Effect of Mechanical Vibration with Different Frequencies on Pore Structure and Fractal Characteristics in Lean Coal

The mechanical vibrations caused by underground operations can easily lead to coal and gas outbursts in coal mines. Using the MVGAD-I experimental platform that we designed, the raw coal (0Hz) was treated with vibration frequencies of 25, 50, 75, and 100 Hz, and the coal samples with diﬀerent frequency vibrations were obtained. The total pore volume (TPV), speciﬁc surface area (SSA), pore size distribution, and the pore fractal dimension (PFD) of ﬁve coal samples were analyzed by mercury intrusion porosimetry and low-pressure nitrogen adsorption data. We found that the TPV, SSA, and PFD of the coal samples ﬂuctuate with the increase of vibration frequency. The changes of the TPV and SSA of coal samples treated with 25 and 75 Hz vibrations were signiﬁcantly greater than those subjected to vibrations of 50 and 100 Hz. Compared with the raw coal (0Hz), the TPV and SSA of macropores, mesopores, and micropores increased the most in 75 Hz vibration coal sample. Therefore, the 75 Hz vibration excitation can improve the permeability of a body of coal mass and is conducive to the diﬀusion and seepage of coalbed methane and its production.. The inﬂuence of 25Hz vibration on the TPV and SSA of macropores and mesopores is not obvious, but the TPV and SSA of minipores and micropores decrease signiﬁcantly, which is not conducive to gas diﬀusion and adsorption. In addition, 25 and 75Hz vibrations obviously damaged the fractal characteristics of both mesopores and micropores, resulting in the change of gas adsorption and diﬀusion ability. The rational use of a 75 Hz vibration is beneﬁcial to both the production of gas and the prevention of outbursts, while a 25Hz vibration should be avoided. The results are expected to reveal the microscopic mechanism of a vibration-induced outburst and provide theoretical guidance for employing the appropriate frequency of vibration to improve the rate of gas drainage and reduce the risk of outbursts.


