Journal of Nanomaterials

Volume 2012 (2012), Article ID 427310, 6 pages

doi:10.1155/2012/427310

Research Article

Fabrication of Magnetite/Silica/Titania Core-Shell Nanoparticles

Suh Cem Pang, Sze Yun Kho, and Suk Fun Chin

Department of Chemistry, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak, Kota Samarahan, 94300 Sarawak, Malaysia

Received 25 September 2012; Revised 26 November 2012; Accepted 27 November 2012

Academic Editor: Yanbao Zhao

Copyright © 2012 Suh Cem Pang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract.

Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles were synthesized via a sol-gel method with the aid of sonication. Fe₃O₄ nanoparticles were being encapsulated within discrete silica nanospheres, and a layer of TiO₂ shell was then coated directly onto each silica nanosphere. As-synthesized Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles showed enhanced photocatalytic properties as evidenced by the enhanced photodegradation of methylene blue under UV light irradiation.

1. Introduction

Over the past decades, titanium dioxide (TiO₂) nanoparticles have gained much attention as a photocatalyst and catalyst support [1, 2]. TiO₂ nanoparticles have many advantages as compared to other photocatalysts, which include excellent high stability against chemical and photonic corrosion and high photocatalytic activity [3]. TiO₂ nanoparticles of small mean particle sizes possess high surface area and photocatalytic activity. However, TiO₂ nanoparticles of high surface area are thermally unstable and lose their surface area readily [3]. Therefore, much effort has been focused on coating of TiO₂ on high surface area supports such as silica or alumina in order to stabilize TiO₂ nanoparticles.

TiO₂ nanoparticles could be difficult to recover and lost readily upon being dispersed into wastewater. One of the ways to overcome this problem is to coat TiO₂ onto magnetite (Fe₃O₄) cores and the resulting Fe₃O₄/TiO₂ core-shell nanoparticles can be recovered easily through manipulation by external magnetic field. Li et al. synthesized Fe₃O₄/TiO₂ nanocomposite photocatalyst using a sol-gel method [3]. However, it was difficult to achieve complete coating of Fe₃O₄ nanoparticles with TiO₂ at nanometer scale using the sol-gel method. Besides, TiO₂ would oxidize Fe₃O₄ nanoparticles and lead to a reduction of magnetic moment. Some researchers had attempted to coat a thin layer of SiO₂ between Fe₃O₄ nanoparticles and TiO₂ shell. The presence of a SiO₂ layer between TiO₂ shell and Fe₃O₄ nanoparticles could increase the lifetime of photogenerated holes which in turn, resulted in increased photoreactivity [3, 4]. This is attributed to the SiO₂ layer which serves as an insulating layer between Fe₃O₄ nanoparticles (hole-electron trap center) and the TiO₂ shell.

However, there are currently very few literature which report on the synthesis of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles and their photocatalytic properties. Besides, the reported synthesis methods for Fe₃O₄/SiO₂ nanoparticles were generally complicated and time consuming. Besides, the coating of Fe₃O₄ with SiO₂ using TEOS was a very slow process which required 12 to 48 hours of mechanical stirring at room temperature [5]. Santra et al. used the microemulsion method for the preparation of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles which was a lengthy process and involved the use of several types of surfactants [6]. Gad-Allah et al. and Watson et al. reported the preparation of Fe₃O₄/SiO₂/TiO₂ nanocomposites [4, 7]. However, Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles prepared by them were in the form of patches and not discrete nanoparticles. As such, these core-shell nanoparticles exhibited in reduction on their surface area and photocatalytic properties. Song and Gao reported the use of the sol-gel process to synthesize Fe₃O₄/SiO₂/TiO₂ nanoparticles but the particles synthesized were very big size of about 500 nm [8].

Herein, we have reported a facile and efficient synthesis approach for the fabrication of Fe₃O₄/SiO₂/TiO₂ discrete core-shell nanoparticles by the sol-gel method with the aid of sonication. Fe₃O₄ nanoparticles were being encapsulated inside discrete SiO₂ nanospheres within 90 minutes, and a TiO₂ layer was then coated directly onto each SiO₂ nanosphere via the sol-gel method. The photocatalyst properties of as-synthesized Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles were evaluated by the photodegradation of methylene blue (MB) with or without UV light irradiation.

