Application of Multiwalled Carbon Nanotube Nanofluid for 450 W LED Floodlight

Overheating of the high-power light emitting diode (LED) has a dramatic effect on the chip’s lifetime. Heat dissipation for highpower LED is becoming a major challenge for researchers and technicians. Compared with the air cooling method, the liquid coolingmethod hasmany advantages and high efficiency because of higher specific heat capacity, density, and thermal conductivity. Carbon nanotubes with remarkable thermal properties have been used as additives in liquids to increase the thermal conductivity. In this work, multiwalled carbon nanotubes nanofluid (MWCNTs nanofluid) was used to enhance heat dissipation for 450W LED floodlight. MWCNTs nanofluid was made by dispersing the OH functionalized MWCNTs in ethylene glycol/water solution. The concentration of MWCNTs in fluid was in the range between 0.1 and 1.3 gram/liter. The experimental results showed that the saturated temperature of 450W LED chip was 55C when using water/ethylene glycol solution in liquid cooling system. In the case of using MWCNTs nanofluid with 1.2 gram/liter of MWCNTs’ concentration, the saturated temperature of LED chip was 50.6C. The results have confirmed the advantages of the MWCNTs for heat dissipation systems for high-power LED floodlight and other high power electronic devices.


Introduction
In recent years, the problem of heat dissipation with features and strengthening functions of products has become more significant.Many approaches can improve the cooling system performance.The most feasible one is to enhance the heat transfer (dissipation) performance through the working fluid without modifying the mechanical designs or key components of the system.Recent studies have shown that the thermal conductivity of the suspension which contains suspended metallic or nonmetallic nanoparticles can be much higher than that of the base fluid, and it was called as "nanofluid" [1,2].On this basis, adding certain kinds of nanomaterials into base fluid is considered to be a novel approach to enhance the thermal conductivity in heat transfer medium [3].Results showed that the thermal conductivity enhancements of nanofluids could be influenced by multifaceted factors including the volume fraction of nanoparticles, the tested temperature, thermal conductivity of the base fluid, nanoparticles size, pretreatment process, and the additives of the fluids [4,5].
Carbon nanotubes (CNTs) have attracted much attention because of their unique structure and remarkable mechanical, thermal, and electrical properties [6][7][8][9][10].CNTs have been used as additives in liquids to increase the thermal conductivity, one of the most important issues in industry [11].Owing to their very high thermal conductivity (2000 W/m⋅K compared to thermal conductivity of Ag 419 W/m⋅K) [12,13], CNTs become one of the most suitable nanoadditives to fabricate the nanofluid for thermal dissipation in many industrial  and consumer products [14,15].In this paper, we present the results on application of multiwalled carbon nanotube nanofluid (MWCNTs nanofluid) for 450 W LED floodlight.

