Geochemical, Mineralogical, and Geomorphological Characterization of Ash Materials as a Tracer for the Origin of Shifting Sands near Oldupai Gorge, Ngorongoro, Tanzania

Shifting sand (SS) is a single dune-shaped mass of black ash material moving across western Ngorongoro in northern Tanzania. The moving sand has become an important tourist destination for several decades. Despite being part of the important geosites at the Ngorongoro Conservation Area, the nature, origin, and behaviors demonstrated by SS remain poorly understood. This work contributes toward understanding the nature and identification of the possible origin of the SS through the correlation of geochemical, mineralogical, and geomorphological data of ash material from four selected locations in the study area. To achieve this goal, elemental, mineralogical, and morphological characterization of ash samples was performed by energy-dispersive X-ray fluorescence, polarized petrographic microscopy, automated sieve shaker, and binocular microscopy techniques, respectively. Correlation studies were based on magnesian-ferriferous associations, similarities in mineralogy, particle size, shape, and distribution patterns of ash materials, and weather data. There are close similarities in the chemical compositions among ash samples of SS, Ootun area, and Oldoinyo Lengai. Augite and magnetite minerals appear only in samples of SS, Ootun area, and Oldoinyo Lengai, while hornblende appears only in the samples from the Ngorongoro crater. Oldoinyo Lengai rock petrography revealed significant amounts of augite minerals. Blocky and elongated-shaped ash particles dominate the samples from SS, Ootun area, and Oldoinyo Lengai. The particle size of ash materials decreases westwards across the study site. The distribution patterns of ash material align with the west-south-west wind direction. Based on these findings, the study concludes that SS and Ootun ash could be tephra depositions resulting from past volcanic eruptions of Oldoinyo Lengai.


