Characteristics of GaN/InGaN Double-Heterostructure Photovoltaic Cells

1 Institute of Microelectronics and Department of Electrical Engineering, Advanced Optoelectronic Technology Center, Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan 70101, Taiwan 2 Graduate Institute of Precision Engineering, National Chung Hsing University, Taichung 402, Taiwan 3 Electronics and Optoelectronics Research Laboratories, Industrial Technology Research Institute, Chutung, Hsinchu 310, Taiwan 4 Department of Electronic Engineering, Chang-Gung University, Taoyuan 333, Taiwan


Introduction
GaN-based material system has been extensively investigated in light-emitting diodes (LEDs) [1], laser diodes (LDs) [2], and solar-blind photodetectors (PDs) [3] applications.With the revised band gap of InN [4], InGaN material can be varied continuously from the infrared (0.7 eV) to the ultraviolet (3.4 eV) region.InGaN-based ternary alloys showed an optical match to most of the solar spectrum and were suitable for photovoltaic (PV) applications [5,6].However, several critical issues in In-rich InGaN would limit the photovoltaic characteristics, such as conductivity in ptype InGaN alloy, high In incorporation in InGaN material, and epitaxial growth of thick InGaN film.The p-GaN/i-InGaN/n-GaN double-heterostructure photovoltaic cells have been experimentally demonstrated with open-circuit voltage (V oc ) of approximately 2.4 V and internal quantum efficiency (IQE) of approximately 60% [5].In this study, the photovoltaic properties of double-heterostructure p-GaN/i-InGaN/n-GaN photovoltaic cells with In composition of 10%, 12%, and 14% were fabricated and characterized under standard AM 1.5G measurement condition.Theoretical photovoltaic properties of the fabricated GaN/InGaN photovoltaic cells were also calculated for comparison with the measured photovoltaic properties.conduction layer (ITO film), p-GaN top layer, i-InGaN active layer, and n-GaN layer.High absorption coefficient of GaN-based material (>10 5 cm −1 at the band edge) has been indicated in the literature [7].The inset graph in Figure 1 shows that about 99% of the incident light was absorbed in the GaN/InGaN photovoltaic cells within the first 500 nm.The thickness of p-GaN layer was designed of 150 nm to maximize the light absorbed by i-InGaN active layer and offer good p-ohmic property.To obtain good epitaxial quality of GaN/InGaN double heterostructure, the thickness of i-InGaN active layer with In composition of 10%, 12%, and 14% were all defined of 150 nm.Theoretical photovoltaic properties were calculated for comparison with the measured photovoltaic properties of the p-i-n GaN/InGaN photovoltaic cells fabricated in this work.In our simulation model, photovoltaic efficiencies were calculated based on some assumptions listing below.

Theoretical Efficiency Calculation Model
(1) Perfect quantum response of the GaN/InGaN materials; (2) photocurrent induced from the electron and hole pairs were generated from incident photons of energy hν > E g ; (3) no transmission loss during the collection of photoinduced carriers; (4) AM 1.5G solar spectrum illumination was performed based on American Society for Testing and Materials (ASTM).
Short-circuit current density (J SC ) is given by the photocurrent density (J ph ) of the GaN/InGaN photovoltaic cells.The photocurrent density is produced from the incident photons with hν > E g [8].Then, photocurrent density of the GaN/InGaN photovoltaic cells can be defined as where q is the electron charge, Q s is the number of photons with hν > E g per unit area and unit time, α is the absorption coefficient of the materials, and d is the thickness of the absorption layer.
The current density-voltage (J-V ) function of the GaN/InGaN photovoltaic cells under illumination is given by where J 0 is the saturation current density, k is the Boltzman constant, and T is the temperature.The saturation current density J 0 can be calculated from where n i is the intrinsic carrier concentration.The electronic properties of the GaN and InGaN system, such as D n , D p , L n , and L p , were cited from [9].
From ( 2), the open-circuit voltage (J = 0) can be expressed as Then, the maximum power (P m ) can be obtained from the differential of (2), and the photo-electrical conversion efficiencies of the GaN/InGaN photovoltaic cells can be defined as where P in is the incident irradiance per unit area in mW/cm 2 .

Experiments
The p-GaN/i-InGaN/n-GaN double-heterostructure photovoltaic cells were grown on 2-inch c-plane sapphire substrates by MOCVD using the conventional two-step growth process.The growth details have been described elsewhere [6].The p-i-n GaN/InGaN photovoltaic structure consists of 3 μm n-GaN, 0.15 μm InGaN, and 0.

