Analysis of Heat and Mass Transfer of Fractionalized MHD Second-Grade Fluid over Nonlinearly Moving Porous Plate

is study investigates the heat and mass transfer in the MHD ow of fractionalized second-grade uid induced by impulsively moved bottom porous plate with nonlinear velocity of the magnitude KTD. To acquire the fractionalized nondimensional set of ow administering dierential equations, fractional calculus and dimensionless variables are considered. e solution process utilizes Laplace transform and results in the acquired outputs in terms of generalized functions. e exact solutions for concentration, temperature, velocity, and the shear stress are then reduced by certain limits into fractional/traditional second-grade and Newtonian uids as per the special cases within and out of the magnetic and porous eects. It is observed that these special cases occur in the previous published literature which verify the results of this study. e results are pictorially visualized to perform the analysis for impacts of diverse physical parameters and dimensionless quantities on concentration, temperature, and velocity elds. It is learned from the analysis that magnitude of viscoelastic parameter is directly proportional to velocity whereas the porous and magmatic eects are inversely proportional. Increasing fractional parameter values reduce ow elds of velocity and temperature. Eects of dimensionless parameters for heat and mass transfer are analysed in detail.


Introduction
A number of technological developments and industrial applications of uids require the complete information about their complex rheological ow, due to which the study of non-Newtonian uids is carried out at large scale with a variety of enclosure limitations in di erent situations. ese situations practically appear in many electrochemical, geophysical, biorheological, petroleum engineering, metallurgical, and other industrial practices like plastic and polymer melts, pulps, oil, and greases, etc. A second-grade submodel of a non-Newtonian di erential type model suitably describes the complex rheological behavior of the above-mentioned uids [1]. e analytic solutions of this type of uid model are found in literature serving as a solution to such existing ow problem, and it supports a veri cation of di erent numerical schemes for extremely complex ows. Haq [2] investigated solutions of di erent ow forms of second-grade uid with MHD Darcy's law using an Caputo-Fabrizio derivative approach. Salman [3] calculated the values for movement of second-grade uid over the plane having constant acceleration and presented the exact solutions as the collection of high magnitude time and transient exact solutions simply reducible to the similar solution for Newtonian uid there by concluding that non-Newtonian e ects diminish by time.
For a proper and accurate investigation of all the viscoelastic properties of a uid, fractional calculus is adopted to acquire the fractionalized form of ow administering equations [4]. Like the rate type uids, the second-grade fluid model is passed through a modification for the purpose of generalization, that is, roughly speaking, nothing but a replacement of integer order differential operator of time derivative with one of the broadly applied fractional order differential operators as here we use the Caputo [5]. Flow produced by a heated plane moving impulsively having fractionalized second grade fluid is studied by Tassaddiq [6]; he concluded that the fractional approach is more useful for theory analysis of viscoelasticity. Riaz and Iftikhar [7] compared local and nonlocal derivative study to analyse heat transfer in MHD Maxwell fluid. Khan and Wang [8] investigated the generalized second-grade fluid flow enclosed by two perpendicular walls induced through the impulsive movement of surface over which fluid is supposed to be, and they verified their results with previous literature by vanishing the perpendicular bounding walls. Fahad et al. [9] analysed MHD second grade fluid, Newtonian heating, and Dufour effect over an infinite vertical plate with fractional mass diffusion and thermal transports using nonintegerorder derivative Caputo Fabrizio (CF) with nonsingular kernel.
MHD flow incorporated with porous medium is reported in many processes of the biology and medicine industry. It is utilized in chemical industry for filtration, separation, and purification processes which involve the interaction of electric or magnetic field with hydrodynamic boundary layers. Analytical results including porous and MHD terms in second-grade fluid are acquired by Ali et al. [10], where there exists the magnetohydrodynamic fluctuating free convection flow of incompressible electrically conducted viscoelastic fluid in a porous medium in the presence of a pressure gradient. Salah [11] analysed the rotationally accelerated fluid and found that variable and constant accelerated MHD flow behave equivalently. Bajwa et al. [12] found that when the transpiration parameter approaches zero, the solution for the flow with transpiration tends to the solution corresponding to the case without perspiration. Influence of hall currents with MHD and porous effects is investigated in the second grade fluid with oscillations by Hussain et al. [13].