Introduction
Coal and gas outbursts are one of the major disasters that threaten the safety of coal mine production [1][2][3]. Among recorded outburst accidents, the vast majority were induced by "small disturbances" that, in turn, were produced by blasting in mines and tunnels and drilling [4][5][6][7][8][9]. ese "small disturbances" often provide energy for gas desorption, the crushing of coal, and the ejection of gas-solid mixtures in the form of vibrating at different frequencies (VDF) [10]. As a complex porous medium, coal has a dual-porosity system, which affects the adsorption and diffusion of gas in coal and the mechanical properties of coal [11][12][13][14]. Often, coal and gas outbursts occur in areas that have been disturbed by tectonism, and the coal bodies in those areas are then characterized as crumpled and cracked [15]. e vibration caused by a "small disturbance" may lead to a change in the pore structure of the coal, which has an important influence on its permeability, coal strength, elastic modulus, gas adsorption, and diffusion [16][17][18][19][20]. erefore, it is of great significance to study how vibration affects the evolution of pores and fissures in the coal to reveal the microscopic mechanism of "small disturbances" that affect the instability of coal rock and the gas adsorption and diffusion characteristics of the coal seam.
At present, some scholars have carried out research on the effect of vibration caused by "small disturbance" on the storage and transport of gas in coal and the permeability and mechanical properties of coal. Li et al. [5] concluded that vibration can reduce the coal's capacity to absorb gas but did not consider the differences caused by the vibration frequency in their research. Furthermore, some scholars take the vibration frequency as an important parameter by which to carry out adsorption and desorption experiments of gas in coal. Li et al. [7,21,22] concluded that a low-frequency mechanical vibration of 0∼30 Hz is not conducive to the adsorption and desorption of gas in coal and will reduce the permeability of the coal and hinder the gas diffusion and seepage. In other words, the higher the frequency, the greater the likelihood that it will cause a local outburst. In contrast, Chen et al. [23] concluded that the shear force and thermal effect of a 30-100 Hz mechanical vibration on gas molecules can promote gas desorption and diffusion. While affecting the adsorption and desorption capacity of coal to gas, the stress wave generated by the vibration can also accelerate the development of internal cracks in the coal and rock mass, resulting in increased permeability of the coal rock [24][25][26], and the permeability increases exponentially with the increase of frequency [27]. In addition, from the perspective of fracture mechanics, Li et al. [5] asserted that vibrations will expand the cracks in the coal body and form a large-area network of fractures, which will reduce the strength of the body of coal which, in turn, would then be more prone to instability, thus increasing the risk of an outburst. At the same time, Ren and Pan et al. [28][29][30] also found that when the initial stress level reaches a certain critical state, a vibration has an obvious effect of cracking the body of coal, and the compressive strength and elastic modulus of the body of coal decrease significantly. Moreover, Li and Sun et al. [31,32] believed that the closer the forced vibration frequency of coal and rock is to the natural vibration frequency, the more likely the coal and rock mass will be damaged and, thus, becoming unstable. ere were a few studies on the evolution of the size of the pores in coal--ranging from micro-to nanoscale pores-caused by vibration. However, the nan and microscale pores and fissures are also directly related to the gas desorption and diffusion in the coal and the mechanical properties of coal [16,33,34]. erefore, it is necessary to characterize the process of porefracture evolution in coal with VDF quantitatively in the range from micro-to nanopore sizes.
To date, the methods of qualitative and quantitative characterization of the pore structure of coal include mercury intrusion porosimetry (MIP), low-pressure nitrogen adsorption (LPNA), scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and small-angle X-ray scattering [35][36][37][38][39]. Researchers generally use a combination of the characterization methods of the MIP and LPNA tests to analyze the characteristics of micro-and nanoscale pores and fractures [14,37,[40][41][42] and then analyze the influence of different pore-fracture characteristics on the adsorption, desorption, and diffusion of gas in coal [43,44].
Fractal geometry is a powerful tool for quantitatively characterizing the morphology of pores and fractures in coal samples [20,42,45]. e fractal characteristics of coal are also one of the important factors affecting the adsorption, desorption, and diffusion of gas in the coal matrix [13,37,46]. e influence of vibration on the pore-fracture structure of a coal sample will inevitably lead to a change in the surface morphology characteristics of the pore-fractures [38,47]. However, a few studies use fractal geometry to quantitatively characterize the complexity of the porefracture surface morphology of coal samples under VDF.
Based on the shortcomings of the existing research, we selected tectonic coal from an outburst risk coal seam as the research object and used the methods of MIP and LPNA to quantitatively characterize the total pore volume (TPV), specific surface area (SSA), and pore size distribution (PSD) of coal samples under VDF. Based on the Menger and Frenkel-Halsey-Hill (FHH) models, the fractal dimensions of pores with different pore sizes under VDF were obtained by calculating MIP and LPNA data. And, in order to reveal the mechanism of vibration affecting gas permeability and diffusion in coal, this research deeply explores the evolutionary characteristics of pore structure in coal samples caused by vibrations which were caused by "small disturbances." is plays an important role in deeply understanding the mechanism of gas storage and transportation in coal and the mechanical change of coal under the influence of vibration and provides theoretical guidance for implementing engineering measures with different vibration frequencies to reduce coal and gas outburst accidents.

Materials and Methods
e MVGAD-I experimental device was designed to prepare coal samples with VDF. e pore and fracture distribution characteristics of the coal samples were quantitatively characterized by high-pressure mercury injection and lowtemperature liquid nitrogen adsorption. e pore fractal dimension of the coal samples was calculated by fractal theory combined with MIP and LPNA data. e flowchart of this study is shown in Figure 1.

Description of Coal Samples.
e coal samples used in the experiment were collected at 15021 working face of Wangxingzhuang coal mine in Henan Province. e coal sample belongs to lean coal with the characteristics of being soft and broken. According to the standard GB/ T23561.1∼2009 [48,49], fresh coal samples were taken from the working face; transported to the laboratory; screened out, 0.25∼0.5 mm coal samples; dried in a vacuum at 45°C for 8 h; and prepared, 1500 g experimental samples. After the preparation of the coal samples, vibration experiments at different frequencies were carried out. en, the coal sample was divided into five parts, each 200 g; the remaining coal sample was reserved; and all coal samples were sealed.

2.2.
Equipment. An MVGAD-I experimental device, which can carry out gas adsorption and desorption experiments under different vibration conditions (frequency and amplitude), was designed independently in the laboratory. e platform was composed of the gas supply subsystem, the vacuum degassing subsystem, the isothermal adsorptiondesorption subsystem, the mechanical vibration generation subsystem, and the data acquisition subsystem. e schematic diagram is shown in Figure 2.
e device can not only apply vibration excitation to a coal sample but also carry out gas adsorption and desorption experiments of coal samples at a constant temperature under vibration conditions. It has the following characteristics: (1) the vibration condition is adjustable. e device adopts an HX/ZD-TF electromagnetic vibration table, with an adjustable vibration frequency (0∼600 Hz) and amplitude (0∼5 mm). (2) Data automatic measurement and acquisition: the device can measure in real-time and collect the temperature (accuracy less than 0.5%) and pressure (accuracy less than 0.5%) and gas flow and velocity (accuracy less than 0.5%). (3) e temperature is controllable. Temperature control (10∼75°C) at a constant temperature is realized by using an automatic heating belt and insulation layer.

