ZnO:In thin films were grown from 100 mL of spray solution on glass substrates by chemical spray at Ts=400°C using solution spray rates of 0.5–6.7 mL/min. Zinc acetate and indium(III)chloride were used as Zn and In sources, respectively, with [In]/[Zn] = 3 at.%. Independent of solution spray rate, the crystallites in ZnO:In films grow preferentially in the (101) plane parallel to the substrate. The solution spray rate influences the surface morphology, grain size, film thickness, and electrical and optical properties. According to SEM and AFM studies, sharp-edged pyramidal grains and canvas-resembling surfaces are characteristic of films grown at spray rates of 0.5 and 3.3 mL/min, respectively. To obtain films with comparable film thickness and grain size, more spray solution should be used at low spray rates. The electrical resistivity of sprayed ZnO:In films is controlled by the solution spray rate. The carrier concentration increases from 2·1019 cm−3 to 1·1020 cm−3 when spray rate is increased from 0.5 mL/min to 3.3 mL/min independent of the film thickness; the carrier mobilities are always lower in slowly grown films. Sprayed ZnO:In films transmit 75–80% of the visible light while the increase in solution spray rate from 0.5 mL/min to 3.3 mL/min decreases the transmittance in the NIR region and increases the band gap in accordance with the increase in carrier concentration. Lower carrier concentration in slowly sprayed films is likely due to the indium oxidation.
1. Introduction
The wide band gap zinc oxide can be used in many applications, for example, in piezoelectric transducers, as transparent conductive layers (TCO-s), and as window layers in photovoltaic devices [1]. Various methods such as atomic layer deposition (ALD) [2], pulsed laser deposition (PLD) [3], chemical bath deposition (CBD) [4], RF magnetron sputtering [5], and chemical spray pyrolysis (CSP) [3, 6–16] have been used to deposit ZnO thin films. Among these methods, the spray pyrolysis is a versatile and cost-effective method for the rapid production of large-area metal oxide thin films.
Up to date, the effect of several technological parameters (zinc source and concentration, dopant type and concentration, solvent, growth temperature, etc.) on the properties of sprayed ZnO films have been studied [6–16] to determine the optimal deposition conditions to obtain as high electrical conductivity and optical transparency as possible. Earlier studies have shown that the preferred crystallite orientation of intrinsic ZnO and gallium- and aluminium-doped ZnO is along c-axis [8, 9, 15] while the preferred crystallite orientation of indium-doped ZnO film is (101) plane parallel to the substrate [7–9, 12, 15]. The use of Ga or Al as the dopant leads to smaller grains than the use of In as a dopant [6, 7, 9]. Additionally, the density and the optical transmittance of sprayed ZnO film is controlled by the dopant type and concentration [7]. It has been reported that an optimal growth temperature for sprayed ZnO films is in the range of 350–500°C. Independent of dopant, the optical transmittance is ca. 85% [7, 9, 17–19] while the lowest resistivities of sprayed indium-doped and gallium-doped ZnO thin films are in the order of 10-4–10-3 Ωcm [17, 18] and in the order of 10-3–10-2 Ωcm for aluminium-doped ZnO [19].
Sprayed ZnO:In thin films have been used successfully as front electrodes in thin film silicon solar cells [20] and as window layer in Cu(In,Ga)(S,Se) solar cells [21]. Our long-term goal is to study the feasibility of ITO substitution with ZnO:In, for use as the front electrode in the CSP-prepared extremely thin inorganic absorber (ETA) solar cell [22].
Among mentioned technological parameters, the solution spray rate (or solution flow rate) and its effect on ZnO thin films have received little attention. Ebothé et al. [16] studied the effect of the solution flow rate on the growth of undoped ZnO films prepared from ZnCl2 solution and reported that the solution flow rate influences the surface topology. Dedova et al. [10] concluded that the solution spray rate affects the surface morphology and roughness of undoped ZnO thin films produced by spraying Zn acetate solutions.
Recently, we showed that the electrical resistivity of chemically sprayed In-doped ZnO thin films grown at 400°C can be altered within an interval of 102–10-3 Ωcm by varying the solution spray rate [12]. In this study we will not focus on obtaining the highest electrical conductivity or optical transmittance; we study the effect of the solution spray rate on the structural, morphological, optical, and electrical properties of ZnO:In thin films deposited by chemical spray. The aim is to find the optimal solution spray rate to deposit transparent and conductive ZnO:In thin films.
