Cauliflower-Like Co 3 O 4 / Three-Dimensional Graphene Composite for High Performance Supercapacitor Applications

Cauliflower-like Co 3 O 4 /three-dimensional (3D) graphene nanocomposite material was synthesized by a facile two-step synthesis route (heat reduction of graphite oxide (GO) and hydrothermal synthesis of Co 3 O 4 ). The phase composition, morphology, and structure of the as-obtained products were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD). Electrochemical properties as supercapacitor electrode materials were systematically investigated by cyclic voltammetry (CV) and constant current charge-discharge tests. It was found that the Co 3 O 4 /3D graphene composite showed a maximum specific capacitance of 863 F g, which was obtained by means of CVs at a scan rate of 1mV s in 6M KOH aqueous solution. Moreover, the composite exhibited improved cycling stability after 1,000 cycles. The good supercapacitor performance is ascribed to the combination of 3D graphene and cauliflower-like Co 3 O 4 , which leads to a strong synergistic effect to remarkably boost the utilization ratio of Co 3 O 4 and graphene for high capacitance.


Introduction
With the impending energy crisis, the concerns about the environment are increasing.The research on alternative energy conversion and storage systems which have high efficiency, low cost, and environmental benignity is urgently called for.Supercapacitors, also known as electrochemical capacitors or ultracapacitors, have been intensively investigated in the fields of energy storage and conversion [1,2].Compared with the conventional capacitors and secondary batteries, supercapacitors can provide high power density, strong cycle stability, and remarkable pulse charge-discharge properties [1][2][3][4][5].They are being employed in different applications [1,[6][7][8], such as mobile electronic devices, backup power supplies, and hybrid electric vehicles.The chargestorage mechanism in supercapacitor is usually electrical double-layer and Faradic capacitor [7,9].The electrical double-layer capacitor (EDLC) roots in charge separation at the electrode/solution interface, whereas the Faradic pseudocapacitance arises from the reversible redox reactions occurring within the supercapacitor electrode material [10,11].As the core component of supercapacitors, electrode material plays an important role in determining the performance of electrochemical capacitors.Recently, tremendous attention has been focused on the development of new materials for supercapacitor electrodes with higher specific capacitance and better cyclic life whilst using environmentally benign materials in easily processable ways.
Among the major materials studied for pseudo-capacitor electrodes, transition metal oxides, such as RuO 2 [12], InO 2 [13], NiO [14], MnO 2 [15], Co 3 O 4 [16,17], and SnO 2 [18], have attracted much attention due to their high theoretical capacities and promising potential.RuO 2 is known as an ideal electrode material for supercapacitors, which shows outstanding electrochemical properties.In some reports, the specific capacitance (SC) of RuO 2 , which has a higher conductivity than carbon materials and remarkable stability, shows as high as 720-768 F g −1 [19,20].However, the high cost and toxic nature of ruthenium substantially limits its commercial application [21].Hence, the relatively inexpensive metal oxides have been studied widely.Among them, cobalt oxide is considered as a promising electrode material for supercapacitors due to its relatively low cost, well-defined redox behavior, ultrahigh theoretical SC (∼3560 F g −1 ), and environmental friendliness [22,23].For instance, it has been reported that the CoO  xerogels thermally treated at 150 ∘ C showed a good capacitive behavior with a SC value of 291 F g −1 [24].Tummala et al. [7] have synthesized nanostructured Co 3 O 4 by plasma spray technique and studied its capacitance properties.The results showed a high SC value of 162 F g −1 in 6 M KOH electrolyte.
Graphene, as a new carbon material, has attracted much attention since it was isolated from layer-by-layer graphite in 2004 [25].It is a promising electrode candidate for EDLCs due to its superb characteristics including the excellent mechanical strength and chemical stability, high electrical and thermal conductivity, and large surface area (a theoretical value of 2630 m 2 g −1 ) [25].But the serious agglomeration and restacking between individual graphene sheets result in limited surface utilization percentage and a lower capacitance than the anticipated value [26].In our recent work [27,28], three-dimensional (3D) graphene (strictly speaking, it should be reduced graphene oxide (RGO), but it is still called graphene here for convenience) was acquired by heat reduction of graphite oxide in vacuum, which has a higher specific surface area (487 m 2 g −1 ).Different from Dong's work [29], it has a predominant mesoporosity which centers at 4 nm, and these mesopores can provide a high specific surface area while allowing good mass transport in an electrode process [30].
Recently, many researchers have constructed a graphenebased metal oxide composite structure [17,[31][32][33][34].It was found that these composites showed improved performance with higher electron transport rate, electrolyte contact area, and structural stability.It can be attributed to the special composite structure in which metal oxides are attached on the surface or intercalated into the interlayer of large patches of graphene [31].Yan et al. [17] reported that graphene nanosheet (GNS)/Co 3 O 4 composite has a maximum specific capacitance of 243.2 F g −1 at a scan rate of 10 mV s −1 in 6 M KOH aqueous solution.However, the composite of 3D graphene which was reported in our previous work [27] and Co 3 O 4 has never been investigated so far.Herein, a facile hydrothermal strategy was proposed to deposit cauliflowerlike nanostructured Co 3 O 4 on 3D graphene nanosheets.Cyclic voltammetry (CV) and galvanostatic charge-discharge measurements were used to assess the electrochemical properties of the Co 3 O 4 /3D graphene composite in KOH solutions.Graphene oxide was prepared from nature graphite by a modified Hummers' method.3D graphene material was obtained by reducing graphite oxide powder in a glass bottle under vacuum followed by heating to 250 ∘ C from room temperature [27].

