Effect of Recycled Rubber on the Properties of Road Bitumen

Commercially available road bitumen 50/70 (EN 12591) was modified by recycled rubber and synthetic poly(butadiene) in the presence of sulfur donor. Modification was carried out at 190°C and 220°C. Under such conditions, devulcanization of rubber took place. Prolonged heating in the presence of sulfur caused that devulcanized rubber and poly(butadiene) to revulcanize. .e influence of rubber concentration as well as temperature and time of the modification process on the properties of resulted bitumens was studied..e results show that proposed process modifies the properties of base bitumen very effectively. Particularly noteworthy are values of Fraass breaking points, melting temperatures, penetrations, and elastic recoveries.


Introduction
Improvements in bitumen properties have been achieved by selecting the proper starting crude or tailoring the refinery processes used to make asphalt.According to Becker et al. [1] there are only a few crudes that can produce very good bitumens and only a limited number of actions that can be taken to control the refining process to make improved bitumen product.More possibilities make modification processes.Air blowing makes bitumen harder.Fluxing agents or diluent oils are occasionally used to soften the asphalt [2,3].e method that can significantly improve bitumen quality is the addition of polymers.Polymer modification of bitumen (PMB) has become a more accepted method for addressing pavement distresses.e heavier vehicle loads, higher traffic volumes, and increased tire pressure have forced road administration to explore polymer modification for asphalt pavement applications.
is was observed as a decrease of their glass transition temperature (T g ).Bitumen-rubber mixtures have been shown to have useful properties with respect to distresses observed in bitumen concrete pavements.Most notably, at low temperatures, a large increase in viscosity and improved low-temperature cracking resistance has been measured [2,13].Generally, rubber modification causes asphaltic materials to become tougher, and they reduced the tendency of the surface to crack and bleed and improved aggregate retention [11,15].e results published by Wang [16] indicate that the swollen rubber powder is mutually adhered to form a network structure and the matrix bitumen changes from a homogeneous body into a two-phase continuous blending structure system constituted by rubber powder and bitumen.In the review paper, it was found that regardless of temperature modification, the introduction of crumb rubber into the paving technology can not only solve the disposal issue of waste tires but also improve the performance of asphalt pavements, including reducing traffic noise [17].
is paper presents the results of bitumen modification.e modifiers used were recycled rubber and synthetic poly (butadiene).e purpose of the study was to determine if the final products would have properties comparable to the properties of polymers modified bitumen (PMB) if recycled rubber was used in the modification process.e introduction of rubber to asphalt was done in such a way that it could create a common network with polybutadiene during cross-linking with sulfur.In order to make possible joint cross-linking of rubber and polybutadiene, at the beginning, it was necessary to carry out devulcanization of rubber.
A study was made of the influence of rubber concentration, as well as the temperature and time of the modification process on the properties of resulted bitumens.e sulfur donor was from POCh (Gliwice, Poland).e rubber powder in the experiments presented here had granulation 0-0.4 and 0-0.8 mm.Poly(butadiene) was added as 12% solution in biodiesel oil.

Asphalt Modification.
In a 3000 cm 3 round bottomed three-necked flask equipped with a mechanical stirrer, a thermometer, and a reflux condenser, 1794 g of bitumen (87%, w/w) was placed together with 200 g of crumb rubber (10%, w/w) and earlier prepared biodiesel solution of poly (butadiene) and the content was heated to 190 °C-the temperature which is necessary for the devulcanization of rubber [18][19][20].After 1 hour of stirring, sulfur was added.Stirring was continued and the total heating time was respectively: 2, 4, 8, and 16 h.
e same experiments were carried out at 220 °C with bitumen containing 15% (w/w) of rubber [21].After completion of the modification process, the bitumen was poured from the reactor and cooled to ambient temperature.e hot bitumen was poured into the tank through a set of 2 sieves.
All syntheses were repeated three times and the product was averaged.

