Photocatalytic Characterization of Fe- and Cu-Doped ZnO Nanorods Synthesized by Cohydrolysis

Feand Cu-doped ZnO nanorods have been synthesized by a novel process employing a hydrolysis of metal powders. Zn, Fe, and Cu nanopowders were used as starting materials and incorporated into distilled water.The solution was refluxed at 60C for 24 h to obtain the precipitates from the hydrolysis of Zn and dopants (Cu and Fe).The TEM results for ZnOwith and withoutmetal doping showed that the produced powders had a rod-like shape. The rod shape was attributable to the zinc oxide from the hydrolysis of Zn. With an increasing doping content, the UV-vis spectra were shifted to a long wavelength and this result indicates that the band gap was changed by the metal doping. The values of phenol degrading Feand Cu-doped ZnO by a solar simulator were measured to be 60 and 75%, respectively.


Introduction
Zinc oxide (ZnO) powders show important applications in catalyst, surface acoustic wave devices, cosmetic pigments, varistors, ultraviolet (UV) absorbers, optical materials, gas sensors, and as window material for displays and solar cell [1].Microstructure and chemical properties of ZnO powders depend upon the synthesis method of this material.Different synthesis methods were used to fabricate ZnO particles with various sizes and morphologies.Accordingly, the synthesis of ZnO fine particles is of great importance for basic research.The size-dependent effects are correlated with the physical properties and structure of the system, for example, the size dependence of the electron-phonon coupling, the size dependence of surface luminescence of ZnO nanowires, the compressibility, and the transition pressure [2].Metaldoped ZnO is generally investigated in the form of diluted magnetic semiconductor (DMS) materials and photocatalyst, because it shows much higher Curie temperature than room temperature, along with strong stability in UV light [1][2][3].A visible-ray-active photocatalyst is very important with respect to solar energy and interior lighting applications.For practical application, it has been reported that the enhancement of photocatalytic activity can be achieved by introducing foreign metal ions into ZnO or creating oxygen vacancies with hydrogen plasma or X-ray irradiation.Thus, many scientists have been studying a method to introduce foreign metal ions, such as W 6+ , V 5+ , Cu 2+ , Fe 3+ , and into ZnO.In particular, both Fe-and Cu-doped cases have been widely examined [4][5][6][7].To obtain metal-doped ZnO powders suitable for their intended applications, the control of particular properties including chemical composition, purity, morphology, and particle size is very important.ZnO powder has various shapes such as prismatic, ellipsoidal, bipyramidal and dumbbell-like, nanowire, and nanorod by different synthesis method [1].There are several methods for the synthesis of ZnO nanopowder, such as sol-gel method, hydrothermal process, gas condensation method, and spray pyrolysis [8][9][10][11].Among them, the hydrolysis synthetic route has the advantage to simply obtain high-crystallized powders.Particularly, cohydrolysis method for preparing metal-doped ZnO nanorods is simple one-step process.This method is easily control crystallization not only of the target materials but also of dopant without any surfactants.The present paper describes the processing details to synthesize ZnO nanoflower and rods as well as their particulate morphologies such as the phase, size, and shape.We synthesized Fe-and Cu-doped ZnO nanorods using a simple process employing the hydrolysis of Zn, Fe, and Cu nanopowders, which were produced by pulsed wire evaporation (PWE) of metal wire [12].The present paper describes the processing details for the synthesis of Fe-and Cu-doped ZnO nanorods as well as the particulate properties of the produced powders such as the phase, size, and photocatalytic effect.

