Influence of Nanographite on Dry Sliding Wear Behaviour of Novel Encapsulated Squeeze Cast Al-Cu-Mg Metal Matrix Composite Using Artificial Neural Network

Department of Mechanical Engineering, Saveetha School of Engineering, SIMATS, Chennai, 602105 Tamil Nadu, India Department of Mechanical Engineering, K.Ramakrishnan College of Engineering, Samayapuram, 621112 Tamil Nadu, India Centre for Additive Manufacturing and Computational Mechanics, Chennai Institute of Technology, Chennai, 600069 Tamil Nadu, India Department of Mechanical Engineering, Ramco Institute of Technology, Virudhunagar, 626125 Tamil Nadu, India Department of Mechanical Engineering, National Institute of Technology, Calicut, 673601 Kerala, India Mechanical Engineering Department, Wollo University, Kombolcha Institute of Technology, Kombolcha, South Wollo, 208 Amhara, Ethiopia


Introduction
In modern society, there is an increasing demand for new hybrid composites. Particularly, the demand emphasizes lightweight alloys. Most previous studies indicate that this demand trend comes from construction price decrease, mass construction reduction, and working life increase [1]. One of the examples of the demand concerns the use of aluminium and its associated alloys to substitute steel and materials similar to the latter. Notably, the demand for aluminium alloys has arisen from the affirmation that the alloys exhibit good mechanical properties [2,3]. However, some studies caution that the alloys have poor tribological characteristics. Imperative to highlight is that tribological characteristics concern wear, lubrication, and friction of interacting surfaces, especially those found to be in relative motion [4].
The demerit of poor tribological characteristics of aluminium alloy, although lightweight materials, has paved the way for improvements. Related composite materials have been developed in a quest to steer improvements to the material tribological characteristics [3,4]. An example of composite materials is a case of Al-Si alloy (A356). Some scholarly investigations have also analyzed the information obtained from referent literature reviews concerning composite material exploitation [5]. For these studies, findings avow that the addition of specific reinforcements tends to improve the aluminium alloy mechanical characteristics [6]. Some of the reinforcements that have gained application in the quest to improve the aluminium alloy mechanical characteristics include Al 2 O 3 and SiC.
Imperatively adding some volume amounts or masses of reinforcements to the aluminium alloys has led to a problem concerning the composite material mechanical treatment [7]. To solve this problem, nanographite has been proposed as an ideal material that could be added at a certain quantity. For investigations that have examined the latter process, most of the results concur that the resultant composite's tribological characteristics, due to nanographite addition, tend to improve [6,7]. When two or more reinforcements are used to develop composite materials, the latter is translated into hybrid composite materials [8]. Some of the areas that have received attention relative to aluminium alloys and the hybrid composite tribological behaviour include electronic industry, aircraft, and automobiles. Currently, composite material production usage and annual growth lie at 6%, with the aluminium base on focus [9]. Different methods have been applied to steer the development of hybrid aluminium matrix composites (HMMC), which are mostly achieved by combining soft graphite particles and hard ceramic. Some of these methods include full factorial and response surface, analysis of covariance (ANOVA), and Taguchi [10][11][12][13][14]. The role of these methods has been to provide information regarding the possible impact of different parameters, assuming hierarchical rank orders. The methods mentioned above have tested the specific parameters: the impact of graphite or reinforcement weight percentage, the sliding speed and distance, and the normal load on hybrid AMCs' friction and wear properties [15,16]. Most of the researchers have employed the ANOVA method and an orthogonal array. For these studies, findings suggest that in dry sliding conditions, the use of graphite particles proves effective in decreasing friction and increasing the wear resistance of AMCs [17].
For hybrid Al/SiC/Gr composite materials, the tribological behaviour has been investigated. For these investigations, graphite content with 2.5 and 8 wt% and SiC content with 10 wt% have been considered. The base used has been aluminium alloy Al 2024, with the semisolid powder densification method aiding in making composites [18]. Also, the metal matrix Al-Si7Mg composite's tribological behaviour has been investigated [16][17][18][19]. The reinforcement for the latter investigation has been achieved via 10% SiC and graphite particles without lubrication. With full factorial design gaining application, the central objective has been to unearth the impact of reinforcement content in terms of sliding distance, sliding speed, load, and percentage on the wear of Al alloy/ SiC/graphite composite materials, Al alloys/SiC, and Al alloy/graphite. In the finding, these experimental studies suggest that hybrid composite material exhibits the best characteristics.
Imperative to note is that the decision to incorporate approaches such as factorial and surface response and Taguchi, which constitute the design of experiment (DOE) concepts, has been informed by the need to gain insights into the impact of different parameters, with the results obtained in terms of hierarchical rank order [20]. The techniques have also proved important by providing room for establishing correlation terms and the analysis of the parameters' combined effects [21]. Some investigations have focused on graphite (Gr) and silicon carbide (SiC) as reinforcements to understand the different behaviour of hybrid composites. For these studies, aluminium base Al 2219 has been used. The liquid metallurgy synthesis approach has been employed during the making of the hybrid composites [22]. With the Taguchi method embraced, a major focus has been to analyze the impact of reinforcement content in wt%, sliding distance, sliding speed, and normal load [20,21]. For the latter investigations, findings indicate that in wt%, where reinforcement is done via the increase of graphite content, there is likely to be an increase in the hybrid composites' resistance to wear.
Imperatively, the aluminium bases used in most previous studies have been Al 2219 and Al 2024 [22]. Also, the majority of the studies have focused on hybrid AMCs or aluminium hybrid composites under dry sliding conditions [20][21][22]. It is also worth noting that from the critical review of the current literature, the majority of the investigations have used techniques such as Taguchi and ANOVA to establish hierarchical rank orders of test parameters independently [23]. Some of the test parameters considered include the weight percentage of graphite or reinforcements, the sliding speed and distance, and the normal load. As such, most of the experiments have not focused on the combined impact that the parameters pose on wear and friction. Therefore, the main aim of the current study is to find out the tribological behaviour of aluminium hybrid composites with Al-Cu-Mg reinforced nanographite. It is also imperative to highlight that the investigation employs the Taguchi method.

