Effect of Chloride Ions on Electrochemical Behavior of Canister Materials

Various canister candidate materials (SS316L, Ti-Gr.2, Alloy 22, and Cu) were studied using groundwater at the Korea Atomic Energy Research Institute (KAERI) underground research tunnel (KURT), with the addition of chloride ions using dierent electrochemical techniques. e corrosion potential and corrosion current of test materials were obtained by the polarization measurement. e polarization measurements revealed that the addition of chloride ions was detrimental to the SS316L and Cu materials by increasing corrosion current, which is an indicator of corrosion rate. Impedance measurements and tting analysis showed that the corrosion resistance of Cu was more than 10 times lower than that of other materials in the KURTgroundwater solution containing 0.1M of chloride ions.


Introduction
A metal canister, which enables the isolation of high-level radioactive waste and prevents its leakage, is regarded as the rst barrier in a multi-barrier deep geological disposal system. Several countries have adopted di erent candidate materials for canisters according to the nature of the radioactive waste and the geological environment. Typically, a Cu canister with a cast-iron insert is used in Sweden and Finland; a Cu-coated steel vessel was designed in Canada, and an inner stainless-steel (SS316) cylinder with an outer alloy 22 cylinder and titanium drip shield is considered in the US as canisters [1][2][3][4][5][6][7][8][9]. e lifetime of a canister must be longer than at least 10 4 years, and it is signi cantly a ected by geochemical environmental factors such as dissolved oxygen, chemical composition of groundwater, and temperature. In particular, the initial corrosion of canisters is caused by aggressive species in groundwater such as chlorides, sulfates, and nitrates [4]. Previously, we have reported the corrosion behavior of di erent canister materials (SS316L, Ti-Gr.2, Alloy 22, and Cu) in a Korean domestic repository environment [10].
In this study, we investigated the e ect of chloride ions on the electrochemical behavior of the materials to extend the scope of our previous research [10] by comparing the corrosion potential and corrosion current of test materials and by calculating the polarization resistance through impedance tting analysis. Chloride is known to be the most aggressive anion and strongly in uences the corrosion behavior of metals. erefore, NaCl was added to groundwater at the Korea Atomic Energy Research Institute (KAERI) underground research tunnel (KURT), and potentiodynamic measurements were performed to examine the corrosion potentials and currents of the test materials. Furthermore, electrochemical impedance spectroscopy was performed to observe the corrosion resistance ability of the canister materials.

Materials and Methods
Stainless steel 316L, titanium grade 2 (Ti-Gr.2), nickel alloy 22 (Alloy 22), and copper (Cu) were used as working electrodes (surface area: 1 cm 2 ). e chemical composition of the test materials used in this study is presented in Table 1.
Before the experiment, the electrodes were polished with SiC paper (∼2000 grit) and 0.15 μm alumina paste. Subsequently, the electrodes were sonicated in distilled water and dried. A saturated calomel reference electrode (SCE) and a Pt-mesh counter electrode were used to complete the cell. e electrolyte solution was KURT groundwater mixed with NaCl (0.1 M). e chemical composition of KURT groundwater has been reported previously [10]. A BioLogic SP-300 potentiostat/galvanostat with a typical three-electrode cell configuration was employed in the electrochemical experiment. All experiments were conducted at room temperature (25°C). Potentiodynamic polarization curves were obtained at a scan rate of 1 mV/s. Electrochemical impedance spectroscopy (EIS) measurements were performed at open circuit potential (OCP) by applying an AC signal of ±10 mV amplitude RMS in the frequency range of 100 kHz to 10 mHz. Figure 1 shows the polarization curves of the aforementioned four materials immersed in the chloride ion-added groundwater solution. Compared with the previous result obtained for KURT groundwater solution without the addition of 0.1 M NaCl [10], it is evident that the addition of chloride ions to the groundwater solution shifts the corrosion potential to more negative values for all materials.

