Synthesis of Cu-Poor Copper-Indium-Gallium-Diselenide Nanoparticles by Solvothermal Route for Solar Cell Applications

Copper-indium-gallium-diselenide (CIGS) thin films were fabricated using precursor nanoparticle ink and sintering technology. The precursor was a Cu-poor quaternary compound with constituent ratios of Cu/(In + Ga) = 0.603, Ga/(In + Ga) = 0.674, and Se/(Cu + In + Ga) = 1.036. Cu-poor CIGS nanoparticles of chalcopyrite for solar cells were successfully synthesized using a relatively simple and convenient elemental solvothermal route. After a fixed reaction time of 36 h at 180C, CIGS nanocrystals with diameters in the range of 20–70 nm were observed. The nanoparticle ink was fabricated by mixing CIGS nanoparticles, a solvent, and an organic polymer. Analytical results reveal that theCu-poorCIGS absorption layer prepared from ananoparticle-ink polymer by sintering has a chalcopyrite structure and a favorable composition. For this kind of sample, its mole ratio of Cu : In : Ga : Se is equal to 0.617 : 0.410 : 0.510 : 2.464 and related ratios of Ga/(In +Ga) and Cu/(In +Ga) are 0.554 and 0.671, respectively. Under the condition of standard air mass 1.5 global illumination, the conversion efficiency of the solar cell fabricated by this kind of sample is 4.05%.


Introduction
CIGS-based solar cells have great potential for use in portable devices because of their high absorption coefficient, wide absorption spectrum, and high stability.Chalcopyrite compounds of CuInGaSe 2 and related alloys are among the most promising materials for photovoltaic applications [1].Recent studies have demonstrated efficiencies of thin-film CIGSbased solar cells as high as 20.3% [2].
A set of low-cost methods with the realistic possibility of reducing direct manufacturing cost have been developed in the past five years.Recently, CIGS absorbing layers have been fabricated using nanoparticles [12][13][14] and other coating methods.Two nanoparticle-based methods are used to form a CIGS absorption layer.One is the preparation of a precursor film by synthesizing CIGS powder [12] and the other is a mechanochemical process (MCP) [13], such as a rotary ball milling (RBM) method that is implemented before nonvacuum coating [14].In an MCP, the four elemental metal powders of Cu, In, Ga, and Se are mixed and milled by planetary ball milling, yielding particles of size 1 m [13].In the RBM, the precursor has quaternary compound 2 International Journal of Photoenergy composition ratios of Cu/(In + Ga) = 0.95, Ga/(In + Ga) = 0.39, and Se/(Cu + In + Ga) = 0.75.After milling, the particles of the agglomerated CIGS powder have diameters of less than 100 nm [14].Follow, thermal sintering can form a dense absorption layer on precursor films for use in solar cells [15].All steps that are conducted in a nonvacuum environment are relatively simple and inexpensive, facilitating scaling-up [16] and control of the ratios of the metal concentrations.In 2011, Lee et al. [17] developed a nanoparticle-based method using a precursor solution for fabricating printable CIGS thin-film solar cells at low cost.They obtained an almost carbon-free CIGS film by applying a three-step heat treatment process: the first step is the elimination of carbon residues by annealing in air; the second step is the formation of CIGS alloys by sulfurization, and the third step is the growth of grains and the densification of CIGS films by selenization.
This work is going to develop another process for fabricating a Cu-poor CIGS absorption layer precursor using a quaternary compound with constituent ratios of Cu/(In + Ga) = 0.603, Ga/(In + Ga) = 0.674, and Se/(Cu + In + Ga) = 1.036.Cu-poor CIGS nanoparticles used for solar cells were successfully synthesized by using a relatively simple and convenient elemental solvothermal route.The nanoparticle ink could be fabricated by mixing CIGS nanoparticles, a solvent, and an organic polymer.The Cu-poor CIGS absorption layer that was prepared by sintering with a nanoparticle-ink polymer had a chalcopyrite structure.Its favorable composition was examined and analyzed by making various energy dispersive spectrometric (EDS) measurements; the morphologies of the samples were determined by scanning electron microscopy (SEM); their electrical properties were analyzed by making Hall effect measurements; their crystallographic structures were determined using X-ray diffraction (XRD).Solar cells that were produced using this sample were analyzed; their I-V characteristics under illumination were obtained by simulation under standard test conditions of AM 1.5 G and 1000 W/m 2 at 25 ∘ C.