Experimental Details
2.1. Materials. In this study, Al-Cu-Mg is used as the base for metal matrix composite. The squeeze casting process is used to fabricate the composite specimens. Figure 1 shows the squeeze casting machine. The materials used in squeeze casting include nanographite with each stretching to 10 nm. The experiment also involved overheating and melting the matrix alloy to ensure that it was clean of slag. The overheating and melting procedure extended to 650°C. This process preceded the compocasting procedure. Homogenous mixing was done with nanographite powders. With the process conducted in the solid state, the preheating stage that followed extended to 150°C. The procedure followed involved the cooling of the alloy matrix, which was brought down to a range of 597°C-603°C. Imperative to note is that the latter temperature range was maintained for 10 minutes. With a semisolid melt obtained, a plate mixer was introduced, followed by a five-minute isothermal stirring procedure. This procedure was set at 500 rpm. Also, a squeeze casting procedure was conducted. The procedure lasted 15 seconds, and pressure was set at 90 MPa.
The nanographite particle was filled in the metal cap and melt in a squeeze casting furnace. The novel encapsulated metal cap is shown in Figure 1. The motivation to increase the temperature was informed by the need to promote the infiltration process with the secondary phase particle addition making the semisolid matrix increase in velocity. The temperature was also increased to 610°C in response to the increasing particle amount. Figure 2 shows the Pin on Disc wear testing machine. On completing the infiltration procedure, the moving process that followed was in two stages. The initial stage lasted two minutes and was aimed at stabilizing the moving process. At this point, 1000 rpm was the rotation speed of the plate mixer. Similarly, this initial stage was marked by a restoration of temperature back to 600°C. The stage that followed was conducted in five minutes. Particularly, 1500 rpm was the rotation speed of the plate mixer, taking place in an isothermal context.
To ensure that the semisolid melts were cast successfully, the experiment employed a mold. This mold had been preheated to 500°C. Later, a special tool was set at 570°C and used to hot press the obtained castings. The hot pressing also involved a 100 MPa pressure. Particularly, commercial T6 heat treatment was the platform to which the experiment's specimens were subjected. Wear specimens are shown in Figure 3. Parameters of commercial T6 included artificial ageing and water quenching for 6 h and at 160°C, and the solution is heat-treated for 4 hr and at 540°C. Table 1 illus-trates the chemical properties or composition of the Al-Cu-Mg used.