Vibration Excitation Experiments of Coal Sample.
In the coal mine site, the vibration frequency range caused by "small disturbances," such as blasting, drilling, coal cutting by shearer, and tunnelling, is 5 ∼ 100 Hz [6,50,51]. To characterize the influence of VDF on TPV, SSA, and PSD of the coal samples, mechanical vibrations with the frequencies of 0, 25, 50, 75, and 100 Hz were selected for the coal sample vibration experiment.
Before the experiment, the vibration frequency (0∼100 Hz) and amplitude (1 mm) were set by the control panel, and the power was turned off after the parameters had been set. en, we put the coal sample with the mass of 100 g after vacuum drying into the coal sample tank, turned on the power supply to carry out the vibration with different frequencies test of the coal samples, and set the vibration time to 20 min. Finally, after vibrating under different frequencies, the coal samples were poured out of the coal sample tank and put into a sealed bag for sealed preservation, to conduct the pore and fissure characterization experiment.

MIP.
According to ISO 15901∼1 : 2005 (PSD and porosity of sturdy materials by mercury porosimeter and method adsorption, Part 1: mercury porosimeter) [48,49], the MicroAutoPore IV 9500 mercury intrusion instrument (test aperture range d > 3 nm, mercury injection pressure 0.1∼413.05 MPa) was used to carry out the MIP test on the coal samples with frequencies of 0 Hz (S 0 ), 25 Hz (S 25 ), 50 Hz (S 50 ), 75 Hz (S 75 ), and 100 Hz (S 100 ), respectively, to obtain TPV, SSA, and PSD data on the pore-fissures. e fractal dimension D 1 of pores in coal is calculated by formula (1) based on mercury injection data and using the Menger model and thermodynamic method [20,37,47]: where V p represents the cumulative injection volume at a given pressure P, mL/g; P represents the absolute injection pressure, MPa; and D 1 represents the fractal dimension of the pores. Shock and Vibration adsorption [15,49], the MicroActive software for the ASAP 2460 instrument was used to confirm the pore structure characteristics of the VDF coal samples at a temperature of 77 K and a relative pressure (P/P 0 ) of 0.01∼0.99. e aperture test range of the instrument was 1.3∼300 nm. e density functional theory (DFT) was applied to quantify the adsorption-desorption isotherms, in which the TPV, SSA, and PSD of minipores and micropores were analyzed. At present, the FHH fractal model is widely applied to calculate the adsorption data of LPNA and obtain the pore fractal dimension [20,37,42]: where P represents the equilibrium pressure, MPa; P 0 represents the saturation pressure of methane gases, MPa; V represents the volume of adsorbed gases at the equilibrium pressure p, cm 3 /g; C represents a constant; A represents the slope of double logarithm curve of ln V versus ln (ln (P 0 /P)).
To date, the pore fractal dimension of a coal sample can be obtained by using formulas (3) and (4) based on the FHH model to calculate LPNA data [20,46]: where D 2 is the fractal dimension.
In the low-medium pressure region (P/P 0 < 0.5), the main force between the pore adsorption interface and N 2 is Van der Waals force (VDWF). Formula (3) represents the relationship between D 2 and A. In the experimental high-pressure region (P/ P 0 ≥ 0.5), coal pore capillary condensation occurs, the adsorption mechanism changes, and the relationship between D 2 and A changes synchronously, which meets formula (4). Most of the D 2 values obtained by formula (3) are less than 2, which violates the geometric meaning of the fractal dimension of coal pores; that is, D 2 should be between 2 and 3 [37,52]. Comparatively speaking, D 2 obtained by formula (4) has practical geometric significance. erefore, the FHH fractal dimension of the coal sample pore (d < 100 nm) is uniformly obtained by formula (4) [42].

