for 1 hour.The dried powder was calcined at 400 • C for 1 hour to obtain crystalline sol-gel TiO 2 powder.

Characterization of TiO 2
Powder.The gel TiO 2 powders were characterized by thermogravimetric and differential thermal analysis (TG/DTA) (Pyris Diamond, Perkin Elmer) to determine the weight loss and phase changing of the powder.X-ray Diffractometer machine (XRD 6000, Shimadzu) was utilized for phase analysis.Fourier Transform Infrared (FTIR) (Spectrum 100, Perkin Elmer) was used to identify the existing bonds before and after calcination of TiO 2 powder.Powder particle size was measured by Zetasizer (Nano S, Malvern Instruments), and surface morphology was examined by a field emission scanning electron microscopy (FESEM) (JSM 6700F, JEOL).Surface area analysis of the powders was measured by a surface area analyzer (BET-Autosorb-1, Quantachrome Instrument).The change in phenol solution concentration was measured using UV-Vis spectrometer (Lambda 35, Perkin Elmer).

Phenol Degradation Experiment.
The sol-gel TiO 2 powder in suspension form was used to degrade aqueous phenol solution.TiO 2 powder (5 g) was added into 250 mL phenol solution of 50 mg/L initial concentration.Phenol photodegradation process was carried out in a reactor consisting of black light bulbs with the wavelength of 369 nm as the UV source with intensity of 2.6 mW/cm 2 .The suspension was magnetically stirred during photocatalytic test conducted for 5 hours.The sampling was done every one hour and the decrease in phenol solution concentration was measured by the UV-Vis spectrometer.

Results and Discussion
3.1.Photocatalyst Characterization.Figures 1, 2, 3, and 4 show the TG/DTA curves of TiO 2 Powders A, B, C, and D, respectively.From the TG curves, all powders show first weight loss at temperatures below 100 • C, indicating that methanol and water started to evaporate from the powders [19][20][21].At temperature of 100     lower temperatures (below 400 • C) due to their large particles that needed less heat to crystallize.This finding can also be explained that when the mol ratio of water-to-TPT increased, crystallization temperature tends to be lower due to the formation of bigger particles.progressive which accelerated the TiO 2 phase formation rate.Rapid hydrolysis likely formed inhomogeneous nonspherical shape powder particles as shown by Powders C and D. Thus, the amount of water added during the synthesis process plays an important role in controlling the formation of TiO 2 particles.
It is important to note, a slower polymerization process and hydrolysis rate are required to produce smaller particle with more uniform size.It is preferable to have a uniform size of TiO 2 powder as it can control the degradation of organic molecule to happen at faster rate.With uniform particles size, it can increase the amount of pollutants molecules adsorbed on the catalyst's surface and increase its photocatalytic activity.Meanwhile, smaller powder particles will provide shorter distance to be traveled by the electrons from the valence band to the catalytic site.Hence, more holes will be left at the valence band by the electrons that move to the conduction band.The conduction band electrons are the reduction centers that will react with oxygen while the valence band holes become the oxidation centers that will react with water to produce more hydroxyl radicals.
Figure 6 shows the FTIR spectra for methanol (a), titanium tetraisopropoxide (b), TiO 2 gel powder (c), TiO 2 powder after drying at 200 • C (d), and TiO 2 powder after calcination (e).In Figure 6(a), absorption peaks of methanol appear at 3314 cm −1 which is attributed to O-H stretching band and at 1113 cm −1 attributed to C-O stretching band.Figure 6  987 cm −1 belonged to aliphatic C-H stretching band and C-H alkene bending band, respectively.From Figure 6(c), it is clearly shown that the gel powder after filtration process resembled mixture of spectra of both chemicals.After drying at 200 • C, all the bands disappeared and only Ti-O bond's weak stretching band at 394 cm −1 remained.This peak was stronger after the powder was calcined at 400 • C showing a densified inorganic phase of TiO 2 .It is important to note that the inorganic bond of Ti-O does not always exist at low wavenumber as reported here.Wang et al. [22] reported that their TiO 2 submicrospheres showed Ti-O stretching mode at higher wavenumber of 568 cm −1 .
From XRD analysis presented in Figure 7, all TiO 2 powders have the highest peak at 25 • in 2θ indicating that the powders are purely anatase structure.No other peak other than anatase was identified from the analysis.It is noticed that as the mol ratio of water-to-TPT increased, the powder particles increased both in size and crystallinity.The XRD patterns prove that TiO 2 Powder A has the smallest particle size with low crystallinity while Powders B and C have the highest crystallinity but still maintaining its purity.