Boundary layer flow of viscoelastic non-Newtonian fluids is of fundamental importance in industrial and applied sciences. Sticking to the problem under study, heat transfer is observed due to both the exponential motion of plate and the buoyancy force that is generated by the difference of temperatures between the fluid and moving bottom plate. In practical applications, reduction of drag due to friction; paper production processes; and the cooling mechanisms of electronic, nuclear, chemical, and industrial processes involve such issues. A lot of research material is available over the flow in touch with the first layer of boundary and heat transfer for being found in much application of industrial interest. e presence stretching sheet with fluid flow of second-grade type is effected by heat of friction, heat absorbed or generated internally, and the heat in terms of deformation work is dealt by Vajravelu and Roper [14]. Tan and Masuoka [15] solved Stokes' first problem over the hightemperature surface in a semipermeable space. ey obtained the steady-state solution in the form of damping exponential function of distance to a hot plate. Concentration and chemical reaction are considered by Hayat et al. [16] with heat transfer in second-grade fluid thereby taking into account the HAM method. Hayat and Abbas [17]also obtained the solutions to same problem in the presence of MHD and porous effects. e movement of fluid of second-grade type in the presence of stretching sheet in unsteady form is discussed by Sajid et al. [18]; they addressed both processes of heating and the prescribed surface temperature, as well as prescribed surface heat flux, and obtained the analytic solutions valid for all times by using HAM method. In recent years, Baoku et al. [19] adopted numerical approach to find the approximate solutions, where they applied the Runge-Kutta-Fehlberg of order five by shooting method strategy. Das [20] did the same in addition with heated sheet of stretchable form but utilized Nachtsheim-Swigert shooting method for sixth order Runge-Kutta scheme. El-Dabe et al. [21] analysed the second-grade fluid flow with nonlinear form of transfer of both the mass and heat and discussed the thermophoresis applications in detail. Khan [22] studied heat transfer in a thin film of the steady form of flow in touch with the first layer of boundary of porous material in the presence of second-grade fluid. Wakif analysed the analytical and numerical solution of fluid flow with convection heat transfer [23][24][25]. Bhatti et al. [26] analysed higher-order slip flow of Eyring-Powell nanofluid for Darcy-Forchheimer in the presence of bioconvection and nonlinear thermal radiation and proved that bioconvection Lewis number declines the microorganism profile while the increasing trend is noted for higher values of slip parameter. Bhatti et al. [27] also carried out group analysis and used a robust computational approach to examine mass transport and found successive linearization approach (SLM) more efficient.
is study investigates the heat and mass transfer in the MHD flow of fractionalized second-grade fluid induced by impulsively moved bottom porous plate with exponential velocity of the magnitude K⊺ d . To acquire the fractionalized nondimensional set of flow administering differential equations, fractional calculus and dimensionless variables are considered. e solution process utilizes Laplace transform and results in the acquired outputs in terms of generalized functions. e solutions in the exact form for concentration, temperature, velocity, and stress are then reduced by certain limits into fractional second-grade and Newtonian fluids as per the special cases within and out of the magnetic and porous effects. e results are pictorially presented to perform the analysis for impacts of diverse physical parameters and dimensionless quantities. is study mainly focuses on the following research questions.
What is the compact form of analytical solutions of flow field in the presence of MHD and porous medium in terms of summation style and newly defined M function?
What are the effects of nonlinear movement of plate over the fluid velocity, heat, and mass transfer?
How the shear stress profile behaves for nonlinear movement of porous surface in presence of MHD effect? 2 Mathematical Problems in Engineering Differentiate the responses of the flow field between the linear and nonlinear/exponential movement of the porous surface (Table 1).