Experimental
Co 3 O 4 /3D graphene composite was synthesized as follows.First, 15 mg of 3D graphene was dispersed in 15 mL ethanol with the assistance of ultrasonication for 60 min.Then, 0.5 mmol Co(NO 3 ) 2 ⋅6H 2 O and 34 L of 37% ammonia were added to the 3D graphene suspension simultaneously.The as-obtained mixture was magnetically stirred for 20 min.After that, the above suspension was loaded into a 25 mL of Teflon-lined stainless steel autoclave and heated at 170 ∘ C for 5 h.The obtained black products were washed by centrifugation for several times using ethanol and deionized water to remove excess ions and then dried in a vacuum oven at 60 ∘ C. Afterwards, the material was calcined at 350 ∘ C for 3 h in air and then cooled to room temperature.For comparison, Co 3 O 4 was also prepared by the same steps without the addition of 3D graphene.

Characterization Methods.
The crystallographic structures of the samples were determined by X-ray diffraction system (XRD, X' Pert-PRO MPD) equipped with Cu K  ( = 1.5406Å) radiation.The morphological analysis was conducted using scanning electron microscope (SEM, JEOL JSM-6700F) and transmission electron microscope (TEM, JEOL JEM-2011, 200 kV).The specific surface area and pore volume of the samples were determined by analyzing the standard nitrogen adsorption isotherm measured at 77 K.An electrochemical workstation system (CHI760D, Chenhua, Shanghai) was employed to study the electrochemical properties.The electrodes were fabricated by mixing 80 wt% active materials, 15 wt% acetylene black, and 5 wt% polyvinylidene fluoride (PVDF) as binder.The mixtures were well blended using alcohol, coated the paste onto nickel foam current collectors (1 cm × 1 cm), were dried at 100 ∘ C for 10 h, and were pressed under 20 MPa for 3-5 min.Each electrode contains 2-3 mg active materials.A conventional three-electrode system was employed to investigate the capacitive behaviors.Platinum foil and Hg/HgO (1 M KOH aqueous solution) electrodes were used as the counter and reference electrodes, respectively.