2. Materials and Methods

2.1. Materials

Iron (II) chloride tetrahydrate, FeCl₂·4H₂O (Merck); Iron (III) chloride 6-hydrate, FeCl₃·6H₂O (AnalaR); tetraorthosilicate, TEOS (99.3%, J.T. Baker); absolute ethanol, EtOH (99.0%, HmBG Chemicals); hydrochloric acid, HCl (37%, HmbG Chemicals); ammonia solution, NH₄OH (28%, R&M Chemicals); titanium (IV) isopropoxide, TIPP (97%, Aldrich); and Milli-Q water (18.2 MΩ cm⁻¹) were used throughout the experiment. All chemicals were used as received without further purification.

2.2. Preparation of Fe₃O₄ Nanoparticles

Fe₃O₄ nanoparticles were prepared using a simple chemical coprecipitation method [8]. Typically, 0.15 moL of FeCl₂·4H₂O and 0.30 moL of FeCl₃·6H₂O were freshly prepared in aqueous HCl (2 M), respectively. Both FeCl₂·4H₂O and FeCl₃·6H₂O aqueous solution were then added rapidly to 20 mL of de-aerated Milli-Q water under nitrogen flow at 80°C with the mixture being continuously stirred under nitrogen. Upon adding an aqueous NH₄OH solution (28%, 4 mL), a distinctive black precipitate of Fe₃O₄ nanoparticles was formed immediately. Fe₃O₄ nanoparticles were isolated and purified by centrifugation and then washed with Milli-Q water three to four times to remove excess NH₄OH solution.

2.3. Preparation of Magnetite/Silica (Fe₃O₄/SiO₂) Core-Shell Nanoparticles

A modified Stöber method was used to coat Fe₃O₄ nanoparticles with SiO₂ shell [9]. About 30 mg of freshly prepared Fe₃O₄ nanoparticles were dispersed in a mixture of 30 mL of ethanol and 6 mL water as seeds. The dispersion was homogenized by sonication for about 10 minutes. 3.3 mmol of TEOS was then added into the mixture and sonicated for another 20 minutes. Finally, 30 mmol of aqueous ammonia was added and the mixture was sonicated for 60 minutes. Fe₃O₄/SiO₂ core-shell nanoparticles were isolated by magnetically separation and then washed with ultrapure water.

2.4. Preparation of Fe₃O₄/SiO₂/TiO₂ Core-Shell Nanoparticles

A layer of TiO₂ shell was coated directly onto Fe₃O₄/SiO₂ nanoparticles via the hydrolysis and condensation of TIPP in the presence of Fe₃O₄/SiO₂ nanoparticles as seeds. 0.36 mL of TIPP was added into Fe₃O₄/SiO₂ suspension and stirred continuously for 18 hours at room temperature. The resulting Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles were dried in an oven and finally calcined at 450°C for 3 hours to convert the TiO₂ outer shell from amorphous phase to photocatalytically active crystalline anatase phase [10].

2.5. Photocatalytic Activity Evaluation

The photocatalytic activity of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles was investigated by measuring the photodegradation rate of an aqueous solution of MB in the presence of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles and under UV irradiation. 0.02 mmol MB solution (25 mL) and a measured amount of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles were placed inside a glass vial. A 6 W UV tube with a wavelength of 254 nm was used as the irradiation light source. During the photocatalytic reaction, the core-shell nanoparticles were being well dispersed by stirring the suspension continuously. At predetermined intervals of UV irradiation, a subsample of the suspension was collected and analyzed by UV-Vis spectrophotometer at its characteristics absorption wavelength ( nm) of MB.

2.6. Morphological Characterization

The morphologies of all samples were examined using a scanning electron microscopy (SEM) (JEOL Model JSM-5300LV) and a transmission electron microscopy (TEM) (JEOL JSM-6710F). The elemental composition of the core-shell nanoparticles were analysed by SEM associated energy-dispersed X-ray microanalysis (EDX) operated with the beam energy of 20 kV. The BET surface area analysis was conducted using the nitrogen absorption-desorption method at 77.30 K (Micromeritics ASAP 2010). The phase of the Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles was identified using an X-ray diffractometer (XRD) (RIGAKU, Getgerflex D/MAX-1C).