2. Experimental
ZnO thin films were grown from 100 mL of spray solution that was pneumatically sprayed onto preheated soda-lime glass substrate (25×25×1 mm3). The chemical spray pyrolysis (CSP) setup is described elsewhere [23]. The spray solution consisted of Zn(CH3COO)2 · 2H2O (Merck, analytical grade, 99.5%), dissolved in a mixture of deionised water and isopropyl alcohol (2 : 3 by volume) with Zn(CH3COO)2 concentration of 0.2 mol/L. To avoid the precipitation of zinc hydroxide, a few drops of acetic acid were added to the spray solution. As a doping agent, indium(III)chloride (InCl3) was added to the spray solution with an indium to zinc atomic ratio of 3 ([In3+]/[Zn2+] = 3 at.%). Compressed air (flow rate 8 L/min) was used as the carrier gas. The glass substrate was washed with soapy water, rinsed with deionised water, and cleaned ultrasonically in ethanol. After cleaning, the substrate was dried using compressed air and placed onto a hot plate. According to the results of our previous study [12], a film growth temperature of 400°C was chosen as optimal and kept constant within ±5°C throughout the experiments using a feedback control system for the heater. The solution spray rate was varied from 0.5 mL/min to 6.7 mL/min. We verified that the solution spray rate has no effect on the growth temperature.
For a comparison, films with spray rates of 0.35 mL/min, 0.5 mL/min, and 1.5 mL/min were grown from 150 mL of spray solution on a soda-lime glass substrate to obtain films with comparable thicknesses throughout the solution spray rate range.
The structure of the films was characterised by X-ray diffraction (XRD) using a Rigaku Ultima IV diffractometer with monochromatic Cu Kα radiation (λ=1.5406Å), a tube voltage of 40 kV, and a current of 40 mA using a D/teX Ultra silicon strip detector. The crystallite size was calculated by the Debye-Scherrer method from the FWHM (full width at half maximum) of the (101) reflection of ZnO. The surface morphology of the films was characterised by scanning electron microscopy (SEM) and atomic force microscopy (AFM). SEM was performed with a Zeiss EVO-MA15 microscope at magnifications of 25000x and 50000x. AFM was performed on NT-MDT Solver 47 Pro system in tapping mode. The samples were studied over a 2 × 2 μm2 area. The grain sizes estimated from the SEM images were comparable to those measured with the AFM. The surface roughness analysis was performed according to the ISO 4287/1 standard. The root mean square (RMS) roughness was calculated over a 3 × 3 μm2 scanned surface area with an accuracy of ±0.5 nm. Image analysis (IA) was achieved using the Media Cybernetics Image-Pro 7 analysing system. The specular UV-VIS-NIR transmittance was recorded in the wavelength range of 350–2500 nm with Jasco V-670 spectrophotometer. The film thickness was calculated using the Spectra Manager software (version 2.02.00) by analysing the interference in the transmittance spectra. The film thickness calculated from the optical spectra is in good agreement (less than ±10% variance) with that obtained from the SEM images. The elemental composition of the thin films was evaluated from four different 20 × 20 μm2 areas on the film using energy dispersive X-ray (EDX) analysis with an Oxford Instruments INCA at an accelerating voltage of 7 kV. The electrical properties of the thin films (resistivity, charge carrier concentration, and mobility) were measured at room temperature using MMR’s Variable Temperature Hall System supplied with Hall, Van der Pauw Controller H-50. The contact material used for the Van der Pauw and Hall measurements was graphite.
3. Results and Discussion3.1. Structural Properties
The X-ray diffraction patterns of ZnO:In thin films deposited at various solution spray rates at 400°C are presented in Figure 1. All of the determined peaks belong to zincite (PDF card number 01-079-0208) [24]. According to Figure 1, ZnO:In film is preferably orientated in the (101) plane parallel to the substrate irrespective of the solution spray rate. Solution spray rates below 3 mL/min lead to smaller crystallites (average size of 20 nm), whereas solution spray rates above 3 mL/min result in crystallite sizes of ca. 35 nm (Table 1).