Experiment
MWCNTs were produced at the IMS by thermal CVD technique on solid catalyst in a gas mixture of acetylene, hydrogen, and nitrogen.The diameter and length of the grown MWCNTs were in the range 15 nm-90 nm and several ten m, respectively [16].The stability of carbon nanotubes in fluids can be increased by introducing hydroxyl groups onto the surface of CNTs [17].Process for functionalization of the MWCNTs with hydroxyl functional group (-OH) was shown in Figure 1 with the following steps [16].
Step 1. MWCNTs were treated in the mixture of hot acid (HNO 3 : H 2 SO 4 in ratio 1 : 3) at 60 ∘ C in 6 h.
Step 2. The suspension obtained in Step 1 was dried in argon atmosphere at 80 ∘ C for 24 h.
Step 3. The mixture obtained in Step 2 was treated in the thionyl chloride (SOCl 2 ) to obtain MWCNTs-COCl.
Step 4. The MWCNTs-COCl was filtered in hydrogen peroxide (H 2 O 2 ) and dried in argon atmosphere at 80 ∘ C for 24 h to obtain MWCNTs-OH.
The ethylene glycol/distilled water solution (EG/DW solution) was prepared by heat-magnetic stirring at 50 ∘ C and 6.5 rps (rounds per second) in 60 minutes.The percent by volume of ethylene glycol in EG/DW solution was 45%.In order to disperse MWCNTs-OH in EG/DW solution, we used the Tween-80 surfactant and Hielscher Ultrasonics vibration instrument.The MWCNTs-OH was dispersed in EG/DW solution with concentration from 0.1 to 1.3 g/L to obtain MWCNTs nanofluid.The prepared MWCNTs nanofluid had good stability by using functionalized carbon nanotube and the Tween-80 surfactant.This was caused by a hydrophobicto-hydrophilic conversion of the surface nature due to the generation of a hydroxyl group, and the Tween-80 surfactant provides lower surface tension of liquids and increases immersion of CNTs [17][18][19].
We develop a heat dissipation system using MWCNTs nanofluid for a 450 W LED floodlight.Figure 2 is the schematic view of the heat dissipation system for 450 W LED floodlight using the MWCNTs nanofluid.
In Figure 2, the aluminum heat-sink was set to directly contact the 9 LED chips; the tracks inside the aluminum heat-sink were fabricated to allow fluid flows through it and absorb heat from the LED chips.The MWCNTs nanofluid was pumped into the aluminum heat-sink with 3 cm 3 /s of flow rate.The pump power consumption of cooling system was 1.8 W. The dimension and power consumption of fan were 120 × 120 × 38 mm and 3.6 W, respectively.The volume of the liquid tank was 500 mL.The heat radiator was made by aluminum material, and dimensions of heat radiator were  The environmental temperature was kept at 20 ∘ C for all measurements by using air conditioner.The temperature of LED chip was directly measured by using an attached temperature sensor and WH7016E Electronic Digital Temperature Controller.