Materials and Methods
High purity Zn, Fe, and Cu nanopowders were synthesized using a pulsed wire evaporation (PWE) method.The Zn, Fe, and Cu nanopowders have spherical shapes and average sizes of about 80-120 nm, as shown in Figure 1.For a precondition of the hydrolysis reaction, the nanopowders were immersed into distilled water at a regular rate (Fe or Cu: 0, 2, 5, 8, 10 wt.%) and ultrasonically treated for 10 min [13,14].A small amount of acetic acid was added into the solution, where the acid played a role of promoting the hydrolysis reaction between the nanopowders and H 2 O. Hydrolysis has been carried out at 60 ∘ C for 24 h to produce the precipitation of both iron and copper doped zinc hydroxide gel.The produced gel was precipitated as ZnO powders.The precipitated powder has been drawn through filtering using a 0.2 m filter and subsequently dried in an oven at 6 ∘ C for 12 h.After that, the precipitated powders were heat treated at 300 ∘ C for 1 h [13].The particle size and morphology of the particulate samples were examined using a MTE10 transmission electron microscope (TEM) at accelerating voltages up to 300 kV.The particles were also analyzed by selected area diffraction.
To investigate the structural properties of the samples produced after the hydrolysis process, an X-ray diffractometer (RIGAKU D/MAX-3C) with Cu K radiation was carried out.The absorption spectra of the samples were recorded using a UV-visible spectrometer.The phenol degrading was measured to evaluate the photocatalytic properties using a solar simulator.The solar simulator consists of Hg-Xe lamp with a wavelength of 200∼2500 nm and 1 kWatt of power.The photocatalytic activity of the Fe-and Cu-doped ZnO nanorod was evaluated according to the photodegradation of phenol aqueous solutions under different irradiation conditions.For experiments under UV-visible light, a 100 mL 50 ppm phenol aqueous solution with 0.5 g sample powders was loaded in a glass container and stirred with a magnetic stirrer a under irradiation of a Hg-Xe lamp.Total organic carbon (TOC) values as a function of time were measured after filtration under reduced pressure [15,16].

Synthesis of Fe-and
Cu-Doped ZnO.The ZnO nanoparticles were synthesized by the hydrolysis of nanometal powders.When Zn metal particles are hydrolyzed with distilled water, the ZnO phase is formed by the following reaction [5,13,17]: After the hydrolysis reaction of the Zn nanopowder in distilled water, white precipitated materials were obtained and were found to be zinc oxide [13,14].Figure 2 shows the transmission electron microscopy (TEM) images for Fe-and Cu-doped ZnO nanorods that were synthesized by hydrolysis.The starting material of the produced Zn nanopowder is spherical with a mean size of ∼100 nm.The image shows that the produced ZnO powder has a rod-like shape with a diameter of 80 nm and a length of 200 nm, as shown in Figure 2(a).The aspect ratio of the ZnO nanorod is about 2 : 5. Figures 2(b) and 2(c) show the images for the 5 wt.%Fe-and Cu-doped ZnO nanorods prepared by hydrolysis.As for the Fe-and Cu-doped case, a rod shape with a diameter of 40 nm and a length of 270 nm is observed, in which the large aspect ratio of the shape is attributable to the hydrolysis of iron and copper.

Crystal Structure of Fe-and Cu-Doped ZnO NanoRod.
Fe-and Cu-doped ZnO nanorods (Fe = 0, 2, 5, 8, and 10 wt.%) have been synthesized by the hydrolysis of nanometal powders.Characterizations of the crystal structure for the Fedoped ZnO nanoparticles were carried out at previous studies [13].Also, characterizations of the crystal structure for the Cu-doped ZnO nanorods synthesized by the hydrolysis process were carried out by XRD and the results are presented in Figure 3.When the copper powder was cohydrolyzed with zinc in distilled water, Cu-oxides and Cu-hydroxides forms were rarely observed as shown in Figure 3.The copper were well substituted into Zn sites without changing the crystal structure [18].The sharp diffraction peaks imply the good crystallization of the samples.The positions and relative intensities of all the main diffraction peaks were in good agreement with those of the standard JCPDS card (JCPDS No. 89-1397, 89-0511, and 89-0510) of ZnO.
Infrared (IR) spectrum is an important measurement, which provides useful information about the structure of a compound.The IR spectrum shape of the ZnO powder is generally influenced by the particle size and morphology, the degree of a particles aggregation, or the crystal structure of the ZnO powder [17].Figure 4 exhibits IR spectra for the pure ZnO and Cu-doped ZnO nanopowders.In the IR region, ZnO usually shows distinct absorption bands around wave numbers of 450 cm −1 .Also, this maximum band broadens and often splits into two maxima if the particle morphology changes from a spherical to a needle-like shape, which corresponds well with the two absorption maximum bands observed at around 500 and 400 cm −1 as shown in Figure 3.The same IR spectra for the Fe-doped ZnO were observed [13].