Introduction
Sand dunes are well-known in desert areas [1]. e structures of dunes are made up of sand masses of different morphologies as a result of prevailing winds. ere are two types of dunes, namely, linear dunes, and barchans, which are formed by fluid dynamics at the particle level above sand surfaces that explain the relationship of sand particles with the wind [2]. e size of sand particles is essential in determining morphological fate. Particles with a diameter of less than 0.050 mm are deemed cohesive, thereby resisting erosion by wind. On the other hand, particles with diameters between 0.062 and 2.0 mm are easily carried by the wind due to their noncohesive nature. is property explains why sand dunes are composed of sand particles of 0.125 to 0.250 mm [2]. It has generally been known that dunes are the geomorphologic signatures of wind-surface interactions [3]. eir shape, size, direction, and orientation result from complex wind dynamics involving several factors that should not be viewed simplistically [1]. ese factors may include the accretion rate of particles, erosion loss of surface particles, turbulence, deposition, and accreted dust [4]. e genesis of a dune landform from an unstable surface has been explained by steady-state theory [2]. Steady-state theory (waveform theory) defines the stable nature of the dune landform while advancing. It explains the equilibrium that exists between the wind and the resistance of the sand particles on the surface of the dune landform to cancel wind energy, thereby adjusting the dune shape to balance the effect. e balance is achieved by deflection of the incident wind from the tail side that spreads sand particles parallel to the crest, thereby shaping the horns on the leeward side. At this stage, the dune is said to be in a steady state [1,2].
Volcaniclastic dunes, on the other hand, are extremely rare on the Earth [5]. eir occurrences have primarily been observed in the Ka 'u Desert in Hawaii, United States of America, which is thought to have been derived from Kilauea volcanic eruptions [6]. Volcaniclastic dunes have also been observed in parts of New Zealand and Iceland [5]. Northern Tanzania is endowed with several unique features of geological significance [7][8][9][10][11][12][13], including substantial amounts of volcaniclastic ash material scattered across the rift valley enclave at the Ngorongoro Conservation Area (NCA) spreading from Oldoinyo Lengai (OLA) to Oldupai Gorge ( Figure 1) at varying amounts, shapes, and behavior.
ere are two types of ash bedforms on the study site. ese are migrating dunes known as shifting sands (SSs) and vegetation-covered stationary bedforms known as Ootun sands (OTSs), located about 35 kilometers west of OLA (Figures 2(a) and 2(b)). e area is characterized by vegetative piles made up of ash material that has been deposited in the past from the Gregory Rift volcanoes. e Google Earth landscape across the study area is shown in Figure 3. e coordinates of SS in Google Earth Pro are 2°56′32″S 35°18′42″E, and for OTS, they are 2°46′44″S 35°36′16″E.
Black ash material, which is a barchan dune famed as shifting sands (Figure 2(a)), is located near Oldupai Gorge, about 80 km west-south-west of OLA [15] (Figure 1). e SS is a single mass of ash bedforms moving slowly in a westward direction across the western Ngorongoro plains at a rate of about 16 to 20 meters per year. Normally, its size is about 3.5 meters high, 28 to 36 meters wide, and 10 meters from the windward to the leeward side. It is composed of unique fine black ash particles of unknown parentage of varying sizes and shapes. For many years, SS has been thought to be a bedform whose structure is likely to be modified by the wind. It has been a tourist destination for many decades as a unique structure, featuring many spiritual narratives on its behavior by the local Maasai communities around it.
Volcanogenic bedforms result from tephra depositions [16,17]. Tephra is any pyroclastic material ejected during an explosive volcanic eruption regardless of grain size, composition, grain shape, or origin [18][19][20][21]. eir sizes, shapes, mobility, and distance from the source volcanoes are primarily determined by climatic conditions [18]. ey are embedded with rich geological information associated with volcanism and can be interpreted to ascertain events in the distant past [21]. e ash material of SS is a subset of tephra, by definition consisting of particles with a diameter <2 mm [14]. e review in [22] points out the accuracy of using tephra to link and synchronise geochemical data and transfer them from one site to another. With the aid of credible and reliable chronology techniques, tephrochronological studies involve data correlation of tephra from different locations and ultimately come up with scientific estimations of the nature and origin of materials at a high degree of certainty [23,24].
Tephra geochemistry remains among the strongest stratigraphic markers of the Holocene and Pleistocene [23][24][25][26]. e chemistry of volcanic ash has been applied as a tool for differentiating between volcanic bedforms and has been used as a historical marker for elucidating conditions and events that took place during and after volcanic eruptions [24][25][26][27][28].
is approach has essentially been important in addressing the source volcanoes of respective volcanic ash through tephra correlation studies and the geology of surrounding volcanoes. Nowadays, the interpretation of geochemistry, stratigraphy, and chronology data has been central to ascertaining desired information on archaeology, petrogenesis, chronostratigraphy, and explosive volcanisms with their time-space relationships [23]. ese studies are essential in uncovering geological events as well as risk management and hazard predictions [25,29].
Ash chemistry is related to magma chemistry and is influenced by processes following magma fragmentation, such as heterogeneous interactions in the eruption plume [30,31]. Volcanic ash is typically dominated by the volcanic glass with lesser amounts of crystalline minerals and hence, in some instances, difficult to classify based on its mineralogical composition [32]. Ash and rock types around volcanoes can be correlated to reveal a source volcano of particular distal ash through the total alkali-silica (TAS) diagram, CaO versus K 2 O plot [23,33], and various geochemical correlation tools as described in [34]. e attention to the movement of SS had only been paid from 1969 by recording its positions every year even though SS has existed for several decades. ere is only one published work on the geochemistry of SS which is by Kafumu [35], who compared his results with the geochemistry of OLA rocks published by Bell and Simonetti [36]. In his study, Kafumu [35] found similarities between some elements in SS and rocks from OLA. However, detailed evidence from the ash comparison and a multidisciplinary approach to potential ash sources in the region are necessary to understand the nature and origin of the Shifting Sands. In this study, multidisciplinary techniques and critical analysis of the composition and origin of SS were adopted to investigate its nature and origin. Similar ash materials from other parts of the region were investigated for correlation purposes and processed by various geochemical tools, including those described in [32].
2°S40' 36°E 35°E Figure 1: A map of part of the northern Tanzanian sector of the Gregory Rift was modified by the GeoMapApp global multiresolution topography [14], to show the study sites. e red star points are the four sampling locations. Great care was taken to ensure that the right representation of the material was taken. Each sample weighs about 1 kg. Each pooled sample was homogenized and reduced to about 250 g by the quartering method. e samples were taken for elemental, mineralogical, particle size, shape, and loss on ignition (LOI) analyses. Four samples of igneous rocks (ijolite) from OLA were also taken for petrographic studies. OLA is an active volcano and is thought to be the most likely source volcano of ash material. OTS contains stabilized ash dunes and is located about 35 km west of OLA. Samples from NCA were used as a control since they came from the Ngorongoro volcanic center, which, unlike OLA, ceased its activities more than 2 million years ago [37]. Table 1 shows a list of all samples.

