Effects of Thermal Barrier Coating Using Various Dosing Levels of Aluminium Oxide Nanoadditive Fuel on Diesel in Compressed Ignition Engine

Department of Automobile Engineering, Vels Institute of Science Technology and Advanced Studies (VISTAS), Chennai, India Department of Automobile Engineering, Easwari Engineering College, Chennai, India Department of Mechatronics Engineering, Bharath Institute of Higher Education & Research, Chennai, India Department of Mechanical Engineering, Sri Ganesh College of Engineering & Technology, Puducherry, India Department of Mechanical Engineering, Vels Institute of Science Technology and Advanced Studies (VISTAS), Chennai, India Institute of Mechanical Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Techanical Science, Chennai, India Department of Mechanical Engineering, Faculty of Manufacturing, Institute of Technology, Hawassa University, Hawassa, Ethiopia


Introduction
The prime reason for ecological issues, global warming, climate changes, etc. are because of human's ambitious need for material sophistication. With transportation being the major contributor among all, rapid industrial growth and urbanization have also surged the demand for electricity which in turn is majorly derived from noneco-friendly practise like coal, oil, natural gas, and nuclear energy. Additionally, because of the competitive market practise, big industries compromise on environment-friendly approaches to produce the product at a faster rate. At present, because of the lack of stringent environmental policies and regulations, all these have aggravated and have already started to haunt life on earth. The most critical issue among all is air pollution is major because of automobile emission. Particularly, the internal combustion engine has a hard effect on the environment than anything else among automobile emissions, and it is more commonly used over gasoline engines because of its better fuel economy. According to Navigant Consulting, the worldwide stock of motor vehicles will exceed 2 billion units in 2035.
In an internal combustion engine, the chemical energy of the fuel is converted to thermal energy, which is then used to perform mechanical work in the form of piston movement. In this process, toxic compounds are released from the engine exhaust. A number of researchers have proposed a variety of approaches to reduce this harmful emission by in-cylinder treatment; however, only a significant portion of proposals have proved to be effective practically. Further, catalytic prereaction treatment reduces the minimum threshold ignition energy required while also amplifying the flame velocity. This approach also seemingly formulates the catalytic surface temperature along with the contact between gas-phase reactants and the catalyst. Aluminium oxides, copper oxides, cobalt oxides, and iron oxides have also been used as fuel additives to change the composition of diesel fuel in order to minimise emissions.
Researchers were able to minimise engine emissions and improve the performance of a diesel particle filter in the lab by using an aluminium diesel fuel borne catalyst and bimetallic platinum [1][2][3][4]. One of the findings of the study reveals that there is a substantial difference in particle density, lightoff temperature, and oxidation kinetics in accumulation mode. Despite the fact that the rate of oxidation increased following the addition of aluminium to the fuel, the amount of dosage had no effect [5][6][7][8]. Kamo et al. evaluated the impact of introducing aluminium oxide into biodiesel and discovered that it improved performance while also lowering NO x and HC emissions [9,10].
Currently, researchers around the globe are relentlessly working on discovering an automobile engine which does not emit toxic compounds in its exhaust fume while also not compromising on its performance. One of these breakthroughs is the application of thermal barrier coating (TBC) within the combustion chamber to improve thermal resistance and stability when working at many leap temperatures. It is important to keep in mind that the barrier coating material should have a greater thermal coefficient of expansion than the metal substrate in order to withstand more thermal shock [11]. Similar coating approaches with ceramic materials like TiO2, CeO₂, mullite, CaO/MgO-ZrO2, and YSZ were also employed for practical purposes for engine applications [12,13].
Thermal barrier coating materials like partially stabilised zirconia (PSZ) and nearly stabilised zirconia with 6-9 percent yttria (YSZ) are commonly utilised. Even under harsh circumstances absorbed in gas turbines, diesel engines, and other engines, these materials have been shown to function better [14]. The efficiency of a diesel engine covered with 0.1 mm thickness and 0.5 mm breadth of YSZ was enhanced by 6% in Ramalingam et al.'s experiment at all speeds and loads. The heat barrier coating is applied to the piston crown, piston, and cylinder head to fully use the finding [15][16][17] Because of its wide variety of physical qualities, such as a high coefficient of thermal expansion, a high Poisson's ratio, low thermal conductivity, and structural stability at high temperatures, YSZ was chosen as a feasible material for TBC I [18][19][20][21].
In this discussion, the performance and combustion of a diesel engine, as well as the emission difficulties develop when yttria-and aluminium-stabilised zirconia coatings are applied to the cylinder liner and piston head and when aluminium oxide additive is added at various amounts (35 ppm, 45 ppm, and 55 ppm). The goal of this experiment is to reflect the engine's changes in performance and emission characteristics [22][23][24][25]. This research's findings are analysed, examined, reviewed, and presented in a systemic manner. At first, the diesel engine coated with aluminium oxide nanoparticle is subjected to varying level of dosage (35 ppm, 45 ppm, and 55 ppm, respectively). Then, on the second phase, the same engine is modified and experimented with thermal barrier coating to compare the outcome from both the methods.