Structure and Morphology of the Samples.
The XRD patterns of 3D graphene, Co 3 O 4 , and the as-prepared composite before and after calcination were shown in Figure 1.For 3D graphene, a broad peak was observed at 25.6 ∘ , which is attributed to the C (002) plane [31,35].The main peaks in the XRD pattern of pure Co  assigned to the crystal planes of (111), ( 220), (311), (400), (511), and (440) [36].From Figure 1(c), it can be found that the XRD pattern of the as-prepared composite before calcination does not show any other peak except a broad hump at 2 of about 25.6 ∘ which is attributed to the diffraction peak of C (002) in 3D graphene [35].However, several peaks appear at 2 of around 19 ∘ , 31 ∘ , 37 ∘ , 45 ∘ , 59 ∘ , and 65 ∘ obviously in the XRD pattern after calcination.These diffraction peaks are assigned to the crystal planes of (111), (220), (311), (400), (511), and (440), which agree with the typical spinel Co 3 O 4 [36].Thus, the chemical reactions in the synthetic process are supposed as follows: The absence of diffraction peaks of Co(OH) 2 in Figure 1(c) may result from the amorphous state of Co(OH) 2 .It is inferred that the composite before calcination consists of Co(OH) 2 and graphene.Additionally, from the XRD pattern of the composite after calcination, the characteristic peak of 3D graphene for C (002) is also found.Based on these results, the asobtained calcinate material can be undoubtedly identified as Co 3 O 4 /3D graphene composite.Moreover, it is notable that the C (002) peaks in Figures 1(c) and 1(d) shift toward left as compared to that in Figure 1(a), which indicates that Co(OH) 2 and Co 3 O 4 may lead to the increase of the unit cell volume of graphene because the shift of entire diffraction peaks toward lower 2 usually suggests the increase of unit cell volume.
The morphology of the as-prepared materials was investigated by SEM, as shown in Figure 2. The graphene material has a 3D structure composed of homogeneous micrometer-sized flakes (Figure 2(a)).Moreover, according to our previous work [27], the 3D graphene material has mesoporosity centered at 4 nm, demonstrating that it belongs to mesoporous materials.Figure 2(b) shows the SEM image of the composite before calcination (i.e., the precursor of Co 3 O 4 /3D graphene composite).It can be seen that the graphene skeleton maintains structural integrity except that the Co 3 O 4 particles are distributed over the graphene surface.After the calcination treatment, it seems that the morphology and structure are similar to those of the precursor of the composite (Figure 2(c)).The high-magnification SEM image in Figure 2(d) reveals that many small Co 3 O 4 granules agglomerated together to form some big circular particles with nonuniform diameters from 50 to 250 nm.However, from Figures 2(e 3(d), it can be found that the big spherical Co 3 O 4 particles in the composite are composed of numerous assembled nanoparticles with a size of 10-25 nanometers, and these small nanoparticles assemble together to display cauliflower-like morphology.This can lead to abundant pore structures, which is beneficial to the electrochemical utilization of metal oxides and the passing of the ions in the electrolyte.Additionally, the HRTEM image of the composite is presented in the inset of Figure 3(d).The Co 3 O 4 exhibits high crystallinity and the lattice spacing of 0.26 nm is corresponding to the interspacing of the (311) planes [35].
Nitrogen isotherms of Co 3 O 4 and Co 3 O 4 /3D graphene composite are presented in Figure 4.It is interesting to see that the composite adsorbs much more N 2 than pure Co 3 O 4 .It suggests that the structural characteristics change greatly after the addition of 3D graphene.The BET surface area increases from 0.111 to 69.7 m 2 g −1 while the pore volume increases from 0.0016 to 0.17 cc g −1 .This is the normal sequence since 3D graphene possesses a large specific surface area and pore volume, and the cauliflower-like morphology of Co 3 O 4 in the composite further contributes to the surface area and pore volume.

Electrochemical Properties.
For potential supercapacitor applications, the capacitor behaviors of the electrodes were examined.

Cyclic Voltammetry (CV)
The SC of the electrode, based on CV curves, can be calculated as where  is the SC of electroactive materials (F g −1 ),  is the response current (A),  is the potential (V), ] is the potential scan rate (V s −1 ), and  is the mass of the electrode materials (g).According to ( 5), the SCs of the Co 3 O 4 /3D graphene composite, Co 3 O 4 , and 3D graphene electrodes are calculated to be about 457, 134, and 97 F/g at a scan rate of 10 mV s −1 , respectively.If the SCs are represented by volumetric capacitance, these values are 965, 335, and 103 F/cm 3 , respectively.Clearly, the SC of the composite is not simple sum of Co 3 O 4 and 3D graphene but significantly larger than expected.Moreover, the SC value is much higher than that of a Co 3 O 4 /reduced graphene oxide scrolled structure (163.8F/g) reported recently [31].The desirable performance could be attributed to the synergistic effect between graphene sheets and Co 3 O 4 nanoparticles in the nanocomposite [37].This effect may be associated with the fact that conductive graphene is hydrophobic, while Co Additionally, as compared to twodimensional (2D) graphene which has been reported [38], 3D graphene has a much higher specific surface area (487 m 2 g −1 ) and larger pore volume (1.04 cc g −1 ) [27].The 3D graphene has predominant mesoporosity which centers at 4 nm, which is in favor of improving the electrochemical accessibility of electrolyte ions and providing preferable EDLCs [30].
Both the pseudocapacitance derived from the cauliflower-like Co 3 O 4 and the superior surface and pore properties of 3D graphene contribute to the high capacitance.the SC values of the composite decrease gradually with the increase of scan rate.This may be because, at high scan rates, diffusion limits the movement of electrolyte ions due to the time constraint, and only the outer active surface is utilized for charge storage.At lower scan rates, however, all the active surface area can be utilized for charge storage and the electrochemical utilization of Co 3 O 4 [39].As shown in Figure 5(b), 6 M electrolyte provided the largest SC values.
The maximum SC value is 863 F g −1 in 6 M KOH electrolyte at a scan rate of 1 mV s −1 .According to the equations of the electrochemical reactions of Co 3 O 4 in alkaline electrolyte, there is OH − in the reactions.Thus, a high concentration of hydroxyl ions is in favor of increasing the reaction rate.This results in the largest SC value in 6 M KOH solution.

