Analysis of Heat Transfer Rate for Different Annulus Shape Properties-Enhanced Beeswax-Based Phase Change Material for Thermal Energy Storage

. Thermal exploration of melting phenomena of four diﬀerent annulus shapes’ (circular-circular, circular-rectangular, rectangular-circular, and rectangular-rectangular) beeswax-based phase change material for latent heat energy storage system is discussed here. To overcome the low eﬃciency in heat transfer because of low thermal conductivity of beeswax (the energy storage material in the current study), the composite-beeswax approach has been investigated numerically. Three metal oxides (Al 2 O 3 , MgO, and SiO 2 ) with diﬀerent volume concentrations (1%, 3%, and 5%) containing high thermal conductivity are dispersed into the pure beeswax. The 2-d continuity and momentum as well as energy transport mathematical model inside the composite-beeswax system have been adopted for the study, and we validated the model by available results in the literature. The obtained results revealed that both the melting rate and heat transfer are improved slightly in the case of rectangular-rectangular annulus shape. It was also shown from the result that the melting rate and heat transfer are improved signiﬁcantly with the presence of metal oxide particles. Moreover, it was obtained that the types of particles have not aﬀected noticeably the melting rate and heat transfer. For the three investigated nanoparticles, temperature of the system attained 346.4K at 15000s of process; at the same time, it is 341K as noted for the beeswax, which shows an improvement of 1.4% in the case of circular-circular annulus and Al 2 O 3 . In the same conditions, melt fraction increases from 0.58 for beeswax to 0.91 for composite unit, thus showing 56.8% of improvement in the melting rate.