The effect of the solution spray rate on the sprayed ZnO:In film thickness (t), crystallite size (d), average grain size (D), electrical resistivity (ρ), main carrier mobility (µ), carrier concentration (n), and optical band gap (Eg). Soda-lime and borosilicate glasses are designated as Na-gl and B-gl, respectively.
Spray rate, mL/min
V, mL
Substrate
t, nm
d, nm
D, nm
ρ, Ωcm
µ, cm2/Vs
n, cm−3
Eg, eV
0.5
100
Na-gl
700
22
~100
6.3·10−2
4.4
2.3·1019
3.28
0.5
150
Na-gl
1400
26
~250
3.3·10−2
9.2
2.1·1019
3.24
0.5
150
B-gl
1350
26
*n.m.
7.8·10−2
3.9
2.0·1019
3.24
1.5
100
Na-gl
900
21
~120
1.2·10−2
7.7
6.9·1019
3.31
1.5
150
Na-gl
1400
29
~250
7.3·10−3
11
7.6·1019
3.27
3.3
100
Na-gl
1100
34
~250
3.7·10−3
16
1.1·1020
3.34
4.7
100
Na-gl
1100
35
~250
3.2·10−3
15
1.4·1020
3.36
6.7
100
Na-gl
1350
36
~250
4.6·10−3
12
1.2·1020
3.32
*n.m.: not measured.
X-ray diffraction patterns of ZnO:In thin films deposited from 100 mL of spray solution at solution spray rates of 0.5 mL/min, 1.5 mL/min, and 6.7 mL/min.
The microstructure of ZnO:In films was studied using SEM and AFM. According to the SEM study, sprayed ZnO:In films exhibit a dense inner structure and relatively smooth surface with no cracks or pinholes. The SEM surface and cross-sectional images of ZnO:In films obtained at various solution spray rates are presented in Figure 2. The surface of the film deposited at the solution spray rate of 0.5 mL/min has well-shaped prismatic grains with similar sizes of ca. 100 nm (Figure 2(a)). The surface of the film grown with the solution flow rate of 1.5 mL/min consists of grains that vary in size from 50 nm to 500 nm (Figure 2(b)). The surface structure of the film deposited with the solution spray rate of 3.3 mL/min is a network of interweaving grains (size of ca. 250 nm) resembling canvas or burlap (see Figure 2(c)). Further increase in the solution spray rate to 6.7 mL/min has a minor effect on the surface of ZnO:In thin film (Figure 2(d)).
SEM images of ZnO:In thin films deposited from 100 mL of spray solution at solution spray rates of (a) 0.5 mL/min, (b) 1.5 mL/min, (c) 3.3 mL/min, and (d) 6.7 mL/min. The cross-sectional views are presented as insets on the surface images.
The surface morphology of the ZnO:In films deposited at different solution spray rates was also characterised by AFM using images acquired over a 2 × 2 μm2 area (Figure 3). The AFM images reveal that the solution spray rate has a strong effect on the surface morphology. The surface of the ZnO:In film obtained at a solution spray rate of 0.5 mL/min (Figure 3(a)) consists of well-shaped pyramidal grains with sharp edges and tip. The mean grain size is ca. 100 nm and the grain aspect ratio (the ratio of the major axis length to the minor axis length of an equiareal ellipse) is ca. 2.0. For the ZnO:In film with solution spray rate of 1.5 mL/min, the peaks and edges of the grains are rounded (Figure 3(b)), and the grain size varied from 70 nm to 200 nm (Figure 3(b)). According to the SEM image (Figure 2(b)), some of the grains had a diameter of ca. 500 nm. According to the AFM study, the mean grain size is ca. 120 nm and the aspect ratio of the grains is ca. 1.7. In contrast, the ZnO:In films prepared at solution spray rates of 3.3 mL/min and above have more complex surface structure (Figures 3(c) and 3(d)). Using the solution spray rate of 3.3 mL/min, the film surface (Figure 3(c)) shows a fine-grain structure on top of grains with the size of ca. 200–250 nm and an aspect ratio of ca. 1.6, forming a double-layer surface. The fine-grain layer is composed of particles with an average diameter of ca. 40 nm. The surface structure of the film deposited at a solution spray rate of 6.7 mL/min (Figure 3(d)) is similar to that prepared at 3.3 mL/min (Figure 3(c)). The ca. 200–300 nm sized grains are covered by individually distinct particles with an average diameter of ca. 50 nm (Figure 3(d)).