Elemental Composition.
Ash samples from the four sites were dried at 105°C to constant weight, well homogenized, and pulverized to 75 µm particle size and analyzed as in [16]. e energy dispersive X-ray fluorescence (EDXRF) spectrometer (Model XL3t) was used to estimate the elemental composition of the samples. e EDXRF instrument is designed for carrying out analytical work in atmospheric conditions and helium gas environments. When analyzing light elements (with an atomic number less than 11), the instrument automatically opens helium gas to enhance detection. e rest elements are analyzed in the atmospheric conditions. e EDXRF measuring time (live time) was set at 100 s. Samples at 75 µm were pressed into cups and kept in a sample compartment and read. e machine was equipped with Au and Ag anodes and a high-performance semiconductor detector. e samples were scanned at a maximum of 50 kV and 40 µA while enhanced with external helium gas for light element detection. e Certified Reference Standards (DC73026) from the China National Analysis Centre for Iron and Steel (Beijing) were used to validate the data. e analyses were performed at the Geological Survey of Tanzania.

Loss on Ignition.
Loss on ignition (LOI) for ash samples was determined by using the Nabertherm muffle furnace (Model L-241K2TN). A smaller particle size (75 µm) enhances each part of the material to be exposed to high temperature equally and remove organic matter. e LOI determination was accomplished by following the methodology explained in [38], where empty crucibles were preheated at a temperature of 550°C for four hours, cooled in a desiccator, and weighed. en, a mass of 200 mg of each sample was weighed in the cooled porcelain crucibles and left in the muffle furnace at a temperature of 550°C for four hours, removed from the furnace, cooled in desiccators for two hours, and weighed. e weight of the empty crucible and ignited samples were determined by using an ultrasensitive balance (Mettler Toledo, Model AB104-S). Weight differences were calculated to get LOI. e Certified Reference Standard (NCS DC 73027) from the China National Analysis Centre for Iron and Steel (Beijing) was used to validate the data.

Mineralogical Studies.
To address the mineralogy of rock (thin section) samples, petrographic studies were conducted by visual estimation using a digital polarized  e Scientific World Journal microscope (ZEIS Model LR. 66238C and OPTIKA Model B-600POL-1) enhanced with image processing software Optica Vision. e ash mineralogy was determined using a binocular microscope (Model WILD M3C). ese studies were carried out at the Geological Survey of Tanzania.

Particle
Size and Shape. e particle size of the samples from the four sites (after drying at 105°C to constant weight) was determined according to the procedure described in [39]. e analysis was accomplished using a heavy-duty analytical sieve shaker controller (Model TMA-1170 with ANALYSETTE 18) loaded with different sieve sizes ranging from 0.045 mm to 2.00 mm. e sieve shaker controller was set to 10 minutes and a waiting interval of 5 seconds with an amplitude of 2.0. Shape classification was performed according to the procedure mentioned in [40], where samples were observed under the binocular microscope (Model WILD M3C). e shapes of the particles and counts were recorded.