Introduction
Energy is the backbone of the whole world because all the necessities of a society are fulfilled by it. As the population of the society is increasing drastically, the demand of energy is also increasing in the same manner and that leads to a gap between energy supply and demand chain [1]. e utilization of available renewable energy source such as solar energy may reduce this mismatch. Since some of the energy (like solar energy) only exists in daytime, that is why it is becoming progressively challenging to overlook the gap [2]. Since solar energy is not available all the time, that is, only available in the day, the application efficiency is low. In this regard, energy storage system is a significant section that plays a crucial role in the application efficiency enhancement of the solar thermal energy system [3][4][5]. Nowadays, for universal population and pollution issue, latent heat energy storage has gained a larger attention in the viewpoint of energy storage and utilization. e main advantages of latent heat storage system are that it can absorb energy without further temperature increment and at the same time it can contain high energy storage density. Phase change material (PCM) is a kind of material that works in the principle of heat energy storage in the form of sensible and latent heat. In both absorbing capabilities, latent heat is more useable because of negligible temperature variation. PCM works in cyclic manner first charging and then discharging. In solidliquid kind of PCM, heat is absorbed during charging and melts. In this process, PCM gains melting latent heat. For the discharging case or solidification process, heat is released when the surrounding temperature was lesser than solidification temperature of PCM [6,7]. PCM is classified normally into three fashions: first is organic, second is inorganic, and third one is the combination of organic and inorganic or called eutectic [8]. Among all the three, organic PCM got great devotion because of the appropriate phase alteration temperature, congruent melting, good amount of heat absorbing capacity, low vapour pressure, no supercooling, nontoxicity, no volume alteration during phase change, and excellent chemical and thermal stability [9]. At the same time, organic PCMs contain less thermal conductivity which is approximately 0.1-0.35 W/m-K, which confines their applications. Organic PCMs are utilized in various engineering applications like the solar system, building energy management, Li-ion battery, spacecraft, packaging, etc. [10][11][12][13][14][15]. Organic kind of PCM is subdivided into two categories, paraffin and nonparaffin. Paraffin is a by-product of petroleum and it is a limited resource. So, it is the responsibility of the researcher to explore the natural kind of nonparaffin PCM [16]. In this regard, beeswax (BW) can fill the gap if paraffin wax (PW) will be unavailable in the future. In the midst of all PCMs reconnoitred, BW can be a desirable selection to be employed as the PCMs due to its large amount of heat-storing capacity, being environmentally friendly, having a cheap price, and being nonflammable and nontoxic. BW is the outcome of the metabolic practice of bees where wax is excreted from the abdominal parts of bees. BW consists of hydroxypalmitate, palmitoleate, palmitate, and oleate esters with long-chain aliphatic alcohols, which is classified as organic nonparaffin PCM with chemical formula C 15 H 31 COOC 30 H 61 . But, BW has a less thermal conductivity and medium range melting temperature, which limits the array of applications. At the same time, leakage during phase change process will also hamper the application BW [17,18]. To eliminate the huddle of less thermal conductivity, several methods have been adopted for improving rate of heat transfer and speeding up the meltfreeze cycle. ere are mainly two approaches to improve thermal conductivity, either disperse the high thermal conductivity particles into melted PCM [19,20] or impregnate the melted PCM into high conductivity porous or foam structure [21,22]. Iasiello et al. [23] employed metallic foam made up with net-like structure that connected with high conductivity metallic ligaments that produce pores, which is helpful for conductivity increment and leakage prevention of PCM. Ghahremannezhad et al. [24] incorporated highly porous, large surface area and high thermal conductivity metal foam that makes a good candidate for various PCM integrated thermal system. References [25,26] studied PCM coupled with finned metal foam. Metal foam integrated fin enhanced the heat transfer performance of PCM. e incorporation of properties-enhancing material not only raised the cost and weight of the energy storage units, but also reduced the PCM volume, which is the matrix material of energy storage system [27,28]. Recently, various innovative experimental and numerical analyses on thermal performance of various PCMs are tried with the combination of various nanoparticles. But, accurate nanoparticle selection also affects the heat transfer efficiency in a great manner. For the numerical analysis, ANSYA fluent software has been adopted to solve thermal performance of heat transfer problem by solving collectively continuity, momentum, and energy equation for various composite PCM. Tasnim et al. [28] investigated porous metal foam impregnated composite PCM analytically which is enclosed in a rectangular box. Darcy model was used to solve the current problem after assuming that PCMs act as single phase nanofluid for metal foam. Phase alteration process starts by the heat transfer initially through the conduction and after melting by convection. Sebti et al. [29] investigated by enthalpy-porosity method of composite PCM in 2D square cavity. ey stated that, after incorporation and increment of nanoparticles inside the PCM, the rate of heat transfer also increases; this is because of the thermal conductivity increment. However, viscosity escalation is leading to the reduction of the velocity of melted PCM. Zarma et al. [30] investigated the performance of nanoparticle-PCM incorporated with concentrator photovoltaic system. Complete performance of the hybrid system under different nanoparticles (Al 2 O 3 , CuO, and SiO 2 ) concentration into the PCM is discovered. Results revealed that, by adding Al2O3, the thermal conductivity of PCM has considerably increased, when compared with two other nanoparticles. Cheng et al. [31] prepared BW/tetradecanol/carbon fiber/expanded perlite (EP) composite PCM for the storage of heat energy. ermal conductivity of the composite enriched from 0.24 to 1.245 W/m-K which could form efficient charge-discharge cycle. e porous EP structure could prevent leakage during the molten state with the help of surface tension force. During the development of BW as PCM, Putra et al. [32] explored the BW/CNT composites for thermal energy storage. ey tried to examine the two main hampers of PCM, less thermal conductivity, and volume decrement at the time of phase conversion. Results disclosed that the thermal conductivity of the composite PCM was enriched by 132%. Putra et al. [33] inspected the character of BW and CuO as composite PCM. Five samples have been prepared and characterized. During the characterizations, it was found that the melting temperature of samples reduced slightly at the same time heat storage capacity also reduced, but caused no significant effects on the performance of composite. Moreover, utilization of nanoparticle enhanced properties PCM allows attaining a higher thermal regularity and electrical efficiency for the system. However, various researchers tried to analyse the behaviour of metaloxide particles and found less effect on the outcomes [34,35]. us, the nanooxides incorporation is still under argument with the PCM incorporation.
Ghalambaz et al. [36] explained the melt behaviour and heat transfer rate of PCM. e PCM was electrically conductive, enclosed in a square container exposed in nonuniform magnetic field. Magnetic field location and magnitude do not reveal the significant effect over natural convection during starts of melting. In time the melt fraction advancement takes place, the melt fraction value increases which enhances the fluid velocity and the magnetic field effect boosts.
In Ghalambaz and Zhang [37], the conjugate flow and heat transfer of phase change materials (PCMs)-metal foam confined between two annuli is addressed. e results are compared with theoretical and experimental studies available in the literature and found in good agreement. e steady-state solution and transient characteristics are addressed. e results demonstrate that the heat sink filled with PCM-metal foam can enhance the heat transfer at the hot surface, particularly at low external cooling power (Biot number <0.2). e results reveal that the fusion temperature of phase change material is the key parameter on temperature controlling of the hot surface. Using the phase change heat sink results in a cooling power four times higher than that of pure external convection during the pulse load.
In Ho et al.'s [38] experimental study, nanoencapsulated phase change material (NEPCM) nanoparticles with particle sizes in the range of 250-350 nm are synthesized. e impact of the nanoparticle's concentration, the heating power, and the flow rate is investigated on the channel wall temperature, Nusselt number, convection ratio, performance index, and coefficient of performance. e results show that the presence of NECPM particles improves heat transfer and the index of performance up to 70% and 45%, respectively. e observed enhancement of heat transfer is particularly notable at low Reynolds numbers. However, at the high Reynolds numbers, the presence of NECPM particles may reduce the convection ratio and performance index, which is mainly due to the increase of the viscosity and reduction of the sensible heat of the working fluid in the presence of NEPCM nanoparticles. e current article aims to perform numerical investigation on three commercial metal oxides-based composite PCM samples with three different volume concentrations of nanoparticles in four different annulus shapes' nano-PCM container to evaluate their thermal performance. e first objective is to establish a melting process's mathematical model for PCM through ANSYS Fluent and validate it from experimental results available in literature. e second objective is to perform a comparative study to analyse the thermal behaviour of the various annulus shape energy storage unit filled with BW. e last objective is to conduct a comprehensive approach of various energy storage systems containing dispersed nanoparticle (Al 2 O 3 , MgO, and SiO 2 ). For estimating the complete performance of the unit, temporal evolutions of the average composite PCM liquid fraction and temperature have been calculated for the various investigated cases. e motivation for the current work is to gather our knowledge about the new kind of energy storage system that may be utilized for various heat exchanger units, food safety containers, battery thermal management, etc.