AFM 3D images of ZnO:In films deposited from 100 mL of spray solution with solution flow rates of (a) 0.5 mL/min, (b) 1.5 mL/min, (c) 3.3 mL/min, and 6.7 mL/min (d). AFM images are of a 2 × 2 μm2 area.
0.5 mL/min
1.5 mL/min
3.3 mL/min
6.7 mL/min
Interestingly, the RMS roughness was ca. 20 nm for all sprayed ZnO:In films independent of solution spray rate and surface morphology. This RMS is similar to that reported by Dedova et al. [10] for sprayed ZnO:In films.
AFM study showed that the grain size increases with increasing solution spray rate. It is generally recognised that large grains are formed due to the recrystallisation of smaller grains. An extra phase on the grain boundaries may inhibit the growth of grains. This problem will be discussed in more detail in Section 3.2.
3.2. Electrical Properties
The resistivity, carrier concentration, and mobility of ZnO:In thin films dependent on the solution spray rate are presented in Figure 4. The films presented in Figure 4 are sprayed from 100 mL of spray solution. The resistivity of the sprayed ZnO:In films decreases from ca. 6.3·10-2 Ωcm to 3.7·10-3 Ωcm while increasing the solution spray rate from 0.5 mL/min to 3.3 mL/min, respectively (Figure 4 and Table 1). Increasing the solution spray rate from 0.5 mL/min to 3.3 mL/min increases the carrier concentration from 2.3·1019 cm−3 to 1.1·1020 cm−3 and mobility from 4.4 cm2/Vs to 16 cm2/Vs, respectively. The increase in the carrier mobility with increasing solution spray rate can be ascribed to the increased grain size from 100 to 250 nm as shown by AFM (Figure 3 and Table 1). This hypothesis is further supported by the following. The positive correlation between the carrier concentration and carrier mobility observed in our films is presented in Figure 5. A similar relation has been noted for ZnO:Al films grown by PLD [25], indicating that the conduction mechanism is driven by grain boundary scattering. Further increase in spray rate from 3.3 mL/min to 6.7 mL/min has minor effect on the electrical properties of ZnO:In thin films. The films prepared with spray rates above 3 mL/min show carrier concentrations around 1·1020 cm−3 and carrier mobilities in the range of 12–16 cm2/Vs. A minor rise in resistivity (to 4.6·10-3 Ωcm) in the film deposited at spray rate of 6.7 mL/min is attributed to lower carrier mobility of 12 cm2/Vs. Wienke and Booij [15] reported similar carrier mobility of ca. 14 cm2/Vs and concentration of 1.4·1020 cm−3 for ultrasonically sprayed ZnO:In film.
Resistivity (□), carrier concentration (Δ), and carrier mobility (○) of ZnO:In thin films deposited from 100 mL of spray solution at solution spray rates of 0.5–6.7 mL/min.
Carrier mobility versus carrier concentration of ZnO:In thin films deposited from 100 mL of spray solution at solution spray rates of 0.5–6.7 mL/min.
The films grown with the spray rates of 0.5–1.5 mL/min show carrier mobilities of 4.4–7.7 cm2/Vs that is up to three times lower than recorded for the films grown with the spray rates above 3 mL/min (Figure 4, Table 1). It is known that the carrier mobility in the film is thickness and grain size dependent [26]. To prepare films with comparable thicknesses, the ZnO:In films with spray rates of 0.5 mL/min and 1.5 mL/min were deposited from 150 mL of spray solution and as a result, films with thicknesses of ca. 1400 nm were grown (Table 1). According to SEM images in Figure 6, the shape of the grains in the thicker films is similar to that reported for the thinner films with spray rates of 0.5 mL/min and 1.5 mL/min in Section 3.1 (Figures 2(a) and 2(b)). The grain sizes of the thicker films with spray rates of 0.5–1.5 mL/min were estimated from SEM images (Figure 6). The grain size of the thicker films is ca. 2 times higher when compared to the thinner films (Figures 2(a) and 2(b)). Thus, larger grains (size of ca. 250 nm) were obtained in thicker films and that is in accordance with the literature [9, 27, 28]. The carrier mobilities increased with the film thickness from 4.4 cm2/Vs to 9.2 cm2/Vs and from 7.7 cm2/Vs to 11 cm2/Vs for films deposited at 0.5 mL/min and 1.5 mL/min, respectively. Still, the mobilities in the films deposited at spray rates of 0.5–1.5 mL/min are slightly lower than in the films grown with solution spray rates above 3 mL/min regardless of comparable thicknesses (Table 1). The decrease could be due to the larger grain size distribution (75–700 nm) in the film with spray rate of 0.5 mL/min (Figure 6(a)) compared to the film with spray rate of 3.3 mL/min (200–300 nm) (Figure 2(c)).
