Study on Emission and Performance of Diesel Engine Using Castor Biodiesel

1 Department of Chemistry, Faculty of Science, Universiti Putra Malaysia (UPM), 43400 Serdang, Selangor, Malaysia 2 Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Malaysia Sarawak, 94300 Kota Samarahan, Sarawak, Malaysia 3 Research and Development Division, Active Fine Chemicals Ltd., West Mukterpur, Munshiganj 1500, Bangladesh 4Department of Physics, Faculty of Science, Universiti Putra Malaysia (UPM), 43400 Serdang, Selangor, Malaysia


Introduction
An update on the advances production technique can reinforce the biodiesel as an alternative fuel to combat against global warming.The interest in renewable fuels has increased dramatically in recent years due to high demand of energy and the limitation of fossil fuel [1].It could offer the opportunities to develop domestic resources in a cost effective manner.Supplementing the petroleum consumption with renewable biomass resources might be one of the components of strategic approach to reduce dependence on petroleum based fuels [2].Nowadays, the search for alternatives of biofuels is a major environmental and political challenge worldwide.These biofuels can be derived from renewable carbon sources to mitigate greenhouse gas emissions, and the end products can be employed as dropin replacements for petroleum fuels.Furthermore, usage of biodiesel has almost zero emissions of sulfates, a small net contribution of carbon dioxide (CO 2 ) when whole lifecycle is considered, and biodiesel is about 10% oxygen by weight [3,4].Biodiesel is one of the sustainable energies that can be produced from the transesterification process of oils or fats which are from plant or animal with short chain alcohols such as methanol and ethanol as shown in Figure 1 [5].
Biodiesel has become an interesting alternative to be used in diesel engine which is due to the similar properties to the conventional fossil diesel fuel in terms of power and torque and none or very minor of engine modification is required [6].Moreover, the biodiesel has a few special features which are biodegradability and being much more environmentally friendly compared to the conventional fossil diesel and resulting in less environmental impact upon accidental release to the environment [7].Although biodiesel has many environmental advantages, it has some drawbacks performance also.The biodiesel behavior is worsening during the cold conditions compared to the fossil diesel fuel.This is due to that in low temperature, biodiesel and diesel will form wax crystals that can restrict the flow in a vehicle fuel system clogging fuel lines and filters [8].The increasing pressure of demand on the use of energy in agricultural, industrial, domestic, and public sectors is an area of concern.Simultaneously, the needs to meet energy demand have created huge capital requirements needed for setting up power plants, pipelines, ports, terminals, and railway tracks to move fuel [9].
Mainly, biodiesel is being produced by the crops like sunflower, soybean, mustard oil, and more in many parts of the world.As the nation is facing a shortage of edible oils, it would not be feasible to produce biodiesel by edible oil.However, first generation technologies have drawbacks in that they rely on feedstocks that are not sufficiently available to satisfy the demands presently met by petroleum, and they rely on easily accessible edible feedstocks fractions, thereby impacting the supply of food for humans and animals.Thus, the utilization of nonedible feedstocks to convert biofuel may be more sustainable strategy to meet the future energy demand.Moreover, the country has enormous potential to produce tree borne oilseeds for biodiesel production to cope with the demand of about 40% of diesel requirements from total crude oil [10].
The main biodiesel production challenge in commercialization is high cost of production compared to fossil fuel diesel.This is due to that the cost in producing biodiesel is heavily depending on feedstock cost or raw materials [3,10].The higher feedstock production costs are in turn due to high prices of inputs including fertilizer and energy, low recovery of biofuel from feedstock, and availability of a narrow range of inputs for biofuel production [11].Biodiesel has a very high flash point (300 ∘ F) making it one of the safest of all alternative fuels, from a combustibility point of view.It has a closed carbon cycle 3.2 : 1 production value which is highly efficient [12].It is noted that biodiesel has a cetane number of over 51 which will make the vehicle perform better in term of fuels ignition with a low idle noise [13].The most common ratio is 80% conventional diesel fuel and 20% vegetable oil ester which is also termed as B20 as indicated by 20% level of biodiesel.Moreover, consumption of biodiesel blends is only 2-5% slightly higher than that of conventional diesel fuel [14].Zhu et al. studied the performance and emissions on Mahua biodiesel blended with ethanol [15].In their study, they found reduction of CO and NO x emissions using 20% blended fuel but an increase in HC emission.Hulwan and Joshi reported the performance, emission, and combustion characteristics of a multicylinder diesel engine running on diesel-ethanolbiodiesel blends of high ethanol content [16].However, there is lack of detailed data on combustion and emission of diesel blended with biodiesel produced from caster seed oil [17].Thus, the aim of this study is to investigate the combustion, performance, and emissions of a diesel engine operating on diesel-biodiesel blends, using biodiesel produced from caster seed oil.