Flow Field Description and Its Solutions
e free convection heat and mass transfer in MHD unsteady flow of second-grade fluid over an infinite vertical porous plate in (x, z) plane is considered, while y-axis being normal to the plate. Species concentration ℷ, temperature distribution ℸ, velocity υ in x-direction, and shear stress are considered as function of only ⊺ and ξ. Initially the plate is at rest and the fluid too with ambient fluid temperature ℸ ∞ (constant) and the constant concentration ℷ ∞ . At the moment ⊺ � 0 + , plate starts to move in its own plane with the nonlinear velocity K⊺ d there by raising the temperature and concentration level of the plate to ℸ w and ℷ w , respectively. A transverse magnetic field B 0 with uniform strength is normally applied to the plate in the direction parallel to y-axis as shown in Figure 1, while assuming the negligible induced magnetic field as compared to transverse magnetic field due to very low Reynold's number. e viscous dissipation, Soret and Duoffer effects are also neglected for low level of concentration.
From the above assumptions with constant Boussinesq approximation, the set of flow administrative equations for heat and mass transfer in incompressible second-grade fluid is shown [28][29][30].
subject to the following initial, boundary and natural conditions, respectively.
where q stands for transform parameter while image function of υ(ξ, ⊺) is represented by υ(ξ, q).

Calculation of the Mass Concentration.
Taking the Laplace transform of (20) and using the initial condition (14), we get Solving (24) using the natural condition (23) and boundary condition (22), we obtained In terms of series, the above equation can be written as 4 Mathematical Problems in Engineering Applying the inverse discrete Laplace transform, we have In the form of general Wright function [31], where the general Wright function is defined as

Calculation of the Temperature Distribution.
Taking the Laplace transform of (19) and using the initial condition (14), we have Solving (31) using natural condition (23) and boundary condition (22), we get In terms of series, the above equation can be given as Applying the inverse discrete Laplace transform, we have Presenting the above equation in more generalized way of M function, where the newly formulated M-function with the help of Fox H-function [31][32][33] is explained by 2.3. Calculation of the Velocity. Initial conditions (14) are imposed after taking Laplace transform of (17), which yield the results Mathematical Problems in Engineering 5 Solving (37) utilizing conditions (22) and (23), we get Presenting (38) in series form to easily produce υ(ξ, ⊺) � L − 1 υ(ξ, q) without prolix computational complexities of residuals and contours integrals, Practicing the discrete inverse Laplace transform, we obtain

Mathematical Problems in Engineering
Rewriting the velocity expression using generalized M-function, (14) are imposed after taking Laplace transform of Equation (18) yielding the results
With the help of (38), the given expression can be rearranged as Writing the given expression in the form of a series

Mathematical Problems in Engineering
Inverting the Laplace transform results, In terms of M-function

Fractionalized MHD Second-Grade Fluid in Porous
Medium with Constant Radiative Heat Flux. For the constant radiative heat flux along y-direction, q r � constant or F ⟶ 0, the flow results are

Mathematical Problems in Engineering 13
with velocity and the respective shear stress is

Fractionalized Second-Grade Fluid in Porous Medium.
For M ⟶ 0, in (41) and (46), the obtained velocity results are Mathematical Problems in Engineering and the corresponding shear stress is

Fractionalized MHD Second-Grade Fluid after
Vanishing Porosity. Substituting Ψ ⟶ 0, in (41) and (46), the acquired velocity is whereas the related shear stress is Mathematical Problems in Engineering

Fractionalized MHD Newtonian Fluid in Porous
Medium. By making λ ⟶ 0, in (38) and (43), proceed as in the previous section, we obtain the velocity of fractionalized Newtonian fluid: and the associated shear stress is