Results and Discussion
is increases the current density for materials, except Alloy 22. e polarization curve for SS316L shows obvious anodic behavior with a corrosion potential (E CORR ) of -0.230 V vs. SCE and a corrosion current (i CORR ) of 0.243 μA/cm 2 . As the electrode potential was increased above the corrosion potential, the anodic current increased gradually, followed by a rapidly increasing current near 0.6 V vs. SCE (pitting potential, E pit ). Ti-Gr.2 exhibited the highest E CORR among the test materials and passivation characteristics, unlike other metals.
e high corrosion resistance of titanium in an aggressive environment is ensured by chemically stable oxide films such as TiO 2 [11]. Alloy 22 exhibited an E CORR close to that of Cu, and the current density increased gradually as the potential increased. Cu showed a more apparent increase in corrosion current density than the other materials in the presence of chloride ions in the solution. It was also observed that the potential range decreased above the corrosion potential, wherein the anodic current density increased rapidly. is result shows the aggressiveness of chloride ions; the corrosion potential decreases, and the current density increases with the addition of chloride ions [12]. e corrosion potentials and currents of the test materials are listed in Table 2.
EIS measurements at the OCP were performed on the test materials (SS316L, Ti-Gr.2, Alloy 22, and Cu) by exposing them to the KURT groundwater solution, to which chloride ions were added. In the chloride-added KURT groundwater solution, a single capacitive semi-circle with a tail showing that the corrosion process was mainly charge transfer controlled [13] was found at SS316L, Ti-gr.2, and Alloy 22, whereas Cu exhibited more than one semi-circle (Figure 2). e comparison of arc radius in Figure 2 allows for a relative order of magnitude of corrosion resistance of materials [14].
In the presence of chloride ions, it was confirmed that the corrosion resistance of Ti-Gr.2 was relatively low compared to SS316L, which coincided with the previous study [15]. e three kinds of relaxation of Cu are clearly identified in Figure 3(a), which is quite similar to previous study [16]. e three time constants are attributed to the double-layer capacitance with charge transfer resistance, oxide layer-related capacitance in parallel with resistance, and reversible reactions or diffusion. e total impedance magnitude at intermediate frequency region can be attributed to the electrochemical corrosion reaction on metal surface. e total impedance magnitude of materials, immersed in the chlorideadded KURT groundwater, in the low frequency range attributed to the electrochemical corrosion process was Cu < SS316L < Ti-Gr.2 < Alloy 22 (Figure 3(b)).  e measured impedance data in the chloride-added groundwater solution were fitted using equivalent circuits (Figure 4) to quantify and compare the impedance components of the test materials. e equivalent circuits were mostly used to elucidate the obtained data [16,17]. In equivalent circuits, R represents the resistance, and Q     represents the constant phase element (CPE), which was adopted to represent non-ideal capacitive behavior due to uneven current distribution or surface inhomogeneity. e CPE can be expressed as where Q, ω, and n represent the CPE amplitude, angular frequency, and CPE exponent, respectively [18]. e value of n can be 0 ≤ n ≤ 1, where 0 and 1 represent an ideal resistor and capacitor, respectively. e fitted curves are shown in  At the surface of the metal that is in contact with the chloride-containing solution, RC is related to the doublelayer capacitance with charge transfer resistance [16,17,[19][20][21], oxide film capacitance with resistance experienced by the ions while traveling through the oxide [22][23][24], and reversible reaction or diffusion process [25,26]. Diffusion is replaced by Warburg impedance instead of an RC combination to describe mass transfer from or to the surface [17,22]. For SS316L, Ti-Gr.2, and Alloy 22, the third component was fitted satisfactorily using a model with a Warburg element (W 3 ), indicating that the diffusion process is involved in the corrosion mechanism [17]. In this study, the polarization resistances (R p ) of the test materials were calculated as R p � R 1 + R 2 , where R 1 and R 2 represent the oxide film resistance and charge transfer resistance, respectively [27,28]. e calculated R p values are given in Table 3. It can be observed that the polarization resistance of Cu is one order lower than that of other materials.

Conclusions
Electrochemical characterization of various canister materials was performed using KURT groundwater with the addition of chloride ions. e corrosion potential and corrosion current of the test materials (SS316L, Ti-Gr.2, Alloy 22, and Cu) were measured using the polarization technique. e presence of chloride ions lowered the corrosion potential of SS316L and Cu. From the impedance measurements, we determined that Cu has a higher initial corrosion susceptibility than SS316L, Ti-Gr.2, and Alloy 22; in particular, the polarization resistance of Cu in the groundwater solution containing chloride ions is one order lower than that of other materials.

Data Availability
e data used to support the findings of this study are included within the article.

Conflicts of Interest
e authors declare that there are no conflicts of interest regarding the publication of this paper. Table 3: R p values of SS316L, Ti-Gr.2, Alloy 22, and Cu exposed to chloride-added KURT groundwater solution.