Experimental Methods and Specification
2.1. Test Engine. The test was conducted in a single-cylinder, water-cooled, 4-stroke diesel engine (Tv1 type Kirloskar, India) that produced 5.2 kW at 1500 rpm. An eddy current dynamometer was used for the loading. The engine's drive shaft is attached to the dynamometer. To determine the mass of airflow rate, an orifice metre and a manometer with a 1% error are employed. The engine's specifications are summarised in Table 1(a). In addition, Figure 1 and Table 1(b) shows the experimental setup and component description of the tested engine. By manual calibration, a glass tube is utilised to calculate the amount of fuel consumed. The calculation was done by comparing the time necessary for a normal diesel engine to consume 10 cc of fuel.
Engine parameters: A piezoelectric pressure transducer (AVL INDIMICRA 602-T10602A) was used to monitor cylinder pressure, while a magnetic pickup was used to assess crank angle. An AVL 365C Angle Encoder Indi Advanced was fitted at the frontend of the engine crank to measure the engine speed. After 50 repetitions of cylinder pressure at steady-state, an average value is determined. Heat dissipation at different cylinder pressure was determined carefully and loaded into the system. The data were then compared to a graph of a conventional diesel engine. A five-gas analyser was used to measure CO, HC, NO x , CO 2 , and O2 emissions (AVL Digas 444). A K-type chromyl alumni thermocouple was used to measure the temperature of the exhaust gas, while an AVL437 smoke metre was used to detect smoke.
The entire process was done at a steady speed of 1500 rpm in a nominal functioning state. To arrive at an average result, the tests were repeated three times. After allowing the engine to attain its ideal operating state, all emission characteristics were recorded. The data was personally checked and placed into the system to be analysed further.

Thermal Barrier Coating Synthesis by Plasma Spraying.
Physical vapour deposition, atmospheric plasma, and other forms of thermal spraying techniques were used to grind the top facet of the cylinder liner and piston, respectively. Spray, 2 Journal of Nanomaterials chemical deposition, and plasma arc methods were used in this technique. In this exploratory trial, the plasma spray technique is being used. The compression ratio in the cylinder liner and coated piston is maintained by a surface layer with a thickness of 0.30 mm and 0.15 mm. The sprayed powders and bulk were mechanically bonded by sandblasting the   Table 2 shows the spray details for the piston and cylinder liner coatings of the engine, and Figure 2 depicts a plasma spray coating method.