Results and Discussions
Here Assurance of present work is manifested by constructing comparison with pervious published literature by limiting cases in " section 3" of this study. ese special cases are compared to those of Amanet al. [29] and Shahid [30]. Flow field results with ordinary derivatives and flectional derivatives are compared graphically, and the analytical results are the same as those of the previously published literature by vanishing few parameters.
In Figure 2 we have discussed the variations in mass concentration at different values of time and space above the plate. A natural behavior of decay in mass concentration is observed for higher position of the fluid over the plate. e significance of fractional parameter η and the effects of variations in Schmidt number over the dimensionless mass concentration are analysed in Figure 3. is reveals the facts of increase in mass concentration with increase in fractional parameter values. On the other hand, the opposite behavior is observed for increase in Schmidt number. Figure 4 reflects the temperature distribution with respect to increasing time and vertical space values. e thermal boundary layer thickens by increasing time while temperature values decrease by considering the increasing vertical position of fluid over plate. e effects of fractional parameter and Prandtl number on temperature of fluid over the moving plate are portrayed in Figure 5. Naturally, the viscosity of fluid gets minimized by increasing Prandtl number that ultimately yields the reduction in thermal boundary layer. Figure 6 depicts the influence of fractional parameter and thermal diffusivity on temperature distribution which implies that thermal boundary layer gets thinner with increasing thermal diffusivity whereas fractional parameter acts opposite to that of thermal diffusivity on temperature distribution.
Velocity fields along with shear stress behavior are given in Figure 7 for vertical space values above the moving plate which shows that velocity of the particles at the moving surface is higher to that of the particles away from plate, whereas shear stress profile behaves numerically opposite to it. It can be noted from Figure 8 that as the time passes, velocity of the fluid increases and the stress too, while the impact gets more intense with passage of time. Figure 9 shows the effects of increasing second-grade parameter λ; it reduces the flow velocity and the stress numerically which is due to the characteristics of second-grade fluid. e influence of magnetic and porous parameters is displayed in Figures 10 and 11, where both parameters have similar effect, and the speed and stress increase numerically by raising either the magnetic or porous parameter values.
To discuss the impacts of thermal Grashof number and modified Grashof number, we plot Figures 12 and 13, where velocity and stress mount numerically for the dimensionless numbers individually since it is buoyancy force that flows the fluid, whereas the impacts of modified Grashof number are more intense than those of the thermal Grashof number. e importance of Prandtl and Schmidt number can be observed in Figures 14 and 15; both the dimensionless numbers endorse their definition there by increasing the stress and velocity of the particles for increasing values of these numbers. Figures 16 points out the relation of thermal diffusivity to the stress and velocity of the particles. Increasing the thermal diffusivity parameter, velocity of the fluid reduces and the stress reduces too. Figures 17-19 are prepared to analyse the significance of fractional parameters on the flow field. It can be noted that the increase in fractional parameters reduces the stress and velocity of the particles.
us, fractional derivatives are essential in studying the fluid flows more significantly and accurately.          Figure 15: Descriptions of the velocity υ(ξ, ⊺) and the stress Ł(ξ, ⊺) given by (41) and (46) Figure 16: Descriptions of the velocity υ(ξ, ⊺) and the stress Ł(ξ, ⊺) given by (41) and (46), for λ � 3, M � 0.5, Ψ � 0.2, G m � 0.6, S c � 0.6, P r � 0.6, F � 0.2, η � β � c � 0.5, d � 1, ⊺ � 0.5s for variational points of F. 26 Mathematical Problems in Engineering   numerically higher in comparison with Newtonian fluid. Figure 22 is plotted to analyse the significance of fractional parameter. In comparison with Figure 21, it can be observed that increasing the fractional parameters values, flow characteristics get closer to those of the ordinary fluid flow for both the second-grade and Newtonian-type fluids. e obtained results are compared with the analytical solutions of the flow field presented by the recent studies [23][24][25] which are found to be more compact and simplified. e accuracy of the flow behavior is graphically analysed by setting three decimal places in numerical calculations. However, solutions are analytical, thus the numerical solutions and their comparison are beyond the scope of this study.

Conclusions
In this article, transfer and flow characteristics of fractional MHD second-grade fluid on the porous plate moving with nonlinear velocity is analysed. Solutions for velocity, temperature distribution, and mass concentration are acquired using Laplace transforms after nondimensionalising the system of differential equations. Obtained results satisfying all imposed natural initial and boundary limitations are graphically analysed for transfer and rheological parameters at different times and positions over the plate. e investigation reveals the following results ⋆. All solutions are represented in simpler forms in terms of new summation style and natural generalized function M for such flows. (vi) It is also verified from graphical results that when fractional parameters approach to 1, the behavior of fractionalized second-grade fluid turns into the usual fluid.

Data Availability
No data were needed to perform this research.

Conflicts of Interest
e authors declare that they have no conflicts of interest.

Authors' Contributions
Muhammad Jamil formulated the problem and similarity transformation. Israr Ahmed solved the problem and obtained results. Umar Faryaz computed results and did analysis. Ilyas Khan provided software, coding, and simulation. Abdulaziz H. Alghtani computed results, updated coding, and carried out revision. Mulugeta Andualem improved the model, used the software, did the revision, and carried out the discussion.