Weather Data Collection.
Temperature, pressure, humidity, rainfall, wind, direction, and speed, were monitored and recorded for one year (October 2020-September 2021) using a set of digital meteorological systems installed within the study site (2°59.614′S 35°21.068′E). e Youshiko digital weather station (Model YC9387 (W)) was used to collect the weather data. e digital weather station's specifications include barometric pressure measuring range of 525 to 825 mmHg at an operating temperature of −5 to 50°C, temperature readings in the range of −40 to 60°C with 0.6°C accuracy, wind speed range of 0 to 180 km/h with a resolution of 0.1 km/h, a 0 to 360°, sixteen wind direction measurement scale with a resolution of 1%, and relative humidity ranging from 20 to 99% with an accuracy of about 1% and rain gauge with an accuracy of 7%. e digital weather station was connected to the Internet via Wi-Fi, and data collection was monitored and downloaded from the host website https://www.wunderground.com.  Table 2. Furthermore, based on a cursory analysis, it appears that W, Ba, and Zr are good discriminants between OLA/OTS/SS and NCA.

Loss on Ignition.
Samples from OTS, OLA, and NCA registered relatively higher values for LOI than those from SS. e order of LOI for different samples is NCA > OTS � OLA > SS ( Table 2).

Mineralogy.
e mineralogy of SS is dominated by augite (86% of particles), magnetite, quartz, and the remaining percentage by olivine and haematite. At the same time, the composition of OTS samples includes augite, magnetite, and quartz in a major percentage (89%) and olivine, muscovite, and biotite present in minor percentages. Samples from OLA showed the presence of augite, magnetite, and quartz in higher quantities (92%), and remaining olivine, biotite, muscovite, and haematite were present in lower quantities. NCA samples showed the presence of quartz, hornblende, and olivine. Generally, augite, quartz, and magnetite form more than 80% of the samples from OLA, OTS, and SS, while the rest of the sample proportions are olivine, biotite, and muscovite. e proportion of augite in the samples decreases from SS to OLA, while that of quartz decreases from OLA to SS. ere is no augite in NCA samples, but there is a high proportion of quartz, hornblende, and olivine. NCA samples contain the highest percentage of organic matter. is result is also supported by the results obtained for LOI (Table 2). Muscovite and biotite are present in less than 1%, which cannot be seen in the graph due to a meagre percentage ( Figure 4).
Furthermore, a mineralogical examination of four rock samples collected from the foot of OLA reveals the presence of fine to coarse subhedral augite crystals that exist as matrices as well as phenocrysts ( Figure 5). is study shows pyroxene signatures (augite, Av, or Aug) and nepheline (Nh).

Particle Size.
e particle size analysis results indicate that a large portion of SS comprises 250 µm particles (76.91% by volume), followed by a particle size of 150 µm (20.40%). e rest of the material constitutes small portions of other particle sizes (2.52%). e particle size of OTS showed that the materials are dominated by particles of 250 µm (53.70%), followed by 450 µm and 150 µm (about 21.40% each). Only 2.38% of the material from OTS has a diameter of 75 µm.
e rest, about 0.63%, has a diameter of 710 µm. On the other hand, an analysis of OLA shows significant variations in particle sizes ranging from e Scientific World Journal 5 150 µm to 1 mm, with the majority of the material at 425 µm (42.50%), as shown in Figure 6. e particle size of NCA samples was dominated by 710 µm (83.20%). e rest were organic debris which could not be accounted for this classification. Figure 7 shows images of the ash material under the binocular microscope.

Particle Shape.
Particle shape analysis of SS shows that most particles have an elongated shape. At the same time, there are an almost equal percentage of blocky and roundedshaped particles with very few vesicular-shaped particles. In the samples of OTS, OLA, and NCA, sand is dominated by rounded-shaped particles, whereas in the case of SS, it is dominated by elongated particles. Particle shapes are represented in Figure 8.

3.6.
Weather. e monthly data (from October 2020 to September 2021) of weather elements gathered by using the Youshiko digital weather station on the study site registered the west-north-west ( Figure 9) wind direction traveling at an average speed of 9.6 km/h. e maximum wind speed value attained during this period was 65.5 km/h, while the minimum speed was 0 km/h. An average temperature of 21.5°C and 64.4% humidity were registered. Annual precipitation was 669.5 mm.