Test Method.
e standard tests used to determine the properties of bitumen are given below: Penetration (Pen25) at 25 °C was measured according to standard method (EN 1426).Penetration is the depth at which the penetrometer needle is immersed in the asphalt under test at a load of 100 g at 25 °C for 5 seconds.Ring and ball (SP R&B ) softening point was determined according to EN 1427.e test consists in cutting the asphalt layer through a steel ball.e value of shear stress on the asphalt surface is 0.25 kPa.e asphalt softening point is the conventional asphalt transition temperature from the viscoelastic state to the viscous state.Penetration index (IP) was calculated according to EN 12591/Ann.A. e value of PI should range from around −3 for high temperature susceptible bitumens to around +7 for highly blown lowtemperature susceptible (high PI) bitumen [22].e Fraass breaking point, characterizing the behavior of bitumens at low temperatures, was determined according to EN 12593.Determination of the breakthrough point consisted in cooling the steel plate with the asphalt layer and the bending test every 1 minute until the asphalt layer cracked.Increase of the softening point SP R&B was measured with use of roller thin film oven tester (RTFOT) (according to EN 1427).e elastic recovery at 25 °C (according to EN 13398) was evaluated by the percentage of recoverable strain measured after elongation during a conventional ductility test.
Storage stability was determined using metal test tubes Φ25 mm × 160 mm. e samples of asphalt in aluminum tubes were heated in a vertical position at 180 for 72 hours.After cooling, the aluminum coating was removed and the sample was cut into 3 parts.e middle part was discarded and penetration and softening tests were carried out for the lower and upper parts (difference between penetration top/penetration bottom as delta Pen25 and difference between SP R&B top/SP R&B as delta SP R&B ).Retained penetration at 25 °C after RTFOT (according to EN 1426) and mass change after RTFOT (according to EN 12607-1) were determined for samples heated in rolling thin oven and compared for those of fresh bitumen.Cohesion energies at 5 °C and 10 °C were determined by the force ductility method (according to EN 13589 and EN 13703).Under the same tests, additional values were recorded as maximal tensile force (N).
e solid residual was measured by gravimetric method consisting in weighing the dry residue on a sieve.

