Converting Biomass andWaste Plastic to Solid Fuel Briquettes

is work examines the production of briquettes for household use from biomass in combination with plastic materials from di�erent sources. Additionally, the combustion characteristics of the briquettes in a common open �replace were studied. It is clear that the geometry of the briquettes has no in�uence on the smoke emissions. When the briquettes have a small amount of polyethylene terephthalate (PET), the behavior in the combustion is steadier because of the increase of oxygen supply. e smoke levels are between the 3rd and 4th grades of the smoke number scale. Measuring the carbon monoxide emission, it was observed that the burning of the plastic in themixture with biomass increases the carbonmonoxide emissions from 10% to 30% as compared to carbon monoxide emission from sawdust biomass emissions which was used as a reference.


Introduction
In cities and other industrialized landscapes, the sources of pollution are predominantly transport, industrial, and domestic activities.ese activities are the basic cause of the phenomenon which is commonly referred to as climate change [1].In response to climate change, the use of biomass fuels is increasing as sustainable and carbon (climate) neutral fuels are sought.Additional to climate factors, increasing market prices of traditional fossil fuels have driven consumer preference towards alternative fuels [2].Furthermore, the price explosion of oil and gas has given a push to the use of renewable energy resources.e recent switch from conventional to renewable energy sources (RES) and their gradually extensive use is a common feature of the energy policy adopted by the developed world.In Greece, in the middle of the economic crisis, the fuel wood consumption in urban regions presents an increasing trend due to the �replaces used in residences [3].
Additionally the Directive 2000/76/EC for Waste Incineration is in force which sets the limits and the requirements for the waste incineration [4].In order to enforce this directive the European Commission has issued the mandate M/298 to European Standardization Organizations to elaborate technical means to conforming to Essential Requirements of this New Approach Directive.Under this mandate, a number of standards for solid biofuels and solid recovered fuels have been issued.Solid biomass and solid recovered fuels as a combustion fuel encompass solid materials (e.g., wood logs or pieces) [5][6][7][8], processed materials (wood chip, pellets) [9], waste products (recycled wood, agricultural byproducts) [10,11], gasi�ed materials (methanization of solid fuels) [12], and lique�ed materials (e.g., esteri�cation products) [13].ese fuels can be classi�ed according to their origin and production method (life cycle stage).Primary material is sourced speci�cally for the purpose of combustion/energy generation, while secondary material has undergone processing to reach its preferred combustion format (e.g., new wood used to make pellets or chips).Finally, tertiary fuels are those derived from materials having already undergone a greater portion of their lifecycle (e.g., recovered building materials).ese materials are then recycled, producing pellets, chips, or briquettes for use as combustion fuels [5].Solid fuels can be burned in a variety of manually and automatically operated burners and boilers.Appliances are classi�ed by their intended use and operational methods (batch �red or automatic).In this study only open �replaces are addressed.e other household combustion appliances are the focus of undergoing work.Open �replaces are the simplest class of residential biomass and solid waste combustion appliance with the combustion zone positioned upon a simple grate in a solid form base (i.e., stone or brick).As the name suggests, open �replaces have at least one exposed side.Exposure of the combustion zone allows for signi�cant heat losses.ese losses constrain maximum possible combustion temperatures, limiting combustion rates and leading to high concentrations of particulate and gas-phase emissions [14].Closed �replaces are similar in structure to open �replaces with the addition of side panels closing the gap between the ventilation hood and the base.To facilitate loading and cleaning of the �replace, a door is �tted to one side of the appliance.
Combustion cycles in residential heating are transient in nature.During transient cycles, there are four clear phases during which emissions vary (ignition, startup, steady state, and burnout.).Of all the phases, the startup phase alone contributes up to 50% of total particulate matter emissions and up to 70% of organic material [5].Soot (carbonaceous) particles are formed via condensation of volatilised organic materials [5].Aside from appliance type, fuel composition and combustion conditions are known to in�uence particulate and gas-phase emissions [15].Combustion conditions can be characterised according to the combustion air-tofuel ratio and the concentration of carbon monoxide emissions [5].Carbon monoxide is an indicator of combustion efficiency and is known to be detrimental to human health [16,17], while interest in organic carbon and particulate organic matter has increased in recent years as their role in climate and human health impacts is better understood [18][19][20].High levels of soot, particulate emissions are formed when the air to fuel ratio is near to 1 and the carbon monoxide is high (mean concentration of above 1000 mg m −3 ), while high levels of condensable organics are formed when the air to fuel ratio is greater than 4 and the carbon monoxide is similarly high.Under optimal conditions where the air to fuel ratio is near to 1.5 and the concentration of carbon monoxide is below 100 mg m −3 , high mineral to carbon ratio emissions are produced [5].
In this paper a variety of raw materials were used for the manufacturing of briquettes.e raw materials were two different series of used lubricant bottles, bottles from polyethylene terephthalate (PET), high density polyethylene (FIANTHENE 5502), and wax polyethylene, two series of Biomass from kernel, beech sawdust, particle board sawdust, and straw.e manufactured briquettes have been burned in an open �re place where the combustion temperatures have been measured along with the emitted soot in smoke number scale, carbon monoxide, and nitrogen oxide.e aim of this work is to study the production characteristics of the briquettes for household use.Additionally, the combustion characteristics of the briquettes and their emissions in a common open �replace were studied.