Experimental
An Mo thin-film electrode layer was prepared by using the DC magnetron sputtering process [18].In order to form an Mo layer with a thickness of 350 nm, its deposition conditions were a temperature of 150 ∘ C, a chamber working pressure of 3-4 mtorr, and a deposition rate of 20 nm/min.
The elemental solvothermal procedure that can be found in the literature [19] was used to produce the CIGS nanoparticles.Adding elemental gallium in the CIS synthesis reduces the reaction temperature required to obtain CIGS particles because gallium has a lower melting temperature than the other reactants.Cu powder (99.99%, 5 N plus), In powder (99.95%,Swiftek), Ga(NO 3 ) 3 (99.99%,Spectrum), and Se powder (99.95%, 5 N plus) were used as raw materials, whereas the solvent was ethylenediamine (99%, Spectrum).Analytical grade reactants of Cu (1.04 g, 0.0164 mol), In (1.0 g, 0.0087 mol), Ga(NO 3 ) 3 (4.5 g, 0.0176 mol), and Se (3.55 g, 0.0499 mol) powders were loaded into a 100 mL Teflon-lined autoclave, which was then no more than half-filled with anhydrous ethylenediamine.The precursor of the preparation of CIGS nanoparticles was fabricated by the following steps [20].
Step 1.When the reaction temperature exceeds the melting temperature of indium metal, the indium formed an In 2 Se 3 phase and liquid droplets which could be attached to the solid phase.
Step 2. Gallium can also form a Ga 2 Se 3 phase and liquid droplet as Step 3.Then, Cu + and Se 2− ions from the solution are fed into liquid droplets (In and Ga) and got (3) as The sealed autoclave was maintained at a reaction temperature of 180 ∘ C for 36 h and then cooled to room temperature in the furnace.The synthesized powders were firstly washed with anhydrous ethanol to remove by-products, and then they were vacuum-dried at 80 ∘ C to obtain the required drying CIGS nanoparticles.Closely examining scanning electron microscope (SEM) photographs of the agglomerated CIGS powder revealed an average grain size of smaller than 70 nm (Figure 1).To obtain the information about chemical composition of nanoparticles, each product had been analyzed with EDS (Figure 2).The precursor utilized a quaternary compound with constituent ratios of Cu/(In + Ga) = 0.603, Ga/(In + Ga) = 0.674, and Se/(Cu + In + Ga) = 1.036.A mixed precursor solution was prepared by dissolving the necessary amount of CIGS (5 g) in propanol (20 mL) and then adding triethylenetetramine (1.0 mL), polyvinylidene fluoride (PVDF, 1.0 g), and dimethylformamide solution (16 mL).Under reduced pressure, the condensation of mixed solution at 50 ∘ C would yield a viscous paste with rheological properties that were appropriate for coating by means of a doctor's blade.
The CIGS nanoparticle ink was coated onto the Mo/glass substrate using a doctor's blade.The solvent was then removed by placing the sample into an oven and increasing the temperature from 25 ∘ C to 120 ∘ C with a rate of 20 ∘ C/min, which was maintained for 5 min.After the oven was turned off and the sample cooled to less than 25 ∘ C, the required dry precursor films could be obtained.Thus, the performance of the precursor films could be evaluated by SEM.A crosssectional SEM photograph of a CIGS precursor sample (Figure 3) reveals that the sample has a thickness of ∼2 m.
The prepared precursor sample was heated in a rapid thermal annealing (RTA) furnace to yield a highly crystalline state of CIGS.Before sintering, the sample was firstly placed in a graphite box and the graphite plate was completely covered with selenium powders of 2.5 g, and then the sample was placed into a tube furnace.Successively, the nitrogen gas with a flow rate of 200 sccm was introduced into the quartz tube, coming in from one end and going out from the other end.Both processes of sintering and selenization were performed at 520 ∘ C for 30 min, and then the sample was cooled to less than 50 ∘ C. Thus, the solar cell devices could be fabricated according to conventional configuration of ITO/ZnO/CdS/CIGS/Mo/glass.