Preparation of Test Fuel.
Diesel is the primary fuel used in this research. Using a standard instrument, the calorific value and density of biodiesel were determined to be 850 kg/m 3 and 34.5 MJ/kg, respectively. This method used aluminium oxide nanoparticles with a size of 10 to 20 nanometers and a density of 7.13 g/mL as fuel additives. The volume levels of aluminium oxide nanoparticles in the base fuel were changed between 35 ppm, 45 ppm, and 55 ppm. The volume levels of the nanoparticle sample were then calculated using an electronic balance. With the aid of an ultrasonic shaker, the sample was blended with the fuel. To get a homogeneous suspension, agitation is conducted for 30 minutes. To avoid sedimentation, the produced fuel was used as soon as possible.  Table 3.
Fuel properties: 2.5. Procedure for Testing. Readings were observed three times after attaining the engine steady state, and mean value was determined. Enhanced combustion was witnessed when air intake is provided while using aluminium oxide as an additive in diesel. As a result, full oxidation of hydrocarbons occurred. In addition, the additive aluminium oxide was miscible with fuel. Different volume levels of 35 ppm, 45 ppm, and 55 ppm were added with diesel, following which the mixture is agitated for 30 minutes with help of ultrasonic shaker. Following that, the engine was started with varied amounts of aluminium oxide-containing diesel. The readings were removed. The coated piston and cylinder liner were reinstalled, and the process was repeated after the baseline piston and cylinder liner operation was completed. The combustion, emission, and performance metrics of coated and uncoated engines were compared between additive-containing diesel and regular diesel. The coated engine was removed after roughly 100 hours of operation to look for any changes in the coated piston crown and cylinder liner. Before starting the engine, the coated piston crown and cylinder liner are shown in Figure 3. Figure 4 shows the coated piston crown and cylinder liner after the engine has been operating. The images also show that the coating used had small cracks around the margins of the piston crown. The outstanding sections, on the other hand, showed almost no fractures or abnormalities, indicating that the thermal barrier coating was stable under all loading conditions of engine running.

Results and Discussion
In terms of pollution, performance, and combustion, the coating's effects on the cylinder liner and piston head were investigated. The operation was carried out in a watercooled single-cylinder, four-stroke engine using diesel fuel containing aluminium oxide additions at volume levels of 35 ppm, 45 ppm, and 55 ppm. Several performance parameters were observed and analysed for discrepancies under engine loading conditions, including BTE, BSFC, NO X , CO, CO 2 , and HC emissions and smoke.

Engine Performances
3.1.1. BSFC. Figure 5(a) shows the difference in TBC BSFC in uncoated and coated engines with different load and volume levels of aluminium oxide. When compared to regular diesel, aluminium oxide diesel has a lower BSFC (Kannan, Karvembu, and Anand 2011). The BSFC for diesel and diesel with aluminium oxide additions drops even more for engines with TBC. This is due to a greater combustion temperature, which results in a faster energy conversion rate during combustion. This ultimately leads to better combustion and better conservation of fuel [19]. A significant 3% lesser BSFC has been observed for coated engines with diesel containing various volumes of aluminium oxide than diesel-employed coated engines at part load conditions. From the preceding condition, it clearly illustrates that the presence of aluminium oxide improves the performance of the engine at part load conditions. In addition, an increased temperature is observed because of TBC. The BSFC of the coated engine is increased by 1% and 2% when diesel is added with aluminium oxide of 45 ppm and 55 ppm, respectively, in comparison to diesel operated engine at 75% load. At 75% load, 3% lesser BSFC is noticed for dieseloperated coated engine than standard diesel operation. Figure 5(b) illustrates the difference in BTE of TBC coated and untreated engines with load for all tested fuels. When aluminium oxide is introduced, the BTE value rises. The addition of aluminium oxide nanoparticles to the fuel promotes complete combustion, as opposed to typical aluminium oxide fuel, which acts as an oxygen barrier, releasing or keeping oxygen depending on partial pressure. Finally, the BTE is increased when the aluminium oxide is used as a fuel additive. The coated diesel engine with aluminium oxide has a higher thermal efficiency than the base diesel. This happens because the piston crown has thermal resistance, which inhibits heat from being transported to the coolant or other media. As a result, the combustion is more uniform. At 85 percent load, the TBC engine with diesel improves BTEby 2.1 percent over conventional diesel performance.         Figure 6(a) presents the change in CO 2 discharge with engine load. When the amount of aluminium oxide in diesel is changed, the CO 2 emissions rise when compared to regular diesel. As a result, enhanced combustion results from the use of all oxygen in the combustion chamber. This results in increased generation of CO 2 from CO [22], thereby reducing the levels of CO. CO 2 emission is increased for TBC engines. The combustion in the cylinder is improved by different dosages of aluminium oxide and high cylinder temperature. As a result, there is an increased CO 2 emission. At 75% of engine load with dosages of 35 ppm, 45 ppm, and 55 ppm of aluminium oxide, CO 2 emission is more than about 5.7%, 7%, and 8.9% for coated engines, respectively, when compared to that of the base diesel.