Materials and Methods
For the purpose of this study, used empty bottles from lubricants have been collected from car repairing workshops.Aer the collection their size was shrunk about 5% with the help of a commercial use shrunk machine manufactured by Carstens GmbH.Additionally, empty bottles from polyethylene have also been collected from a recycling company.Apart from these, two series of biomass from kernel, beech sawdust, particle board sawdust, and straw were ordered.ree patents were applied for the manufacturing of the briquettes, US patent 4561860 [21], US patent 4236897 [22], and the European patent EP0262083 (A1) [23].With a help of a plastics company's installation using a commercial Adelmann BP 650 press briquettes for �replaces were produced.All the briquettes have a weight of ca.300 grams.For the simulation of the combustion an open �re place was installed in the National Technical University of Athens, School of Chemical Engineering, Fuels and Lubricants Technology Laboratory.e installation has been traced in Figure 1.e raw material and the manufactured briquettes have been analyzed and the key properties (volatile matter, moisture, ash, and �xed carbon) have been examined.A Carlo Erba 1108 CHNS-O elemental analyzer was used to determine the content of carbon (%wt.), hydrogen (%wt.), nitrogen (%wt.), and sulfur (%wt.) in the raw material and in the produced briquettes.e results are presenting in Tables 1 and 2, respectively.ese have been examined according to ASTM standard test methods [24][25][26][27].
e produced briquettes have all a weight of 300 gr/piece and a cylindrical shape.e geometrical characteristics are presenting in Table 3.All the products were burned in an open �replace and the temperature of the combustion of each one was measured with the help of KIMO TK 102 (K thermocouple) instrument.e smoke was measured with a typical smoke number scale probe according to ASTM D2156 method [28].e emissions of carbon monoxide and nitrogen oxides were measured with the help of a Horiba instrument (type MEXA 574-GE, that gauges, CO exhaust emissions near dispersive infrared analyzer) and a NO  analyzer (42C NO-NO 2 -NO  high level analyzer, ermo Environmental Instruments Inc.), respectively.In order to evaluate them, results are expressed in comparison with the emission from burning 300 gr of pure straw.e �replace was cleaned aer the combustion of each type of briquettes and the residues were removed.Each measurement was taken aer one hour of combustion in a cold �replace.

