Synthesis of High-Purity SnO 2 Nanobelts by Using Exothermic Reaction

This paper presents a new method to synthesize high-purity single-crystalline SnO2 nanobelts with rutile structure. The purity, morphology, crystal structure, and sizes of the as-grown SnO2 nanobelts are characterized by X-ray diffraction, energy-dispersive X-ray analysis, scanning electron microscopy, transmission electron microscopy, and Raman-scattering spectroscopy. The scanning electron microscopy and transmission electron microscopy reveal tetragonal SnO2 nanobelts of 50–120 nm in width, 20–50 nm in thickness, and 2–10 μm in length. The three observed Raman peaks at 475, 633, and 774 cm−1 indicate the typical rutile structure of the SnO2, which is in agreement with the X-ray diffraction results, and other peaks of impurity are not found. High-resolution transmission electron microscopy demonstrates that the nanobelts have a high degree of crystallinity, without typical imperfects in it. And the growth mechanism of the SnO2 nanobelts is discussed.


Introduction
In recent years, one-dimensional nanostructures, such as nanorods, nanowires, and nanobelts, have attracted considerable attention in the field of material, because of their peculiar structure characteristics and size effects [1,2].In fact, different kinds of one-dimensional nanostructures with different materials (SnO 2 , ZnO, PbO 2 , In 2 O 3 , CdS, MgO, etc.) have been successfully synthesized [2][3][4][5].Among these materials, one-dimensional nano-SnO 2 with rutile structure, as an n-type semiconductor with a wide bandgap (Eg = 3.6 eV at room temperature), is well known for its excellent gas sensitivity and electrical properties.According to earlier reporters [2,[6][7][8][9][10][11], one-dimensional nano-SnO 2 is synthesized by a variety of methods, such as hydrothermal process, thermal evaporation, chemical vapor deposition (CVD), physical vapor deposition (PVD), laser ablation technique, carbothermal reduction, and calcination process.However, all of these methods are hard to be widely used due to either their high requirements for experimental equipments or the complexity of processes.
This paper presents a new method, namely, the exothermic reaction synthesis (ERS), to synthesize high-purity SnO 2 nanobelts.The ERS relies on self-thermal reaction of source chemicals to keep the reaction going and get the product.For example, in our experiment, SnO 2 powders, CuO powders, and Al powders are mixed and put into a reactor at first, and then they are induced to react vigorously, which produces a lot of heat to maintain the reaction system, so that SnO 2 nanobelts can be obtained in the process.And characterization and growth mechanism of the obtained SnO 2 nanobelts will be discussed in detail.
The ERS is similar to the self-propagating high-temperature synthesis (SHS), though they are actually different.The product obtained by ERS is the soot spurting out of the reactor, while the product obtained by conventional SHS is the solid residue in the reactor.Compared to other methods for the synthesis of SnO 2 nanobelts, the ERS has some advantages, such as easiness, high efficiency, convenience, and low cost, so that it can be applied into a vast range of fields.mesh, AR) powders, were mixed and stirred adequately with a mixer and then put into a graphite mold.As shown in Figure 1, at the bottom of the cylindrical graphitic mold was a slight tapering hole covered with a paper gasket beforehand, which was burned in the reaction to let the waste residue from the reaction drip out into the dirttrap.Then a layer of ordinary pyrophoric powders was scattered on the mixture with a magnesium ribbon sticked in it as a primacord.Some more paper gaskets were placed around the mold to collect the product.After the magnesium ribbon was ignited, a cotton-like product sprayed out from the mold and landed on the paper in about 30 seconds.

Experimental Procedures
The product was characterized by X-ray diffraction (XRD; D8 Advanced XRD, Bruker AXS, Germany, with Cu K α radiation and a normal θ-2θ scan), scanning electron microscopy (SEM; with EDX GENESIS 7000, FEI SIRION, Netherlands), transmission electron microscopy (TEM; JEOL JEM 2010, Japan, voltage at 200 KV), high-resolution transmission electron microscopy (HR-TEM; JEOL JEM 2010), and Raman spectroscopy (Renishaw, RM-1000, Ar laser, excitation at 514.5 nm).211), (220), and (002), respectively.This result matches well with the standard XRD data file of SnO 2 (JCPDS-041-1445) [12].All the diffraction peaks can be indexed to tetragonal rutile structure of SnO 2 with lattice constants of a = b = 0.4738 nm and c = 0.3188 nm.These cliffy diffraction peaks indicate high crystallinity of the SnO 2 product obtained in this experiment.In addition, no traces of Al or Cu can be detected.The result of energy dispersive X-ray analysis of the SnO 2 product is shown in Figure 3.It reveals that the product is made up of O (64.87 at %), Sn (29.35 at %), and Al (5.78 at %), which confirms that the product is high-purity SnO 2 with little Al 2 O 3 impurities.Moreover, these Al 2 O 3 impurities are possible amorphous and trace amounts, so that those cannot be detected by XRD analysis.