Results and Discussion
According to the B.B. Hotdot pore diameter classification system, coal matrix pores can be divided into four categories: micropore (pore diameter d < 10 nm), minipore (10 nm < d < 100 nm), mesopore (100 nm < d < 1000 nm), and macropore (d > 1000 nm) [37]. Among them, minipores and micropores provide the main storage space for gas adsorption, while macropores and mesopores will provide the main paths for gas diffusion and fluid flow [37,46]. Figure 3 shows the MIP intrusion and extrusion curves of coal samples with vibration at different frequencies. When the mercury injection pressure is below 0.1 MPa (D ≈10000 nm), mercury mainly penetrates the intergranular pores [52], and when the mercury injection pressure is greater than 10 MPa (D ≈120 nm), the coal matrix is compressed and this deformation causes pore damage [42]. erefore, MIP is mainly used to analyze the structural characteristics of mesopores and macropores.

MIP Results for Coal Samples Subject to Different Vibration Frequencies.
ere is an obvious hysteresis loop between the MIP intrusion and extrusion curves of the VDF coal samples. e possible reasons for the formation of the hysteresis loop are the different contact angles between the coal during mercury intrusion and extrusion, and mercury and the existence of an "ink-bottle" hole in coal [49]. Moreover, the hysteresis loop formed by the mercury intrusion and extrusion curves reflects the connectivity of the pore-fracture network structure [34]. Broad hysteresis loops indicate excellent pore connectivity. Compared with the raw coal sample, the hysteresis ring width of S 75 is significantly increased, which indicates that the 75 Hz vibration caused the pore-fracture structure of the coal sample to expand and develop and then promoted the maximum increase of connectivity. Except for S 75 , there is no obvious change to the hysteresis loop width of the coal samples, which indicates that the pore connectivity has had little change. Figure 3 shows that the total mercury intrusion volume of VDF coal samples first increases and then decreases with an increase in vibration frequencies. At 378.89 MPa high pressure, the maximum mercury intrusion volumes of S 0 ,  S 25 , S 50 , S 75 , and S 100 were 0.0587 ml/g, 0.0621 ml/g, 0.0627 ml/g, 0.0629 ml/g, and 0.0596 ml/g, respectively. S 75 was the maximum and S 0 the minimum volumes. Compared with S 0 , S 75 increased the mercury intrusion volume by 7.16%. ere are two possible reasons why vibration caused an increase in the mercury injection volume. First, when the amplitude is constant, the greater the frequency, the greater the acceleration and force of the vibration of the coal matrix [21,22]. e coal matrix is destroyed and deformed due to mechanical extrusion, which leads to the expansion and development of pores and microcracks. Second, the increase of the vibration frequency makes the number of collisions between coal particles increase, resulting in the expansion and development of microcracks on the surface of coal particles. e reason for the largest pore volume of S 75 is that the vibration frequency of 75 Hz is close to the natural frequency of raw coal, and then resonance occurs. For four frequency vibration coal samples, the pore volume of S 100 is the minimum, which may be due to the destruction and collapse of the skeleton of the coal matrix due to great extrusion stress, and some pore channels are blocked. Figure 4 shows that the PSD of macropores and mesopores in VDF coal samples first decreases and then increases with the decrease of pore size. With the increase of vibration frequency, the volume of macropores first increases and then decreases, the value of S 75 is the maximum, and the value of S 0 is the minimum; the volume of mesopores shows a wavy trend of first decreasing, then increasing, and after that decreasing with the increase in vibration frequencies, the value of S 75 is the maximum, and the value of S 25 is the minimum. e variation range of the total volume of the macropores with the vibration frequency is obviously larger than that of the mesopores. Compared with S 0 , the macropores volume of S 75 has the largest increase, up to 25.44%. And compared with S 0 , the mesopores volume of S 25 decreases by 2.33%, and the mesopores volume of S 75 increases by 8.78%. e influence of vibration on the total volume of macropores is obviously stronger than that of mesopores, and the impact of the 75 Hz vibration on the total volume of macropores and mesopores is the most significant. Song et al. [24][25][26] used CT scanning technology to draw the conclusion that vibration promotes the expansion of coal rock fractures and new fracture development, resulting in a permeability increase. is conclusion also proves the above results, to a certain extent.