SEM images of ZnO:In thin films deposited from 150 mL of spray solution at solution spray rates of (a) 0.5 mL/min, and (b) 1.5 mL/min. The cross-sectional views are presented as insets on the surface images.
It can be seen from Table 1 that carrier concentration depends on the solution spray rate independent of the film thickness. The carrier concentration of ca. 2·1019 cm−3 in film grown at 0.5 mL/min is ca. 10 times lower than in films with solution spray rate above 3 mL/min (ca. 1·1020 cm−3). Moreover, a ZnO:In film with thickness of 1400 nm was grown with solution spray rate of 0.35 mL/min and the carrier concentration of the mentioned film was 6·1018 cm−3. As the carrier concentration depends on the doping level [6, 8, 15] then it is possible that part of the indium was not incorporated into the ZnO lattice at lower solution spray rates.
It could be speculated that part of the dopant source might have left the system at slow spray rates due to relatively high InCl3 vapour pressure of ca. 1.0 kPa at 400°C [29]. For this reason, the elemental composition of the films obtained with different spray rates was studied. According to EDX, the films deposited at different solution spray rates have similar elemental compositions (Table 2). Thus, the [In]/[Zn] ratio in the film is constant at varied spray rates. As the EDX measurements were performed using factory-defined standards only, the atomic percentages of the elements are not absolute values. However, EDX confirms that there is no loss of the dopant source or that the loss is similar at all solution spray rates used.
Elemental composition (in at.%) of ZnO:In thin films deposited at solution spray rates of 0.5 mL/min and 3.2 mL/min according to EDX.
Solution spray rate, mL/min
Zn
O
In
0.5
43.4
54.4
2.2
3.2
43.3
54.7
2.0
Another cause for lower electron concentration while using low solution spray rates can be the diffusion of Na to the ZnO film from the soda-lime glass substrate at 400°C during long spray process [30]. In that case, Na could create defects that reduce the concentration of free electrons. Unfortunately, EDX cannot be used to detect Na due to the overlapping peaks of Zn and Na. To overcome this problem, a thicker ZnO:In film (from 150 mL) with thickness comparable to that on a soda-lime glass was deposited onto a borosilicate substrate at 0.5 mL/min. Film with thickness of ca. 1350 nm has a resistivity of 7.8·10-2 Ωcm, carrier mobility of 3.9 cm2/Vs, and concentration of 2.0·1019 cm−3 (see Table 1). The carrier concentrations of ZnO:In films on soda-lime and borosilicate glass substrate are comparable and thus the diffusion of Na is not responsible for the lower concentration of electrons in the films with low spray rates.
As there is no difference in the dopant concentration in the films deposited at different solution spray rates and the diffusion of sodium is not the case, the lower carrier concentration in the films with lower solution spray rates could be due to the failing of In incorporation into the ZnO lattice due to the oxidation of indium source. The study of ZnO:In films structural properties supports this hypothesis, as an extra phase on the grain boundaries inhibited the grain growth at low solution spray rates (see Section 3.1).
3.3. Optical Properties
The optical transmittance spectra of the ZnO:In films grown from 100 mL of spray solution using various solution spray rates are presented in Figure 7. In the visible light region, the ZnO:In thin films show specular transmittance above 75% irrespective of the solution spray rate.
Specular transmittance of ZnO:In thin films deposited from 100 mL of spray solution at solution spray rates of 0.5 mL/min, 1.5 mL/min, and 3.3 mL/min.
For the film prepared at 0.5 mL/min or lower, the transmittance in the near infrared region (NIR) is comparable to that in UV-VIS region. The increase in solution spray rate decreases film transmittance in the NIR region and the lowest transmittance is recorded for the film with solution spray rate of 3.3 mL/min. The decrease in the optical transmittance in the NIR spectral region corresponds to the increased concentration of carriers in the films sprayed at higher solution spray rates (Table 1). According to the literature, the decrease in the transmittance of TCO films in NIR spectral region is caused by the free carrier absorption [31–33]. This has been recorded for conductive ZnO films with electron concentrations of 3·1020 cm−3 and 6·1020 cm−3 deposited by ion-layer gas reaction spray [31] and PLD [32], respectively.