Physical and Computational Model
Beeswax is selected as thermal energy storage material and air is utilized as a heat transfer fluid (HTF). e latent heat energy storage system used in the current study is four different annulus shapes with internal and external geometry: (1) rectangular-rectangular (rec-rec), (2) rectangular-circular (rec-cir), (3) circular-circular (cir-cir), and (4) circular-rectangular (cir-rec). e surface areas of all the annuli ar equal, where air flows over the outer side with temperature 340 K and at the same time over the inner side of the annulus exposed to a heat flux of 363 W/m 2 . e cross section of annulus system is displayed in Figure 1 where the initial temperature of PCM is 330 K. To enhance the rate of heat transfer and to overcome the less thermal conductivity of the BW, three different kinds of nanoparticle (Al 2 O 3 , SiO2, and MgO) with high thermal conductivity are mixed into the beeswax. ermophysical properties of the pure beeswax and the metal oxide nanoparticles are shown in Table 1 [7]. To execute numerical investigations on melting process of PCM system in suggested computational field, there are some assumptions which are considered: (1) Liquefied phase of composite PCM system and the movement inside the annulus container is Newtonian, laminar, and incompressible (2) Volume extension or reduction of system related with phase alteration in annulus container is not considered (3) Because container material contains higher thermal conductivity, the thickness of (1 mm) is ignored and variations of temperature are also ignored (4) Boussinesq approximation is considered to calculate density difference and relevant buoyancy motivated natural convection Current numerical solution acquired enthalpy-porous model in ANSYS Fluent15.0. All the units of length were fixed to mm and meshing quality was checked by grid independence test. Two-dimensional transient model with first-order implicit function was selected to solve the available problem.
e melting solidification as well as energy was designated and mushy region is constant adopted as default value. Physical properties of the composite are entered in the material panel. e specific heat and thermal conductivity are fixed as constant and density follows to Boussinesq hypothesis. SIMPLE algorithm was used for coupling velocity and pressure parameter during solution. For converging the solution, second-order upwind scheme is adopted for energy equation. Finally, the monitor window is set accordingly for specific model and enters in the convergence and next iteration.

Mathematical Model
Enthalpy-porosity technique is widely used to study phase change problems nowadays. ANSYS fluent software has a code for solid-liquid phase alteration module according to this model. With the use of enthalpy model, the problem of phase alteration becomes simpler with some advantages; that is, the equation is governed with single phase, there is no way for interface meeting, and it occupies a mushy zone. To understand the melt front accurately, the used governing equation is as follows.