Collection of Crude Castor Oil.
The oil extraction was carried out with manual oil expeller having a high pressure continuous screw press and containing a stainless steel helical screw.The extracted oil was kept at room temperature for few hours in order for solids to settle down.The decant oil was then filtered with filter paper (Whatman, Grade 557 1/2) in the force air convection oven with temperature of 80 ∘ C (boiling point = 313 ∘ C).

Pretreatment of Crude Coconut
Oil.The extracted crude castor oil was filtered and heated to remove unwanted particles in the oil.After filtration, the crude castor oil was then heated to 120 ∘ C to remove any water content in the oil.Finally, the pretreated crude castor oil was stored in the 500 mL conical flask sealed with aluminium foil.

Measurement of Free Fatty Acid (FFA) in Crude Castor
Oil.The titration method was used to determine the acid value or Free Fatty Acid (FFA) content in the crude castor oil.At first, 10 mL of 95% ethanol and 10 mL of diethyl ether were prepared and poured into the 250 mL conical flask with 5 drops of phenolphthalein indicator.And then, 50.0 g of sample of oil was taken into the conical flask and finally titrated with the KOH solution with continuous stirring to the end point of the indicator where the pink color persisted.

Transesterification Process (Acid-Based Catalyzed).
Acid-catalyzed (sulfuric acid) and based-catalyzed (sodium hydroxide) were conducted to complete the transesterification process.The preheated castor oil was poured into the conical flask containing methanol and then the mixture was stirred at 250 rpm and heated continuously for 1 hour.There were 2 methods of heating, namely, direct heating and reflux heating as shown in Figures 2(a) and 2(b).After 1 hour, the mixture was left to settle in the separatory funnel for about 2 hours.Then, 2 layers were found in which upper layer was for methanol-water fraction and the bottom layer for the methyl ester.

Purification Process.
Once the mixture has settled completely, the bottom layer of glycerol was removed.The methyl ester was washed with distilled water to remove impurities such as diglycerine and monoglyceride, catalyst, soap, and excess methanol.Lastly, the biodiesel is kept in a beaker and sealed with aluminium foil to prevent contamination.

Blending.
Collected pure biodiesel is denoted as B100.The blending percentage of biodiesel with diesel was set to 0%, 10%, 20%, 30%, and 40% and they are mentioned as B0, B10, B20, B30, and B40.All the biodiesel blends were stored in different conical flasks and sealed with aluminium foil for further tests.

Smoke Emission Test.
The smoke emission tests were conducted for all blended fuels.A piece of paper was soaked into the fuel and put into an aluminium container.Then, the paper was burned and emitted smoke which was captured with camera.
2.9.Diesel Engine Test.Diesel engine test was performed using Techno-mate, TNM-TDE-700 machine.The diesel engine testing was done 3 times with each blend of biodiesel and important values such as motor speed, output voltage, output current, and time for 20 mL fuel flow were recorded.The brake load for the diesel engine testing was fixed at 120 N and the radius of brake arm was set to 0.5 m.

Comparison of Biodiesel Yield Percentage with Different
Methods.The comparisons of yield percentage between different types of methods used are shown in Table 1.From Table 1, it can be found that the first step with direct heating method obtained highest percentage yield compared to the reflux heating.However, the FFA of methyl ester for direct heating is much higher than the reflux heating method.This is due to the reversible process of acid esterification and high FFA could lead to lower yield of biodiesel in based catalyzed transestnerification. Whereas, highest percentage yield in second step was achieved with orbital shaker method.A significant yield was obtained for second step of based catalyzed transesterification.Therefore, the best method to produce the highest yield percentage of biodiesel is through acid/based catalyzed transesterification with 1 : 3 of oil to methanol ratio for first step with reflux heating and 1 : 3 of oil to methanol ratio with 0.05 g of KOH per 20 mL of oil in the second step with orbital shaker.3.2.FTIR Analysis.In the infrared spectrum of castor biodiesel (Figure 3(a)), the FTIR spectrum of caster diesel showed the alkane C-H bond which lies on the wave numbers from 2800 cm −1 to 3000 cm −1 and 1350 cm −1 to 1480 cm −1 .Thus, it can be confirmed that both conventional diesel and biodiesel had the same functional group of C-H (Figure 3(b)).However, the conventional diesel had no oxygen group, whereas biodiesel showed oxygen functional group such as C-O and C=O at 400 cm −1 to 1500 cm −1 [18].Therefore, the biodiesel with the existence of oxygen could be promoted cleaner and complete combustion.On the other hand, the conventional diesel without any oxygen produced more black smoke and incomplete combustion during burning.