The Case of Wear and Friction
Tests. The wear and friction tests focused on material tribological behaviour. The ASTM G77 standard governed the investigation whereby block-on-disc contact geometry dominated the procedure. Also, TPD 93, a computer-aided tribometer, formed a platform for testing the tribological behaviour. As the experiment proceeded, the thickness of discs and blocks was 6.35 mm, which marked the initial contact. Ra = 0:2 μm  On the other hand, Ra = 0:3 μm reflected the disc's surface roughness. Also, 90MnCrV8 steel was selected for the disc. The hardness of this disc stretched from 62 HRC to 64 HRC. The lubricant employed in this study involved ISO VG 46 hydraulic oil. The selection of this form of oil was informed by its recommended industrial application in situations involving high-pressure mechanical systems such as roller bearings, chain gears, and gearboxes. The submergence of the selected discs (into the oil) extended to 3 mm.
As the friction and wear tests progressed, the lubricated conditions involved five major sliding speeds. These speeds included 0.75, 1.5, and 2.25 m/s. Also, the normal loads embraced included 10, 20, and 30 N. Regarding the sliding distances, the study focused on nanographite such as 1, 3, and 5 wt% for the speeds and loads above, respectively. The choice of these ranges of normal load and sliding speed arose from their wide practical applications at roller bearings, chain gears, and gearboxes. The tribological behaviour of the selected materials have measured wear tracks, and the coefficient of friction was read continuously at the end of the respective tests. Dry sliding wear parameters and their levels are exposed in Table 2. Imperative to note is that each test or experiment was repeated thrice.

Experimental
Design: Taguchi Method. The Taguchi method is employed in controlled settings, and its purpose is to analyze the impact that process variables are likely to have on other specific variables. The specific variables under investigation are usually unknown functions of process variables. After implementing the Taguchi method, the findings are used to inform industrial designs of improved and quality systems [24]. Practically, the Taguchi method has been applied by many previous researchers to understand aluminium metal matrix composites' sliding wear behaviour. Hence, the Taguchi method supports the creation of standard orthogonal arrays responsible for accommodating the influence of different variables on target values. To study the impact of parameters on the independent variables, ANOVA was used to analyze the results and make the Taguchi method meaningful [25].
When experimental results are established after applying the Taguchi method, they are usually converted into signalto-noise (S/N) ratios. The Taguchi method incorporates statistical analyses of variance to predict optimal combinations that could be used based on the test parameters. As avowed by other studies, the latter procedure seeks to define or establish parameters that are deemed statistically significant and worth considering [26,27].
With Taguchi giving the "smaller the better" characteristics relative to the wear rate ratio (S/N), In equation (1), n represent the number of observations made while y 1 , y 2 , ⋯, y n reflect sliding wear responses. Table 3 summarizes the average of characteristics associated with various levels of experimental factors.

Results and Discussion
This study sought to establish the most significant parameters and parameter combinations that are likely to exhibit the greatest impact on the coefficient of friction and the wear rate. By establishing these parameters, the experiment would then give an insight into how their values could be reduced to the minimum. The orthogonal array governed the tests to connect the impacts of nanographite wt%, sliding speed (S), and load (L). These parameters were also used due to their capacity to define the composite tribological behaviour and important influence on this process. Tables 4 and 5 show the signal-to-noise ratio for wear rate and coefficient of friction response.