3. Results and Discussion

3.1. Preparation of Fe₃O₄/SiO₂ Nanoparticles

In this study, Fe₃O₄ nanoparticles with mean diameter of approximately 10 nm (Figure 1) were prepared by a chemical coprecipitation method [11]. These Fe₃O₄ nanoparticles were subsequently used as seeds for coating of SiO₂ shell.

Figure 1: Fe₃O₄ nanoparticles were used as seeds for coating of SiO₂ and TiO₂ shells.

Fe₃O₄ nanoparticles were being encapsulated within the SiO₂ shells upon the hydrolysis and condensation of TEOS as new bonds of Fe–O–Si were formed between the interface of Fe₃O₄ and TEOS. Ultrasonication was used to accelerate the hydrolysis of TEOS. This was followed by lateral polymerization, and the formation of a three-dimensional network via siloxane formation (Si–O–Si), to produce a homogenous SiO₂ coating [4]. TEM micrographs as shown in Figure 2(a) show that Fe₃O₄ nanoparticles were fully encapsulated within the SiO₂ shell using the sonication method. The mean diameters of Fe₃O₄/SiO₂ core-shell nanoparticles were observed to be approximately 120 nm.

(a)

(b)

Figure 2: TEM micrographs of (a) Fe₃O₄/SiO₂ nanoparticles prepared by sonication; inset shows an individual Fe₃O₄/SiO₂ nanoparticles and (b) Fe₃O₄/SiO₂ nanoparticles prepared by the stirring method.

Fe₃O₄ nanoparticles were observed to have dispersed uniformly within the SiO₂ matrix. However, Fe₃O₄/SiO₂ core-shell nanoparticles obtained in this study were not spherical in shape after the inclusion of Fe₃O₄ nanoparticles. This could be due to the dispersing status of magnetic nanoparticles which was related to their surface charge density and in turn directed the formation of Fe₃O₄/SiO₂ core-shell nanoparticles of various morphologies and structures [12].

Besides the sonication method, the stirring method was also being used for coating Fe₃O₄ nanoparticles with SiO₂ shell. However, this approach had failed to encapsulate all the Fe₃O₄ nanoparticles within the SiO₂ shells, as shown in Figure 2(b). This shows that sonication is an effective way for rapid coating of Fe₃O₄ nanoparticles core with the SiO₂ shells. Besides, the high speed of coating by the sonication method had prevented the oxidation and aggregation of Fe₃O₄ nanoparticles. Fe₃O₄/SiO₂ core-shell nanoparticles prepared in this study were more discrete and uniform in size as compared to that reported by Morel et al. who had also used the sonication method for coating Fe₃O₄ nanoparticles with SiO₂ shell [5]. Deng et al. had reported on the effect of reaction parameters such as the types of alcohol, the volume ratio of alcohol to water, the amount of catalyst, and the amount of precursor on the formation of Fe₃O₄/SiO₂ nanoparticles [13]. Although they were able to prepare nanoparticles of spherical shape, their preparation method was lengthy and required 12 hours of stirring. In this study, no surfactant was necessary during the formation of Fe₃O₄/SiO₂ nanoparticles. Stjerndahl et al. reported that Triton-100 was used in the emulsion method for preparing Fe₃O₄/SiO₂ core-shell nanoparticles [14]. Kobayashi et al. also reported on the need to modify the surfaces of Fe₃O₄ nanoparticles with silane coupling agent before the preparation of Fe₃O₄/SiO₂ nanoparticles [15].

3.2. Preparation of Fe₃O₄/SiO₂/TiO₂ Core-Shell Nanoparticles

TiO₂ was deposited on SiO₂ nanoparticles by the hydrolysis of TIPP precursor. Figure 3(a) shows the TEM micrograph of SiO₂/TiO₂ nanoparticles without inclusion of Fe₃O₄ nanoparticles. All of these SiO₂/TiO₂ nanoparticles were spherical in shape with rough surfaces. The direct coating of TiO₂ onto surfaces of Fe₃O₄/SiO₂ nanoparticles resulted in the formation of core-shell type structures with Fe₃O₄ nanoparticles being the cores and SiO₂ and TiO₂ are the shells (Figure 3(b)). The EDX spectrum as shown in Figure 3(c) revealed the presence of four types of elements (Si, Fe, O, and Ti). This suggested that TiO₂ was being coated onto the surfaces of Fe₃O₄/SiO₂ nanoparticles. On the basis of the above analysis and observations from TEM images, we could conclude that a thin layer of TiO₂ layer of approximately 20–30 nm in thickness had been coated onto the surfaces of Fe₃O₄/SiO₂ nanoparticles (Figure 3(b)). The overall mean diameters of Fe₂O₃/SiO₂/TiO₂ core-shell nanoparticles were approximately 140 nm.