Results and Discussion
e bitumen-rubber modification is influenced by the blending/reaction temperature, the time of mechanical mixing, the size and microtexture of the crumb rubber, and the chemical nature of bitumen (concentration of aromatics).
As a cross-linked polymer, rubber does not form a homogeneous solution with bitumen.ree dimensional networks of crumb rubber reinforced by carbon black absorb the light oils from the bitumen causing their swelling and softening [23].For this reason, in some technologies devulcanized or partially devulcanized rubber was used as modifiers.At elevated temperatures, some of the polysulfide and disulfide bonds in the rubber are converted to monosulfide bonds, which lead to the formation of uncured rubber [24].In devulcanized form, rubber can be treated as a thermoplastic polymer.
In the studies presented here both devulcanized rubber and synthetic poly(butadiene) (PB) were used as bitumen modifier.PB was preliminarily diluted in biodiesel.It could not be added as solid polymer because at elevated temperatures, it tends to cross-link.Rubber was added as a 0-0.4 mm and 0-0.8 mm granules.
Modifications of bitumen with PB and devulcanized rubber in the presence of sulfur donor were carried out in 190 and 220 °C [19][20][21].e influence of modification time on the concentration of insoluble residue is presented in Tables 1 and 2 With the increase of modification time, the amount of insoluble residue decreased which means that devulcanization of rubber took place (Figure 1).After 16 h devulcanization time, only 4.5% of insoluble residue remained.It contained carbon black and residues of rubber whose remains were not devulcanized.Decrease of residue concentration with increase of reaction time is also visible for sample no. 3 which contained coarser rubber (0-0.8 mm).In this case, devulcanization process ran more slowly.
In 220 °C, the concentration of rubber was increased to 15%.Similarly to the temperature 190 °C, increase of reaction time was accompanied by decrease of residual solid.Depending on the grain size of rubber, the devulcanization process should run faster or slower.For the 0-0.4 mm granulation rubber, the amount of insoluble residue decreased from 5.3% to 2.8%, whereas for sample no.11 with rubber 0-0.8 mm, it was 3.7%.
e properties of bitumen after modification are presented in Tables 3 and 4. For samples modified at 190 °C, increase of modification time caused rather insignificant changes of properties (Table 3).Penetration at 25 °C changed in the range of 66-71 units (0.1 mm).When samples with rubber of 0-0.4 mm are taken into account, irrelevant decrease of penetration values was observed.Increase in modification time was paralleled by increase in ring and ball (R&B) softening points and improvement in lowtemperature properties tested with Fraass breaking points.Softening points for samples modified for more than 2 h achieved values that meet the standards (EN 14023, Polish National Annexe for PMB 45/80-55).A similar tendency was observed for their elastic recoveries at 25 °C.
Stability of samples in tube test, expressed as penetration top/bottom, grew with the increase of modification time at 190 °C whereas that for samples modified at 220 °C insignificantly decreased (Figure 2).Simultaneously, the delta SP R&B (difference between SP R&B at top and bottom of the tube) decreased, which was a very positive phenomenon.Similar behavior can be observed for the delta SP R&B of the samples modified at 220 °C.
Table 3 also presents the data obtained after the rolling thin film oven test (RTFOT).is test represents an aging potential of the binder, especially in simulating binder's thin film during contact with the surface of very hot aggregates in the presence of air.From these data, one can see that with increase of modification time, an insignificant increase of retained penetration at 25 °C after RTFOT is observed whereas softening point R&B after RTFOT and mass change after RTFOTshow a downward trend.It is important that for this series of samples, mass changes are very small, and with increasing time of modification, they drop from 0.16 to 0.12%.
Modifications without the addition of rubber were also carried out to investigate the effect of the presence of rubber on the properties of bitumen.Reactions lasting 2 hours were performed for several PB concentrations.Introduction of more than 10% of PB was difficult due to drastic decrease in bitumen viscosity.e basic properties of bitumens modified in this way, presented in Table 3, indicate that the lack of rubber has the greatest impact on the values of breaking points.
e data for bitumen samples modified with rubber at 220 °C presented in Table 4 are not so clear.Values of penetration at 25 °C are much higher than those obtained for samples modified at 190 °C.Increase of modification time causes that bitumen samples containing rubber of granulation 0-0.4 mm become less soft.Similarly, for samples with rubber 0-0.8 mm penetrations have increasing tendencies.
e softening points for the latter samples increase with the extension of modification time whereas those for samples containing rubber 0-0.4 mm become smaller.Modification at 220 °C has positive influence on Fraass breaking points.Independent of the time of modification, breaking points for all the studied samples were in the range of −26 to −28 °C.ese data suggest that modification at 220 °C leads to the creation of a more homogeneous bitumen structure.At this temperature, the degree of degradation of the rubber is greater than that at 190 °C.Rather high values of elastic recoveries also confirm the effectiveness of the modification process but samples modified at 220 °C behave a bit differently.Elastic recoveries for samples containing 0-0.4 mm rubber decrease with increasing modification time.For samples containing 0-0.8 mm rubber, elastic recovery decreases first and next increases.It will be remembered that the temperature 220 °C is suitable for re-cross-linking of rubber and PB linear polymer, the more so as the sulfur donor was added to this system.Under these conditions, a homogeneous structure of the polymer network is created, Journal of Chemistry in which bitumen is dispersed.Probably for samples with 0-0.4 mm rubber, 8 h modification is sufficient to achieve such effect whereas 0-0.8 mm rubber degrades slowly, and a uniform structure is obtained after 16 h.Values of delta penetration and retained penetration after RTFOT additionally confirm the appearance of uniform homogeneous phase.Such bitumens retain their viscoelastic properties at low temperatures and do not flow at higher temperatures at extended load.Independent of modification time, they exhibit resistance to aging.e values of penetration indices are also very promising.According to Ehinola et al. [21], penetration index represents a quantitative measure of the response of bitumen to variation in the temperature.Knowing the penetration index of a particular bitumen, it is possible to predict its behavior in an application.IP values should be around −3 for high temperature susceptible bitumens to around +7 for highly blown low-temperature susceptible bitumen.
Cohesion energies at 5 °C and 10 °C determined by force ductility method change between 1.1 and 4.8 J/cm 2 and are rather independent of temperature and time of modification whereas those of maximal tensile forces have larger values for samples modified at 190 °C.ese results correspond to earlier conclusions that the proposed process creates modified bitumens with homogeneous and spatially stable structures.

Conclusions
In order to reduce the cost of preparing polymer modified bitumen, it was proposed to replace part of poly(butadiene) with the waste product: recycled rubber.In this process, rubber in a degraded form is a substrate for the production of PMB.
Pre-devulcanized rubber was next used for creating the joint net with polybutadiene in the process of cross-linking.e devulcanization and cross-linking were carried out at different times at temperatures 190 °C and 220 °C.e modification process carried out at 220 °C with 10% of rubber content is very fast, whereas for samples with 15% of rubber, . e influence of modification time on the 2 Journal of Chemistry percentage concentration of residue is evident at 190 °C.

Table 3 :
Properties of bitumen modified at 190 °C.

Table 4 :
Properties of bitumen modified at 220 °C.theoptimalmodification time is 8 hours.Modification at 190 °C requires a longer time.Most of the obtained products meet all standards (PMB 45/80-55 and PG 70-22 according to AASHTO-MP1).Particularly noteworthy is their behavior at low temperatures.