ANOVA and the Resultant Impact of Factors or
Parameters. The variance analysis (ANOVA) aided in analyzing the experimental results. ANOVA sought to give an insight into percentage factors that tend to influence the friction coefficient and wear intensity individually. Tables 6 and  7 highlight the ANOVA results. At P < 0:05, the results    Journal of Nanomaterials suggest that the interactions of the experimental factors pose a statistically significant impact on the performance measures examined. Tables 6 and 7 illustrate both the percentage influence of individual factors and the role they play in shaping the overall outcome. The values were also converted to the S/N ratio to determine the quality of characteristics. Also, the S/N ratio was established after determining the process' control factors' role on the friction and wear rate coefficient. From Tables 4 and 5, nanographite addition forms the main parameter influencing the wear rate. Those that follow include normal load and sliding speed. Similarly, nanographite addition is the main factor influencing the coefficient of friction, but sliding speed and normal load follow, respectively. The last two parameters are different from the case of the wear rate in which normal load precedes sliding speed. Hence, Tables 6 and 7 illustrate the ANOVA results relative to the composites tested, giving an insight into the friction and wear rate coefficient.
The analysis in Tables 6 and 7 shows the nanographite addition, which translates into the load and poses the   5 Journal of Nanomaterials greatest impact on the wear rate (F = 44:71). The other two factors affect the wear rate in terms of load (F = 19:31) and sliding speed or velocity (F = 10:82). The implication is that the need to pay more attention to this factor cannot be overemphasized. Figures 4 and 5 illustrate the impact of different parameters on the coefficient of friction and wear rate. In situations where a given parameter's line was closer to horizontal, it was inferred that it did not exhibit a significant impact. On the other hand, in situations where lines for certain parameters showed the highest degree of inclination, it was inferred that the effect was the most significant. Indeed, nanographite addition depicted the strongest impact on the rate of wear. Therefore, it was established that an increase in normal load tends to increase the wear rate. However, nanographite addition accompanied  Signal-to-noise: smaller is better  Journal of Nanomaterials by increased sliding speed depicted a decrease in wear rate. At the highest sliding speed, nanographite addition, and the lowest normal load, the wear rate was the lowest. From Figures 4 and 5, it was also evident that for the curve of nanographite addition, the largest slope was the most significant factor affecting the coefficient of friction. With a decrease in sliding speed and nanographite addition, the coefficient of friction was found to decrease. As the normal load increased, the coefficient of friction also increased. The interactions between the analyzed parameters and their impact on the friction and wear rate coefficient are illustrated in Figures 6 and 7. Interaction plot for SN ratios data means

Focusing on the Impact of the Test Parameters on the Coefficient of Friction and Wear Rate.
Signal-to-noise: smaller is better   Journal of Nanomaterials From the coefficients obtained in equations (2) and (3) above, the study established that when each factor was considered individually, the impact posed on the coefficient of friction and wear rate of the composites under examination differed. As the normal load increased, the coefficient of fric-tion and wear rate increased. However, the friction and wear rate coefficient decreased with an increase in nanographite content and sliding speed. The eventuality is that the models developed to predict the coefficient of friction and wear rate relative to the composites that were tested proved adequate,  (2) and (3), with the points in Figures 8 and 9 confirming this result because they lie closer to the estimated line perceived to exhibit small disintegration.