Mathematical Problems in Engineering 3
Continuity equation: Momentum equation: where Su and Sv represent appropriate momentum sink terms, which are added to account for the pressure drop caused by the solid material, as follows: A mush is the constant value for mushy zone lies between 10 4 and 10 7 . ε is the constant value below 10 −4 . c is liquid volume fraction which could be obtained by Note that c � 0 represent solid phase of PCM, c � 1 represents the liquid phase of the PCM, and 0 < c < 1 is the indication of mushy zone.
ermal conductivity of the composite PCM that depends upon temperature, volume ratio, size of particle, properties of PCM, and properties of particle that is in Brownian motion is calculated with the help of the given equation (8).
e effective thermal conductivity of the composite PCM which includes the effects of particle size, particle volume fraction, and temperature dependence as well as properties of the base PCM and the particle subject to Brownian motion is given by where K B is Boltzmann constant with value 1.38 × 10 −23 J/K and d np is diameter of particle. f(T, ∅) is correction factor which is defined as Dynamic viscosity of composite is calculated as follows:

Grid Independence Test and Validation of the Numerical Model Used
For accuracy of the model and mesh generation, grid independence test has been performed for the melt fraction and temperature variation. For the given model, four kinds of number of elements that is 20000, 30000, 40000, and 50000 have been chosen. e time dependent problem performs the calculation for 2500 sec in cir-cir annulus and found the melt fraction and temperature variations shown in Figure 2.
ese results show that the variation of melt fraction and temperature is in little manner for all the four numbers of elements. e error percentage of two consecutive grid sizes has been taken into account and we found that the error is less than 0.05 percent for all the cases. So, for less solution time, 20000 elements is chosen for the calculations.
For any mathematical model used in engineering problem, it is an important task to investigate the validity of the proposed model. So, for validation, the comparative analysis of obtained numerical results with available experimental or numerical results is performed. In a short note, it is a routine operation in every numerical problem. In the present case, the accuracy for numerical model has been compared by the experiment results available in the literature [40]. Al-Abidi et al. [40] examined the enhancement of heat transfer through external and internal fins in triplex tube heat exchanger for melting of PCM experimentally as well as numerically. For numerical investigation, a two-dimensional ANSYS model was also developed by the researcher, where natural convection and pure conduction were considered for the simulation. e experimental results have provided the PCM average temperature during melting which is given in Figure 3. It was shown that the HTF temperature is at 363 K, which flows at the mass flow rate of 8.3 L/min and initial average temperature of PCM is at 300 K. e melting range of the PCM was in between 343 K and 355 K which is shown in the experimentation. As seen from Figure 3, the results of current model revealed worthy agreement with experimental results at the time of the melting. at is why the present model exhibited an acceptable behaviour for further investigations.

Variation of Average Liquid Fraction and Temperature with respect to Time for Pure Beeswax.
ermal behavior of beeswax is simulated according to the given numerical model and initial boundary condition. With the application of HTF temperature and heat flux from outer and inner walls, respectively, the different annulus PCM system starts heating sensibly in the beginning time. When the time is spent, the annulus PCM system temperature reaches the phase alteration temperature; at this time, the interface of phase change initiate and system starts capturing latent heat. Now, the PCM is at that condition where solid as well as liquid both phase occurred simultaneously and the system attains mushy zone where the temperature of system remains constant. Afterwards, when the system completely melts, the system temperature increases sensibly. In the phase change heat transmission model, the efficiency of heat transfer of PCM is significantly affected by temperature field, phase change interface, maximum temperature, and minimum temperature. Table 2 displays the phase alteration interface progress cloud diagram of different annulus beeswax system after various heating time.