Results and Discussions
The existence of carboxyl (COOH) and hydroxyl (OH) functional groups bonded to the ends and sidewalls of the CNTs was demonstrated by Raman and Fourier transform infrared (FTIR) spectra.Raman scattering is a powerful technique to probe the changes of surface and structure of MWCNTs.The Raman scattering spectra were clearly seen such that the two bands around 1583.10 and 1333.69 cm −1 in the spectra were assigned to the tangential mode (Gband) and the disorder mode (D-band), respectively.The Dband intensity was increased in the functionalized MWCNTs compared to pristine MWCNTs.The peak intensity ratio (I D /I G ) at D-band and G-band of 0.99 and 1.87 corresponding to MWCNTs-COOH and MWCNTs-OH exceeded those of pristine MWCNTs (I D /I G = 0.79).The intensity ratio of D lines and G lines is different, suggesting some changes of the surface and structure of MWCNTs.This result indicates that some of the sp 2 carbon atoms (C=C) were converted to sp 3 carbon atoms (C-C) at the surface of the MWCNTs after the acid treatment in HNO 3 /H 2 SO 4 .The intensity ratio of MWCNTs-OH is higher than that of MWCNTs-COOH indicating that by two chemical treatment processes, the new defects were formed on the surface of MWNCTs [20].
The typical FTIR spectrum of MWCNTs-COOH shows some important peak after MWCNT was treated by mixture of H 2 SO 4 and HNO  showed the existence of vibration of C=O bonding in carboxyl group.This exhibits the importance of proving the existence of carboxyl (COOH) functional groups that appeared due to the oxidation resulting from nitric and sulfuric acids.It clearly shows that the kinds of acids functionalized the surface of MWCNTs.The FTIR transmittance spectra of MWCNTs-OH show that the peak of conjugated O-H stretching vibration mode appeared at 3431.81 cm −1 , and the central position of O-H peak shifted to a lower frequency as well; the expansion of vibration peak and the disappearance of vibration peak of C=O bonding at 1707.31 cm −1 indicated the generation of hydroxyl groups on surface of MWCNTs [20].
In order to evaluate the dispersion of MWCNTs-OH in EG/DW solutions, we used the Malvern Zetasizer Nano ZS Instrument. Figure 4 is the spectra of the MWCNTs-OH size distribution in EG/DW solutions by number with 10 minutes of ultrasonication.Line (a) in Figure 4 showed that immediately after the ultrasonication, the MWCNTs-OH was still gathering into large bundles with two peaks at 437 nm and 93.5 nm.The 437 nm peak was corresponding to the large bundles of MWCNTs-OH, whereas the 93.5 nm peak was corresponding to the individual of the MWCNTs-OH in EG/DW solutions.In order to remove large bundles from EG/DW solutions, the solutions were settled in 72 hours.Line (b) in Figure 4 showed that after 72 hours from the ultrasonication, the 437 nm peak disappeared, which means that there were no longer large bundles of MWCNTs-OH in EG/DW solutions.However, the MWCNTs were still gathering into small bundles with the size distribution from 70 nm to 170 nm. Figure 5 was the spectra of the MWCNTs-OH size distribution in EG/DW solution by number with 20, 30, and 40 minutes of sonication.In the case of 20 minutes of ultrasonic vibration time (showed as line (a) in Figure 5), the spectra of the MWCNTs-OH size distribution by number were from 18 nm to 95 nm.This result showed that MWCNTs-OH was better dispersed in EG/DW solutions with 20 minutes of ultrasonic vibration time.However, the range of spectra did not match with 15-90 nm of the diameter of MWCNTs-OH.In the case of 30 minutes or 40 minutes of ultrasonic vibration time, the MWCNTs-OH was well dispersed in EG/DW solutions shown as line (b) and line (c) in Figure 5.The spectra of the MWCNTs-OH size distribution by number in line (b) and line (c) matched with 15-90 nm of the diameter of MWCNTs-OH.The results showed that the ultrasonic vibration time more than 30 minutes is required for well dispersion of MWCNTs-OH in EG/DW solutions, so we chose 30 minutes of ultrasonic vibration time for all subsequent experiments [20]. 2 times.Thus, the lifetime of LED was estimated as the following expression: where  0 , L, and Δ indicated the basic-lifetime, the extended-lifetime, and the temperature reduction of LED, respectively.Thus, the extra-lifetime percent of LED is determined by the expression: From ( 2), the extra-lifetime percent of LED was estimated as shown in Figure 8.It clearly showed that the lifetime of LED is extended when the CNTs concentration is increased.The extra-lifetime percent of LED reached a saturated value at 33% with 1.2 g/L of CNTs concentration.The extra-lifetime percent of LED almost did not increase with 1.3 g/L of CNTs concentration.Thus, we have chosen 1.2 g/L for the optimal concentration of CNTs for the 450 W LED floodlight.

Conclusions
The heat dissipation efficiency of the 450 W LED floodlight using the MWCNTs nanofluid was examined and evaluated.The temperature of the LED chip was saturated after 40 minutes of working time.By mixing CNTs-OH with 1.2 g/L of concentration in the nanofluid, the saturated temperature of LED chip decreased by 4.5 ∘ C compared to fluid without CNTs.The extra-lifetime percent of LED also reached a saturated value at 33% with 1.2 g/L of optimal CNTs concentration.The experimental results have confirmed the advantage of the MWCNTs based liquid in heat dissipation for 450 W LED floodlight and other high-power electronic devices.

Figure 1 : 2 Figure 2 :
Figure 1: Process for functionalization of the MWCNTs with hydroxyl functional group.

Figure 3 :
Figure 3: Scheme (a) and real image (b) of aluminum heat-sink with 9 LED chips.

Figure 4 :Figure 5 :
Figure 4: Spectra of the MWCNTs-OH size distribution in EG/DW solutions by number with 10 minutes of ultrasonication time: (a) immediately after the sonication; (b) 72 hours after the sonication.

Figure 6 Figure 7 :Figure 8 :
Figure 7: The temperature of 450 W LED floodlight measured as a function of operation time with different concentrations of CNTs in nanofluid.