XRD pattern of the product synthesized by ERS is shown in
SEM image of the SnO 2 product is shown in Figure 4.It reveals that the obtained products are a large quantity of wire-like nanostructures with a small number of particles attached to them.The length of these wire-like nanostructures can reach several microns, and radial dimensions of them are no more than 100 nm.These wire-like nanostructures are crooked and disperse, without particular orientation.Their average diameter can be estimated at  about 50 nm by using an image zoomer.This result is close to the result of XRD, 70 nm, calculated by Jade5.0.
For a further observation of the individual wire-like nanostructure, some TEM images of the SnO 2 product are taken, as they are shown in Figure 5.These TEM images indicate that most of these nanobelts are smooth and uniform along the fiber axis, and typical width, thickness, and length of these nanobelts are in the range of 50-120, 20-50, and 2000-10000 nm, respectively.The statistical results of the number of the nanobelts observed in all the TEM images reveal that the ratio of the nanobelts in the SnO 2 products is found to be up to 72%. Figure 5(e) shows an individual SnO 2 nanobelt and its corresponding selectedarea electron diffraction pattern (SAED, inset in Figure 5(e)).The single set of diffraction spots in the SAED pattern reveals that this belt is a tetragonal single crystal and grows along the (101) orientation, which is in agreement with the previous reports [13].However, some nanobelts can also be found to grow along the (110) orientation, which verifies that these nanobelts do not grow in one orientation; in other words, preferential growth of these nanobelts did not take place in the crystal growth process.This conclusion can be verified by the HR-TEM image, as is shown in Figure 6.It also demonstrates that the nanobelt is a single crystal with high crystallinity, and its inner structure is highly orderly.Any characteristic imperfects such as big dislocation, twin plane, and subgrain boundary cannot be observed in Figure 6.
The Raman peaks of the SnO 2 nanobelts are detected at 475, 633, and 774 cm −1 , corresponding to the E g , A 1g , and B 2g vibration modes of standard SnO 2 sample, respectively, as are shown in Figure 7.These peaks further verify that these nanobelts are rutile structure SnO 2 , in accordance with papers reported by Scott [14], Peercy and Morosin [15], and Yu et al. [16].In fact, widths of these peaks are wider than those of SnO 2 nanoparticle [17], which can be explained by the effect of the small dimension of nanobelts.
Based on the experimental data, the mechanism of the ERS of the obtained SnO 2 nanobelts can be briefly described by the following reactions: The result of energy dispersive X-ray analysis of upper scrap in the dirt trap is shown in Figure 8.It reveals that the upper scrap is made up of Cu (84 at %) and Sn (16 at %), which confirms that Cu is indeed formed in these reactions.The synthetic process can be generalized into two procedures.During the first procedure, Al deoxidizes SnO 2 into Sn, which is melted immediately by the large amount of heat released from the reaction system.During the second procedure, the molten pool sharply heats up and explodes, thus the solid-liquid biphasic Sn sprays out of the mold.Once the solid-liquid biphasic Sn is exposed to air, oxidation takes place immediately.Due to the huge press from the explosive blast and great plasticity of the solid-liquid biphasic Sn, an elongation takes place during the oxidation.These reaction products solidify and cool immediately in the air, and the cotton-like SnO 2 nanobelts are obtained.

Conclusions
A convenient and fast method with inexpensive experimental equipment has been developed to synthesize SnO 2 nanobelts.The number ratio of the nanobelts in the product is as high as 72% (others are particle or fiber).The as-grown SnO 2 nanobelts have a width of 50-120 nm, thickness of 20-50 nm, and length of 2-10 μm.The results from XRD pattern, EDX pattern, and Raman spectra indicate that the high-purity SnO 2 is single crystal with rutile structure.SAED pattern and HR-TEM image reveal that preferential growth of these nanobelts does not take place in the crystal growth process, and inner structure of the showed nanobelt is highly orderly without characteristic imperfects.A new growth mechanism of the SnO 2 nanobelts is also discussed.

Figure 2 :
Figure 2: XRD pattern of the product synthesized by ERS.

Figure 3 :
Figure 3: Energy dispersive X-ray analysis of the product synthesized by ERS.

Figure 4 :
Figure 4: SEM image of the SnO 2 product synthesized by ERS.

Figure 5 :
Figure 5: TEM images of the SnO 2 nanobelts.The inset is the selected-area electron diffraction pattern taken from a section of the nanobelt beside it.

Figure 8 :
Figure 8: Energy dispersive X-ray analysis of upper scrap in the dirt trap.