Smoke Emission Test.
From the snapshot of few photos which is shown in Figure 4.The black smoke emitted from the diesel burning is much more compared to the B20, B40, and B100.Anyhow, the black smoke that emitted is reducing from B20 to B100 due to higher biodiesel blend.It is observed that the biodiesel (B100) produced almost no black smoke when it is compared with conventional diesel (B0).On the other hand, the B40 emitted lesser black smoke compared to the B20.
The biodiesel blend produced less black smoke compared to the conventional diesel due to the oxygen content.Moreover, the incomplete combustion of hydrocarbon will produce black smoke too.Thus, the conventional diesel is an incomplete combustion but when it is mixed with biodiesel, the combustion produced is more complete.A complete combustion was obtained with higher biodiesel blend.Hence, the biodiesel blend is much more environmentally friendly compared to the conventional diesel as the biodiesel blend produced less CO and CO 2 and almost zero sulphur emission.Furthermore, the higher cetane number of the biodiesel will lead to lower black smoke emission too.This is explained by the oxygenated nature of biodiesel fuel.Cetane number is an indicator for the fuel in terms of quality.Hence, the higher the cetane number, the better the ignition property of the fuel by producing lesser black smoke [19]. 2 is the calculation results based on the data collected from diesel engine testing which is ranged from B0 to B40.It is observed that the brake horse power, engine power output, and mechanical efficiency are decreasing while the biodiesel blend ratio is increasing.However, the specific fuel consumption increased differently while the biodiesel blend ratio increased.Nevertheless, the engine power output, specific fuel consumption, and mechanical efficiency for every biodiesel blend are plotted into a graph for ease of comparison.Based on Figure 4, it is shown that the castor biodiesel blending percentage is inversely correlated to the engine power output.In other words, the engine power output decreased while the castor biodiesel blending percentage increased.The percentage of decrement for B10, B20, B30, and B40 relative to B0 is 0.03%, 0.04%, 0.05%, and 0.06%, respectively.From the calculated decrement percentage, it is analyzed that the reduction in engine power output of biodiesel blends is insignificant when compared to the conventional diesel, B0.However, it can be concluded that the low energy content of biodiesel per volume results in the low engine power output.

Engine Performance Testing. Table
From Figure 5, it can be observed that the specific fuel consumption is directly correlated to the castor biodiesel blending percentage.In other words, the specific fuel consumption increased when the castor biodiesel blending percentage increased.The increment of the specific consumption of B10, B20, B30, and B40 relative to B0 is 3.59%, 3.96%, 4.68%, and 6.23%, respectively.From the increment percentage, it can be spotted that the B40 has the highest SFC value and it consumes more fuel to produce 1 KW of power when compared to conventional diesel (B0).The higher SFC of those higher percentage blends ratio is due to the fact that the biodiesel has lower calorific value than the conventional diesel [20].
Furthermore, higher containments of oxygen in biodiesel are also the cause of the lower calorific value.Despite the better combustion of biodiesel compared to the conventional diesel, the oxygen in biodiesel takes up space in the blend and slightly increases the fuel consumption rate.Thus, higher oxygen content in biodiesel leads to the low calorific value of biodiesel.
On the other hand, the mechanical efficiency is decreasing with the increasing of castor biodiesel blending percentage which is shown in Figure 6.The decrement percentage of mechanical efficiency for B10, B20, B30, and B40 relative to B0 is 0.085%, 0.085%, 0.163%, and 0.241%, respectively.From the decrement percentages that were calculated, they obviously shows that the reduction in mechanical efficiency of castor biodiesel blends is insignificant.However, the lower mechanical efficiency of biodiesel is mainly due to the low volatility and high density of ester which affects the automization of the fuel and thus leads to poor combustion [21].