Results and Discussion
For this experimental work raw materials of biomass and used bottle for lubricants were collected from various car repair and petrol stations across Athens area.Additionally, plastic bottles of polyethylene terephthalate were collected too.e high and low heating value of the raw material as received are presented in Figure 2. It can be easily observed that the heating values of used lubricant oil bottles and the polyethylene are higher than the other products.us, it was tried to produce briquettes with a standard average weight of ca.300 gr, high heating value of 31,40 MJ/kg and low heating value of 29,31 MJ/kg.e heating values of the produced briquettes have been depicted in Figure 3. e rest of the characteristics for these products are presented in Table 2. e higher heating value is observed for the briquette which contains 60% high density polyethylene and 40% beech sawdust, whilst the lower heating value is observed for the briquette which contains 10% polyethylene terephthalate, 25% polyethylene, and 65% beech sawdust.All of these products have been burned in an open �replace.
Figure 4 presents the range of the combustion temperature for each briquette examined.e temperature was recorded when the �ame was in full length.e temperature measurement referred to the intermittent �ame region which is above the continuous �ame region.In this region the �ame temperature of the open �replaces drops as a function of distance up the plume.Additionally the thermocouple was unshielded.As it can be easily seen the shorter range appeared when the briquette contained biomass in a percentage of around 65%, polyethylene and polyethylene terephthalate.is is expected because the increased amount of oxygen which these briquettes contain gives more steady behavior during the combustion.e combustion of the above-mentioned briquette appeared to be similar to wood combustion and the briquette retains its original shape.
Figure 5 depicts the smoke number scale for the combustion of the briquettes.If the level of polyethylene is above 40% then the smoke exceeds the grade nine (9+) in the scale.When the biomass is around 70% with a percentage of polyethylene of around 30% the smoke is between seven (7) and eight (8) of the Bacharach scale.It is also observed that when the percentages between biomass and polyethylene shi a bit there was no change in the above-mentioned scale.Additionally, the commercial available product has a smoke scale of nine (9).e comparisons of emissions of carbon monoxide and nitrogen oxides are presented in Figure 6.It is obvious that when the briquette contains plastic and biomass, the amount of carbon monoxide is increased from 10% to 30% as compared to pure straw biomass briquette.When the biomass is around 70% with a percentage of polyethylene of around 30% the carbon monoxide emissions increased 10%.Furthermore, no change was observed when the percentages between biomass and polyethylene shi a bit.On the contrary with the carbon monoxide emissions the nitrogen oxide emissions are decreased between 20% and 35%.is is expected since for briquettes that contain polyethylene, which has no nitrogen, the amount of nitrogen present in the briquette is signi�cantly lower leading to lower production of nitrogen oxides from the combustion.Similar results are observed when the briquette contains polyethylene terephthalate.At all circumstances the amount of carbon monoxide and nitrogen oxide emissions are better than the emissions from the combustion of the commercial available briquette.

Conclusions
All briquettes examined have no problem in the combustion procedure.e used plastic material has polyethylene content from 30% to 70%.e basic observation is that the briquettes with content in polyethylene greater than 40% burned intensely and lose their basic shape rapidly because of the combustion's high temperature.
On the other hand, when the polyethylene content is higher than 40% the smoke exceeds the smoke number scale level of 9+.When the briquettes samples have concentration 70% biomass and 30% polyethylene the smoke is between 7 and 8 of smoke number scale.It is also observed that the smoke has no measured alterations when the concentration changes slightly.Additionally, the geometry of the briquettes has no in�uence to the smoke emissions.Measuring the carbon monoxide emission, it was found that the burning of the plastic in the mixture with biomass increases the carbon monoxide emissions from 10% to 30% as compared to carbon monoxide emission from sawdust biomass emissions.When the proportion of biomass to plastic is 70 to 30 the carbon monoxide emissions increased 10% in relation to the sawdust biomass emissions.
In reverse with the carbon monoxide emissions the nitrogen oxide emissions decreased from 20% to 35%.
When the briquettes have a small amount of Polyethylene terephthalate (PET) the behavior in the combustion is steadier because of the increased concentration in oxygen.Additionally the smoke levels are between the 3rd and 4th grades of the smoke number scale.ese levels are similar to the rest of the biomass samples which were burned into the open �replace.

F 1 :
�iew of the open �re place installation.

T 1 :
Proximate analysis of the raw material on as received basis.
• C) F 4: Range of combustion temperature in the open �replace.
F 6: CO and NO emissions variation in comparison with the straw emission.