The optical band gap of the films is determined from the transmittance spectra. The optical band gap values were determined from the commonly used equation
(1)αhν=A·(hν-Eg)1/n,
where A is the parameter that does not depend on the photon energy, h is the Planck constant, Eg is the band gap energy, hν is the incident photon energy, and 1/n is an exponent that depends on the nature of the optical transition (n=0.5 for direct transition). The determination of Eg from (αhν)2 versus the hν plot is shown in Figure 8 and the Eg values of ZnO:In films depending on the solution spray rate are given in Table 1. The ZnO:In film band gap increases from 3.24 eV to 3.36 eV as the solution spray rate increases from 0.5 mL/min to 4.7 mL/min, respectively. The increase in the band gap is in accordance with the increase in the carrier concentration (Table 1) and can be explained by the Burstein-Moss effect [33]. Thus, we have achieved a good agreement with the results of similar studies on ZnO [11, 13, 15, 25, 33].
Graphical determination of direct optical band gap of ZnO:In thin films deposited from 100 mL of spray solution with solution spray rates of 0.5 mL/min and 4.7 mL/min.
4. Conclusions
At constant spray solution volume, an increase in the solution spray rate results in thicker ZnO:In films with larger crystallites and grains; also the surface morphology and electrical conductivity are affected. The grains in the film with spray rate of 1.5 mL/min are roundish when compared to the sharp-edged grains in the film with spray rate of 0.5 mL/min. The surface of the films with spray rate above 3 mL/min is composed of canvas-resembling grains (size ca. 250 nm) covered with particles with the size of ca. 40–50 nm. Increasing the spray rate from 0.5 mL/min to 3.3 mL/min decreases the electrical resistivity from 6.3·10-2 Ωcm to 3.7·10-3 Ωcm as the carrier concentration increases from 2.3·1019 cm−3 to 1.1·1020 cm−3 and mobility from 4.4 cm2/Vs to 16 cm2/Vs, respectively.
To obtain films with comparable thicknesses throughout the solution spray rate range, more spray solution has to be used for films deposited at 1.5 mL/min and below. An increase in film thickness from 700 nm to 1400 nm and in grain size from 100 nm to ca. 250 nm increases the carrier mobility from 4.4 cm2/Vs to 9.2 cm2/Vs and from 7.7 cm2/Vs to 11 cm2/Vs for films deposited at 0.5 mL/min and 1.5 mL/min, respectively. Independent of the similar film thicknesses and the mean grain sizes, the mobilities in the slowly grown films are lower than in films with spray rate above 3 mL/min. Higher spray rates lead to higher carrier concentrations: spray rates of 0.5, 1.5, and 3.3 mL/min result in carrier concentrations of ca. 2·1019, 7·1019, and 1·1020 cm−3, respectively. The decreased carrier concentrations characteristic of the films with lower spray rates could be due to the oxidation of indium source that prevents indium from acting as the dopant in ZnO. Sprayed ZnO:In films with thickness of 1.1–1.4 μm transmit 75–80% of visible light. A decrease of the transmittance in NIR spectral region and an increase in band gap is characteristic of films with higher spray rate and corresponds to the increased carrier concentration in these films.
This study shows that the solution spray rate is an important technological parameter controlling the film thickness, morphology, grain size, optical properties, and electrical conductivity of the sprayed ZnO:In films. Still, the optimal spray rate should be determined for every setup to obtain films with properties required for a transparent and conductive material.
Conflict of Interests
The authors declare that they have no conflict of interests in the submitted paper.
Acknowledgments
Financing by the Estonian Ministry of Education and Research under Project SF0140092s08, the Estonian Science Foundation (ETF9081), and the European Regional Development Fund (Centre of Excellence “Mesosystems: Theory and Applications” TK114 and Project 3.2.1101.12-0023) is gratefully acknowledged. This work has been partially supported by the graduate school “Functional materials and technologies” receiving funding from the European Social Fund under Project 1.2.0401.09-0079 in Estonia.
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