Mathematical Problems in Engineering
e solid-liquid boundary can be differentiated by colour design of the melt volume fraction. e boundary of solid-liquid in the cloud diagram is denoted by 0-1. Solid phase is the blue area shown by 0 in colour cloud during phase transformation process and liquid phase in red area shown by 1. In the initial investigation, a constant HTF temperature and heat flux are applied at outer and inner part of different annulus PCM for 1000 sec and we found that few zones of the PCM attend 100% melt fraction; at the same time, temperature of inner and outer wall increased sharply. e melting space begins to appear from both sides of annulus and a slim phase transformation interface appears. When the PCM sample is heated for 2500 sec-15000 sec, most part of the annulus PCM melts completely and as the time increases melt fraction reaches 100%. e completely melted zones are displayed on both sides of the annulus and a temperature zone of 330-345 K appears in large phase alteration boundary. e reason behind the accumulation of big amount of latent heat is that the melting temperature range of the PCM is 330-345 K at the time of phase change, leading to a broader mushy zone. From Figure 4, the average melt fraction of different annulus shape PCM system for different time zones is revealed. e melt fraction varies from 0.12 to 0.58 for cir-cir shape, 0.13 to 0.6 for cir-rec case, 0.14 to 0.62 for rec-cir case, and 0.145 to 0.64 for rec-rec case when time varies from 2500 to 15000 sec.  ese data show that rec-rec shape annulus PCM system melts 10% more compared to cir-cir, 6% more compared to cir-rec, and 3.2% compared to rec-cir annulus shape. So, the rec-rec annulus PCM system melts little faster compared to other system. Heat transfer is arbitrated by the temperature gradient, material properties, and the system configuration. In the present case, temperature gradient and material properties are the same for all cases; the only variation is in its configuration. Transfer of heat is diffusive in nature and based on transformation thermodynamics heat flow reflects directionally like the mirror for light beam. So, for the rec-rec configuration, the direction of heat flow distortion is very less compared to other configuration that means less thermal resistance. e losses of heat energy in this case are very less and dominating in melting than others. Table 3 is the illustration of temperature field colour cloud at various heating time of the beeswax PCM annulus system. e colour contour of the annulus system provides details about the range of temperature in the unit K. From the variation of temperature range, it is illustrated that the variations in temperature lie between 330 and 345 K at the time of phase alteration. When the annulus beeswax system is heated for initial 2500 sec, the heat conduction starts due to constant HTF temperature from inner side of annulus and constant heat flux on outer side of the annulus. Due to the application of heat energy, a temperature difference occurs in the inner and outer part and wall temperature increases quickly. Initially, a steady-state temperature achieves in very short period of time because the inner and outer wall temperature    Mathematical Problems in Engineering of the PCM increases rapidly. In this initial time, a very small portion of the energy storage material completely melts and the peak temperature reaches 345 K. At the time when annulus sample is heated for 5000 sec-10000 sec, the mode of heat transfer is dominated by convection, and melting of the annulus PCM system moves towards solid part from inner and outer side. Meanwhile, in the mushy zone where slow increment in temperature has huge amount of phase alteration, latent heat and the lowest temperature occur inside the temperature field somewhere between inner and outer wall. e peak or extreme temperature reached the wall. When mushy zone is finished, the annulus system melts completely. is is because the supplied heat is no more used for melting or not for utilizing in latent heat absorption. When the heating time reached 15000 sec, the whole annulus system achieved the phase alteration temperature and the peak temperature at this time reaches 345 K but the entire system is not melted completely. e gained liquid area is heated sensibly at this time. In the phase transition from solid to liquid, when time is spent, the heat transfer due to convection starts to dominate over conduction and the liquid region moves up and down rapidly. Figure 5 reveals the average temperature of different annulus shape PCM system for different time zone. e temperature varies from 335 to 341 K for cir-cir shape, 335.4 to 341.4 for cir-rec case, 335.6 to 341.6 for rec-cir case, and 335.8 to 341.8 for rec-rec case when time varies from 2500 to 15000 sec. ese data show that temperature rise of rec-rec shape annulus PCM system is 0.2% more compared to circir, 0.1% more compared to cir-rec, and 0.05% compared to rec-cir annulus shape. Results show that there is a negligible effect of temperature variation in all the cases.