Galvanostatic
Charge-Discharge Measurement.Furthermore, galvanostatic charge-discharge measurement was utilized to study the capacitor performance of the as-prepared samples.Figure 6 depicts the charge-discharge behaviors of Co 3 O 4 , 3D graphene, and the Co 3 O 4 /3D graphene composite electrodes between 0 and 0.5 V at a constant current density of 5 A g −1 in 1 M KOH aqueous solution.From the charge-discharge curves of 3D graphene, it is evidently seen that the voltage decreases linearly along the discharge time, which shows an ideal double-layer capacitive behavior.However, the discharge curve of Co 3 O 4 /3D graphene composite consists of a slow potential drop from 0.5 to 0.2 V and a sudden potential decay from 0.2 to 0 V.The latter indicates short charge/discharge duration, which is a pure double-layer capacitance behavior from the charge separation at the electrode/electrolyte interface.However, the former is a typical pseudocapacitance behavior, caused by electrochemical adsorption/desorption or a redox reaction at the electrode/electrolyte interface [40].Usually, Faradaic redox reaction is accompanied by the double-layer chargedischarge process, and thus the combination of electric double-layer capacitance and Faradaic pseudocapacitance is responsible for the longer charge/discharge duration [17].
From the discharge curves, SC could also be calculated using the following equation: where  is the SC of the active materials (F g −1 ), , Δ, Δ, and  are constant discharge current (A), discharge time (s), the voltage change after a full discharge (V), and the mass of the active material (g), respectively [41].The SC values calculated from the galvanostatic charge and discharge curves are 40, 46, and 337 F g −1 for 3D graphene, Co 3 O 4, and the composite, respectively, which are similar to the trend of those calculated from CVs.A larger specific capacitance value of 402 F g −1 for the composite is obtained at 0.5 A g −1 .The much larger SC value of the composite than the sum of that of graphene and pure Co 3 O 4 further proves that the combination of 3D graphene and cauliflower-like Co 3 O 4 is very beneficial to improving the supercapacitor performance.Subsequently, the galvanostatic charge-discharge properties of the composite are investigated with different current density in different concentration of KOH electrolytes.The SC values are calculated in accordance with (6) and listed in Table 1.It is found that the SC of the electrode based on the as-prepared composite reached a maximum value of 522 F g −1 in 6 M KOH electrolyte at the current density of 0.5 A g −1 .
The results are similar to the results obtained from the CVs, further indicating that a high concentration of hydroxyl ions is in favor of increasing the reaction rate.
To investigate the cycling performance of the Co 3 O 4 /3D graphene composite, the charge-discharge tests were performed at 2 A g −1 for 1,000 cycles.Figure 7 shows the results of cycling stability measurement.After 1,000 cycles, the specific capacitance of the Co 3 O 4 /3D graphene composite decreased apparently.An initial total capacitance of 75% was retained after the 1000th discharge cycle.The decay of capacitance can be ascribed to the increased impedance with increasing number of cycles, and it is inferred that the increased impedance could be due to fatigue of the active material during cycling [7].As compared to some nanostructured Co 3 O 4 electrodes reported recently [7], the retention rate of capacitance of the Co 3 O 4 /3D graphene composite was improved a little, which may be attributed to the special structure of 3D graphene and cauliflower-like Co 3 O 4 .During cycling, the three-dimensional nanoporous structure of 3D graphene, as well as the cauliflower-like morphology of Co 3 O 4 , can inhibit the volume change and detachment of Co 3 O 4 particles more effectively and thus result in a better cyclic life.