Experimental Confirmation.
Focus on the eventual impact of the control parameters examined. In this case, the role of experimental confirmation is to verify the results accruing from the Taguchi method. The experimental confirmation is also used to ensure that the quality characteristics are tested. Also, the optimal impact factor levels are used to establish values of the optimal friction coefficient and wear rate. Total error losses are considered to estimate the optimal levels. ANN mean square error and training state plot are shown in Figure 10.
Equation (4) was used to predict the optimal rate of wear rate and considered individual effects of nanographite (R), sliding speed (S), and load (L). The equation was Levels of the factors under examination were used to predict the optimal coefficient of friction. With personal effects of the respective factors governing the predicted optimal friction coefficient development, equation (5) was used: 3.5. The Case of Artificial Neural Network (ANN). In this experiment, ANN training and testing were achieved via MATLAB R2016a. From the results, this study established that a reasonably good performance arises from the trained ANN. The inference was informed by the similarity between the test and validation curves. It is also worth highlighting that the ANN training would extend to the 4 th epoch, but epoch 1 formed the point associated with optimal or the best validation performance. At this point (epoch 1), a value of 0.0078254 was obtained. On the other hand, a value of 1:8374 × 10 −9 was obtained for the case of epoch 4, illustrating a value closer to zero. Another notable trend was that as the number of epochs increased, the gradient value decreased. Table 8 summarizes the results of the confirmation experiments for the wear rate and coefficient of friction.
The regression equation was obtained upon employing the ANN output of training and ANOVA analysis before comparing the findings with experimental data. Figure 11 shows the findings after comparing the study's coefficient of friction and wear rate with the experimental data. Indeed, the analysis of the data obtained revealed that the two methods are highly reliable. Particularly, there was a close similarity between the findings established by ANN training and the experimental data. As such, the ANN was highly efficient relative to the prediction of the coefficient of friction and wear rate.
3.6. Analysis of the Worn Surface. Energy-dispersive spectroscopy (EDS) and scanning electron microscopy aided in testing and analyzing the tested composites' worn surfaces.
In most of the composites, the main mechanism of wear was similar. This dominant mechanism involves combinations of light abrasion and wiping or light adhesion identified in Figures 12(a)-12(d). Also, the backscattered electron image (BEC) aided in illustrating the morphology of the alloy, while the secondary electron image (SEI) aided in presenting the worn surface. Imperative to highlight is that the EDS analysis revealed the presence of nanographite particles.
Over the worn surface, the particles were randomly distributed. Hence, they were avowed to account for relatively high values of the coefficient of friction. It was also observed that silicon carbide is more brittle compared to the rest of the composite matrix. The EDS analysis also confirmed that all composite contact surfaces experienced counterbody material transfer. Notably, the majorities of counterbody materials transferred were in front of and around the nanographite particles (Figure 12(b)). Figure 13 shows the worn surface of hybrid composite (sample S11) SEM with corresponding EDS analysis results. From the observations about the EDS analysis that focused on transferred material, it was established that counterbody material, oxides, and nanographite constituted the mixture in the transferred material, reflecting a mechanically mixed layer similar to that which is mostly observed in AMCs that have been examined under experimental settings with dry sliding conditions [22]. In the AMCs, the layer exists as a thin lubricant film occurring between the disc surface and the counterpart block. Effects of this layer include reductions in the coefficient of friction, wear, and heat generation because of the friction [20,21]. Nanographite has also been found on the worn surfaces of hybrid composites. During the compocasting or composite preparation process, nanographite particles were fragmented to form small and fine particles. As such, they could not be detected in the form of large particles.

Conclusion
The Taguchi method plays a significant role in analyzing aluminium matrix composites' sliding tribological behaviour. The Taguchi method offers an efficient, systematic, and simple methodology for optimizing wear and friction test parameters. This study established that wt% addition of nanographite and an increase of sliding speed tend to decrease the coefficient of friction and wear rate of tested 10 Journal of Nanomaterials composite tends. On the other hand, findings suggested that the increase of normal load leads to an increase in friction and wear rate coefficient. In the hybrid composites, minimal friction coefficient and wear rate were observed to be at maximal sliding speed and minimal load for the case of nanographite. The study concluded that sliding speed and normal load factors exhibit the lowest effect on wear rate while wt% of nanographite exhibits the largest effect. Also, individual parameter interactions revealed a smaller impact (interactions involving wt% of nanographite and sliding speed, sliding speed and normal load, and wt% of nanographite and normal load). From the results of MATLAB R2018 S1 S2 S3 S4 S5 S6 S7 S8 S9 S10 S11 S12 S13 S14 S15 S16 S17 S18 S19 S20 S9 S10 S11 S12 S13 S14 S15 S16 S17 S18 S19 S20 S21 S22 S23 S24 S25 S26 S27 Sample number COF (b)  Journal of Nanomaterials software, ANN proved efficient in predicting the coefficient of friction and wear rate because the results obtained by ANN and ANOVA were similar to the experimental data.

Data Availability
The data used to support the findings of this study are included within the article. Should further data or information be required, these are available from the corresponding author upon request.