Elemental Composition.
As described by previous researchers in tephrochronology and volcanology, various correlation tools have been applied in this study. ese include the TAS diagram, CaO versus K 2 O plot, major oxide multiplots, and magnesian-ferriferous associations [22,33]. Data in Table 2, which shows the elemental composition of samples from the four sites, are visualized in a grouped bar chart in Figure 10. Except for CaO, Na 2 O, and MgO, which vary slightly, all oxides from the four sample locations are substantially comparable.
TAS classification gives clues on the similarities of samples of volcanic origin taken from different locations in the same geographical area. It is an appropriate correlation tool in conjunction with other tools for searching for materials that originate from a common volcano [33]. When the elemental compositions from this study are plotted in a TAS classification diagram (Figure 11), SS, OTS, and OLA fall under the tephrite-basanite group. On the other hand, samples from NCA fall under the foidite group.
TAS classification generally indicates that there is a correlation between SS, OTS, and OLA samples. is suggests that the material (ash) may have originated from OLA's volcanic eruption. Ngorongoro lavas were described in earlier studies by Mollel [37]. Classification of lavas using a TAS plot placed lavas in basalt-trachyandesite, trachydacite, and trachydacite groups, contrary to the NCA samples. ese variations may be due to following reasons: (1) the ash material (NCA) might have undergone mineralogical alterations due to environmental changes and (2) the Ngorongoro volcanic center may have produced numerous types of lava over time.
A plot of CaO against K 2 O ( Figure 12) for the identification of source volcanoes, as described in [23], shows a positive correlation between SS, OTS, and OLA, suggesting the materials are from a common source that could probably be from OLA. Differences in the concentrations of K 2 O in SS, OTS, and OLA samples can be due to the absence of easily weathered K-rich minerals such as biotite and muscovite, which have been lost as SS migrates along its path over the years [35]. Previous researchers reported changes in the chemical and mineral compositions of aeolian materials such as sand dunes, though the mechanisms of these changes are not fully understood [41]. e isolation of NCA samples on the left side of the plot is due to their low CaO content compared to SS, OTS, and OLA samples (Figure 12). e difference in CaO content shown on this plot is significant because it demonstrates agreement with previous studies on the nature of volcanic materials released from the OLA and Ngorongoro volcanic centers. Previous studies reported carbonatite material from OLA, which contains elevated amounts of up to 25 wt% CaO [9]. Geochemical studies of lava from the Ngorongoro volcanic center report low values of CaO, which range from 2 to 11 wt% [37]. Figure 12 shows that the SS, OLA, and OTS samples plot close to each other and far from the NCA samples, potentially reflecting a correlation between SS, OTS, and OLA. From this compositional comparison, SS materials most likely to have originated from OLA and NCA originated from the Ngorongoro volcanic center. A multiplot of SiO 2 against major oxides ( Figure 13) shows correlations between SS, OTS, and OLA samples. e close agreement among these samples may be due to similarities in their mineralogical compositions, particularly in augite and magnetite (Figure 4). e isolation of the NCA samples suggests that they may have a different source from the other three ( Figure 13). SS has been rolling for thousands of years [42]. As a result, the major glass component of the ash deposit (non-Fe/Mg-bearing silicate minerals such as quartz, feldspar, and muscovite) was easily weathered, leading to a gradual enrichment of SS in  [43]. e distribution patterns between magnesian and ferriferous magmatic series for samples from SS, OTS, OLA, and NCA are shown in Figure 14. e separation on a plot is based on the position of the reference line passing through granite, adamellite, granodiorite, tonalite, quartz diorite, and gabbro points. Except for the samples from the Ngorongoro crater (NCA), the plot revealed that all the 8 e Scientific World Journal samples (SS, OTS, and OLA) in this study belong to the ferriferous magmatic series [33]. Magnesiohornblende in the NCA samples ( Figure 4) partly contributed to magnesian magmatic nature. e presence of the magnesiumrich foidite lava group and Mg-rich olivine has been reported in the Ngorongoro crater [37,44]. e distribution pattern of the samples suggests there are the existing similarities between SS, OTS, and OLA. Generally, results of the elemental composition of ash material in this study show a strong indication that OLA is the most likely source of both SS and OTS.