Variation of Average Liquid Fraction and Temperature with respect to Time for Composite-Beeswax.
e overall thermal performance of the annulus PCM area with different shape annulus container shown in Figure 1, under the effect of various nanoparticles (Al 2 O 3 , SiO 2 , and MgO) distribution into the beeswax PCM, is discovered. e average melt fraction and temperature for three metal oxides with three volume fraction concentrations of nanoparticles (1%, 3%, and 5%) are explored. e low volume fraction participation of particles (5% maximum) slightly affects the thermophysical properties of the resulting composite PCM.
However, there is no suggestion for utilization of high concentration of particles; with the loss of mass of PCM, the heat storage volume of the system reduces. At the same time, particle concentration increases the composite viscosity that causes the loss of heat exchange [41]. e heat transfer process dominates by natural convection in the case of melting; as the viscosity increases, the buoyancy of the fluid reduces which leads to slowing of the melting procedure [42]. From the results shown below, it is shown that the addition of nanoparticles in a very little proportion could increase thermal conductivity of the beeswax that is the major cause for quick increment of melt fraction and annulus temperature. But higher proportion of particles could upsurge the composite viscosity which causes the temperature quenching in the PCM that affects the melting rate of PCM [43]. It is noted that as the nanoparticle concentration increases, the energy storage by the composite PCM decreases, because the increment of particle fraction decreases the occupied volume of base PCM. Hence, less particles concentration in PCM does not only show healthier melting behaviour but also have greater energy storage performance for a given annulus compared with higher concentrations of particles. e results found for average melt fraction and temperature of different annulus beeswax at different nanoparticle concentrations are discussed in the next sections.

Evolution of Melt Fraction and Temperature in Cir-Cir
Annulus PCM. From Figures 6 and 7 it is revealed that both the average melt fraction and temperature are meaningfully improved in the presence of nanomaterials. It is remarked that, due to the slight variation in thermophysical properties of the particles, there is no critical variation in rate of heat transfer and phase transformation. For the three examined metal oxide particles, the temperature rise in the cir-cir annulus composite PCMs attained 340 K in case of 1% volume fraction for Al 2 O 3 , at 2500 sec and 346 K for 15000 sec, whereas, as noted for the pure BW PCM at the time of 2500 sec and 15000 sec, it is 335 K and 341 K, which shows an improvement of 1.49% and 1.46%. e liquid fraction for the same condition increases from 0.12 at 2500 sec and 0.58 at 15000 sec for the pure BW to 0.2 at 2500 sec and 0.88 at 15000 sec, respectively. It is shown from the results that the melting Mathematical Problems in Engineering 9

Evolution of Melt Fraction and Temperature in Rec-Rec
Annulus PCM. e average liquid fraction and temperature are shown in Figures 12 and 13. It is found that heat transfer properties enhanced significantly in the presence of metal oxides nanomaterials. e rise in temperature for rec-rec annulus composite PCMs in the case of three investigated metal oxides was found as 340.6 K in case of 1% volume fraction for Al 2 O 3 , at 2500 sec and 346.7 K for 15000 sec, whereas it is noted for the pure BW PCM at the time of 2500 sec and 15000 sec as 335.8 K and 341.9 K, which shows an improvement of 1.43% and 1.4%. e liquid fraction for the same condition increases from   process, the change in temperature difference reflects a change in Stefan number and is formulated as where C p is PCM specific heat, L is PCM latent heat, T is surface temperature, and T m is PCM melting temperature; Stefan number directly depends upon the temperature difference as the higher the difference, the higher the Stefan number value. e melt fraction with time for three different Stefan numbers of 0.044, 0.073, and 0.118 for three temperature differences gives the idea about operating situation at the time of melting process of annulus PCM system. It can be revealed from Figure 14 that surface temperature and melting temperature during the heat transfer process of PCM affects the melting rate; the more the temperature difference, the higher the rate of the melt fraction increment and the shorter the melting time.
Rayleigh number shows the strength of the convection induced inside annulus system domain. High value of Rayleigh number means higher convective current causing faster melting method. e Rayleigh number is formulated as Temperature changes of the PCM inside the annulus unit after a different time interval of melting for the different cases as shown in Figure 14.
e heat transfer occurred between the hot wall of the annulus and the solid part of the PCM by conduction, which dominated the melting at the early stage of melting and caused a thin layer of liquid to form due to the heat transfer phenomena. As the time progressed, this layer expanded and the liquid fraction increased; the hotter liquid of the PCM was pushed upward to the top of the annulus due to the natural convection effects

Data Availability
Supporting data are available in the workstation of computational laboratory of Prof. K M Pandey. However, these data cannot be generalized to be sent to everybody. is is the reason that the results have been provided but the raw data are kept confidential by the authors. e graphs have been generated from the software used and the institute has license of the software used.

Conflicts of Interest
e authors declare that they have no conflicts of interest.