(a)

(b)

(c)

Figure 3: TEM micrograph of (a) SiO₂/TiO₂ nanoparticles, (b) Fe₃O₄/SiO₂/TiO₂ nanoparticles, and (c) EDX spectra of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles.

Figure 4 shows the XRD pattern of Fe₂O₃/SiO₂/TiO₂ core-shell nanoparticles after calcination at 450°C in air. The broad peaks were characteristic of the SiO₂ matrix [15]. The XRD patterns also demonstrated that the apparently amorphous nature of TiO₂ coated on the surface of Fe₂O₃/SiO₂ nanoparticles. In this case, the anatase phase of TiO₂ could have been formed after heat treatment at 450°C for 3 hours [3, 8]. The BET specific surface area of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles prepared in this study was 138 m²/g, and this value was substantially higher than that of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles reported by Gad-Allah et al. at 21–54 m²/g [4].

Figure 4: XRD pattern of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles after being calcined at 450°C in air.

Figure 5 presents a photograph of the Fe₃O₄/SiO₂/TiO₂ aqueous dispersion before and after a magnet was being attached to the outside of the sample vial. Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles were observed to be attracted to the magnet being attached outside of the sample vial. The result indicated that even after coating of both SiO₂ and TiO₂ layers unto Fe₃O₄ nanoparticles, their magnetic property had remained intact. As such, these Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles could be easily recovered after their application in the aqueous medium.

Figure 5: Photographs of a vial containing (a) Fe₃O₄/SiO₂/TiO₂ core-shell aqueous dispersion and (b) when a magnet was attached to the outside of the sample vial.

3.3. Photocatalytic Properties of Fe₃O₄/SiO₂/TiO₂ Core-Shell Nanoparticles

Figure 6 shows the degradation of MB dye with and without Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles added at various duration with and without UV irradiation. It was observed that without UV irradiation, the concentration of MB dye alone remained almost constant after 24 hours. However, its concentration decreased by about 20% with UV irradiation. The degradation of MB dye was substantially enhanced by the addition of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles with its concentration being degraded by up to 70% with UV irradiation (Figure 6(d)). We can therefore conclude that the degradation of MB dye was attributed to the photocatalytic activities of the TiO₂ layer on the core-shell nanoparticles.

Figure 6: Changes in concentration of MB dye (a) alone, no UV irradiation, (b) alone, UV irradiation, (c) with Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles, no UV Irradiation, and (d) with Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles, UV irradiation.

The photocatalytic decomposition of MB dye catalyzed by Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles was further evidenced in Figure 7, which shows UV spectra of photocatalytic decomposition of MB dye with and without addition of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles, as well as with and without UV irradiation. The intensity of absorption at around 650 nm () was observed to decrease gradually over the one-hour duration of UV irradiation in the presence of Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles. The intensity of absorption of MB dye had remained the same without UV irradiation.

Figure 7: Absorption of MB dye solution (10−5 M, 20 mL), (a) alone, no UV irradiation, (b) alone, UV irradiation, (c) with Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles (5 mg) added, no UV irradiation, (30 mg) (d) Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles (30 mg) added, no UV irradiation, (e) with Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles (5 mg) added, UV irradiation, and (f) with Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles (30 mg) added, UV irradiation.

4. Conclusion

In this study, a simple and facile synthesis approach was developed for the preparation of a magnetically separable photocatalyst consisting of an Fe₃O₄ core, an SiO₂ intermediate layer, and a photocatalytically active TiO₂ shell. This synthesis method was rapid and did not require the addition of any surfactant to direct the formation of SiO₂ or TiO₂ shells. The photocatalytic activity of TiO₂ surface shell was not affected by the intermediate SiO₂ layer and Fe₃O₄ core. The Fe₃O₄/SiO₂/TiO₂ core-shell nanoparticles possessed high specific surface area of 138 m²/g and exhibited a good photocatalytic activity for the photodegradation of MB dye in aqueous solution.