BTE.
3.2.2. CO Emission. Figure 6(b) depicts a decrease in CO emissions as the engine load increases. This reduced CO emission is because of increased higher temperature in a cylinder with an increase in the load of the engine. Due to the aluminium oxide effect in the diesel, there is improved combustion, as a result of which CO emission is reduced. The additive aluminium oxide increases the oxidation of CO into CO 2 . A further reduction in the emission of CO is noticed in engines with TBC. The coating generates high temperature which stimulates the conversion of CO into CO 2 . Hence, TBC engines provide improved combustion [22]. CO emissions are reduced by roughly 0.8 percent, 1.4 percent, and 0.7 percent for coated engines at 75 percent of engine load with doses of 35 ppm, 45 ppm, and 55 ppm of aluminium oxide in diesel, respectively, when compared to basic diesel.

HC Emission.
When there is incomplete combustion, there is an increased HC emission. Figure 6(c) gives the difference of HC emission with respect to engine load. When compared to base fuel operation, the addition of aluminium oxide to diesel results in lesser HC emission of about 7% at 75% load. This is due to the role of aluminium oxide in effecting the improved combustion. The coated engine has lesser HC emission compared to the uncoated one. This may be the result of high combustion temperatures after the burning phase by hindering the heat loss in coated engines. Eventually, effective use of air intake and increased oxidation of fuel [5] was carried out by improved combustion. Aluminium oxide dosages of 35 ppm, 45 ppm, and 55 ppm provide a 9%, 8%, and 6% reduction in HC emission, respectively, for coated engines associated with standard diesel-operated uncoated engines. Figure 6(d) depicts the increase in NO X emissions as engine load increases. The oxygen content and combustion temperature are determined by NO X emissions.

NO x Emission.
As aluminium oxide is added to diesel, it causes an increase in NO X emissions when compared to base diesel. This increased emission is because of oxidation of nitrogen into its oxides by aluminium oxide while combustion. NO X emission is higher comparatively in uncoated engine. This is due to high temperature that stimulates an early beginning of combustion. This changes the peak temperature and pres-sure to TDC proximity. Thus, increase in NO emission is due to burning of fuel in premixed state [11]. Aluminium oxide dosages of 35 ppm, 45 ppm, and 55 ppm provide a 21%, 26%, and 25.5% in NO emission, respectively, for coated engines associated to standard diesel-operated uncoated engine at 75% load.

Conclusion
Following conclusions are arrived through the experimental study and investigation.
(i) Ceria-and yttrium-stabilized zirconia-coated engine with different dosages of aluminium oxide and diesel provides an increase of 2.7% BTE and reduction of 3% BSFC at 75% load. Coated engines show a finer performance characteristics with test fuels at part load conditions (ii) When 35 ppm, 45 ppm, and 55 ppm of aluminium oxide are added to diesel, CO, HC, and Knox emissions are reduced for both coated and uncoated engines when running on regular diesel (iii) Influence of parameters like size of nanoparticle, dosing level, and preparation time has significant role in the fuel performance with fuel added with aluminium oxide nanoparticles as thermal barrier coating. For best performances of engine and emission reductions, Consistent effort has been put to get optimum combination of parameters. In parallel, a further research is being carried out on visualization techniques for analysing the characteristics of combination of additive fuels

Data Availability
The data used to support the findings of this study are included in the article. Should further data or information be required, these are available from the corresponding author upon request.

Disclosure
This study was performed as a part of the Employment Hawassa University, Ethiopia.