With the decrease of pore size, the PSD of all coal samples first decreases and then increases (Figure 4). In the range of 2000∼10000 nm, the pore size distribution of the vibration coal sample is obviously different from that of the raw coal sample. Compared with S 0 , the pore volumes of S 25 , S 50 , S 75 , and S 100 increased by 14.43%, 19.99%, 36.36%, and 21.32%, respectively. e results show that vibration leads to the increase of pore size in the range of 2000∼10000 nm; and except for 75 Hz vibration, the higher the vibration frequency, the more obvious the increase in pore volume. In the range of 800∼2000 nm, the PSD of five coal samples is close, which indicates that the influence of vibration on the pore size is not obvious. Compared with S 0 , the pore volumes of S 25 , S 50 , S 75 , and S 100 increased by 6.45%, 10.47%, and 1.13%, respectively, in the range of 100-800 nm, but the pore volume of S 25 decreased by 1.96%. e 25 and 100 Hz vibrations have little effect on the volume of mesopores in the pore size range of 100∼800 nm. e vibration at 75 Hz has a significant impact on the mesopore volume in this range. And, in this pore size range, with the decrease of pore size, the pore size distribution of the coal samples with different frequencies fluctuates greatly compared with the raw coal samples, showing a single and multipeak distribution. is shows that vibration has a great influence on the pore sizes distribution in this range. e pore size distribution of S 50 and S 100 fluctuated obviously. And compared with S 0 , the pore volume differential of S 50 increases significantly at 226.88 nm, 433.44 nm, and 676.43 nm, and the pore volume differentiation of S 100 at 151.08 nm and 283.81 nm increases significantly. e pore volume distribution of S 75 increases uniformly with the decrease of pore size, and the pore volume differential at 151.17 nm is significantly larger than that of other coal samples. is demonstrates that the effect of resonance on the coal pore structure is more obvious. e PSD of S 25 is the most uniform, and there is no large fluctuation. However, the pore size of S 25 decreases in the range of 100∼800 nm due to the 25 Hz vibration.
ere are two reasons for the influence of vibration on the PSD and TPV change of macropores and mesopores in the coal samples. First, the periodic extrusion stress generated by vibration makes the parts of the coal matrix skeleton with weak antiextrusion ability collapse or fracture, and the pore volume decreases due to the collapse of the coal matrix skeleton blocking some of the pores. At the same time, the pore volume increases due to the expansion and development of pore fractures caused by the fracture of the coal matrix skeleton. Secondly, the matrix pores are  extruded due to the deformation of the part of the coal matrix skeleton caused by periodic extrusion stress, resulting in the bulge or depression of pore surfaces. e greater the vibration frequency, the stronger the extrusion pressure of coal matrix [22], and as a result, the possibility of deformation and failure of coal matrix skeleton is greater. When the vibration condition resonates with the natural frequency of the coal sample, the vibration has the strongest effect on the destruction and deformation of the coal matrix skeleton [29]. e change of the coal pore structure caused by vibration is caused by the superposition of the collapse and fracture of coal matrix skeleton and the concave and convex deformation of some areas, which eventually leads to the increase of the pore size of macropores and mesopores and then increases the permeability of coal seam. e PSD and TPV of coal samples change due to vibration, which inevitably leads to the change of pore SSA. Figure 5 shows the distribution of the macropores and mesopores SSA of the VDF coal samples. Figure 5 shows that the total SSA of mesopores is much larger than that of macropores. With the increase of vibration frequency, the SSA of mesopores first decreases, then increases, and after that decreases. e SSA of S 25 decreased by 1.95% compared to that of S 0 , while that of S 75 increased by 13.16% compared to that of S 0 . e SSA of macropores first increased and then decreased with the increase of vibration frequency. Compared with S 0 , the total specific surface area of macropores of S 75 changed the most, reaching 16.72%. From the perspective of variation quantity, the influence of vibration on the SSA of macropores is greater than that of mesopores. e above results are consistent with the variation trend of the total volume of macropores and mesopores in Figure 4. Because the pore volume increases, the corresponding pore specific surface area increases. e pore SSA distribution in Figure 5 shows that the pore specific surface area differential of all coal samples increases with the decrease of pore diameter. e differential growth of the specific surface area of macropores was slow, and the value of the specific surface area was between 0 and 0.01 m 2 /g. e specific surface area of mesopores differential growth is rapid; the SSA of S 25 in the region increases evenly; and S 50, S 75 , and S 100 in the process of increasing the region show varying degrees of fluctuation. e fluctuation range of pore specific surface area distribution of all coal samples is basically consistent with that in Figure 4. Vibration results in the change of pore volume and pore surface morphology. e deformation and destruction of the coal matrix skeleton result in pore convex deformation or collapse, changing the size of the specific surface area. In addition, vibration may lead to the stripping or peeling of minerals attached to the pore surface, resulting in changes in the specific surface area. e influence of vibration on TPV, SSA, and PSD of macropores and mesopores in coal samples will inevitably lead to the change of surface morphology characteristics of pores and fissures. Fractal geometry is a powerful quantitative expression method, so the fractal dimension is used to quantitatively characterize its surface morphology. e fractal dimensions of macropores and mesopores were defined as D 11 and D 12 , respectively, as shown in Figure 9.