Photocatalytic Characterization of Fe-and Cu-Doped ZnO
NanoRod.In the spectrum of the Fe 2 wt.%-dopedZnO, it is observed that the absorbance between 400 and 500 nm    begins to increase, when compared with the undoped one [13].When ZnO is doped with above 5 wt.%Fe, the spectra show that the absorption edge shifts to a long wavelength.The introduction of Fe into ZnO by substituting the Zn sites with Fe ions leads to the appearance of additional absorption bands [13].These bands are due to the transitions involving crystal field levels in the Fe ions.These transitions are observed in the Fe-doped ZnO with a doping rate of above 5 wt.% [13,14].Figure 5 shows the UV-vis spectra for the pure and Cu-doped ZnO nanorods.In the spectrum of the Cu 8 wt.%-doped ZnO, it is observed that the absorbance between 400 and 500 nm begins to increase.When ZnO is doped with above 10 wt.% Cu, the spectra show that the absorption edge shifts to a long wavelength.The introduction of Cu into ZnO by substituting the Zn sites with Cu ions leads to the appearance of additional absorption bands involving crystal field levels in the Cu ions [16,17].The transitions are observed in a doping rate of above 8 wt.%. Figure 6 shows the photomineralization of phenol with UV-visible light (solar simulator) in the presence of Fe-doped ZnO.Obviously, Fe-doped ZnO shows higher activity for a degradation of phenol in an aqueous solution compared to pure ZnO.ZnO nanorods did not significantly change the total organic carbon value under sunlight irradiation.When ZnO is doped above 8 wt.% Fe, the total organic carbon (TOC) value was reduced to 60%.
Figure 7 shows the photocatalytic effect of Cu-doped ZnO in phenol under UV-visible light (solar simulator).Cu-doped ZnO shows higher activity for a degradation of phenol in an aqueous solution compared to pure ZnO.The introduction of Cu into ZnO by substituting the Zn sites leads to the additional absorption bands.This additional absorption bands played a role of increasing photocatalytic activity.When ZnO is doped from 2 to 8 wt.%, the TOC value was reduced to 50%.The largest reducing value of the TOC, 75%, was observed at 10 wt.% Cu-doped ZnO.This results well correspond to UV-vis spectra.Both Feand Cu-doped ZnO show higher degradation of phenol in an aqueous solution compared to pure ZnO, because of enhanced absorption threshold of UV-visible light.

Conclusions
In conclusion, Fe-and Cu-doped ZnO nanorods have been synthesized using a simple process employing the hydrolysis of Zn, Fe, and Cu nanopowders.TEM result showed that the produced samples had a rod shape.The acetic acid was a key material for the hydrolysis reaction of Zn metal powder with a thin oxide surface layer.With increasing doping contents, the UV-vis spectra were shifted to a long wavelength and the substitution of Cu 2+ and Fe 3+ into Zn 2+ led to the appearance of additional absorption bands.Both Fe-and Cu-doped ZnO show higher degradation of phenol in an aqueous solution compared to pure ZnO.

Figure 6 :
Figure 6: Photomineralization of phenol with sunlight (TOC: total organic carbon content at times) in the presence of Fe-doped ZnO.(Hg-Xe lamp with a wavelength of 200∼2500 nm and 1 kWatt of power).

Figure 7 :
Figure 7: Photomineralization of phenol with sunlight in the presence of Cu-doped ZnO.(Hg-Xe lamp with a wavelength of 200∼ 2500 nm and 1 kWatt of power).