Composition and Electrical
Properties of CIGS Film.The stoichiometric compositions of sintered CIGS samples could be analyzed by using energy dispersive spectrometric (EDS) data.The EDS spectrum of the CIGS absorption layer for use in solar cells, as shown in Figure 4, indicated that the atomic proportions were Cu = 15.42%,In = 10.24%,Ga = 12.74%, and Se = 61.60%,respectively.Based on these data, the related Ga/(In + Ga), Cu/(In + Ga), and Se/(Cu + In + Ga) ratios could be obtained.
Processes of sintering and selenization could significantly change the composition of the sample thin film: the ratio of Ga/(In + Ga) decreased 0.119; the ratio of Cu/(In + Ga) increased 0.068, and the ratio of Se/(Cu + In + Ga) increased 0.568, respectively.During sintering, selenium atoms would be to fill vacancy defects of the added Cu, In, and Ga such that the related ratio of Se/(Cu + In + Ga) increased.Due to the minimum loss of indium atoms, the PVDF polymer on indium atoms could have a stronger binding.Sintered samples undergone selenization could form a Cu-poor CIGS film with a Cu : In : Ga : Se mole ratio of 0.617 : 0.410 : 0.510 : 2.464, that is, approximately Cu(In 1− Ga  ) 2 Se 3.5 , which had been reported elsewhere [9].Optimal heating for selenization could yield Ga/(In + Ga) = 0.554 and Cu/(In + Ga) = 0.671.At room temperature, the resistivity, mobility, and carrier concentration of the sintered CIGS sample determined by Hall measurements [21]   and 1.45 + 18 cm −3 , respectively.Furthermore, the sample prepared was p-type.

Structural Characterization.
Figure 5 presents XRD patterns of samples before and after sintering.The grazing incidence angle was 1 ∘ and diffraction angles were scanned from 20 to 60 ∘ .After sintering, it could be seen that the orientation of the sample was (112) after sintering, and the angle had changed from 27.47 to 27.03, as shown in Figure 5.
As is well known, the full width at half maximum (FWHM) reflects the healing of point defects and grain growth [22].For the sample sintered at 520 ∘ C for 30 min, the angular FWHM of preferred orientation (112) would be reducing from 0.82 ∘ to 0.19 ∘ .From the SEM photograph shown in Figure 6, it could also be observed that the surface of the CIGS layer had larger grains.Closely examining XRD patterns, it revealed that this sample was highly crystallized and the ratio of Cu/(In + Ga) was 0.671.During sintering, due to thermal activation, Se atoms would quickly diffuse to occupy vacancies of each Se site of the CIGS layer, such that the ratio of Se/(Cu + In + Ga) would be increasing.Because the interstitial diffusion on the surface of the CIGS layer was faster than that inside the layer, different structures could be formed respectively on the surface and inside the layer.From cross-sectional SEM image of the CIGS film shown in Figure 7, it can be seen that the thickness of the CIGS layer and the MoSe 2 with Mo layer approximately is 1.5 m and 1.35 m, respectively.From Figure 6, it can be seen that the surface morphology of the CIGS film is dense and granular.Furthermore, there is no columnar grain to be observed in cross-sectional image of the film, as shown in Figure 7. Before removing PVDF, the film on the surface is dense and crystallized, which is more easy to form the required chalcopyrite structure of Cu-poor CIGS.From Figures 5 and 7, it can be observed that the crystal growth of MoSe 2 comes from a combination of selenium and molybdenum.At high temperature for sintering, Mo atoms reacting with Se atoms could form MoSe 2 [23].It is noticed that the MoSe 2 layer between the Mo and CIGS films is essential to form a good ohmic contact [23,24].