Results and Discussions
Figure 2 shows the XRD images and PL images (inset graph) of GaN/InGaN photovoltaic cells with In compositions of 10%, 12%, and 14%.The peak wavelength (λ peak ) and fullwidth at half maximum (FWHM) were listed in match with the degradation of FWHM measured from XRD analysis and photovoltaic properties.Double-heterostructure GaN/InGaN photovoltaic cells with In compositions of 10%, 12%, and 14% were also theoretically calculated for comparison.Figure 4 showed the theoretical photovoltaic characteristics of the GaN/InGaN photovoltaic cells with In composition of 10%, 12%, and 14%, and all the related photovotlaic characteristics were listed in Table 2.For comparison, the photovoltaic characteristics of fabricated GaN/InGaN photovoltaic cells measured under standard AM 1.5G solar illumination were also shown in Figure 4.With the increase in In composition from 10% to 14%, the open-circuit voltage decreases and short-circuit current density increases as the energy gap getting small with higher In doped.It is worth to notice, however, the opencircuit voltage of the fabricated photovoltaic cells shows dramatically decay as the In composition increases from 10% to 14%.Such a phenomenon can be attributed to the degradation of epitaxial quality of GaN/InGaN double heterostructure as the increase of In composition.Besides the increase of lattice mismatch between GaN and InGaN, phase separation induced from the low miscibility of InN in GaN also limited the performances of the photovoltaic cell with high In composition [10].Phase separation caused form high In doping in active InGaN layer may dominate the properties of light absorption and cause the decrease in open-circuit voltage.In 0.12 Ga 0.88 N (sim.)In 0.14 Ga 0.86 N (sim.) In 0.1 Ga 0.9 N In 0.12 Ga 0.88 N In 0.14 Ga 0.86 N In 0.1 Ga 0.9 N (sim.)However, double-heterostructure GaN/InGaN photovoltaic cell with In composition of 10% showed high opencircuit voltage of 2.07 V and fill factor over 80% under the standard AM 1.5G solar illumination.Such a good photovoltaic effect can be contributed to the negligible leakage current obtained from dark current-voltage characteristics, which has been shown in Figure 5 [6].Figure 6 showed the ideality factor derived from the dark I-V curve of the GaN/InGaN photovoltaic cells.As the In compositions increasing, the GaN/InGaN photovoltaic cells showed higher ideality factor value at low voltages which could be attributed to the decrease of shunt resistance due to the degradation of epitaxial quality.The series and shunt resistance of GaN/InGaN photovoltaic cells with In composition of 10%, 12%, and 14% were listed in Table 3.The GaN/InGaN photovoltaic cell with In composition of 14% shows a relative low fill factor caused from the increase of series resistance and decrease of shunt resistance shown in Figure 4.The results could be referred to the difference of conversion efficiency between the theoretical calculation and measured photovoltaic properties of GaN/InGaN photovoltaic cells.

Conclusions
GaN/InGaN double-heterostructure photovoltaic cells have been fabricated and their photovoltaic characteristics were also been theoretically calculated in this work.The theoretical conversion efficiency for GaN/InGaN photovoltaic cells with In composition of 10%, 12%, and 14% were 1.80%, 2.04%, and 2.27%, respectively.GaN/InGaN photovoltaic cell with In composition of 10% shows reasonably high V oc and high fill factor of over 80% measured under standard AM 1.5G solar illumination.Such a good photovoltaic performance can be contributed to the good epitaxial quality

Figure 1 2 InternationalFigure 1 :
Figure1shows the light absorption route inside the GaN/InGaN photovoltaic cells, including surface transparent

Figure 4 :
Figure 4: J-V characteristics of GaN/InGaN double-heterostructure photovoltaic cells under experimental measurement and theoretical simulation.

Table 1
there is no phase-separated In-rich quantum dots (QDs) or dislocations that were not observed in the InGaN active layer.However, as In composition increasing to 14%, rough GaN/InGaN interface and dark spots occurred within the i-InGaN active layer and the GaN/InGaN interface.The dark regions shown in the TEM image could be caused from the phase-separated In-rich QDs and such a result showed a

Table 3 :
The series and shunt resistance of fabricated GaN/InGaN photovoltaic cells with In composition of 10%, 12%, and 14%.InGaN photovoltaic cells with higher In composition.The results agree with the TEM image of the GaN/InGaN interface of 10% In composition and the negligible leakage current from the dark I-V performance.Theoretical conversion efficiency of GaN/InGaN photovoltaic cells with In compositions of 10%, 12%, and 14% is 1.80%, 2.04%, and 2.27%, respectively.The difference of GaN/InGaN photovoltaic properties between theoretical simulation and experimental measurement could be attributed to the inferior quality of InGaN epilayer and GaN/InGaN interface generated as the increase of In composition.