LPNA Results for Different Vibration Frequency Coal
Samples. e pore measurement range of LPNA is 1.3∼300 nm, which is commonly used to analyze the micropores and minipores [20,34,42]. e adsorption and desorption isotherm of VDF coal samples are similar in shape and have hysteresis loops ( Figure 6). According to the IUPAC classification of hysteresis loops [40], the hysteresis loops of all coal samples fall into the H3 type, indicating that there are slit-like pores in the coal samples.
When the relative pressure is 0 <P/P 0 < 0.45, the adsorption isotherm increases slowly ( Figure 6), indicating that monolayer and multilayer adsorption are formed in micropores and minipores. When the relative pressure is 0.45 < P/P 0 < 1, the adsorption capacity of gas molecules is enhanced due to capillary condensation. Figure 6(d) shows that the S 75 coal sample presents obvious hysteresis loops under low relative pressure, which may be due to the irreversible absorption of gas molecules and irreversible chemical reaction between gas and pore surface, or due to the existence of some open holes (including cylindrical pores with both ends open and flat pores with four sides parallel) or ink-bottle pores in S 75 [53]. e 75 Hz vibration leads to an increase in the number of open pores in coal samples. Figure 6 shows that the adsorption and desorption isotherms of all coal samples are divided into two regions with P/P 0 ≈ 0.45 as the dividing point, indicating that the adsorption mechanism of these two regions is different. erefore, in the analysis of fractal dimensions, the adsorption and desorption isotherms should be divided into two regions: 0 < P/P 0 < 0.45 and 0.45 < P/P 0 < 1, and the fractal dimensions of the two regions are defined as D 21 and D 22 , respectively. e DFT method is a powerful tool for obtaining the distribution characteristics of micropores and minipores by using the LPNA data [20,49]. To explore the influence of vibration with different frequencies on the TPV and SSA of micropores and minipores in coal samples, the PSD and pore SSA distribution of 1.3∼100 nm is plotted, as shown in Figures 7 and 8. Figure 7 shows that the pore volumes of S 0 , S 25 , S 50 , S 75, and S 100 are dominated by minipores, which are also reflected in the pore volume distribution curves of minipores and micropores. Compared with S 0 , the minipores volume of S 25 decreased most significantly, reaching 13.71%. e minipores volume of S 50 is slightly lower than that of S 0 . However, compared with S 0 , the minipores volume of S 75 and S 100 are not significantly changed. Compared with S 0 , the micropores volume of S 75 increased by 157%, and that of S 25 decreased by 10.21%. e results show that a 75 Hz vibration has the obvious effect of expanding micropores, the pore size increases, and the gas adsorption space increases, while a 25 Hz vibration leads to the decrease of micropore volume and gas adsorption space. e effect of vibration on micropores is greater than that on minipores. e 25 Hz low-frequency vibration produces smaller extrusion stress, and the deformation and destruction of coal matrix skeleton mainly lead to pore extrusion and plugging and a reduced pore volume; the 75 Hz vibration resonates with the coal matrix, which leads to the severe deformation and destruction of coal matrix skeleton and promotes the expansion and development of micropores.
With the decrease of pore size, the pore volume distribution curve of five coal samples in the range of 1.3∼100 nm first decreases, then increases, and after that decreases. With the decrease of pore size, the PSD of S 0 , S 50 ,   In the range of 8∼100 nm and 1.3∼3 nm, the pore volume differential of S 25 is obviously smaller than that of other coal samples, which indicates that the pore volume and pore size of S 25 decrease under the vibration of 25 Hz. However, when the pore size is in the range of 1.3∼30 nm, the pore volume differential of S 75 is significantly larger than that of other coal samples, which indicates that a 75 Hz vibration leads to the increase of pore size and the expansion effect is obvious. e reasons may be as follows: first, the 75 Hz vibration resonates with the coal matrix, resulting in the serious deformation and damage of the coal matrix skeleton so that some of the pores with small pore sizes develop and expand into pores with larger pore sizes, while the vibration of 25 Hz mainly causes deformation of coal matrix, thus squeezing small holes and micropores. e above results show that the volume and pore sizes decrease significantly when the vibration frequency is 25 Hz, but both the pore size and volume increase at the vibration of 75 Hz. Figure 8 shows that the pore (1.3∼100 nm) SSA of the VDF coal sample is dominated by micropores. With the increase of frequency, the total SSA of minipores and micropores first decreases, then increases, and after that decreases.
e total minipores SSA of S 25 , S 50 , and S 100 decreased by 17.23%, 6.30%, and 1.26%, respectively, compared with S 0 , while that of S 75 increased by 9.24%. Compared with S 0 , the total micropores SSA of S 75 and S 50 increased by 76.74% and 2.71%, respectively, while that of S 100 and S 25 decreased by 2.71% and 24.22%, respectively. e 25 Hz vibration significantly reduces the total SSA of micropores and minipores, while the vibration frequency of 75 Hz significantly increases the total SSA of micropores and minipores.
It can be seen from the SSA distribution curve that the minipore SSA of all coal samples is roughly distributed in the range of 0.003∼0.015 m 2 /g with the decrease of pore size, and the change is not obvious (Figure 8). e minipores SSA distribution of S 0 , S 25 , S 50 , and S 100 first increases slowly and then decreases slightly with the decrease of pore size; the minipores SSA distribution of S 75 gradually increases with the decrease of pore diameter. However, the SSA differential of micropores decreases and then increases as the pore size decreases. e micropores SSA distribution of S 25 and S 75 is obviously different from other coal samples. e micropores SSA distribution of S 75 increases slowly and then rapidly with the decrease of pore size and then decreases rapidly after reaching a peak value at about 2.5 nm. Moreover, the SSA differential of S 75 in the range of 2∼10 nm is obviously larger than that of other coal samples. e SSA differential of S 25 in the range of 3∼10 nm is close to that of S 0 , S 50 , and S 100 , but there is no obvious change. However, in the range of 1.3∼3 nm, the SSA differential of S 25 is significantly lower than that of other coal samples.
According to the above results, we can conclude that the effect of vibration on micropores is greater than that on minipores. Among them, a 75 Hz vibration significantly increases the TPV and SSA of micropores, resulting in the increase of gas adsorption space. However, the TPV and SSA of minipores and micropores as gas storage space decrease due to a 25 Hz vibration which, to a certain extent, explains the reason why low-frequency vibrations inhibit gas adsorption [7]. Shock and Vibration