Acknowledgment

This work was supported in part by the Universiti Malaysia Sarawak under the special fundamental research Grant 01(K03)/557/2005(56).

References

E. Beyers, E. Biermans, S. Ribbens et al., “Combined TiO₂/SiO₂ mesoporous photocatalysts with location and phase controllable TiO₂ nanoparticles,” Applied Catalysis B, vol. 88, no. 3-4, pp. 515–524, 2009.

A. Hanprasopwattana, S. Srinivasan, A. G. Sault, and A. K. Datye, “Titania coatings on monodisperse silica spheres (characterization using 2-propanol dehydration and TEM),” Langmuir, vol. 12, no. 13, pp. 3173–3179, 1996.

Y. Li, M. Zhang, M. Guo, and X. Wang, “Preparation and properties of a nano TiO₂/Fe₃O₄ composite superparamagnetic photocatalyst,” Rare Metals, vol. 28, no. 5, pp. 423–427, 2009.

T. A. Gad-Allah, S. Kato, S. Satokawa, and T. Kojima, “Role of core diameter and silica content in photocatalytic activity of TiO₂/SiO₂/Fe₃O₄ composite,” Solid State Sciences, vol. 9, no. 8, pp. 737–743, 2007.

A. L. Morel, S. I. Nikitenko, K. Gionnet et al., “Sonochemical approach to the synthesis of Fe₃O₄@SiO₂ core-shell nanoparticles with tunable properties,” ACS Nano, vol. 2, no. 5, pp. 847–856, 2008.

S. Santra, R. Tapec, N. Theodoropoulou, J. Dobson, A. Hebard, and W. Tan, “Synthesis and characterization of silica-coated iron oxide nanoparticles in microemulsion: the effect of nonionic surfactants,” Langmuir, vol. 17, no. 10, pp. 2900–2906, 2001.

S. Watson, J. Scott, D. Beydoun, and R. Amal, “Studies on the preparation of magnetic photocatalysts,” Journal of Nanoparticle Research, vol. 7, no. 6, pp. 691–705, 2005.

X. Song and L. Gao, “Fabrication of bifunctional titania/silica-coated magnetic spheres and their photocatalytic activities,” Journal of the American Ceramic Society, vol. 90, no. 12, pp. 4015–4019, 2007.

H. S. Yang, S. Y. Choi, S. H. Hyun, H. H. Park, and J. K. Hong, “Ambient-dried low dielectric SiO₂ aerogel thin film,” Journal of Non-Crystalline Solids, vol. 221, no. 2-3, pp. 151–156, 1997.

S. F. Chin, S. C. Pang, and F. E. I. Dom, “Sol-gel synthesis of silver/titanium dioxide (Ag/TiO₂) core-shell nanowires for photocatalytic applications,” Materials Letters, vol. 65, no. 17-18, pp. 2673–2675, 2011.

S. C. Pang, W. H. Khoh, and S. F. Chin, “Nanoparticulate magnetite thin films as electrode materials for the fabrication of electrochemical capacitors,” Journal of Materials Science, vol. 45, no. 20, pp. 5598–5604, 2010.

K. S. Rao, K. El-Hami, T. Kodaki, K. Matsushige, and K. Makino, “A novel method for synthesis of silica nanoparticles,” Journal of Colloid and Interface Science, vol. 289, no. 1, pp. 125–131, 2005.

Y. H. Deng, C. C. Wang, J. H. Hu, W. L. Yang, and S. K. Fu, “Investigation of formation of silica-coated magnetite nanoparticles via sol-gel approach,” Colloids and Surfaces A, vol. 262, no. 1–3, pp. 87–93, 2005.

M. Stjerndahl, M. Andersson, H. E. Hall, D. M. Pajerowski, M. W. Meisel, and R. S. Duran, “Superparamagnetic Fe₃O₄/SiO₂ nanocomposites: enabling the tuning of both the iron oxide load and the size of the nanoparticles,” Langmuir, vol. 24, no. 7, pp. 3532–3536, 2008.

Y. Kobayashi, S. Saeki, M. Yoshida, D. Nagao, and M. Konno, “Synthesis of spherical submicron-sized magnetite/silica nanocomposite particles,” Journal of Sol-Gel Science and Technology, vol. 45, no. 1, pp. 35–41, 2008.