Loss on Ignition.
LOI is attributed to organic contaminants from vegetation mixed with ash materials and accumulating over time. Samples from SS have very low values of LOI compared to other samples. SS is constantly in motion, being blown westward. As a result, the accumulation of any organic contaminant is restricted due to density differences between minerals in ash and organic matter, hence, very low values of LOI (Table 2). On the other hand, samples from NCA have the highest values of LOI. e highest values of LOI for the samples from NCA relate to the accumulation of organic matter over time, which defines materials' age.

Mineralogy.
e polarising microscope reveals blocky and elongated-shaped augite, which is similar to that found in ash samples from SS, OTS, and OLA. Examination of thin section slides showed the prevalence of nepheline minerals which do not appear in all ash samples for unknown reasons that need further studies or could not be erupted at that time [9,45] but could be due to fractionation by density effects during transport and by variations of magmatic compositions over time, which are common in volcanic eruption history of many volcanic centers [9,46].
Mineralogical studies of SS show the domination of augite (86%), magnetite, and quartz minerals (Figure 4). Augite is a member of the pyroxene group of rock-forming minerals and is normally associated with an elongated crystalline shape at the particle level. e presence of augite with the chemical formula (Ca x ,Mg y ,Fe z ) (Mg y1 ,-Fe z1 ) Si 2 O 6 (where 0.4 ≤ x ≤ 0.9, x + y + z � 1 and y 1 +z 1 � 1) [47] is reflected in the chemical composition of SS by the presence of elevated values of oxides of Si, Ca, Fe, and Mg. According to a study by Sigamony [48] on magnetic properties, augite has anisotropic properties at low fields and isotropic properties at high fields. ese observations are in line with the ferromagnetic behavior observed in the SS, OTS, and OLA samples, as their particles are strongly attracted to the magnetic field. Titanium oxide (2.97 to 3.64%) in SS (Table 2) can be attributed to the presence of titaniferous magnetite minerals with the chemical formula Fe 2+ (Fe 3+ , Ti) 2 O 4 ). Other elements such as zinc, manganese, chromium, nickel, and vanadium appear as common inclusions in magnetite and augite minerals.
Augite, quartz, magnetite, olivine, biotite, muscovite, and haematite minerals have also been observed in OTS and OLA (Figure 4). Observations of augite, quartz, and magnetite reveal mineralogical similarities between SS, OTS, and OLA. e three sites are geographically aligned from east to west (Figure 1), hypothesizing the spread of these materials in the east-west direction. A significant difference shown by NCA mineralogy is the absence of augite and the presence of hornblende minerals. Previous studies on the mineralogy of volcanic rocks (lava) at NCA indicate the presence of minor augite and biotite minerals [37], which may have been altered and not detected in ash in this study. erefore, the distinguishable mineralogical composition of ash material from NCA supports the interpretation of the chemical and rock petrology data that SS around Oldupai Gorge may have originated not from activities during or after the formation of the Ngorongoro crater but rather from the volcanic activities of OLA. Figures 6 and 7, the proportion of 250 µm particles increases from east to west (i.e., from OLA to SS). Fine-grained and lighter particles were ejected and transported by the wind to a considerable distance [21]. is pattern is consistent with the tendency for coarse-grained ash material to be deposited closer to the source volcano due to more rapid gravitational settling of larger particles.