Fractal Dimensions of Pores and Fissures in the VDF Coal
Samples. Based on the MIP and LPNA data, the fractal dimensions D 11 , D 12 and D 21 , D 22 were calculated by formulas (1) and (4), respectively. e larger the fractal dimension, the more complex and rougher the pore structure and the pore surface [20,39,42,43]. e fractal curve of the MIP data of all the coal samples is obviously divided into three parts by two points: one point is near lnP � 1 and the corresponding pore size range is about 433.4∼435.4 nm; the other point is near lnP � 4 and the corresponding pore size range is about 26.31∼26.33 nm. When lnP>4, the mercury injection data are discrete, which may be due to the high mercury intrusion pressure resulting in coal matrix deformation and pore failure. And the pressure of the highpressure mercury injection measured by MIP will compress the pore matrix, which will cause errors in the experimental results.

Fractal Dimensions of Mesopores and Macropores
erefore, the data of the high-pressure section cannot be used to obtain the fractal dimensions [34]. It can be seen from Figure 10(f ) that, with the increase of vibration frequency, D 21 presents an "M" shaped wave-like trend, which first increases, then decreases, after increases, and finally decreases, while D 22 presents a "W" wave-like trend opposite to D 21 . e value of D 21 fluctuates in a small range of 2.589∼2.663, the D 21 value of S 0 is the smallest, and the D 21 value of S 75 is the largest. It indicates that vibration causes the surface morphology of pores (3.5∼100 nm) to be complicated but has little effect. e values of D 22 fluctuate in a wide range from 2.106 to 2.473, the D 22 value of S 75 is the smallest, and the D 22 value of S 0 is the largest; it indicates that vibration causes the surface of micropores with pore size less than 3.5 nm to be smoother, and 25 and 75 Hz vibrations can greatly damage the surface morphology of micropores with pore sizes less than 3.5 nm. e variation range of D 21 is obviously smaller than that of D 22   has a more significant effect on the surface morphology complexity of micropores with pore size less than 3.5 nm.