Photovoltaic Applications.
In order to test the photovoltaic effect, an ITO/ZnO/CdS/CIGS/Mo/glass solar cell with an active area of 0.35 cm 2 was fabricated.The CIGS layer was deposited on the substrate of Mo/glass using the same method as that used for preparing the PVDF sample.
The CdS layer was deposited on the CIGS layer by utilizing the chemical bath deposition (CBD) [25][26][27][28] and successively depositing the ZnO layer with the radio-frequency magnetron sputtering [29][30][31].Then, a highly transparent ITO layer was deposited on the ZnO layer by using the direct current magnetron sputtering [32,33] to complete the  whole solar cell.Under the condition of air mass 1.5 global illumination, the I-V characteristics of a solar cell mounted on an absorber can be obtained, as shown in Figure 8.The measuring data of the cell shows that the open voltage  oc is 0.368 V, the current density  sc is 31.87mA/cm 2 , the fill factor FF is 34.57%, and the conversion efficiency is 4.05%.The reason why the value of  oc of this solar cell sample becomes lower is that the high saturation current due to increased recombination in the CIGS solar cell, coupled with reduced shunt resistance and increased series resistance, resulted in a lower  oc , a lower FF, and, consequently, lower conversion efficiency [34].However, the saturation currents increased since they are derived from temperature-dependent quantities, such as the diffusion coefficient , the carrier lifetime , and the intrinsic carrier concentration  i [35].This resulted in increased recombination currents which reduced  oc ,  max , and FF.Also, the extracted values reflect the adverse effect of temperature on parasitic resistance.For this solar cell sample, the high saturation current due to increased recombination in the CIGS solar cell, coupled with reduced shunt resistance and increased series resistance, resulted in a lower  oc , a lower FF, and, consequently, lower conversion efficiency.

Conclusions
Cu-poor CIGS nanoparticles with a chalcopyrite structure for solar cells were successfully synthesized by using a relatively simple and convenient elemental solvothermal route.In this approach, Cu-poor CIGS nanoparticles, a solvent, and an organic polymer are mixed together to prepare the nanoparticle ink.Analytical results reveal that the Cu-poor CIGS absorption layer prepared by sintering from nanoparticleink polymer had a chalcopyrite structure and a favorable composition ratio.The mole ratio of Cu : In : Ga : Se of the sample was 0.617 : 0.410 : 0.510 : 2.464 and related ratios of Ga/(In + Ga) and Cu/(In + Ga) were 0.554 and 0.671, respectively.In addition, the resistivity, mobility, and carrier concentration of the sample were 5.6 − 3 Ωcm, 7.7 + 2 cm 2 /Vs, and 1.45 + 18 cm −3 , respectively.Under the standard test conditions of air mass 1.5 global illumination, it can be seen that the conversion efficiency of the solar cell fabricated is 4.05%.

Figure 1 :Figure 2 :
Figure 1: SEM photographs of agglomerated CIGS powder, revealing average grain size of smaller than 70 nm.

Figure 3 :Figure 4 :
Figure 3: SEM photograph of cross section of CIGS precursor sample, revealing a sample thickness of ∼2 m.

Figure 5 :
Figure 5: XRD patterns of CIGS samples before and after sintering.

Figure 6 :
Figure 6: Surface SEM photographs of CIGS film layer.

Figure 8 :
Figure 8: I-V characteristics of CIGS thin-film solar cell under illumination.