As for Powder D, it has an intermediate crystallinity between
Powders A and B. Theoretically, an increase in powder's crystallinity will lead to an increase in powder's particle size.From the XRD pattern, it is assumed that the particle size of Powder A is the smallest as it has the lowest crystallinity compared to Powder B, C, and D. The powder particle size is confirmed by Scherrer's equation calculation presented in Table 2.
Comparing TiO 2 Powders A, B, and D for further evaluation on the effect of hydrolysis rate on the powders' International Journal of Photoenergy properties, it can be clearly seen that a small change in mol ratio of water-to-TPT affected the particles shape formed.Powder A that experienced slow hydrolysis rate has the smallest particles compared to Powders B and D due to less progressive hydrolysis.Meanwhile, TiO 2 Powder B has a higher crystallinity than Powders A and D while maintaining its purity as shown from XRD analysis.It should be noted that high crystallinity is also an important property for an efficient photodegradation.High crystallinity TiO 2 can produce more charge carriers to the catalytic site to degrade the organic molecules.
From the particle size analysis as shown in Figure 8, Powder A's mean particle size was 118 nm with particle size distribution ranging from 50 to 300 nm.The particle size of Powder B was ranging from 80 to 400 nm with the mean particle size of 167 nm.Powder D particles size range was from 150 nm to 500 nm with mean particle size of 199 nm.It is worthy to note that the particle size measured from this analysis was quite big in size due to the possibility that powder's agglomerates were measured instead of individual particles.In fact, most particles were dispersed into a primary size in aqueous suspension [23].In addition, small particles tend to agglomerate due to its high surface energy to attract other particles to combine together and form large primary particles.Hence, it is presumed that particles are aggregated into agglomerates in this suspension.
BET surface area analysis shows that the sol-gel TiO 2 powders have Isotherm type II which was evaluated from the adsorption curves of Powders A and B shown in Figure 9. Type II isotherms are normal forms of isotherms obtained with a nonporous and macroporous adsorbent.The hysteresis loop formed by the adsorption-desorption curve indicates that both powders had type E hysteresis loop that can be attributed to "ink-bottle" pores.From BET surface area analysis, Powders A and Powder B have surface area of 24.8 m 2 /g and 14.6 m 2 /g, respectively.This BET result is consistent with the results from XRD, FESEM, and particle size analysis that Powder A has much smaller mean particles size than Powder B.