Fractal Dimension of Minipores and Micropores
ere are three main reasons for the destruction of pore surface morphology characteristics caused by vibration: first, the coal matrix deformation caused by vibration will lead to the concave-convex deformation of the pore surface in a different pore size range; second, the coal matrix damage caused by vibration will cause pore development and expansion in a different pore size range; and third, vibration leads to the loosening, peeling, and shedding of minerals attached to the pore surfaces.

Analysis of the Influence on Gas Diffusion and Flow in VDF Coal Samples with Pore Structure Change.
e 75 Hz vibration increases the TPV and SSA of micropores and minipores, so the adsorption and diffusion space of gas increases, and the gas concentration on the pore surface increases, which is conducive to the migration of gas along the pore wall towards the mesopores and macropores. In addition, the increase of D 21 also indicates that the diffusion paths and their surfaces are more complicated, and the number of diffusion paths increases. With the increase of the TPV and SSA of macropores and mesopores, the diameter and number of paths for gas diffusions to escape into the outside environment increase, which is conducive to gas diffusion and flow to the outside environment. e increase of the D 11 value indicates that the macropores and their surfaces are more complex, the paths for gas diffusion are increased, and pore connectivity is enhanced. e decrease of the D 12 value indicates that surfaces of mesopores are smoother, the way is straighter, and the resistance to gas flowing to the macropores is reduced. erefore, the 75 Hz vibration is conducive to the production of gas in the coal seam and contributes to an increased gas extraction rate and the prevention of coal and gas outbursts. e 25 Hz vibration leads to the decrease of TPV and SSA of minipores and micropores, the decrease of gas adsorption and diffusion space, and the decrease of gas concentration on pore surfaces, which is not conducive to gas diffusion. With the increase of the macropores' TPV and SSA, the free gas is easily formed by a larger desorption initial velocity. e decrease of the mesopores' TPV and SSA means that the flow paths of gas to macropores are reduced and the paths are narrowed, which is not conducive to the diffusion of gas to macropores and the outside environment. e increase of the D 12 value also indicates that the complexity of the mesopores increases and the flow path of gas to the macropores is more tortuous. e resistance of free gas in the flow from minipores to mesopores is large, which easily accumulates in large amounts in a short time, resulting in the increase of local gas pressure and concentration.    erefore, the 25 Hz low-frequency vibration is not conducive to the diffusion and flow of gas, which easily leads to local area gas accumulations in the coal, with the risk of inducing local area coal and gas outburst.

Conclusions
In this paper, the lean coal in the outburst coal seam is taken as the research object, and five vibration frequencies (0, 25, 50, 75, and 100 Hz, respectively) are selected. Based on MIP and LPNA data, the Menger and FHH models are used to quantitatively characterize the fractal characteristics of the pore surface morphology, and the fractal dimensions were recorded as D 11 , D 12 and D 21 , D 22 , respectively. e conclusions are as follows: (1) e total pore volume of each vibration coal sample is more than that of the non-\vibration coal sample. e effect of vibration on the total pore volume and the total specific surface area of macropores is stronger than that of mesopores. And vibration makes the pore size distribution of mesopores more complicated. e 75 Hz vibration improves the pore connectivity and increases the volume and specific surface area of macropores and mesopores in coal samples significantly.
(2) e pore volume, specific surface area, and pore size distribution of micropores and minipores are significantly affected by 25 and 75 Hz vibrations. e total volume and specific surface area of minipores and micropores decreased when the vibration frequency was 25 Hz. e 75 Hz vibration mainly resulted in the increase of micropore volume and specific surface area and the increase of gas adsorption space. (3) Vibration leads to the change of fractal dimension of pores in coal, and the complexity of the pores in coal with a pore size of 26∼433 nm and less than 3.5 nm changes significantly. Among them, the 25 and 75 Hz vibrations had the most obvious influence on the surface characteristics of coal pores. (4) e changes of pore structure in coal caused by vibration lead to the path and flow resistance of gas diffusion and flow change. In the study of this paper, the 75 Hz vibration increases the path of gas diffusion and flow, reduces the flow resistance, and is conducive to the diffusion and flow of gas in coal. But the 25 Hz low-frequency vibration increases the diffusion resistance of gas and leads to the narrowing and more tortuous flow path of the gas.

Data Availability
e data used to support the findings of this study are available from the corresponding author upon request.

Conflicts of Interest
e authors declare that there are no conflicts of interest regarding the publication of this paper.