Emission Analysis.
From a study from the United States Environmental Protection Agency (EPA) which has conducted a comprehensive analysis on the emission impacts of biodiesel using the publicly available data, the data was plotted in Figure 7 where the percentage changes of NO x , PM, CO, and HC are observed.Figure 8 shows the exhaust emissions of NO x , PM, CO, and HC with varieties of biodiesel blend.It can be observed that NO x is different from PM,  CO, and HC, where it is increasing with the increasing of percentage ratio of biodiesel, whereas, PM, CO, and HC are decreasing with increasing of percentage ratio of biodiesel.
Basically, the percentage changes in emissions of NO x , PM, HC, and CO for B20 relative to conventional diesel are 2.0%, −10.1%, −21.1%, and −11.0%, respectively [22].The average percentage of change in NO x emission for B20, B40, B60, B80, and B100 that is taken from graph are 2%, 4%, 6%, 8%, and 10%, respectively.This shows that the NO x emission increased with the increase of percentage ratio of biodiesel.NO x emission is primarily a function of total oxygen inside the combustion chamber, temperature, pressure, compressibility, and velocity of sound.Invariably biodiesel has some level of oxygen bound to its chemical structures.Thus, oxygen concentration in biodiesel blends fuel might have caused the formation of NO x [23,24].Furthermore, the increase of NO x emission is due to the higher cetane number of biodiesel which will reduce the ignition delay.The increase of NO x emission is a result of the reduced ignition delay [25].However, the NO x emissions Engine power output (kW)  can be reduced through engine tuning or using exhaust catalytic converter [23,24].Moreover, the use of Exhaust Gas Recirculation (EGR) can reduce the NO x emission too where the temperature of exhaust gas is reduced when passing through the combustion chamber.
Meanwhile, the average percentage of change in PM emission for B20, B40, B60, B80, and B100 is −12%, −23%, −32%, −40%, and 48%, respectively.The negative sign is indicating the reduction of the percentage change in emission, whereas the average percentage of change in CO emission for B20, B40, B60, B80, and B100 is −13%, −24%, −33%, −40%, and −48%, respectively.Meanwhile, the average percentage of change in HC emission for the same biodiesel blends B20, B40, B60, B80, and B100 is −20%, −37%, −49%, −59%, and −67%, respectively.The reduction of PM and HC is due to the additional oxygen content in the fuel, which helps to oxidize these combustion products and improve combustion in the cylinder [24].On the other hand, the reduction of CO and HC is due to the oxygenated fuel of biodiesel, it leads to a more complete combustion.The higher cetane number of biodiesel fuel reduces delay period leading to lower HC emissions.Thus, the higher oxygen content and cetane number of biodiesel-diesel fuel blends tend to reduce HC emissions when compared to conventional diesel [24].Diesel  engine performance showed that the biodiesel blend offered lower engine power output, higher specific fuel consumption, and lower mechanical efficiency.Consequently, the biodiesel producing cleaner emission with the significant drop in PM, CO, and HC emissions compares to the conventional diesel.At any rate, the NO x still can be reduced with the advanced technologies such as catalytic converter, EGR and engine tuning.
As can be seen from Table 3, B20 is the most suitable biodiesel blend among all.The first criterion is that the engine power output of B20 is not much different from conventional biodiesel where there is only 0.04% of decrement.Secondly, the specific fuel consumption of B20 is much lower than the B30 and B40 but slightly the same with B10.In this criterion, B20 is selected, as the SFC is slightly the same with B10, and the higher biodiesel blend produces better combustion.Thirdly, the percentage of decrement in mechanical efficiency of B20 relative to B0 is the same as B10 and not as high as the decrement for B30 and B40.Lastly, the B20 has lower average percentage of change in PM, CO, and HC compared to B10.Yet, B20 is producing higher NO x emission compared The negative sign for biodiesel blends in engine power output and mechanical efficiency is showing the decrement relative to the conventional diesel engine.
to B10.Nevertheless, the B20 is still the suitable biodiesel blend amongst all as the NO x emission can be reduced with the advanced technologies.Consequently, the B30 and B40 are not recommended as appropriate biodiesel blends due to higher SFC consumption of more fuel to produce 1 KW of power, and lower mechanical efficiency.

Conclusions
Biodiesel has been successfully produced from the crude castor oil.Biodiesel yield of 93.3% was achieved using twostep transesterification process.The engine power output is the same as conventional diesel for the B20 blend.Thus, B20 can be selected due to its better combustion with lower average percentage of change in PM, CO, and HC emissions compared to conventional diesel.

Table 1 :
Biodiesel yield percentage in optimum condition for different methods.

Table 2 :
Diesel engine testing results for different blends of castor biodiesel.

Table 3 :
The percentage difference for different biodiesel blends relative to conventional diesel, B0.