Conclusions
In this work, a Co 3 O 4 /3D graphene composite was synthesized via a facile two-step synthesis route (heat reduction  of GO and hydrothermal synthesis of Co 3 O 4 ).SEM and TEM images showed that, in the composite, many small nanoparticles with a size of 10-25 nm assemble together to display cauliflower-like morphology.The supercapacitor performance of the composite, 3D graphene, and Co 3 O 4 was investigated and compared by CV and constant current charge-discharge tests.It was found that the composite showed much larger specific capacitance than the sum of that of 3D graphene and Co 3 O 4 .Moreover, the composite exhibited better cycling stability.The good supercapacitor performance is ascribed to the combination of 3D graphene and cauliflower-like Co 3 O 4 , which leads to a strong synergistic effect to remarkably boost the utilization ratio of Co 3 O 4 and graphene.The cauliflower-like Co 3 O 4 /3D graphene composite is believed to be a promising electrode material for supercapacitors.
) and 2(f), it is clearly seen that, without the addition of 3D graphene, Co 3 O 4 and its precursor display cubic morphology, and these particles have a size about 50-100 nm and were stacked irregularly.It indicates that the morphology of Co 3 O 4 in the composite material is different from that of pure Co 3 O 4 .This may be because of the effects of the electrostatic adsorption and other chemical bonds between the oxygen-containing functional groups on the surface of 3D graphene and the precursor of Co 3 O 4 .TEM images of Co 3 O 4 and Co 3 O 4 /3D graphene composite are shown in Figure 3. Figures 3(a) and 3(b) display the TEM images of pure Co 3 O 4 with different magnification.It can be found that the pure Co 3 O 4 sample is composed of a great deal of irregular cubic particles.However, Figure 3(c) reveals that, in the Co 3 O 4 /3D graphene composite, many nearly spherical Co 3 O 4 particles are attached onto 3D graphene nanosheets, which is similar to the results of SEM.Furthermore, it can be seen that the Co 3 O 4 cubic particles with a size about 50-100 nanometers are complete and solid from the inset of Figure 3(a).However, from the high magnification TEM image of Co 3 O 4 /3D graphene composite shown in Figure

Figure 5 (
a) displays the CV curves of Co 3 O 4 /3D graphene composite, Co 3 O 4 , and 3D graphene at a scan rate of 10 mV s −1 in 1 M KOH electrolyte within the potential window of −0.2-0.5 V. Evidently, the area surrounded by the CV curve is dramatically enhanced by the introduction of Co 3 O 4 nanoparticles onto 3D graphene sheets as shown in Figure 5(a).This result indicates a large specific capacitance associated with the composite electrode.The CV curves are different from the ideal rectangular shape of the typical electric double-layer capacitance.Unlike 3D graphene, two pairs of redox reaction peaks are visible in the CV curve of the composite, which can be ascribed to the redox process of Co 3 O 4 , suggesting that the capacitance mainly results from the pseudocapacitance of Co 3 O 4 .The mechanism of electrochemical reactions of Co 3 O 4 in alkaline electrolyte can be expressed as the following equations [36]:

Figure 3 :
Figure 3: TEM images of Co 3 O 4 with (a) low and (b) high magnification and Co 3 O 4 /3D graphene composite with (c) low and (d) high magnification.Inset: high resolution TEM (HRTEM) images.

3 O 4
is hydrophilic but has poor conductivity.It is very likely that Co 3 O 4 increases the graphene hydrophilicity for significantly increased utilization of the porous electrode and the conductive graphene enhances the charge transfer rate of Co 3 O 4 for higher pseudocapacitance.Furthermore, the large specific surface area and pore volume resulting from the cauliflower-like morphology of Co 3 O 4 in the composite may also increase the utilization of Co 3 O 4 and thus further enhance the pseudocapacitance.These factors result in a much larger SC value of the composite than the sum of that of 3D graphene and Co 3 O 4 .