Photocatalytic Measurement.
Photocatalytic degradation of phenol using TiO 2 Powders A, B, and D has been conducted under UV irradiation of 2.6 mW/cm 2 intensity.In this case, 5 g of TiO 2 powders were mixed with 250 mL of phenol solution with initial concentration of 50 mg/L.The suspension was stirred to obtain the maximum adsorption of organic pollutant molecules on the photocatalyst surface and then exposed to UV irradiation for 5 hours.The sampling was taken every one hour and filtered to remove the excess of TiO 2 powders to get a clear solution prior to UV-Vis spectrometer measurement.
The plots showing phenol degradation by these three TiO 2 powders are presented in Figure 10.It was found that TiO 2 Powder B showed the fastest degradation compared to Powders A and D. Powder B managed to degrade ca.50% of the phenol initial concentration within the first 60 minutes.It can be observed that rate of phenol degradation by Powder A was very slow and almost constant for the whole 5 hours.About 77% of the initial concentration has been completely degraded by TiO 2 Powder B after 5 hours compared to only 26% by Powder A and 57% by Powder D. Some researchers claimed that smaller particle size of powder can lead to faster degradation of organic compound than bigger particles.However, Kanipus et al. [24] reported that degradation rate did not depend on specific surface area of TiO 2 .The influence of the TiO 2 crystalline structure is stronger for the transformations of inorganic anions whereby the rate constants can differ in 30 times.In this research TiO 2 Powder B showed the fastest degradation of phenol in solution due to its high crystallinity than Powder A and D. This is due to the Powder B's optimum crystallinity and particle size that could lead to an efficient removal of phenol.This optimum crystallinity was responsible to form more charge carriers at the photocatalyst's surface to enhance the photocatalytic efficiency.Thus, higher crystallinity of Powder B could compensate its large particles to perform faster photocatalytic process.The low efficiency of Powder A in photodegradation process of phenol molecules can be explained by its small particle size.The solution was clouded by small particles of Powder A and did not permit the maximum UV to penetrate into the solution.If the powder particles are too small, it can create "screening effect" in the solution that can limit the penetration of UV light into the solution and slow down the degradation rate [25].This argument is also supported by Hosseini et al. [26] that the presence of • O 2 − and the • OH radicals depend both on photocatalyst surface and solution composition.This research proves that TiO 2 powder with high crystallinity also shows high potential to degrade organic compound.Kinetic analysis for photocatalytic degradation of phenol under optimal conditions parameters still needs to be carried out for further investigation.

Conclusion
Sol-gel TiO 2 powders with the water-to-TPT mol ratios of 1 (Powder A), 2 (Powder B), 3 (Powder C), and 4 (Powder D) were synthesized and their physicochemical properties were evaluated.All powders are 100% in anatase structure.
Powder A with the smallest individual particles needed more heat energy to become crystalline due to its smaller particle size than Powders B, C, and D. The powder started to form homogeneous spherical shape to inhomogeneous shape as the water-to-TPT mol ratio increased.It was proven that the amount of water added during synthesis process could affect the hydrolysis-polymerization rate and consequently the particle size and shape.Powder's crystallinity became higher when the mol ratio of water-to-TPT was increased due to the acceleration of hydrolysis rate during the synthesis process.From the photocatalytic degradation of phenol, Powder B showed the fastest phenol degradation and higher efficiency than Powders A and D due to its high crystallinity that was capable of producing more charge carriers at the catalyst's surface to degrade the adsorbed phenol molecules.

Figure 8 :
Figure 8: Particle size distribution of TiO 2 Powder A (water-to-TPT mol ratio of 1), Powder B (mol ratio of 2), and Powder D (mol ratio of 4).

Figure 9 :
Figure 9: N 2 adsorption-desorption isothermal analysis of Powder A (water-to-TPT mol ratio of 1) and Powder B (water-to-TPT mol ratio of 2).

Figure 10 :
Figure 10: Plots showing concentration versus irradiation time in the degradation of phenol using Powders A, B, and D.
• C to 300 • C, a weight loss of 14.4% for Powder A, 13.9% for Powder B, 22% for Powder C, and 19.7% for Powder D was recorded, which could be attributed to the removal of unhydrolyzed isopropoxide ligands bonded in the titanium.Meanwhile from the DTA curves, a sharp exothermic reaction peak appeared at ca. 414 • C for Powder A, ca.337 • C for Powder B, ca.310 • C for Powder C, and ca.399 • C for Powder D indicating a phase change of the powder from amorphous to anatase phase.The powder crystallization temperature is summarized in Table 1.With its lower hydrolysis degree, Powder A apparently has smaller individual particle size, thus needing more heat to crystallize.Meanwhile, transformation from amorphous to anatase crystal structure for Powders B, C, and D occurred at

Table 1 :
Crystallization temperature of sol-gel TiO 2 powders as evaluated using the TG/DTA.

Table 2 :
Particle size of sol-gel TiO 2 powders calculated using Scherrer's equation.