Particle Shape.
Particle shape examination of SS, OTS, and OLA show the presence of blocky, elongated, rounded, and vesicular shapes (Figures 7 and 8). Blocky and elongated shapes are mostly associated with augite (Figure 5), which have been observed in SS, OTS, and OLA ( Figure 4). e proportion of blocky and vesicular-shaped ash in OTS is higher than that in OLA. is is because the e Scientific World Journal 9 sampling at OLA occurred in streamsides and valleys where the material is mostly exposed. ere is a high probability that the blocky and vesicular ash material could have been washed out with time (because of shapes). Conversely, vegetative dunes in the OTS area (Figure 2(b)) likely contribute to the preservation of ash. Comparing the morphology of ash allows one to infer whether samples originated from a common volcano. Since blocky and elongated ash dominated in augite, OLA was the most probable source. Other shapes (like rounded) were a mixture of varieties of minerals.
Chemical and mineralogical studies of the ash material in this study suggest that they result from volcanic eruptions from the Gregory Rift volcanoes. e Gregory Rift volcanoes include a series of volcanic cones around Ngorongoro along the east arm of the rift valley. e mineral content of the ash material released by volcanoes from the area [49][50][51][52] is similar to the ash material in this study. Perhaps the most important question is which peak was the source volcano of the materials under investigation. To answer this question, a chronological account of the region's volcanism needs to be addressed. All volcanic peaks in the Gregory Rift ceased their activities around 2 Ma ago except for OLA, which continues its activities to date [53]. e region's chronology indicates that SS formed following the volcanic eruption of one of the Gregory Rift volcanoes. Chronology data of the area, the nature of the SS material, and its dune mobility behavior rule out the possibility of these materials originating from volcanic peaks of the Gregory Rift other than currently active OLA.

Weather.
e general west wind direction is consistent with the current (2020) direction of SS and aligns with the geographical features from OLA ( Figure 15). e weather data collected over one year (at the Oldupai Gorge area) indicated that the wind blows in a west-north-west direction ( Figure 9). e wind travels at an average speed of 9.6 km/h and provides sufficient force to blow the particles of SS in the east-west direction across the flat corridor from the Ootun area to the Oldupai Gorge area (Figure 15). e model shows SS migration from the OTS area to the Oldupai Gorge area, which takes thousands of years [42]. SS has been derived from Ootun tephra deposition, which resulted from OLA eruption. e OTS location is roughly 35 km west of OLA and about 45 km east of SS. e historical east-west wind direction [9,51] supports the   Figure 9: e wind rose presentation of the wind speed data in SS near the Oldupai Gorge area. e data were taken by using the Youshiko digital weather station from October 2020 to September 2021.

Conclusions
Based on the correlation of both geochemical and geomorphological properties of the material, SS ash, OTS ash, and OLA ash seem to contain more augite than any mineral. e study suggests that the ash materials that constitute SS and OTS have attributes of tephra material from past  volcanic eruptions of the same origin. Oldoinyo Lengai, an active volcano east of Oldupai Gorge, has been implicated as a possible source of this tephra material. Significant amounts of tephra depositions observed in OTS located west of OLA are evidence of the magnitude of volcanic plumes, leading to the formation of present tephra bedforms in the region.
Depositions are suggested to have been laid down across the western part of OLA and set in motion as sand dunes for possibly hundreds to thousands of years, of which many were dispersed on the plain and no longer exist. erefore, SS materials are suggested to have been brought from the Ootun area to the Oldupai Gorge region by the action of    Figure 14: A plot of Fe + Mg + Ti against Mg/(Fe + Mg) as described in [43]. A line across the reference points, granite, adamellite, granodiorite, tonalite, quartz diorite, and gabbro is used to differentiate between magnesian and ferriferous associations. e dashed line presents leucogranites, which are granitic, light-colored igneous rocks with hardly any mafic minerals. Abbreviations: sq: quartz syenite, s: syenite, mzq: quartz monzonite, mz: monzonite, mzdq: quartz monzodiorite, mzgo: monzogabbro. 14 e Scientific World Journal wind in the direction of west-south-west through the ground channel. e tephra material at Ootun was heavy enough to be carried away by the wind and form barchan dunes. Eruptive periods of OLA, however, remain a subject of further speculation, which may involve proximal tephrostratigraphy of OTS with an additional chronology component and ultimately unravel time-based tephra dispersal patterns across the region. Data enrichment from these topics could further fine-tune conclusions deduced from this study.

Data Availability
All the data used to support the findings of this study are included in the article.
Disclosure is research was conducted as a part of the Ph.D. program at the University of Dodoma. is is self-sponsored by the Ph.D. candidate (first author) under the supervision of the co-authors.

Conflicts of Interest
e authors declare no conflicts of interest.